Effects of cooling methods on the occurrence of sulfur in the low-titanium slag

2018 ◽  
Vol 115 (2) ◽  
pp. 208 ◽  
Author(s):  
Baohua Wang ◽  
Mingbo Zhang ◽  
Yongyu Gong ◽  
Shiping Huang ◽  
Shengtao Qiu ◽  
...  

The distribution of sulfur existence in the mineral phase and occurrence in the low-titanium slag with different cooling methods (water cooling, air cooling, crucible cooling, and furnace cooling) were studied by XRD, EPMA and XPS. The results show that with the cooling rate decrease, the distribution of S changes from clustering dots to large sheet or surface, and the occurrence of S in the mineral phase transfers gradually from the vitreous, perovskite, merwinite and the intertwined phase of some mineral phases to the gehlenite. During the transfer, the velocity decreases with the increasing of the cooling rate. The S in the water cooling slag only exists in the form of SO32−and SO42−, while the occurrences of S in the air cooling slag, crucible cooling slag, and furnace cooling slag are S2−, SO32−and SO42−.

2019 ◽  
Vol 116 (4) ◽  
pp. 417
Author(s):  
Baohua Wang ◽  
Mingbo Zhang ◽  
Rong Zhu ◽  
Shengtao Qiu

A new idea that the low-titanium slag (LTS) used in the steelmaking process after CO2injection desulfurization is proposed in this paper. The CO2injection process mainly involves the grinding of low-titanium slag, mixing of slag and water, CO2injection, filtration, and then obtains the low sulfur and low titanium slag. The effects of cooling rates (water cooling, air cooling, crucible cooling, and furnace cooling) and CO2injection on the desulfurization of LTS were studied by both experimental and thermodynamic calculations. The results showed that sulfite and sulfate ions couldn’t be removed from LTS using this method, and the main removal substance in slag was sulfide ion S2−. The desulfurization mechanism with CO2injection was that the CO2injection reacted with H2O to form H2CO3, and then the H+disrupted from H2CO3reacted with the S2−in the slag to achieve desulfurization. During the desulfurization process, the desulfurization reaction was mainly determined by S2− + CO2(aq) + H2O (l) = CO32− + H2S(g) within the first 5 min, and then the main desulfurization reaction was S2− + 2CO2(aq) + 2H2O(l) = 2HCO3− + H2S(g). As the cooling rate decreasing, the desulfurization rate of LTS increased. The desulfurization effect of furnace-cooled slag is the highest in four kinds of slag. The desulfurization rate of furnace-cooled slag reaches 72.28%, which is 4.34, 1.75 and 1.15 times than that of water-cooled slag, air-cooled slag and crucible-cooled slag, respectively. The optimal rate of desulfurization is 80.0%.


2021 ◽  
Vol 891 ◽  
pp. 3-9
Author(s):  
Cang Tian Wang ◽  
Qing Long Meng ◽  
Fang Hao Chen ◽  
Jing Hong Wang ◽  
You Ran Zhi ◽  
...  

Industrial pure titanium (TA2) and Ti-6Al-4V (TC4) have been widely available for chemical equipment. However, the corrosion resistance changes during their post-fire performance. In this research, the electrochemical properties of industrial pure titanium and Ti-6Al-4V after heat treatment and different cooling methods were analyzed by AC impedance technique and dynamic polarization method. The results support two conclusions. Firstly, when the temperature is approximate to the phase transition point, for pure titanium and its alloys, water-cooling can obtain better corrosion resistance than air-cooling. With regard to pure titanium, its best corrosion resistance can be obtained at 800°C under water-cooling. For Ti-6Al-4V, its best corrosion resistance can be obtained when the temperature reached 910 °C under water cooling condition. Secondly, the corrosion current density under acid corrosion condition has risen compared with neutral corrosion condition. These results can provide some experimental data and theoretical basis for post-fire anticorrosion performance of titanium materials, and also support the safety, risk evaluation of titanium equipment.


1950 ◽  
Vol 163 (1) ◽  
pp. 221-234 ◽  
Author(s):  
A. G. Smith ◽  
R. D. Pearson

The cooling of turbines offers the alternative advantages of the use of higher cycle-maximum-temperatures than are possible with uncooled turbines, with consequent increase of thermal efficiency and power output for a given size of compressor, or the use of lower quality materials for a given turbine inlet-temperature. Two main methods of cooling the blades, which are the most difficult elements of the turbine to cool, have been investigated in the past. They are internal water-cooling, offering a simpler technical problem in cooling due to the great heat-removing capacity of water as compared with air; and air cooling, offering an inherently simpler “plumbing” system as compared with water cooling. Experimental and theoretical information on both these classes of cooling methods si given, and, in addition, experimental information on a new method of cooling is presented, in which a water spray is injected directly on to rotor-blade exterior surfaces. Work at the National Gas Turbine Establishment (N.G.T.E.) has been concentrated mainly on the application of fundamental heat-transfer information to the design of internally air-cooled blading, and measurements on an internal air-cooled cascade blade showed that the blade could be maintained at temperatures several hundred degrees Fahrenheit below gas temperatures, for small cooling-air quantities. Cooling was non-uniform, and difficulties due to consequent thermal stressing may well appear with blades of the type tested. A great deal of improvement over the performance obtained with this first cascade blade is possible, however, and some information on a type of blade which has theoretically a much better performance is given. All cooling methods so far tested show the feature of non-uniformity of cooling, and the present lack of knowledge on the allowable extent of this non-uniformity is an obstacle to the assessment of the gas temperatures at which the various cooling methods will allow a turbine to be run. Probably the air-injection methods, that is, “effusion” cooling, by effusing air through a permeable blade wall, or “film” cooling, by injecting air through slits pointing backwards along the blade surface, will permit the highest possible gas temperatures, since in both these methods there is an insulating action by the injected air. Results of theoretical work at the N.G.T.E. are presented, showing the need for a higher effusion velocity near the blade edges than elsewhere, for effusion-cooled blades. Information is given from tests on a four-stage turbine whose rotor blades were internally water-cooled by the free thermosiphon method, with steam production. Whilst it is likely that effective cooling was obtained in the sense that metal temperatures were kept low, difficulty was experienced with corrosion of the mild steel rotor, a blade eventually corroding through. Certain difficulties with vibration were experienced, but they are thought not to be inherent in the method of cooling. Another method of liquid cooling, that of spraying a small quantity of water on to the rotor blades (of a Whittle jet-engine) from tubes in the nozzle blades, showed unexpectedly great cooling action. The investigation is as yet, however, in a preliminary stage. A discussion is made of the effect of blade aerodynamic design upon the heat which must be extracted from a stage in order to cool it. It appears from the extrapolation of present blade heat-transfer data, that a high axial-velocity (or, more accurately, a high ratio of axial velocity/peripheral velocity) is advantageous and should lead to low heat-extraction quantities. This high velocity ratio will lead to increased volute losses, and there are other factors tending to cause loss of work and efficiency. Some of these are discussed, but mainly not quantitatively owing to lack of systematic knowledge.


2012 ◽  
Vol 620 ◽  
pp. 66-71 ◽  
Author(s):  
Kolawole Bankole Lateef ◽  
S.A. Rezan Sheikh Abdul Hamid ◽  
Mohd Sharif Nurulakmal

Potassium Calcium Silicate (K2CaSiO4) is a mineral that has been of high interest in the field of applied mineralogy. Crystallization of K2CaSiO4from high chromium EAF slag was studied and the slag samples were characterized using XRF, XRD, SEM/EDX, FTIR and TG/DTA. The distinct mineral phases in the EAF slag were neutralized and formed with a grain boundary by air cooling and dispersed phases by water cooling. The EDX revealed that both the grain boundary and matrix phases are composed of potassium, calcium and silicon. The addition of K2CO3to EAF slag not only imparts the needed potassium but also reduced the heavy metal present in the slag as revealed by the XRF analysis. Using thermodynamic modeling, it is deduced that the percentage of potassium silicate formed during simulation process (when?) increases as the basicity of EAF slag decrease.


Batteries ◽  
2021 ◽  
Vol 7 (4) ◽  
pp. 86
Author(s):  
Morena Falcone ◽  
Eleonora Palka Bayard De Volo ◽  
Ali Hellany ◽  
Claudio Rossi ◽  
Beatrice Pulvirenti

The environment has gained significant importance in recent years, and companies involved in several technology fields are moving in the direction of eco-friendly solutions. One of the most discussed topics in the automotive field is lithium-ion battery packs for electric vehicles and their battery thermal management systems (BTMSs). This work aims to show the most used lithium-ion battery pack cooling methods and technologies with best working temperature ranges together with the best performances. Different cooling methods are presented and discussed, with a focus on the comparison between air-cooling systems and liquid-cooling systems. In this context, a BTMS for cylindrical cells is presented, where the cells are arranged in staggered lines embedded in a solid structure and cooled through forced convection within channels. The thermal behavior of this BTMS is simulated by employing a computational fluid dynamics (CFD) approach. The effect of the geometry of the BTMS on the cell temperature distribution is obtained. It is shown that the use of materials with additives for the solid structure enhances the performance of the system, giving lower temperatures to the cells. The system is tested with air-cooling and water-cooling, showing that the best performances are obtained with water-cooling in terms of cell packing density and lowest cell temperatures.


2012 ◽  
Vol 170-173 ◽  
pp. 3516-3520
Author(s):  
Hui Li ◽  
Shang Qi Zhou ◽  
Jin Ming Fang

In order to provide the best technic parameter for hot pressing, the diffusion bonding temperature fields of Be/HR-1 stainless steel under different cooling methods were simulated by the finite element method. The results show that high temperature parts occur in stainless steel center zone in water cooling and air cooling, and the interface cooling rates follow respectively equation of T = 0.0297 t 2 - 9.3223 t + 1017.6 and equation of T = 0.002 t 2 - 0.7702 t + 1014.8. In funace cooling, high temperature part moves to beryllium center zone and the interface cooling rate follows equation of T = -0.0192 t + 1018.8. While the heat transfer coefficient (h) is taken as 5, the temperature distribution of both sides on the interface is symmetric and temperature gradient is the lowest, so the hot stress on the interface is reduced effectively to improve the diffusion bonding strength, which results fit with the experience ones well.


2020 ◽  
Vol 856 ◽  
pp. 76-84
Author(s):  
Kittawat Srimark ◽  
Panyawat Wangyao ◽  
Tanaporn Rojhirunsakool

Fe-Ni based superalloys have been widely used in land-base gas turbine application. The turbine blade was in service for 50,000 h at high temperature and stresses. When subjected to long-term exposure at high temperature, the microstructure lost its best mechanical properties due to the microstructural instability. The aim of this research is to understand the effect of cooling rate on gamma (γ) grain size and gamma prime (γ’) particle size, morphology, and its volume fraction in rejuvenated Fe-Ni based superalloys. The alloys were solutionized above the γ’ solvus temperature at 1125 °C for 2 h for homogenization and cooling to room temperature at different cooling rates. The alloys were experienced with furnace cooling, air cooling, oil quenching, and water quenching. Microstructural analyses were investigated. Grain size, morphology, volume fraction of γ’ precipitates were investigated. Preliminary mechanical properties such as microhardness was conducted.


Crystals ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 74
Author(s):  
Zhengxing Feng ◽  
Zhixun Wen ◽  
Guangxian Lu ◽  
Yanchao Zhao

The reprecipitation and evolution of γ’ precipitates during various cooling approaches from supersolvus temperature are studied experimentally and via phase field simulation in nickel-based single crystal superalloys. The focus of this paper is to explore the influence of cooling methods on the evolution of the morphology and the distribution of γ’ precipitates. It is demonstrated that small and uniform spherical shape γ’ particles formed with air cooling method. When the average cooling rate decreases, the particle number decreases while the average matrix and precipitate channel widths increase. The shape of γ’ precipitates which changed from spherical to cubic and irregular characteristics due to the elastic interaction and elements diffusion are observed with the decrease of the average cooling rate. The phase field simulation results are in good agreement with the experimental results in this paper. The research is a benefit for the study of the rejuvenation heat treatment in re-service nickel-based superalloys.


Processes ◽  
2021 ◽  
Vol 9 (9) ◽  
pp. 1681
Author(s):  
Shutong Yang ◽  
Youlei Wang ◽  
Yufei Wang

Cascade cooling systems containing different cooling methods (e.g., air cooling, water cooling, refrigerating) are used to satisfy the cooling process of hot streams with large temperature spans. An effective cooling system can significantly save energy and costs. In a cascade cooling system, the heat load distribution between different cooling methods has great impacts on the capital cost and operation cost of the system, but the relative optimization method is not well established. In this work, a cascade cooling system containing waste heat recovery, air cooling, water cooling, absorption refrigeration, and compression refrigeration is proposed. The objective is to find the optimal heat load distribution between different cooling methods with the minimum total annual cost. Aspen Plus and MATLAB were combined to solve the established mathematical optimization model, and the genetic algorithm (GA) in MATLAB was adopted to solve the model. A case study in a polysilicon enterprise was used to illustrate the feasibility and economy of the cascade cooling system. Compared to the base case, which only includes air cooling, water cooling, and compression refrigeration, the cascade cooling system can reduce the total annual cost by USD 931,025·y−1 and save 7,800,820 kWh of electricity per year. It also can recover 3139 kW of low-grade waste heat, and generate and replace a cooling capacity of 2404 kW.


2020 ◽  
Vol 20 (3) ◽  
pp. 167-174
Author(s):  
Hyun Kang ◽  
Oh Sang Kweon

In this study, material performance was analyzed depending on the cooling method of concrete damaged by fire. Various non-destructive and destructive tests were conducted for material performance analysis. Further, the influence of cooling methods was assessed according to each test. As a result of the evaluation, it was confirmed that the residual performance of the concrete was significantly different according to the cooling method (air cooling and water cooling), and the performance difference according to the cooling method was also observed depending on the exposure temperature. Through this study, it was possible to understand the impact of water used in firefighting on fire-damaged RC structures, and it is deemed necessary to further study various concrete mixing models.


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