Corrosion Resistance of Industrial Pure Titanium and its Alloys under High Temperature and Different Cooling Methods

2021 ◽  
Vol 891 ◽  
pp. 3-9
Author(s):  
Cang Tian Wang ◽  
Qing Long Meng ◽  
Fang Hao Chen ◽  
Jing Hong Wang ◽  
You Ran Zhi ◽  
...  

Industrial pure titanium (TA2) and Ti-6Al-4V (TC4) have been widely available for chemical equipment. However, the corrosion resistance changes during their post-fire performance. In this research, the electrochemical properties of industrial pure titanium and Ti-6Al-4V after heat treatment and different cooling methods were analyzed by AC impedance technique and dynamic polarization method. The results support two conclusions. Firstly, when the temperature is approximate to the phase transition point, for pure titanium and its alloys, water-cooling can obtain better corrosion resistance than air-cooling. With regard to pure titanium, its best corrosion resistance can be obtained at 800°C under water-cooling. For Ti-6Al-4V, its best corrosion resistance can be obtained when the temperature reached 910 °C under water cooling condition. Secondly, the corrosion current density under acid corrosion condition has risen compared with neutral corrosion condition. These results can provide some experimental data and theoretical basis for post-fire anticorrosion performance of titanium materials, and also support the safety, risk evaluation of titanium equipment.

1950 ◽  
Vol 163 (1) ◽  
pp. 221-234 ◽  
Author(s):  
A. G. Smith ◽  
R. D. Pearson

The cooling of turbines offers the alternative advantages of the use of higher cycle-maximum-temperatures than are possible with uncooled turbines, with consequent increase of thermal efficiency and power output for a given size of compressor, or the use of lower quality materials for a given turbine inlet-temperature. Two main methods of cooling the blades, which are the most difficult elements of the turbine to cool, have been investigated in the past. They are internal water-cooling, offering a simpler technical problem in cooling due to the great heat-removing capacity of water as compared with air; and air cooling, offering an inherently simpler “plumbing” system as compared with water cooling. Experimental and theoretical information on both these classes of cooling methods si given, and, in addition, experimental information on a new method of cooling is presented, in which a water spray is injected directly on to rotor-blade exterior surfaces. Work at the National Gas Turbine Establishment (N.G.T.E.) has been concentrated mainly on the application of fundamental heat-transfer information to the design of internally air-cooled blading, and measurements on an internal air-cooled cascade blade showed that the blade could be maintained at temperatures several hundred degrees Fahrenheit below gas temperatures, for small cooling-air quantities. Cooling was non-uniform, and difficulties due to consequent thermal stressing may well appear with blades of the type tested. A great deal of improvement over the performance obtained with this first cascade blade is possible, however, and some information on a type of blade which has theoretically a much better performance is given. All cooling methods so far tested show the feature of non-uniformity of cooling, and the present lack of knowledge on the allowable extent of this non-uniformity is an obstacle to the assessment of the gas temperatures at which the various cooling methods will allow a turbine to be run. Probably the air-injection methods, that is, “effusion” cooling, by effusing air through a permeable blade wall, or “film” cooling, by injecting air through slits pointing backwards along the blade surface, will permit the highest possible gas temperatures, since in both these methods there is an insulating action by the injected air. Results of theoretical work at the N.G.T.E. are presented, showing the need for a higher effusion velocity near the blade edges than elsewhere, for effusion-cooled blades. Information is given from tests on a four-stage turbine whose rotor blades were internally water-cooled by the free thermosiphon method, with steam production. Whilst it is likely that effective cooling was obtained in the sense that metal temperatures were kept low, difficulty was experienced with corrosion of the mild steel rotor, a blade eventually corroding through. Certain difficulties with vibration were experienced, but they are thought not to be inherent in the method of cooling. Another method of liquid cooling, that of spraying a small quantity of water on to the rotor blades (of a Whittle jet-engine) from tubes in the nozzle blades, showed unexpectedly great cooling action. The investigation is as yet, however, in a preliminary stage. A discussion is made of the effect of blade aerodynamic design upon the heat which must be extracted from a stage in order to cool it. It appears from the extrapolation of present blade heat-transfer data, that a high axial-velocity (or, more accurately, a high ratio of axial velocity/peripheral velocity) is advantageous and should lead to low heat-extraction quantities. This high velocity ratio will lead to increased volute losses, and there are other factors tending to cause loss of work and efficiency. Some of these are discussed, but mainly not quantitatively owing to lack of systematic knowledge.


Batteries ◽  
2021 ◽  
Vol 7 (4) ◽  
pp. 86
Author(s):  
Morena Falcone ◽  
Eleonora Palka Bayard De Volo ◽  
Ali Hellany ◽  
Claudio Rossi ◽  
Beatrice Pulvirenti

The environment has gained significant importance in recent years, and companies involved in several technology fields are moving in the direction of eco-friendly solutions. One of the most discussed topics in the automotive field is lithium-ion battery packs for electric vehicles and their battery thermal management systems (BTMSs). This work aims to show the most used lithium-ion battery pack cooling methods and technologies with best working temperature ranges together with the best performances. Different cooling methods are presented and discussed, with a focus on the comparison between air-cooling systems and liquid-cooling systems. In this context, a BTMS for cylindrical cells is presented, where the cells are arranged in staggered lines embedded in a solid structure and cooled through forced convection within channels. The thermal behavior of this BTMS is simulated by employing a computational fluid dynamics (CFD) approach. The effect of the geometry of the BTMS on the cell temperature distribution is obtained. It is shown that the use of materials with additives for the solid structure enhances the performance of the system, giving lower temperatures to the cells. The system is tested with air-cooling and water-cooling, showing that the best performances are obtained with water-cooling in terms of cell packing density and lowest cell temperatures.


2012 ◽  
Vol 170-173 ◽  
pp. 3516-3520
Author(s):  
Hui Li ◽  
Shang Qi Zhou ◽  
Jin Ming Fang

In order to provide the best technic parameter for hot pressing, the diffusion bonding temperature fields of Be/HR-1 stainless steel under different cooling methods were simulated by the finite element method. The results show that high temperature parts occur in stainless steel center zone in water cooling and air cooling, and the interface cooling rates follow respectively equation of T = 0.0297 t 2 - 9.3223 t + 1017.6 and equation of T = 0.002 t 2 - 0.7702 t + 1014.8. In funace cooling, high temperature part moves to beryllium center zone and the interface cooling rate follows equation of T = -0.0192 t + 1018.8. While the heat transfer coefficient (h) is taken as 5, the temperature distribution of both sides on the interface is symmetric and temperature gradient is the lowest, so the hot stress on the interface is reduced effectively to improve the diffusion bonding strength, which results fit with the experience ones well.


2018 ◽  
Vol 115 (2) ◽  
pp. 208 ◽  
Author(s):  
Baohua Wang ◽  
Mingbo Zhang ◽  
Yongyu Gong ◽  
Shiping Huang ◽  
Shengtao Qiu ◽  
...  

The distribution of sulfur existence in the mineral phase and occurrence in the low-titanium slag with different cooling methods (water cooling, air cooling, crucible cooling, and furnace cooling) were studied by XRD, EPMA and XPS. The results show that with the cooling rate decrease, the distribution of S changes from clustering dots to large sheet or surface, and the occurrence of S in the mineral phase transfers gradually from the vitreous, perovskite, merwinite and the intertwined phase of some mineral phases to the gehlenite. During the transfer, the velocity decreases with the increasing of the cooling rate. The S in the water cooling slag only exists in the form of SO32−and SO42−, while the occurrences of S in the air cooling slag, crucible cooling slag, and furnace cooling slag are S2−, SO32−and SO42−.


Processes ◽  
2021 ◽  
Vol 9 (9) ◽  
pp. 1681
Author(s):  
Shutong Yang ◽  
Youlei Wang ◽  
Yufei Wang

Cascade cooling systems containing different cooling methods (e.g., air cooling, water cooling, refrigerating) are used to satisfy the cooling process of hot streams with large temperature spans. An effective cooling system can significantly save energy and costs. In a cascade cooling system, the heat load distribution between different cooling methods has great impacts on the capital cost and operation cost of the system, but the relative optimization method is not well established. In this work, a cascade cooling system containing waste heat recovery, air cooling, water cooling, absorption refrigeration, and compression refrigeration is proposed. The objective is to find the optimal heat load distribution between different cooling methods with the minimum total annual cost. Aspen Plus and MATLAB were combined to solve the established mathematical optimization model, and the genetic algorithm (GA) in MATLAB was adopted to solve the model. A case study in a polysilicon enterprise was used to illustrate the feasibility and economy of the cascade cooling system. Compared to the base case, which only includes air cooling, water cooling, and compression refrigeration, the cascade cooling system can reduce the total annual cost by USD 931,025·y−1 and save 7,800,820 kWh of electricity per year. It also can recover 3139 kW of low-grade waste heat, and generate and replace a cooling capacity of 2404 kW.


2020 ◽  
Vol 20 (3) ◽  
pp. 167-174
Author(s):  
Hyun Kang ◽  
Oh Sang Kweon

In this study, material performance was analyzed depending on the cooling method of concrete damaged by fire. Various non-destructive and destructive tests were conducted for material performance analysis. Further, the influence of cooling methods was assessed according to each test. As a result of the evaluation, it was confirmed that the residual performance of the concrete was significantly different according to the cooling method (air cooling and water cooling), and the performance difference according to the cooling method was also observed depending on the exposure temperature. Through this study, it was possible to understand the impact of water used in firefighting on fire-damaged RC structures, and it is deemed necessary to further study various concrete mixing models.


2013 ◽  
Vol 815 ◽  
pp. 712-716
Author(s):  
Yun Long Ai ◽  
Li Liu ◽  
Wen He

Surface potential of TC11 titanium alloy handled by beta phase (1150°C) solid solution for one hour and then taking water cooling, air cooling and furnace cooling as cold method were investigated using scanning Kelvin probe technique. The corrosion resistance difference of samples was analyzed through their surface potential. At the same time, corrosion experiments were adopted to verify it. The results show that the result of the samples corrosion resistance analyzed by scanning Kelvin probe technique is reliable and the method is feasible. Compared with water cooling sample, the corrosion resistance of furnace cooling and air cooling samples is worse and their surface potential present cathode and anode area obviously. The corrosion of furnace cooling sample is slight serious to that of air cooling sample in the early corrosion, but their corrosion resistances are almost equal. Passivation layer formed by alloy elements in the water cooling sample avails to prevent alloy from corrosion.


Tribologia ◽  
2018 ◽  
Vol 282 (6) ◽  
pp. 149-156
Author(s):  
Bartłomiej SZWED ◽  
Marek KONIECZNY

In the present study, commercial pure titanium (Grade 2) was joined to the stainless steel (X5CrNi18-10) by diffusion bonding using aluminium, copper, and nickel as interlayers (100 μm). The investigation focuses on comparing the wear and corrosion resistance of the obtained diffusion joints. The microstructure of the joints was investigated using scanning electron microscopy equipped with an energy dispersive X-ray system (EDS) to determine the chemical composition of joint. The value of friction force and the wear resistance of diffusion bonded joints were carried out by block-on-ring frictional pair, preformed on the tribological tester T-05. The study was carried out under conditions of technically dry friction for the concentrated sliding contact loaded with 300 N. The friction distance for each test was 400 m. The results show that the maximum values of the friction coefficient and mass loss were obtained for joints with a nickel interlayer. The galvanic corrosion tests were carried out in 0.5 M Na2SO4 solution acidified to pH 1 with a sulphuric acid solution. The potentiodynamic polarization curves show that the lowest corrosion current was registered for the joints performed by copper.


Author(s):  
J. Alias

Much research on magnesium (Mg) emphasises creating good corrosion resistance of magnesium, due to its high reactivity in most environments. In this study, powder metallurgy (PM) technique is used to produce Mg samples with a variation of aluminium (Al) composition. The effect of aluminium composition on the microstructure development, including the phase analysis was characterised by optical microscope (OM), scanning electron microscopy (SEM) and x-ray diffraction (XRD). The mechanical property of Mg sample was performed through Vickers microhardness. The results showed that the addition of aluminium in the synthesised Mg sample formed distribution of Al-rich phases of Mg17Al12, with 50 wt.% of aluminium content in the Mg sample exhibited larger fraction and distribution of Al-rich phases as compared to the 20 wt.% and 10 wt.% of aluminium content. The microhardness values were also increased at 20 wt.% and 50 wt.% of aluminium content, comparable to the standard microhardness value of the annealed Mg. A similar trend in corrosion resistance of the Mg immersed in 3.5 wt.% NaCl solution was observed. The corrosion behaviour was evaluated based on potentiodynamic polarisation behaviour. The corrosion current density, icorr, is observed to decrease with the increase of Al composition in the Mg sample, corresponding to the increase in corrosion resistance due to the formation of aluminium oxide layer on the Al-rich surface that acted as the corrosion barrier. Overall, the inclusion of aluminium in this study demonstrates the promising development of high corrosion resistant Mg alloys.


Alloy Digest ◽  
1979 ◽  
Vol 28 (12) ◽  

Abstract RMI 0.2% Pd is a grade of commercially pure titanium to which up to 0.2% palladium has been added. It has a guaranteed minimum yield strength of 40,000 psi with good ductility and formability. It is recommended for corrosion resistance in the chemical industry and other places where the environment is mildly reducing or varies between oxidizing and reducing. The alloy has improved resistance to crevice corrosion at low pH and elevated temperatures. This datasheet provides information on composition, physical properties, elasticity, tensile properties, and bend strength. It also includes information on corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: Ti-74. Producer or source: RMI Company.


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