Effects of calcium carbonate and ammonium sulphate on manganese toxicity in an acid soil

1971 ◽  
Vol 22 (2) ◽  
pp. 201 ◽  
Author(s):  
A Siman ◽  
FW Crodock ◽  
PJ Nicholls ◽  
HC Kirton
Keyword(s):  
Ammonium Sulphate ◽  
Soil Ph ◽  
Acid Soil ◽  
Manganese Content ◽  
Acid Soils ◽  
Manganese Toxicity ◽  
Water Soluble ◽  
North Coast ◽  
The North ◽  
Linear Relationships

The effects of increasing rates of lime and ammonium sulphate on French beans were studied on an acid red basaltic soil (pH 4.5-4.8), rich in manganese, on the north coast of New South Wales. Addition of lime resulted in an increased plant yield, a higher soil pH, and a marked reduction in available soil manganese and plant manganese. Applications of 2 or more tons lime per acre corrected manganese toxicity. Ammonium sulphate applications acidified the soil, increased manganese levels in both soil and plant tissue, and increased the frequency of manganese toxicity symptoms at less than 2 tons lime per acre. At pH 4.7-4.8, exchangeable and water-soluble manganese levels were sensitive to slight changes in reaction. Changes in pH between 5.2 and 6.0 caused only slight alterations in manganese levels in soil and plants. Two tons lime per acre reduced the level of manganese in the soil to about half that in the untreated soil, whereas 3 tons lime was necessary to halve the level of manganese in plants. Close linear relationships were found between rates of lime application and pH, between exchangeable and water-soluble manganese, and between both water-soluble and exchangeable soil manganese and plant manganese. Hyperbolic relationships were found between lime and manganese in soil and plants and also between pH and manganese fractions. Toxic levels of manganese in soil and leaves varied seasonally and yearly, and symptoms usually appeared when the manganese content of the first mature leaves was greater than 600 p.p.m. in the winter crop. Symptoms were more closely related to high levels of plant manganese than to soil manganese. The results of this trial indicate that soil and plant analyses are useful for predicting manganese toxicity in acid soils.

AN ASSESSMENT OF THE SOIL ACIDITY PROBLEM IN ALBERTA AND NORTHEASTERN BRITISH COLUMBIA

1977 ◽  
Vol 57 (2) ◽  
pp. 157-164 ◽  
Author(s):  
D. C. PENNEY ◽  
M. NYBORG ◽  
P. B. HOYT ◽  
W. A. RICE ◽  
B. SIEMENS ◽  
...  
Keyword(s):  
British Columbia ◽  
Soil Ph ◽  
Soil Acidity ◽  
Field Experiments ◽  
Trifolium Pratense ◽  
Acid Soil ◽  
Acid Soils ◽  
Red Clover ◽  
Hordeum Vulgare L ◽  
Crop Species

The amount of cultivated acid soil in Alberta and northeastern British Columbia was estimated from pH values of farm samples analyzed by the Alberta Soil Testing Laboratory, and the effect of soil acidity on crops was assessed from field experiments on 28 typical acid soils. The field experiments consisted of two cultivars of barley (Hordeum vulgare L.) and one cultivar each of rapeseed (Brassica campestris L.), red clover (Trifolium pratense L.) and alfalfa (Medicago sativa L.) grown with and without lime for 2 yr. There are about 30,000 ha of soils with a pH of 5.0 or less where soil acidity seriously restricts yields of all four crop species. There are approximately 300,000 ha with a soil pH of 5.1–5.5 where liming will on the average increase yields of alfalfa by 100%, yields of barley by 10–15%, and yields of rapeseed and red clover by 5–10%. There are a further 1,600,000 ha where soil pH ranges from 5.6 to 6.0 and liming will increase yields of alfalfa by approximately 50% and yields of barley, rapeseed and red clover by at least 4–5%.

A description of acid soils and the relationships between properties of acid soils and the nutrient status of grazed pastures in the southeast of South Australia

Soil Research ◽  
1989 ◽  
Vol 27 (1) ◽  
pp. 149 ◽  
Author(s):  
TJV Hodge ◽  
DC Lewis
Keyword(s):  
Soil Ph ◽  
Acid Soil ◽  
South Australia ◽  
Acid Soils ◽  
Subterranean Clover ◽  
Nutrient Status ◽  
Critical Value ◽  
Soil Types ◽  
Positive Correlations ◽  
Extractable Soil

Areas of low soil pH in the south-east of South Australia were delineated by using previously submitted soil samples and soil association maps. A survey was then undertaken in the major soil associations to determine the severity and characteristics of highly acid soils. The acid soil types identified were a siliceous sand over clay (Db/Dy) and a siliceous sand over organic matter/sesquioxide pan (Uc). The top 2.5 cm of both soil types was significantly less acid than the remaining portion of the A horizon, with pH decreasing rapidly with depth until the B horizon, where a substantial soil pH increase occurred. As soil pH (0.01 M CaCl2) decreased below 4.5, extractable soil aluminium (0.01 M CaCl2) increased rapidly, to a maximum extractable concentration of 17 �g g-l. These soil types were also found to be deficient in both phosphorus and potassium, with 65% of the sites having extractable phosphorus concentrations below the critical value of 20 �g g-1 and 35% below the critical value for extractable potassium of 80 �g g-l. For subterranean clover, significant positive correlations were observed between soil pH and plant calcium and sulfur, and between extractable soil aluminium and plant aluminium. Significant negative correlations were observed between soil pH and plant manganese and between extractable soil aluminium and plant calcium and magnesium. For ryegrass, significant positive correlations were observed between extractable soil aluminium and plant aluminium and manganese. Significant negative correlations were observed between soil pH and plant manganese and between extractable soil aluminium and plant calcium. No other significant correlations were obtained. The results are discussed in relation to further acidification and management of these acid siliceous sands.

scholarly journals Plant-availability of soil and fertilizer zinc in cultivated soils of Finland

1993 ◽  
Vol 2 (3) ◽  
pp. 197-270
Author(s):  
Markku Yli-Halla
Keyword(s):  
Soil Ph ◽  
Field Experiments ◽  
Zinc Concentration ◽  
Acid Soils ◽  
Water Soluble ◽  
Peat Soils ◽  
Zn Uptake ◽  
Zn Concentration ◽  
Mineral Soils ◽  
Cultivated Soils

The Zn status of cultivated soils of Finland was investigated by chemical analyses and bioassays. The effect on ryegrass of different Zn fertilizers and Zn rates was studied in pot experiments and their effect on barley and timothy in field experiments. In an uncontaminated surface soil material of 72 mineral soils and 34 organogenic soils, total Zn (Zntot) was 10.3-202 mg kg-1(median 66 mg kg-1). In mineral soils, Zntot correlated positively with clay content (r = 0.81***) and in organogenic soils negatively with organic C (r = -0.53***). Zinc bound by organic matter and sesquioxides was sequentially extracted by 0.1 M K4P2O7 (Znpy) and 0.05 M oxalate at pH 2.9 (Znox), respectively. The sum Znpy + Znox, a measure of secondary Zn potentially available to plants, was 2 - 88% of Zntot and was the lowest in clay (median 5%) and highest in peat soils (median 49%). Water-soluble and exchangeable Zn consisted of0.3 - 37% (median 3%) of Zntot, the percentage being higher in acid soils, particularly in peat soils. Zinc was also extracted by 0.5 M ammonium acetate - 0,5 M acetic acid - 0.02 M Na2-EDTA at pH 4.65 (ZnAC), the method used in soil testing in Finland. The quantities of ZnAC (median 2.9 mg dm-3, range 0.6 - 29.9 mg dm-3) averaged 50% and 75% of Znpy + Znox in mineral and organogenic soils, respectively, and correlated closely with Znpy. In soil profiles, ZnAC was with few exceptions higher in the plough layer (0 - 20 cm) than in the subsoil (30 - 100 cm). In an intensive pot experiment on 107 surface soils, four crops of ryegrass took up 2 - 68% (median 26%)of Znpy + Znox. The plant-available Zn reserves were not exhausted even though in a few peat soils the Zn supply to grass decreased over time. Variation of Zn uptake was quite accurately explained by ZnAC but increasing pH had a negative impact on Zn uptake. Application of Zn (10 mg dm-3 of soil as ZnSO4 * 7 H2O) did not give rise to yield increases. In mineral soils, increase of plant Zn concentration correlated negatively with soil pH while ZnAC was of secondary importance. In those organogenic soils in which the reserves of native Zn were the most effectively utilized, plant Zn concentration also responded most strongly to applied Zn. In two 2-year field experiments, Zn application did not increase timothy or barley yields. Zinc concentration of timothy increased from 30 mg kg-1 to 33 and 36 mg kg-1 when 3 or 6 kg Zn ha-1 was applied, respectively. The efficiency of ZnSO4 * 7 H2O alone did not differ from that of a fertilizer where ZnSO4 * 7H20 was granulated with gypsum. Zinc concentration of barley grains increased by foliar sprays of Na2Zn-EDTA but only a marginal response to soil-applied Zn (4.8 or 5.4 kg ha-1 over three years) was detected in three 3-year experiments. High applications of Zn to soil (15 or 30 kg ha-1 as ZnSO4 * 7H2O) were required to increase Zn concentration of barley markedly. In order to prevent undue accumulation of fertilizer Zn in soil, it is proposed that Zn fertilizer recommendations for field crops should be based on both soil pH and ZnAC. In slightly acid and neutral soils, even if poor in Zn, response of plant Zn concentration to applied Zn remains small while there is a high response in strongly acid soils.

Effects of lime and gypsum on growth of sweet potato in two strongly acid soils

2000 ◽  
Vol 51 (8) ◽  
pp. 1031 ◽  
Author(s):  
Vele P Ila'ava ◽  
Pax Blamey ◽  
Colin J Asher
Keyword(s):  
Sweet Potato ◽  
Soil Ph ◽  
Acid Soil ◽  
Maximum Yield ◽  
Acid Soils ◽  
Yield Reduction ◽  
A Value ◽  
Exchangeable Al ◽  
Wide Range ◽  
Potato Growth

There were strong relationships between exchangeable aluminium (Al) and relative top yield, and between soil pH and relative top yield in the Garret and Bisinella soils. Sweet potato plants produced maximum top yields at soil exchangeable Al <3.0 cmol ((+)/kg, with a 10% yield reduction coinciding with a value of approximately 5.0 cmol (+)/kg. The value was lower for the Bisinella soil than the Garret soil. In the case of pH, maximum yield in both soils was evident at a soil pH of 5.0 with 90% of maximum yield being achieved at about pH 4.7. These results suggest that soil pH would be a good index for Al toxicity. The close relationships between sweet potato growth and both exchangeable Al and soil pH need to be explored further to determine whether it will hold across a wide range of acid soil groups.

scholarly journals Amending Potassic Fertilizer with Charcoal and Sago (Metroxylon sagu) Bark Ash to Improve Potassium Availability in a Tropical Acid Soil

Agronomy ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 2222
Author(s):  
Puvan Paramisparam ◽  
Osumanu Haruna Ahmed ◽  
Latifah Omar ◽  
Huck Ywih Ch’ng ◽  
Ali Maru ◽  
...  
Keyword(s):  
Soil Ph ◽  
Acid Soil ◽  
Chemical Properties ◽  
Water Soluble ◽  
Soil Chemical Properties ◽  
Kaolinite Clay ◽  
Exchangeable K ◽  
Exchangeable Acidity ◽  
Metroxylon Sagu ◽  
Sago Bark

In Ultisols and Oxisols, potassium (K) in the soil solution is leached from the rhizosphere before it interacts with soil colloids, or exchanged with other cations at the exchange sites of the soils because of the abundance of kaolinite clay minerals. These soils are highly weathered, low in organic matter, and low in pH, but high aluminium (Al) and iron (Fe) ions. Hence, K becomes unavailable for plants, and this compromises crop production and farmers’ profitability. The pH neutralizing effects of sago (Metroxylon sagu) bark ash and the ability of charcoal to chelate Al and Fe could be utilized to improve soil pH, reduce soil acidity, and improve K availability. The objective of this study was to determine the effects of amending muriate of potash (MOP) with charcoal and sago bark ash on selected soil chemical properties in a tropical acid soil (Typic Paleudults) over 90 days in a laboratory incubation. The proportions of charcoal and sago bark ash were varied at 20%, 40%, 60%, 80%, and 100%, but the MOP was fixed at 100% of the recommended rate. Selected soil chemical properties before and after incubation were determined using standard procedures. Results revealed that co-application of the soil amendments with MOP increased soil-exchangeable K compared with conventional practice. Moreover, amending the acid soil with charcoal and sago bark ash positively enhanced the availability of other base cations and soil cation exchange capacity (CEC). This was possible because the amendments increased soil pH and reduced exchangeable acidity, exchangeable Al3+, and exchangeable Fe2+. However, there was no significant improvement in water-soluble K (WSK) in the soil with or without charcoal and sago bark over the 90 days laboratory study. The findings of this study suggested that increasing soil pH could potentially improve soil K sorption capacity. Thus, the optimum rates of charcoal and sago bark ash to increase K availability were found to be 80% charcoal with 80% sago bark ash, 60% charcoal with 60% sago bark ash, and 80% charcoal with 40% sago bark ash, because these rates improved soil-exchangeable K+ and CEC significantly, besides minimizing soil-exchangeable acidity.

scholarly journals Some negative chemical properties of acid soils

2005 ◽  
Vol 70 (5) ◽  
pp. 765-774 ◽  
Author(s):  
Miodrag Jakovljevic ◽  
Mirjana Kresovic ◽  
Srdjan Blagojevic ◽  
Svetlana Antic-Mladenovic
Keyword(s):  
Soil Properties ◽  
Soil Ph ◽  
Acid Soil ◽  
Chemical Properties ◽  
Acid Soils ◽  
Strong Inhibition ◽  
Brown Forest Soil ◽  
Ph Values ◽  
Inhibition Of Nitrification ◽  
Influence Of Ph

Some important chemical properties of various samples of two types of acid soil from Western Serbia (pseudogley and brown forest) are presented in this paper. Mobile Al was found in elevated and toxic quantities (10?30 mg/100 g) in the more acid samples of pseudogley soil. All samples of brown forest soil were very acid and the quantities of mobile Al were in the range from 12.8 to 90.0 mg/100 g. In a selected number of pseudogley soils, the influence of pH and other soil properties on the mineralization and nitrification processes was investigated. Strong inhibition of nitrification at low soil pH was found to be related to high quantities of mobile Al. At pH values less than 4.0 (in 1 M KCl), processes of chemical nitrification and denitrification of applied nitrites were registered in the pseudogley soils. .

scholarly journals Protective effect of divalent cations against aluminum toxicity in soybean

2008 ◽  
Vol 32 (5) ◽  
pp. 2061-2071 ◽  
Author(s):  
Ivo Ribeiro da Silva ◽  
Tarcísio Fernando Côrtes Corrêa ◽  
Roberto Ferreira Novais ◽  
Fabrício de Oliveira Gebrim ◽  
Flancer Novais Nunes ◽  
...  
Keyword(s):  
Root Growth ◽  
Soil Ph ◽  
Plant Tissue ◽  
Aluminum Toxicity ◽  
Divalent Cations ◽  
Acid Soil ◽  
Physiological Mechanism ◽  
Acid Soils ◽  
Al Toxicity ◽  
Base Saturation

A large proportion of soybean fields in Brazil are currently cultivated in the Cerrado region, where the area planted with this crop is growing considerably every year. Soybean cultivation in acid soils is also increasing worldwide. Since the levels of toxic aluminum (Al) in these acid soils is usually high it is important to understand how cations can reduce Al rhizotoxicity in soybean. In the present study we evaluated the ameliorative effect of nine divalent cations (Ca, Mg, Mn, Sr, Sn, Cu, Zn, Co and Ba) in solution culture on Al rhizotoxicity in soybean. The growth benefit of Ca and Mg to plants in an acid Inceptisol was also evaluated. In this experiment soil exchangeable Ca:Mg ratios were adjusted to reach 10 and 60 % base saturation, controlled by different amounts of CaCl2 or MgCl2 (at proportions from 100:0 up to 0:100), without altering the soil pH level. The low (10 %) and adequate (60 %) base saturation were used to examine how plant roots respond to Al at distinct (Ca + Mg)/Al ratios, as if they were growing in soils with distinct acidity levels. Negative and positive control treatments consisted of absence (under native soil or undisturbed conditions) or presence of lime (CaCO3) to reach 10 and 60 % base saturation, respectively. It was observed that in the absence of Aluminum, Cu, Zn, Co and Sn were toxic even at a low concentration (25 µmol L-1), while the effect of Mn, Ba, Sr and Mg was positive or absent on soybean root elongation when used in concentrations up to 100 µmol L-1. At a level of 10 µmol L-1 Al, root growth was only reverted to the level of control plants by the Mg treatment. Higher Tin doses led to a small alleviation of Al rhizotoxicity, while the other cations reduced root growth or had no effect. This is an indication that the Mg effect is ion-specific and not associated to an electrostatic protection mechanism only, since all ions were divalent and used at low concentrations. An increased exchangeable Ca:Mg ratio (at constant soil pH) in the acid soil almost doubled the soybean shoot and root dry matter even though treatments did not modify soil pH and exchangeable Al3+. This indicates a more efficient alleviation of Al toxicity by Mg2+ than by Ca2+. The reason for the positive response to Mg2+ was not the supply of a deficient nutrient because CaCO3 increased soybean growth by increasing soil pH without inducing Mg2+ deficiency. Both in hydroponics and acid soil, the reduction in Al toxicity was accompanied by a lower Al accumulation in plant tissue, suggesting a competitive cation absorption and/or exclusion of Al from plant tissue stimulated by an Mg-induced physiological mechanism.

Phosphate response, base saturation and silica relationships in acid soils

1953 ◽  
Vol 43 (2) ◽  
pp. 229-235 ◽  
Author(s):  
H. F. Birch
Keyword(s):  
Unsaturated Soils ◽  
Field Experiments ◽  
Acid Soil ◽  
Acid Soils ◽  
Water Soluble ◽  
Base Saturation ◽  
Soil Characteristic ◽  
Multiple Regressions ◽  
Percentage Saturation ◽  
Phosphate Response

The inverse relationship described in an earlier publication between phosphate response and the degree of base saturation has been confirmed with three further groups of field experiments. As an alternative to the degree of base saturation soil pH may be employed.The discrepancies sometimes found with the more acid base-unsaturated soils, between actual phosphate responses and those expected from the degree of base saturation were found to be related to the control yields. In general, the higher the control yield on a distinctly acid soil the more the percentage response to phosphate fell short of that expected, and vice versa. By forming multiple regressions of percentage phosphate response on both control yield and the percentage saturation of the B.E.C. a more accurate assessment of phosphate response is possible than by using the simple regression of response on the percentage saturation of the B.E.C. A measurable soil characteristic that could be used in the multiple regressions instead of the control yield was not found.Very significant and inverse relationships were established between percentage phosphate response and the amount of water-soluble or citric acidsoluble silica. These silica contents were also found to be significantly and directly related to the percentage saturation of the B.E.C. It appears that measurements of pH, silica and base saturation function similarly in classifying the soils, distinguishing between the almost neutral soils retaining phosphate in an available form associated with exchangeable bases, acid soils with relatively unavailable phosphate associated with iron and aluminium compounds, and soils intermediate between these.

WATER-SOLUBLE AND EXCHANGEABLE ALUMINUM IN ACID SOILS AS AFFECTED BY LIMING AND FERTILIZATION

1967 ◽  
Vol 47 (3) ◽  
pp. 203-210 ◽  
Author(s):  
L. B. MacLeod ◽  
L. P. Jackson
Keyword(s):  
Soil Ph ◽  
Surface Soil ◽  
Acid Soils ◽  
Water Soluble ◽  
Ph Values ◽  
Exchangeable Al ◽  
Exchangeable Aluminum ◽  
High Fertilization ◽  
Surface Soil Ph ◽  
Representative Samples

The concentration of water-soluble and exchangeable aluminum was determined in the 0–15-, 15–23-, 23–30- and 30–45-cm depths of a Podzol limed to provide surface soil pH values ranging from 4.5 to 7.2. Both soluble and exchangeable Al decreased with increasing soil pH. Soluble Al ranged from 5.7 ppm at pH 4.4 with high fertilization to 0.3 ppm at pH 6.5 with similar fertilization. Increasing the rate of fertilization at pH 4.5 raised the soluble Al from 2.6 to 5.7 ppm. Fertilization still doubled the soluble Al in soil at pH 5.1 but had little effect as the pH was raised further to 5.8 and 6.5. Soluble Al in the subsoil samples was less than in surface soil samples at the same pH, while with exchangeable Al, the concentration was greater in the subsoil than in the surface soil samples.There was not a direct relationship between pH and soluble Al, although the highest soluble Al concentrations occurred at lowest soil pH levels. Analyses of 30 representative samples of surface soil taken from farmers' fields showed that the soluble Al concentration at pH 4.0 ranged from 3.5 to 4.8 ppm, while at a pH of 5.0 it ranged from 0.2 to 2.8 ppm. The concentrations of soluble Al in many of these soils exceeded the levels previously shown by nutrient solution experiments to severely restrict growth of legumes and some varieties of barley.

Influence of soil pH and climate on the tolerances of barley and wheat to chlorsulfuron

1990 ◽  
Vol 30 (5) ◽  
pp. 629 ◽  
Author(s):  
D Lemerle ◽  
AR Leys ◽  
CR Kidd ◽  
BR Cullis
Keyword(s):  
Grain Yield ◽  
Soil Ph ◽  
Climatic Factors ◽  
Acid Soil ◽  
Acid Soils ◽  
Dry Weight ◽  
Triticum Aestivum L ◽  
Annual Rainfall ◽  
Yield Reduction ◽  
Hordeum Vulgare L

The effects of soil pH and seasonal conditions on the responses of barley (Hordeum vulgare L.) and wheat (Triticum aestivum L.) to chlorsulfuron were investigated at 3 sites in southern New South Wales in 1986, 1987 and 1988. The sites varied in soil pH (4.3-6.2) and annual rainfall (360-560 mm). In addition to the variation in soil pH between sites, 2 surface pH levels were obtained at each site by the addition of lime. The effect of post-emergence applications of 7.5, 15.0, 22.5, 30.0 and 37.5 g a.i./ha chlorsulfuron on the yield of weed-free barley and wheat varied with season, site and the addition of lime. The yield reduction was greatest in 1986, and the extent of the reduction was always greater in barley than wheat. In 1986, a recommended rate of chlorsulfuron (15 g a.i./ha) significantly (P<0.05) reduced the grain yield of barley at all sites by up to 18% and of wheat by up to 13%. Therefore, the reduced tolerance of barley and wheat to chlorsulfuron in some seasons was not restricted to the acid soils. Significant lime x chlorsulfuron interactions occurred with barley in 3 of the 9 trials, but the interactions were not consistent. At Ariah Park in 1986, grain yield reductions were greatest in unamended soils, while at both Ariah Park and Goolgowi in 1987, grain yield reductions were greatest with the limed plots. There were no significant interactions for wheat. In pot trials the effect of chlorsulfuron on the shoot dry weight of barley varied with soil type. However, there was no direct relationship between soil pH and dry weight reduction. When the pH of an acid soil was amended by liming to give soils with pH of 4.1-7.3, there was a trend to more damage at pH values of 5-6. With 4 soils of different pH and texture, there was less damage in the barley grown in soils of pH 7.3 and 7.4 than in soils of pH 4.1 and 6.0. While these results suggest that soil pH affects the tolerance of barley to chlorsulfuron, it is likely that soil pH is of less importance than other edaphic or climatic factors.

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