Reactions of Aroyl Peroxides. IV. Benzolyl Peroxide with some halides and oxyhalides of Phosphorus and Sulphur

1958 ◽  
Vol 11 (3) ◽  
pp. 336
Author(s):  
M Karelsky ◽  
KH Pausacker
Keyword(s):  
Carbon Dioxide ◽  
Benzoyl Peroxide ◽  
Benzoyl Chloride ◽  
Phosphorus Oxychloride ◽  
Benzene Solution ◽  
Complex Mixture ◽  
Phosphorus Trichloride ◽  
The Other ◽  
Phenyl Benzoate ◽  
Benzoic Anhydride

When benzoyl peroxide was heated with phosphorus trichloride (1 and 2 mol) in benzene, or chlorobenzene solution, carbon dioxide, benzoyl chloride, and phenyl phosphonyl chloride were the major products. Diphenyl phosphonyl chloride was also formed in small yield, p-Chlorobenzoyl peroxide reacted with phosphorus trichloride, in benzene solution, yielding carbon dioxide, p-chlorobenzoyl chloride, p-chlorophenyl phosphonyl chloride, and p-chlorobenzoic anhydride. The reaction of benzoyl peroxide with phosphorus trichloride alone yielded benzoyl chloride only. Phosphorus oxychloride, on the other hand, does not enter into the reaction. Thionyl chloride, in benzene, gave a complex mixture consisting of carbon dioxide, chlorobenzene, benzoyl chloride, phenyl benzoate, benzene sulphonyl chloride, diphenyl, and benzoic anhydride. Sulphuryl chloride in benzene yielded a mixture of carbon dioxide, chlorobenzene, benzoic acid, phenyl benzoate, and diphenyl. The mechanisms of these various reactions are discussed.

Reactions of Aroyl Peroxides. V. Benzoyl peroxide with ferrocene

1958 ◽  
Vol 11 (4) ◽  
pp. 509 ◽  
Author(s):  
KH Pausacker
Keyword(s):  
Carbon Dioxide ◽  
Benzoic Acid ◽  
Benzoyl Peroxide ◽  
Benzene Solution

When ferrocene reacts with varying amounts of benzoyl peroxide in benzene solution, the iron in ferrocene is almost completely converted into ferric benzoate. The additional benzoyl peroxide apparently reacts with the cyclopentadienyl fragments forming benzoic acid and intractable material. As neither carbon dioxide nor diphenyl could be isolated from the reaction mixture, it would appear that ferrocene acts as an efficient " scavenger " for benzoyloxy radicals.

ORGANIC PHOSPHORUS COMPOUNDS: II: PREPARATION OF CHLOROMETHANEPHOSPHONYL DICHLORIDE

1953 ◽  
Vol 31 (10) ◽  
pp. 976-983 ◽  
Author(s):  
R. A. B. Bannard ◽  
J. R. Gilpin ◽  
G. R. Vavasour ◽  
A. F. McKay
Keyword(s):  
Atmospheric Pressure ◽  
Phosphorus Oxychloride ◽  
Organic Phosphorus ◽  
Phosphorus Pentachloride ◽  
Heating Time ◽  
Phosphorus Trichloride ◽  
The Other ◽  
Phosphorus Compounds ◽  
Subsequent Hydrolysis ◽  
Hydrolysis Of

Hydroxymethanephosphonic acid was prepared by treating paraformaldehyde with phosphorus trichloride at atmospheric pressure and subsequent hydrolysis of the resultant complex. Chloromethanephosphonyl dichloride was obtained by chlorination of hydroxymethanephosphonic acid with thionyl.chloride in the presence of pyridine. On the other hand hydroxymethanephosphonic acid combined slowly with phosphorus pentachloride to give the hitherto unknown dichlorophosphorylmethanephosphonyl dichloride, Cl2P(O)OCH2P(O)Cl2, together with chloromethanephosphonyl dichloride. The structure of dichlorophosphorylmethanephosphonyl dichloride was confirmed by its conversion with phosphorus pentachloride at 78 °C into chloromethanephosphonyl dichloride and phosphorus oxychloride. The preparation of chloromethanephosphonyl dichloride by interaction of paraformaldehyde and phosphorus trichloride in an autoclave at 250 °C was studied in reference to the influence of heating time on the yield.

STUDIES ON THE BACTERIAL OXIDATION OF 2,3-BUTANEDIOL AND RELATED COMPOUNDS

1944 ◽  
Vol 22b (5) ◽  
pp. 140-153 ◽  
Author(s):  
R. Y. Stanier ◽  
Sybil B. Fratkin
Keyword(s):  
Carbon Dioxide ◽  
Aeromonas Hydrophila ◽  
The Other ◽  
Bacterial Oxidation ◽  
Aerobacter Aerogenes ◽  
Aerobic Conditions ◽  
Related Compounds

Aerobacter aerogenes, Aerobacillus polymyxa, and Aeromonas hydrophila, representatives of the three genera characterized by a butanediol fermentation, can all oxidize 2,3-butanediol under aerobic conditions. The configuration of the 2,3-butanediol has considerable bearing on its decomposability: Aerobacter aerogenes is inactive on the l-isomer, but attacks both meso- and d-isomers; Aeromonas hydrophila attacks the meso-isomer but not the l- and probably not the d-isomer; Aerobacillus polymyxa can oxidize both l- and meso-2,3-butanediol, but the rate with the former is many times greater than with the latter. Aerobacter aerogenes oxidizes both 2,3-butanediol and acetoin to carbon dioxide and water, a large part of the substrate being simultaneously assimilated. The other two organisms oxidize 2,3-butanediol to acetoin, but can further oxidize the acetoin thus formed only very slowly, if at all. Both Aerobacter aerogenes and Aerobacillus polymyxa are unable to attack 1,3-butanediol, 2-methyl-1,2-propanediol and 1,2-ethancdiol. However they can oxidize 1,2-propanediol to acetol.

Emergence Change of Carbon Dioxide from Artificial Skin by Titania Photocatalyst

2007 ◽  
Vol 544-545 ◽  
pp. 55-58
Author(s):  
Eiji Watanabe ◽  
Mitsuharu Fukaya ◽  
Hiroshi Taoda
Keyword(s):  
Carbon Dioxide ◽  
Visible Light ◽  
Uv Irradiation ◽  
Visible Light Irradiation ◽  
Human Body ◽  
Light Condition ◽  
The Other ◽  
Artificial Skin ◽  
Irradiation Condition ◽  
Titania Photocatalyst

The influence of the titania photocatalyst particle of the nanometer region on the human being and biology’s to be doubted. Removing the uneasiness will expand further uses for the photocatalyst nanoparticle. Then, we attempted to examine the effect of several titania photocatalyst nanoparticles to the artificial skin like the human body under the UV and visible light irradiation conditions. The decomposition degree of the artificial skin was evaluated from the monitoring of the amount of carbon dioxide generated from them by the titania photocatalyst nanoparticle activity. Under the UV irradiation condition, it was almost found the carbon dioxide emergence from the artificial skin by the activity of the titania photocatalyst nanoparticle. On the other hand, under visible light condition it was mostly detected.

scholarly journals IMPACT EVALUATION OF CARBON DIOXIDE (CO2) IN BHOPAL DUE TO INCREASE IN NUMBER OF PASSENGER CARS

2019 ◽  
Vol 7 (7) ◽  
pp. 422-431
Author(s):  
Niranjan Mudliar ◽  
Paramjeet Singh
Keyword(s):  
Carbon Dioxide ◽  
Public Transport ◽  
Income Group ◽  
The Other ◽  
State Governments ◽  
Passenger Cars ◽  
Lower Income Group ◽  
The Government ◽  
Carbon Dioxide Co2 ◽  
The City

India has been progressing steadily since last two decades in terms of affordability of commodity and purchasing power of the common man. This has given rise to demand which leads to the continuous economic growth. Of course, support from the Government of India as well as various state Governments has come in the form of reforms and infrastructure funding. However this growth has also seen the disadvantage of erratic consumption by wealthy persons as compared to the economically weaker sections, for example on one side there is heavy demand of passenger cars by the higher income group who uses it sparingly but on the other side people of the lower income group who are more in numbers have to rely on public transport. This imbalance creates a wider gap between public affordability to consume a particular commodity like passenger cars. On one side there are persons who buy the latest model introduced by the manufacturer in spite of having sufficient numbers at their disposal and on the other side basic lowest level model are out of reach of some persons in the society, who rely on two-wheeler or public transport which is not reliable. This has not only created a huge gap in public expenditure but has also impact the environment. With year on year increase in number of vehicles in tier 2 cities like Bhopal, there is tremendous influence on the carbon dioxide (CO2) in and around the city. Past decade saw increase in maximum temperatures during summer rise by 3 – 4 degrees above normal in Bhopal and there is clear effect on the monsoon pattern too which has become inconsistent with rains reaching 120 mm in three days. Earlier this quantity was spread over a month. The last major season of winter is seen getting reduced to two months only from the earlier four, again with temperatures dropping suddenly below normal etc. This effect must be the result of increasing number of passenger vehicles in the city apart from other factors which also need detailed study for their influence.

Inhibition of δ-Aminolevulinic Acid Synthesis by Glyphosate

Weed Science ◽  
1981 ◽  
Vol 29 (5) ◽  
pp. 571-577 ◽  
Author(s):  
Lynn M. Kitchen ◽  
William W. Witt ◽  
Charles E. Rieck
Keyword(s):  
Carbon Dioxide ◽  
Zea Mays ◽  
Aminolevulinic Acid ◽  
Higher Plants ◽  
Acid Synthesis ◽  
The Other ◽  
Porphyrin Ring ◽  
Fresh Weight ◽  
Ring Compounds ◽  
Site Of Action

The effect of glyphosate [N-(phosphonomethyl) glycine] on barley (Hordeum vulgareL.) and corn (Zea maysL.) shoot δ-aminolevulinic acid (ALA) production was examined by monitoring ALA content in the tissue and measuring incorporation of14C precursors into ALA and chlorophylla. Barley shoot ALA content was significantly decreased by 1 mM glyphosate after 9, 11, and 15 h of illumination. ALA production by treated barley shoots was 30 nmoles•g fresh weight-1•h-1at each interval tested, compared with 75 to 120 nmoles•g fresh weight-1•h-1for the control. In corn shoots, ALA content was reduced 32, 45, and 58% by 0.1, 1.0, and 10.0 mM glyphosate, respectively, after 12 h illumination. Incorporation studies with14C-glutamate,14C-α-ketoglutarate, and14C-glycine into ALA showed a 77, 92, and 91% inhibition, respectively, in barley shoots treated with 1 mM glyphosate. Incorporation of14C-ALA into chlorophyllawas not affected by 1 mM glyphosate. Thus, the site of action of glyphosate may involve two enzyme pathways:one controlling the conversion of α-ketoglutarate to ALA, and the other controlling the condensation of glycine with succinyl CoA to form ALA and carbon dioxide. Inhibition of ALA synthesis blocks synthesis of chlorophyll, as well as all other porphyrin ring compounds found in higher plants. Thus, inhibition of ALA synthesis may be an integral component of the herbicidal mode of action of glyphosate.

Formulation and Evaluation of Benzoyl Peroxide Injection

2021 ◽  
pp. 198-200
Author(s):  
Ajay Bedadurge ◽  
Mahesh Kadare ◽  
Vinod Matole ◽  
Parikshit Shirure ◽  
Sainath Suryawanshi ◽  
...  
Keyword(s):  
Benzoyl Peroxide ◽  
Functional Groups ◽  
The Other ◽  
Test Results ◽  
Methyl Paraben ◽  
Propyl Paraben ◽  
Sterility Test ◽  
Leakage Test ◽  
Drug Content ◽  
Clear Solution

Objective: The present research has been undertaken for the formulation and evaluation of Benzoyl Peroxide Injection. It is used for Antiacne activity. Methods: Benzoyl peroxide is used as Antiacne. Methyl paraben, Propyl paraben and benzalkoniumchloride were used as preservatives. Water for injection is used as a vehicle. The following parameters were evaluated such as clarity test, leakage test, chearity test, assay and Sterility test. Results: The clearity test shows clear solution. Drug chearity test shows no chear in the vials. Leakage test shows no leakage in the vials. pH and drug content show the F1 batch was better the other batches. IR confirmed that all functional groups are same as benzoyl Peroxide. Conclusion: It was concluded that F1 batch is the good than the other batches. So F1 batch is good for the Parenteral use.

scholarly journals Supersonic dispersion in gases

1934 ◽  
Vol 146 (856) ◽  
pp. 56-71 ◽  
Keyword(s):  
Carbon Dioxide ◽  
Experimental Work ◽  
High Frequency ◽  
Response Curve ◽  
Wave Length ◽  
Soap Film ◽  
The Other ◽  
Rapid Degradation ◽  
Compressional Waves ◽  
Point Electrode

The rapid degradation of intensity suffered by compressional waves of high frequency in gases was first observed by pierce in carbon dioxide for frequencies in the neighbourhood of 2.10 5 cycles/sec. Although in the last few years a considerable number of measurements of the velocity of supersonic waves have been made, less experimental work has been done on the absorption . This present paper describes some work aimed at elucidating the mechanism of the phenomenon. Consideration was first given to the establishment of a source of vibrations of the requisite frequency. The possible apparatus reduces itself to four types: (1) edge-tones, (2) electric sparks, (3) small resonators of gas, (4) solid resonators; both of the latter types to be maintained by oscillating circuits incorporating valves. The frequency of an edge-tone depends directly on the velocity of the blast, and inversely on the distance from the blower to the edge, so that it should be possible to produce supersonic waves by making the former very large and the latter very small; in fact, Hartmann has already used such a source. The difficulty of maintaining constant blast velocity and the complications which the blast introduces in the propagation of such waves would, however, have made such a source unmanageable in the present work. Nekle-pajev has used sparks as sources in the examination of the absorption in air. But here again the frequency is difficult to measure or to maintain constant. Some success was obtained by the author with gaseous resonators consisting of short brass tubes terminated at one end by a brass stopper, and at the other end by a soap film, the distance between the two being half the wave-length at the frequency of excitation. The resonator was maintained in vibration by a valve oscillator, of which the plate was connected to a point electrode just above the soap film, while the grid was connected to the brass tube itself. Response of the resonator due to electrostatic attraction of the film was observed by the image of a glowing filament reflected from the slightly concave film on to a scale. By varying the tuning of the oscillator the response curve of the little resonator could be obtained.

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