The partitioning of zinc, manganese, cadmium and selenium within copepods in oceanic waters east of New Zealand
The partitioning of Zn, Mn, Cd and Se within mesozooplankton, mainly calanoid copepods, is reported for two geographically close but biogeochemically distinct water masses (subtropical (ST) and subantarctic (SA) waters) during a transect east of New Zealand in austral spring 1997. Particular attention was paid to avoiding sample contamination during collection, handling and chemical analysis by using trace metal clean techniques. Mesozooplankton underwent a sequential chemical leaching scheme to determine the degree and type of elemental associations within labile and refractory tissues. All four elements showed a positive correlation with the phosphorus content of each fraction indicating a consistent relationship to the amount of tissue dissolved in each fraction. Ratios of Cd : P and Zn : P in samples from SA waters were over twice those in ST waters. However, no significant differences were found between Mn : P and Se : P ratios for samples from the two water masses.