Lithium-AluminIum Hydroxide Hydrate thin Layers on Al Based Substrates - New Ecological Process for Corrosion Resistance Increase

2004 ◽  
Vol 418 (1) ◽  
pp. 41-53 ◽  
Author(s):  
L. Anicăi ◽  
A. C. Manea ◽  
T. Visan
2015 ◽  
Vol 660 ◽  
pp. 213-218 ◽  
Author(s):  
Petru Lazăr ◽  
Costică Bejinariu ◽  
Andrei Victor Sandu ◽  
Alin Marian Cazac ◽  
Ioan Gabriel Sandu

This paper presents the results of experimental research on the influence of using microcrystalline phosphating process on the OB37 steel used in construction. For this purpose, the samples were immersed in phosphate solution and the structures were characterized using SEM microscope. The results show that the obtained structures, are influenced by pH and immersion time and show a good surface compactity and roughness, which means that the obtained layer on the OB37 reinforcement improves corrosion resistance and adhesion of these reinforcements in the reinforced concrete.


1989 ◽  
Vol 33 ◽  
pp. 171-175
Author(s):  
Toshihiko Sasaki ◽  
Makoto Kuramoto ◽  
Yasuo Yoshioka

Zn-Ni-alloy electroplated steels are one of the surface-treated materials with a high corrosion resistance and are mostly used for automobiles. It is said that the corrosion resistance is more than four times as great as that of Zn-plated steels. Concerning x-ray stress measurement, Kyono et al reported the result of measurement on y (552) planes and showed that the sin2φ diagram was severely curved.X-ray stress analysis in surface-treated materials will become more important. Some problems, however, remain to be studied when we apply the x-ray method to thin layers. For example, the effective x-ray penetration depth may be different from that in ordinary materials. And complex gradients of stresses and compositions may exist.


1998 ◽  
Vol 555 ◽  
Author(s):  
P. D. Fuqua ◽  
J. D. Barrie

AbstractThere is a need in the optics community for highly reflective mirrors that do not degrade in harsh environments. While silver can be a highly efficient reflector of visible light, it suffers from poor resistance to corrosive atmospheric gases. Here, we investigate a durable silver coating scheme, in which silver is sputter deposited between very thin layers of nichrome nitride. Excellent corrosion resistance is achieved with a silicon nitride overcoat. Samples were exposed to a variety of atmospheres and it was found that the nichrome nitride dramatically increased corrosion resistance when compared to bare silver or silicon nitride coated silver. Similar results were found when electrochemical impedance spectroscopy was used to evaluate samples. The enhanced corrosion resistance is achieved even when the thickness of the nichrome nilTide adhesion layer is too thin to be considered continuous.


2014 ◽  
Vol 607 ◽  
pp. 33-36 ◽  
Author(s):  
Nor Azrina Resali ◽  
Koay Mei Hyie ◽  
M.N. Berhan ◽  
N.R. Nik Roselina ◽  
Che Murad Mardziah

Replacement or repair of corrosion damaged equipment is the largest maintenance requirement for the industry. One technique for reducing the corrosion of metals is to coat them with thin layers of less reactive metals or alloys. Unfortunately, most metallic coatings are inherently porous and historically have been of little value as barriers against corrosion. Recently, with the development of new alternative material such as electrodeposited CoNiFe, these problems have largely been overcome. This paper investigated the effects of different aggressive environments on the corrosion behavior of electrodeposited CoNiFe. Interestingly, the mixed morphologies with spherical and dendritic structure were found in the neutral and alkaline environment. This morphology exhibited the smallest particle size with less percentage of oxygen elements. Besides, alkaline environment experienced the slowest corrosion rate due to the mixed morphology. It was found that spherical and dendritic refinement provides higher corrosion resistance. The corrosion rate of the sample prepared in alkaline environment was the lowest compared to the others due to the reduction of particle size.


2010 ◽  
Vol 297-301 ◽  
pp. 1053-1058 ◽  
Author(s):  
Małgorzata Grądzka-Dahlke

The development of arthroplastics places high demands on the materials used for load-bearing elements of orthopedic implants. The most common of implant materials are titanium and cobalt alloys due to their excellent mechanical properties and biocompatibility. Titanium alloys have desirable properties, such as relatively low modulus, good fatigue strength, formability, machinability, superior corrosion resistance and so are frequently used for long-term implants. However, poor wear resistance limits their application for tribological systems of artificial joints. Research on improvement of titanium alloys tribological properties have been undertaken, mainly by using thin coatings. The TiN-layers are reported to be most promising in biomedical applications such. Many authors stress that application of TiN layer improve wear resistance of titanium implant alloys. Presented work is focused on comparison of effect of TiN coating on properties of TiAlV and CoCrMo implant alloys. The structure, microhardness, corrosion resistance as well as tribological properties were analysed. The research did not confirmed the good properties of titanium alloy with TiN coating. The results show that matrix metal hardness definitely affects the efficiency of TiN layers.


2013 ◽  
Vol 837 ◽  
pp. 247-252 ◽  
Author(s):  
Mihaela Luminita Barhalescu

The aim of this research is to determine the corrosion resistance on superficial layers laid-down through electrical sparking on the steel carbon OLC 45 samples, the used electrode being made from corrosion resistant material (Aluminum, Copper and Chromium). The superficial treatment through impulse electrical discharges is a procedure through which the proprieties of the metallic materials can be improved. The proprieties of the superficial layers obtained through this procedure are the same as the electrodes material being used or very close to this one, the properties resulting from micro alloying and the diffusion of the electrode material in the sample of steel. The experiments were done, for the superficial treatment through impulse electrical discharges, using Al, Cu and Cr electrodes. The corrosion speed was determinate through electrochemical corrosion. The corrosion potential and marking the polarization curves (linear and cyclic) was determined with an advanced electrochemical system type VOLTALAB 32. The acquisition and processing of experimental data was made with the help of the specialized software VOLTMASTER 2. The corrosion potential was determined by tracing the curves of linear polarization, recorded in sea water, using the Evans coordinates: E = f (log I). The corrosion process analysis was made also based on the cyclic polarization curves. The fine determining of the topography surfaces exposed to the action of the corrosive environment was made using the atomic force microscope (AFM). The support but also the sparking probes, has present the same type of corrosion; a general corrosion, which in the initial moments is represented by the appearance of corrosion dots. The superficial layers laid through Cr, Al and Cu electrodes sparking proves a improved corrosion resistance to see water compared to the base steel. Aluminium has the highest corrosion tendency while copper has the best protection.


Author(s):  
Олег Федонин ◽  
Oleg Fedonin

The results of theoretical and experimental investigations of parts surfaces corrosion resistance at different methods of their manufacturing are presented. A general theoretical dependence is shown for the definition of surface corrosion resistance depending on environment, material properties, surface quality and coating methods. The equations for the definition of values of different coefficients affecting corrosion resistance are given. Technological measures ensuring corrosion resistance increase in surfaces of machinery are shown.


2021 ◽  
Vol 59 (3) ◽  
pp. 155-161
Author(s):  
Geumhyuck Bang ◽  
Dooho Choi

In this study, we report a methodology that simultaneously improved the corrosion resistance and visible transparency of ZnO/Cu/ZnO transparent heaters with the addition of reactively sputtered Al2O3 layers. To assess corrosion resistance, ZnO and Al2O3 layers with thicknesses in the range of 0-20 nm were deposited onto 20 nm-thick Cu layer, and the corrosion behavior of the underlying Cu layers was investigated by evaluating the sheet resistance change in an 85 °C/85% humidity test. While the 20 nm-thick ZnO layer was not an effective moisture barrier, showing a sheet resistance increase of more than 50% after 10,000 m, the sheet resistance of the Cu layer below the 5 nm-thick Al2O3 layer did not show an observable increase for equal duration. Optical transmittance was also investigated by constructing glass/ZnO/Cu/ZnO/Al2O3 structures with varying thicknesses for the top ZnO and Al2O3 layers, in the range of 10-30 and 10-60 nm, respectively The thicknesses of the bottom ZnO and Cu layers were fixed at 30 nm and 10 nm. The results revealed that the average visible light transmittance of the ZnO/Cu/ZnO/Al2O3 structure increased by 2.5% over the optimized ZnO/Cu/ZnO structure.


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