Influence of C=O groups on the optical extinction coefficient of graphene exfoliated in liquid phase

2021 ◽  
Author(s):  
Julian Rico ◽  
Mario Castano ◽  
Natalia Lopez-Arango ◽  
Yenny Hernandez
Keyword(s):  
Graphene Oxide ◽  
Extinction Coefficient ◽  
Large Scale ◽  
Optical Band Gap ◽  
Exponential Dependence ◽  
Electrochemical Exfoliation ◽  
Optical Extinction ◽  
Production Methods ◽  
The Difference ◽  
High Concentrations

Abstract LiLiquid phase exfoliation of graphite is currently one of the most promising graphene production methods at large scale. For this reason, an accurate calculation of the concentration in graphene dispersions is important for standardization and commercialization. Here, graphene dispersions, at high concentrations, were produced by electrochemical exfoliation. Furthermore, a cleaner methodology to obtain graphene oxide by electrochemical exfoliation at high acid concentrations was implemented. The absorption coefficient for graphene and graphene oxide was determined in the optical range ($\alpha_{660nm}=$ 1414 ($\pm$3\%) mL mg$^{-1}$ m$^{-1}$ and $\alpha_{660nm}=$ 648 ($\pm$ 7\%) mL mg$^{-1}$ m$^{-1}$, respectively) with an exponential dependence with the wavelength. The difference in $\alpha$ for both materials is attributed to an increased presence of C=O groups as evidenced by FTIR, UV-vis and Raman spectroscopy, as well as, in the calculation of the opical extinction coefficient and optical band-gap via Tauc-plots.

scholarly journals Physical and remineralization processes govern the cobalt distribution in the deep western Atlantic Ocean

2014 ◽  
Vol 11 (6) ◽  
pp. 1561-1580 ◽  
Author(s):  
G. Dulaquais ◽  
M. Boye ◽  
M. J. A. Rijkenberg ◽  
X. Carton
Keyword(s):  
Atlantic Ocean ◽  
Large Scale ◽  
Vertical Diffusion ◽  
Mixing Processes ◽  
Western Atlantic ◽  
Western Atlantic Ocean ◽  
Deep Waters ◽  
Bottom Waters ◽  
The Difference ◽  
High Concentrations

Abstract. The distributions of the bio-essential trace element dissolved cobalt (DCo) and the apparent particulate Co (PCo) are presented along the GEOTRACES-A02 deep section from 64° N to 50° S in the western Atlantic Ocean (longest section of international GEOTRACES marine environment program). PCo was determined as the difference between total cobalt (TCo, unfiltered samples) and DCo. DCo concentrations ranged from 14.7 pM to 94.3 pM, and PCo concentrations from undetectable values to 18.8 pM. The lowest DCo concentrations were observed in the subtropical domains, and the highest in the low-oxygenated Atlantic Central Waters (ACW), which appears to be the major reservoir of DCo in the western Atlantic. In the Antarctic Bottom Waters, the enrichment in DCo with aging of the water mass can be related to suspension and redissolution of bottom sediments a well as diffusion of DCo from abyssal sediments. Mixing and dilution of deep water masses, rather than scavenging of DCo onto settling particles, generated the meridional decrease of DCo along the southward large-scale circulation in the deep western Atlantic. Furthermore, the apparent scavenged profile of DCo observed in the deep waters likely resulted from the persistence of relatively high concentrations in intermediate waters and low DCo concentrations in underlaying bottom waters. We suggest that the 2010 Icelandic volcanic eruption could have been a source of DCo that could have been transported into the core of the Northeast Atlantic Deep Waters. At intermediate depths, the high concentrations of DCo recorded in the ACW linearly correlated with the apparent utilization of oxygen (AOU), indicating that remineralization of DCo could be significant (representing up to 37% of the DCo present). Furthermore, the preferential remineralization of phosphate (P) compared to Co in these low-oxygenated waters suggests a decoupling between the deep cycles of P and Co. The vertical diffusion of DCo from the ACW appears to be a significant source of DCo into the surface waters of the equatorial domain. Summarizing, the dilution due to mixing processes rather than scavenging of DCo and the above-mentioned remineralization could be the two major pathways controlling the cycling of DCo into the intermediate and deep western Atlantic.

Relationship between total plasma homocysteine and the risk of aneurysms – a meta-analysis

VASA ◽  
2020 ◽  
pp. 1-6
Author(s):  
Hanji Zhang ◽  
Dexin Yin ◽  
Yue Zhao ◽  
Yezhou Li ◽  
Dejiang Yao ◽  
...  
Keyword(s):  
Large Scale ◽  
Meta Analysis ◽  
Single Species ◽  
Total Plasma ◽  
Control Groups ◽  
Randomized Controlled ◽  
Randomized Controlled Studies ◽  
The Difference ◽  
The Relationship ◽  
Healthy Participants

Summary: Our meta-analysis focused on the relationship between homocysteine (Hcy) level and the incidence of aneurysms and looked at the relationship between smoking, hypertension and aneurysms. A systematic literature search of Pubmed, Web of Science, and Embase databases (up to March 31, 2020) resulted in the identification of 19 studies, including 2,629 aneurysm patients and 6,497 healthy participants. Combined analysis of the included studies showed that number of smoking, hypertension and hyperhomocysteinemia (HHcy) in aneurysm patients was higher than that in the control groups, and the total plasma Hcy level in aneurysm patients was also higher. These findings suggest that smoking, hypertension and HHcy may be risk factors for the development and progression of aneurysms. Although the heterogeneity of meta-analysis was significant, it was found that the heterogeneity might come from the difference between race and disease species through subgroup analysis. Large-scale randomized controlled studies of single species and single disease species are needed in the future to supplement the accuracy of the results.

TO THE PROBLEMS OF COMBATING CORRUPTION IN MODERN RUSSIA AND INTERNATIONAL COOPERATION IN THE FIELD OF ANTI-CORRUPTION

2020 ◽  
Author(s):  
Angela Dranishnikova
Keyword(s):  
Large Scale ◽  
The State ◽  
Point Of View ◽  
Modern Life ◽  
Existing Problems ◽  
Moral Point ◽  
Material Goods ◽  
The Russian Federation ◽  
The Difference ◽  
The Government

In the article, the author reflects the existing problems of the fight against corruption in the Russian Federation. He focuses on the opacity of the work of state bodies, leading to an increase in bribery and corruption. The topic we have chosen is socially exciting in our days, since its significance is growing on a large scale at all levels of the investigated aspect of our modern life. Democratic institutions are being jeopardized, the difference in the position of social strata of society in society’s access to material goods is growing, and the state of society is suffering from the moral point of view, citizens are losing confidence in the government, and in the top officials of the state.

Identification of N-Substituted Triazolo-azetidines as Novel Antibacterials using pDualrep2 HTS Platform

2019 ◽  
Vol 22 (5) ◽  
pp. 346-354
Author(s):  
Yan A. Ivanenkov ◽  
Renat S. Yamidanov ◽  
Ilya A. Osterman ◽  
Petr V. Sergiev ◽  
Vladimir A. Aladinskiy ◽  
...  
Keyword(s):  
Antibacterial Activity ◽  
Large Scale ◽  
Underlying Mechanism ◽  
Luciferase Assay ◽  
Reporter System ◽  
E Coli ◽  
Starting Point ◽  
High Concentrations ◽  
Mic Value

Aim and Objective: Antibiotic resistance is a serious constraint to the development of new effective antibacterials. Therefore, the discovery of the new antibacterials remains one of the main challenges in modern medicinal chemistry. This study was undertaken to identify novel molecules with antibacterial activity. Materials and Methods: Using our unique double-reporter system, in-house large-scale HTS campaign was conducted for the identification of antibacterial potency of small-molecule compounds. The construction allows us to visually assess the underlying mechanism of action. After the initial HTS and rescreen procedure, luciferase assay, C14-test, determination of MIC value and PrestoBlue test were carried out. Results: HTS rounds and rescreen campaign have revealed the antibacterial activity of a series of Nsubstituted triazolo-azetidines and their isosteric derivatives that has not been reported previously. Primary hit-molecule demonstrated a MIC value of 12.5 µg/mL against E. coli Δ tolC with signs of translation blockage and no SOS-response. Translation inhibition (26%, luciferase assay) was achieved at high concentrations up to 160 µg/mL, while no activity was found using C14-test. The compound did not demonstrate cytotoxicity in the PrestoBlue assay against a panel of eukaryotic cells. Within a series of direct structural analogues bearing the same or bioisosteric scaffold, compound 2 was found to have an improved antibacterial potency (MIC=6.25 µg/mL) close to Erythromycin (MIC=2.5-5 µg/mL) against the same strain. In contrast to the parent hit, this compound was more active and selective, and provided a robust IP position. Conclusion: N-substituted triazolo-azetidine scaffold may be used as a versatile starting point for the development of novel active and selective antibacterial compounds.

The metachor as a characteristic of the association of electrolytes in aqueous solutions

1984 ◽  
Vol 49 (5) ◽  
pp. 1061-1078 ◽  
Author(s):  
Jiří Čeleda ◽  
Stanislav Škramovský
Keyword(s):  
Aqueous Solutions ◽  
Apparent Volume ◽  
Solutions Of Electrolytes ◽  
Molal Volumes ◽  
The Difference ◽  
High Concentrations ◽  
Experimental Values ◽  
Suitable Characteristic ◽  
Association Of Ions ◽  
Very High

Based on the earlier paper introducing a concept of the apparent parachor of a solute in the solution, we have eliminated in the present work algebraically the effect which is introduced into this quantity by the additivity of the apparent molal volumes. The difference remaining from the apparent parachor after substracting the contribution corresponding to the apparent volume ( for which the present authors suggest the name metachor) was evaluated from the experimental values of the surface tension of aqueous solutions for a set of 1,1-, 1,2- and 2,1-valent electrolytes. This difference showed to be independent of concentration up to the very high values of the order of units mol dm-3 but it was directly proportional to the number of the free charges (with a proportionality factor 5 ± 1 cm3 mol-1 identical for all studied electrolytes). The metachor can be, for this reason, a suitable characteristic for detection of the association of ions and formation of complexes in the solutions of electrolytes, up to high concentrations where other methods are failing.

scholarly journals Large-Scale Analysis of the Spatiotemporal Changes of Net Ecosystem Production in Hindu Kush Himalayan Region

2021 ◽  
Vol 13 (6) ◽  
pp. 1180
Author(s):  
Da Guo ◽  
Xiaoning Song ◽  
Ronghai Hu ◽  
Xinming Zhu ◽  
Yazhen Jiang ◽  
...  
Keyword(s):  
Large Scale ◽  
Net Primary Production ◽  
Carbon Sink ◽  
Carbon Sources ◽  
Spatial Dynamics ◽  
Tibet Plateau ◽  
Geostatistical Model ◽  
Hindu Kush ◽  
Temporal And Spatial ◽  
The Difference

The Hindu Kush Himalayan (HKH) region is one of the most ecologically vulnerable regions in the world. Several studies have been conducted on the dynamic changes of grassland in the HKH region, but few have considered grassland net ecosystem productivity (NEP). In this study, we quantitatively analyzed the temporal and spatial changes of NEP magnitude and the influence of climate factors on the HKH region from 2001 to 2018. The NEP magnitude was obtained by calculating the difference between the net primary production (NPP) estimated by the Carnegie–Ames Stanford Approach (CASA) model and the heterotrophic respiration (Rh) estimated by the geostatistical model. The results showed that the grassland ecosystem in the HKH region exhibited weak net carbon uptake with NEP values of 42.03 gC∙m−2∙yr−1, and the total net carbon sequestration was 0.077 Pg C. The distribution of NEP gradually increased from west to east, and in the Qinghai–Tibet Plateau, it gradually increased from northwest to southeast. The grassland carbon sources and sinks differed at different altitudes. The grassland was a carbon sink at 3000–5000 m, while grasslands below 3000 m and above 5000 m were carbon sources. Grassland NEP exhibited the strongest correlation with precipitation, and it had a lagging effect on precipitation. The correlation between NEP and the precipitation of the previous year was stronger than that of the current year. NEP was negatively correlated with temperature but not with solar radiation. The study of the temporal and spatial dynamics of NEP in the HKH region can provide a theoretical basis to help herders balance grazing and forage.

scholarly journals Can Mandatory Disclosure Policies Promote Corporate Environmental Responsibility?—Quasi-Natural Experimental Research on China

2021 ◽  
Vol 18 (11) ◽  
pp. 6033
Author(s):  
Yue Liu ◽  
Pierre Failler ◽  
Liming Chen
Keyword(s):  
Property Rights ◽  
Large Scale ◽  
Environmental Responsibility ◽  
Mandatory Disclosure ◽  
Corporate Environmental Responsibility ◽  
Disclosure Policy ◽  
Protection Information ◽  
The Difference ◽  
Csr Disclosure ◽  
Corporate Social

Corporate environmental responsibility (CER) is an important component of the corporate social responsibility (CSR) report, and an important carrier for enterprises to disclose environmental protection information. Based on the corporate micro data, this paper evaluates the effect of a mandatory CSR disclosure policy on the fulfillment of corporate environmental responsibility by adopting the difference-in-differences model (DID) with the release of a mandatory disclosure policy of China in 2008 as a quasi-natural experiment. The study draws the following conclusions: First, a mandatory CSR disclosure policy can promote the fulfillment of CER. Second, after the implementation of a mandatory CSR disclosure policy, enterprises can improve their CER level through two channels: improving the quality of environmental management disclosure and increasing the number of patents. Third, the heterogeneity of the impacts of mandatory CSR disclosure on CER is reflected in three aspects: different CER levels, different corporate scales and a different property rights structure. In terms of the CER level, there is an inverted U-shaped relationship between the CER level and mandatory CSR disclosure effect. In terms of the corporate scale, mandatory disclosure of CSR plays a greater role in large-scale enterprises. In terms of the structure of property rights, mandatory CSR disclosure has a greater effect on non-state-owned enterprises.

scholarly journals Investigating the properties of a galaxy group at z = 0.6

2020 ◽  
Vol 15 (S359) ◽  
pp. 188-189
Author(s):  
Daniela Hiromi Okido ◽  
Cristina Furlanetto ◽  
Marina Trevisan ◽  
Mônica Tergolina
Keyword(s):  
Large Scale ◽  
The Other ◽  
Numerical Density ◽  
Spectroscopy Data ◽  
Stellar Kinematics ◽  
Galaxy Groups ◽  
The Galaxy ◽  
The Difference ◽  
The Impact ◽  
The Universe

AbstractGalaxy groups offer an important perspective on how the large-scale structure of the Universe has formed and evolved, being great laboratories to study the impact of the environment on the evolution of galaxies. We aim to investigate the properties of a galaxy group that is gravitationally lensing HELMS18, a submillimeter galaxy at z = 2.39. We obtained multi-object spectroscopy data using Gemini-GMOS to investigate the stellar kinematics of the central galaxies, determine its members and obtain the mass, radius and the numerical density profile of this group. Our final goal is to build a complete description of this galaxy group. In this work we present an analysis of its two central galaxies: one is an active galaxy with z = 0.59852 ± 0.00007, while the other is a passive galaxy with z = 0.6027 ± 0.0002. Furthermore, the difference between the redshifts obtained using emission and absorption lines indicates an outflow of gas with velocity v = 278.0 ± 34.3 km/s relative to the galaxy.

scholarly journals Grounding semantic transparency in context

Morphology ◽  
2021 ◽  
Author(s):  
Rossella Varvara ◽  
Gabriella Lapesa ◽  
Sebastian Padó
Keyword(s):  
Large Scale ◽  
Point Of View ◽  
Distributional Semantics ◽  
Semantic Transparency ◽  
Inclusion Measure ◽  
The Difference ◽  
Semantic Point ◽  
The Many ◽  
The Relationship

AbstractWe present the results of a large-scale corpus-based comparison of two German event nominalization patterns: deverbal nouns in -ung (e.g., die Evaluierung, ‘the evaluation’) and nominal infinitives (e.g., das Evaluieren, ‘the evaluating’). Among the many available event nominalization patterns for German, we selected these two because they are both highly productive and challenging from the semantic point of view. Both patterns are known to keep a tight relation with the event denoted by the base verb, but with different nuances. Our study targets a better understanding of the differences in their semantic import.The key notion of our comparison is that of semantic transparency, and we propose a usage-based characterization of the relationship between derived nominals and their bases. Using methods from distributional semantics, we bring to bear two concrete measures of transparency which highlight different nuances: the first one, cosine, detects nominalizations which are semantically similar to their bases; the second one, distributional inclusion, detects nominalizations which are used in a subset of the contexts of the base verb. We find that only the inclusion measure helps in characterizing the difference between the two types of nominalizations, in relation with the traditionally considered variable of relative frequency (Hay, 2001). Finally, the distributional analysis allows us to frame our comparison in the broader coordinates of the inflection vs. derivation cline.

scholarly journals Allometric Equations for Estimating Biomass and Carbon Stocks in Afforested Open Woodlands with Black Spruce and Jack Pine, in the Eastern Canadian Boreal Forest

Forests ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 59
Author(s):  
Olivier Fradette ◽  
Charles Marty ◽  
Pascal Tremblay ◽  
Daniel Lord ◽  
Jean-François Boucher
Keyword(s):  
Large Scale ◽  
Ad Hoc ◽  
Black Spruce ◽  
Tree Height ◽  
Jack Pine ◽  
Carbon Stocks ◽  
Allometric Equations ◽  
C Stocks ◽  
The Difference ◽  
Canadian Boreal Forest

Allometric equations use easily measurable biometric variables to determine the aboveground and belowground biomasses of trees. Equations produced for estimating the biomass within Canadian forests at a large scale have not yet been validated for eastern Canadian boreal open woodlands (OWs), where trees experience particular environmental conditions. In this study, we harvested 167 trees from seven boreal OWs in Quebec, Canada for biomass and allometric measurements. These data show that Canadian national equations accurately predict the whole aboveground biomass for both black spruce and jack pine trees, but underestimated branches biomass, possibly owing to a particular tree morphology in OWs relative to closed-canopy stands. We therefore developed ad hoc allometric equations based on three power models including diameter at breast height (DBH) alone or in combination with tree height (H) as allometric variables. Our results show that although the inclusion of H in the model yields better fits for most tree compartments in both species, the difference is minor and does not markedly affect biomass C stocks at the stand level. Using these newly developed equations, we found that carbon stocks in afforested OWs varied markedly among sites owing to differences in tree growth and species. Nine years after afforestation, jack pine plantations had accumulated about five times more carbon than black spruce plantations (0.14 vs. 0.80 t C·ha−1), highlighting the much larger potential of jack pine for OW afforestation projects in this environment.

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