scholarly journals Nitrogen Gas Adsorption Filter (NgAF) to enhance producer gas quality

2021 ◽  
Vol 2053 (1) ◽  
pp. 012023
Author(s):  
Mohd Mahadzir Mohammud ◽  
Nor Azirah Mohd Fohimi ◽  
Muhammad Arif Ab Hamid Pahmi ◽  
Ariffatul Amirah Hairun Anuar
Keyword(s):  
Gas Adsorption ◽  
Calorific Value ◽  
Thermochemical Conversion ◽  
Cylindrical Shape ◽  
Producer Gas ◽  
Nitrogen Gas ◽  
Heating Value ◽  
Small Pore ◽  
Combustible Gases ◽  
Solid Biomass

Abstract Biomass gasification is a thermochemical conversion process of solid biomass into a gaseous fuel called producer gas that can be used to generate power and electricity. The producer gas consists of around 47% of Nitrogen (N2), 24% Carbon Monoxide (CO), 16% Carbon Dioxide (CO2), 12% Hydrogen (H2), and 1% Methane (CH4). However, Nitrogen (N2) content in the producer gas reduces its heating values as N2 acts as a diluent because of the low calorific value (LCV) of gas. This study aims to design a Nitrogen gas filter for capturing nitrogen gas from producer gas to increase the heating value of producer gas as fuel in combustion. The method to increase the heating value of producer gas will increase the number of combustible gases or reduce the composition of non-combustible gases in producer gas. The use of material name zeolite with its microporous structures able to adsorb nitrogen molecules and act as catalysts to chemical reactions. Zeolites 5A have a small pore highly efficient to adsorb nitrogen gas because pore diameter is relatively similar to the size of nitrogen molecules. The quality of the producer gas depends on the design and operating parameters of the zeolite catalyst. Nitrogen Gas Adsorption Filter is a new method that has to be designed to improve the previous producer gas quality. Nitrogen Gas Adsorption Filter consists of a cylindrical shape body packed with crushed zeolites 5A. When this method of adsorption process is applied, the heating value of the producer gas is increased by observing the quantity of blue flame colour produced by NgAF.

Fuel Production From Plastic Wastes Pyrolysis

2017 ◽  
Author(s):  
Emna Berrich-Betouche ◽  
Asma Dhahak ◽  
Abdelaziz Touati ◽  
Fethi Aloui
Keyword(s):  
High Density Polyethylene ◽  
Batch Reactor ◽  
Calorific Value ◽  
Inert Atmosphere ◽  
Fuel Production ◽  
Nitrogen Gas ◽  
Heating Value ◽  
Plastic Wastes ◽  
C 30 ◽  
Pyrolysis Liquids

Energetic valorization of thermoplastic wastes (High-density polyethylene (PE) and Polypropylene (PP)) to produce fuel using pyrolysis process is presented in this paper. HDPE and PP pyrolysis experiments were carried out in a lab-scale batch reactor under an inert atmosphere. Nitrogen gas was used as carrier before and during the experiments. The temperature was varied from 293 K to approximately 773 K. The viscosities of HDPE, PP and the mixture 50% HDPE & 50 % PP pyrolysis liquids are respectively equal to 1.08 cP, 0.67 cP and 0.8 cP. Its densities are respectively equals to 0.735, 0.751 and 0.759 (at 20 °C–30 °C). The high calorific value (the heating Value) is respectively equals to 45.235 ± 0.641 MJ/kg, 46.151 ± 1.33 MJ/kg and 45.393 ± 0.87 MJ/kg. The liquids obtained have approximately the same Kerosene (Coal Oil) high calorific value (46 MJ/kg). The flash points are respectively equal to 32 °C, 31 °C and lesser than 25 °C for the mixture. They are lesser than coal oil and Diesel values which are equal to 38 °C for Kerosene and between 38 °C and 58 °C for Diesel. The mixture of two polymers decreases the viscosity values comparing to coal oil (1.7 cP) and Diesel (3.35 cP).

Influence of intramolecular interactions on carbon dioxide gas adsorption capacity in Mesoporous Imine polymers

2018 ◽  
Author(s):  
Jaya Prakash Madda ◽  
Pilli Govindaiah ◽  
Sushant Kumar Jena ◽  
Sabbhavat Krishna ◽  
Rupak Kishor
Keyword(s):  
Carbon Dioxide ◽  
Adsorption Capacity ◽  
Density Functional ◽  
Gas Adsorption ◽  
Ambient Pressure ◽  
Condensation Reaction ◽  
Intramolecular Interactions ◽  
Carbon Dioxide Adsorption ◽  
Nitrogen Gas ◽  
Adsorption Characteristic

<p>Covalent organic Imine polymers with intrinsic meso-porosity were synthesized by condensation reaction between 4,4-diamino diphenyl methane and (para/meta/ortho)-phthaladehyde. Even though these polymers were synthesized from precursors of bis-bis covalent link mode, the bulk materials were micrometer size particles with intrinsic mesoporous enables nitrogen as well as carbon dioxide adsorption in the void spaces. These polymers were showed stability up to 260<sup>o</sup> centigrade. Nitrogen gas adsorption capacity up to 250 cc/g in the ambient pressure was observed with type III adsorption characteristic nature. Carbon dioxide adsorption experiments reveal the possible terminal amine functional group to carbamate with CO<sub>2</sub> gas molecule to the polymers. One of the imine polymers, COP-3 showed more carbon dioxide sorption capacity and isosteric heat of adsorption (Q<sub>st</sub>) than COP-1 and COP-2 at 273 K even though COP-3 had lower porosity for nitrogen gas than COP-1 and COP-2. We explained the trends in gas adsorption capacities and Qst values as a consequence of the intra molecular interactions confirmed by Density Functional Theory computational experiments on small molecular fragments.</p>

Evaluasi Prediksi Higher Heating Value (HHV) Biomassa Berdasarkan Analisis Proksimat

2020 ◽  
Vol 4 (1) ◽  
pp. 1-7
Author(s):  
Made Dirgantara ◽  
Karelius Karelius ◽  
Marselin Devi Ariyanti, Sry Ayu K. Tamba
Keyword(s):  
Renewable Energy ◽  
Natural Gas ◽  
Key Words ◽  
Critical Analysis ◽  
Fossil Fuels ◽  
Calorific Value ◽  
Proximate Analysis ◽  
Heating Value ◽  
Bomb Calorimeter ◽  
Hhv Prediction

Abstrak – Biomassa merupakan salah satu energi terbarukan yang sangat mudah ditemui, ramah lingkungan dan cukup ekonomis. Keberadaan biomassa dapat dimaanfaatkan sebagai pengganti bahan bakar fosil, baik itu minyak bumi, gas alam maupun batu bara. Analisi diperlukan sebagai dasar biomassa sebagai energi seperti proksimat dan kalor. Analisis terpenting untuk menilai biomassa sebagai bahan bakar adalah nilai kalori atau higher heating value (HHV). HHV secara eksperimen diukur menggunakan bomb calorimeter, namun pengukuran ini kurang efektif, karena memerlukan waktu serta biaya yang tinggi. Penelitian mengenai prediksi HHV berdasarkan analisis proksimat telah dilakukan sehingga dapat mempermudah dan menghemat biaya yang diperlukan peneliti. Dalam makalah ini dibahas evaluasi persamaan untuk memprediksi HHV berdasarkan analisis proksimat pada biomassa berdasarkan data dari penelitian sebelumnya. Prediksi nilai HHV menggunakan lima persamaan yang dievaluasi dengan 25 data proksimat biomassa dari penelitian sebelumnya, kemudian dibandingkan berdasarkan nilai error untuk mendapatkan prediksi terbaik. Hasil analisis menunjukan, persamaan A terbaik di 7 biomassa, B di 6 biomassa, C di 6 biomassa, D di 5 biomassa dan E di 1 biomassa.Kata kunci: bahan bakar, biomassa, higher heating value, nilai error, proksimat  Abstract – Biomass is a renewable energy that is very easy to find, environmentally friendly, and quite economical. The existence of biomass can be used as a substitute for fossil fuels, both oil, natural gas, and coal. Analyzes are needed as a basis for biomass as energy such as proximate and heat. The most critical analysis to assess biomass as fuel is the calorific value or higher heating value (HHV). HHV is experimentally measured using a bomb calorimeter, but this measurement is less effective because it requires time and high costs. Research on the prediction of HHV based on proximate analysis has been carried out so that it can simplify and save costs needed by researchers. In this paper, the evaluation of equations is discussed to predict HHV based on proximate analysis on biomass-based on data from previous studies. HHV prediction values using five equations were evaluated with 25 proximate biomass data from previous studies, then compared based on error value to get the best predictions. The analysis shows that Equation A predicts best in 7 biomass, B in 6 biomass, C in 6 biomass, D in 5 biomass, and E in 1 biomass. Key words: fuel, biomass, higher heating value, error value, proximate 

Production of fuels on the basis of sewage sludge through conditioning using high calorific value fractions

2008 ◽  
Vol 3 (1) ◽  
Author(s):  
Karl-Georg Schmelz ◽  
Anja Reipa ◽  
Hartmut Meyer
Keyword(s):  
Sewage Sludge ◽  
Wastewater Treatment Plants ◽  
Treatment Plant ◽  
Calorific Value ◽  
Fluidised Bed ◽  
Sludge Treatment ◽  
Heating Value ◽  
Fine Coal ◽  
Used Cars ◽  
Plastic Components

Emschergenossenschaft and Lippeverband operate 59 wastewater treatment plants which produce approx. 100,000 Mg TS of sewage sludge each year. Using sludge pressure pipelines, about 60 % of this sludge are transported to the central sludge treatment plant in Bottrop. The digested sludges are conditioned using fine coal and polymers and are dewatered using membrane filters. By adding coal, the heating value of the sludge is raised which enables autothermal combustion of the dewatered sludges in fluidised bed furnaces at the central sludge treatment plant. In order to replace coal, a fossil fuel, as conditioning agent, experiments were conducted using alternative materials with high heating values. The addition of shredder fluff agglomerates proved to be particularly successful. Shredder fluff agglomerates are a residue from the recycling of used cars and are generated in a multistage process (e.g. Volkswagen-SiCon Process) by separating the light shredder fraction (plastic components etc.) from the total shredder fluff. The fibrous material is outstandingly suitable for improving the dewaterability and for sufficiently raising the heating value of the dewatered sludge in order to enable autothermal combustion. Since first experiments showed very positive results, a full-scale long-term test-run will take place in 2007.

Utilization of hydrogen in low calorific value producer gas derived from municipal solid waste and biodiesel for diesel engine power generation application

2016 ◽  
Vol 99 ◽  
pp. 1253-1261 ◽  
Author(s):  
V.S. Yaliwal ◽  
N.R. Banapurmath ◽  
R.S. Hosmath ◽  
S.V. Khandal ◽  
Wojciech M. Budzianowski
Keyword(s):  
Power Generation ◽  
Diesel Engine ◽  
Municipal Solid Waste ◽  
Solid Waste ◽  
Calorific Value ◽  
Producer Gas ◽  
Engine Power

scholarly journals Elementary analysis and energetic potential of the municipal sewage sludges from the Gdańsk and Kościerzyna WWTPs

2018 ◽  
Vol 26 ◽  
pp. 00004
Author(s):  
Arkadiusz Ostojski
Keyword(s):  
Sewage Sludge ◽  
Water Content ◽  
Calorific Value ◽  
High Water ◽  
Municipal Sewage ◽  
Municipal Sewage Sludge ◽  
High Water Content ◽  
Sewage Sludges ◽  
Heating Value ◽  
Elementary Analysis

This paper aims to present municipal sewage sludge (MSS) elementary analysis and energetic potential based on measurement of heat of combustion (higher heating value HHV) and calculation of calorific values (lower heating value LHV). The analysis takes into the consideration water content in sewage sludge, at different utilization stages, in wastewater treatment plants in Gdańsk Wschód and Kościerzyna – Pomeranian Voivodeship. The study yielded the following results (in % dry matter): ash 19÷31 %, C - 31÷36 %, H - 5÷6 %, N - 4÷6 %, O - 28÷32 %, S – 1 %. Calorific value of stabilized sludges in Gdańsk was on average 13.8÷15 MJ/kg. In case of sludges not undergoing digestion from Kościerzyna WWTP, the calorific value was at the level of 17.5 MJ/kg. Thus, sewage sludges are good energy carriers. High water content though is the problem, as it lowers the useful effect of heat. There is no alternative for thermal sewage sludge neutralization, which is in conformity with valid Polish National Waste Management Plan (KPGO 2022).

scholarly journals Municipal solid waste higher heating value prediction from ultimate analysis using multiple regression and genetic programming techniques

2018 ◽  
Vol 37 (6) ◽  
pp. 578-589 ◽  
Author(s):  
Imane Boumanchar ◽  
Younes Chhiti ◽  
Fatima Ezzahrae M’hamdi Alaoui ◽  
Abdelaziz Sahibed-dine ◽  
Fouad Bentiss ◽  
...  
Keyword(s):  
Genetic Programming ◽  
Municipal Solid Waste ◽  
Solid Waste ◽  
Multiple Regression ◽  
Calorific Value ◽  
Heating Value ◽  
Ultimate Analysis ◽  
Msw Management ◽  
Important Challenge ◽  
Programming Techniques

Municipal solid waste (MSW) management presents an important challenge for all countries. In order to exploit them as a source of energy, a knowledge of their calorific value is essential. In fact, it can be experimentally measured by an oxygen bomb calorimeter. This process is, however, expensive. In this light, the purpose of this paper was to develop empirical models for the prediction of MSW higher heating value (HHV) from ultimate analysis. Two methods were used: multiple regression analysis and genetic programming formalism. Both techniques gave good results. Genetic programming, however, provides more accuracy compared to published works in terms of a great correlation coefficient (CC) and a low root mean square error (RMSE).

scholarly journals Performance testing of a downdraft biomass gasifier stove for cooking applications

2018 ◽  
Vol 204 ◽  
pp. 04011
Author(s):  
Woranuch Jangsawang
Keyword(s):  
Primary School ◽  
Thermal Efficiency ◽  
Fixed Bed ◽  
Performance Testing ◽  
Rural School ◽  
High Potential ◽  
Producer Gas ◽  
Biomass Fuels ◽  
Heating Value ◽  
Gas System

A down draft biomass gasifier stove with four steps of cleaning gas system was developed to produce the producer gas for replacing LPG for cooking applications in lunch project for the student in rural school area. This project has been implemented at Bangrakam primary school that located at Pitsanuloke Province, Thailand. The biomass fuels used are Mimosa wood twigs. The gasifier stove was developed based on down draft fixed bed gasifier with the maximum fuel capacity of fourteen kilograms. The performance testing of the biomass gasifier stove showed that the heating value of the producer gas is 4.12 MJ/Nm3 with the thermal efficiency in the percentage of 85.49. The results from this study imply that it has high potential to replace LPG with producer gas.

scholarly journals Characterization of Refuse Derived Fuel Production from Municipal Solid Waste: The Case Studies in Latvia and Lithuania

2020 ◽  
Vol 24 (3) ◽  
pp. 112-118
Author(s):  
Dace Âriņa ◽  
Rūta Bendere ◽  
Gintaras Denafas ◽  
Jānis Kalnačs ◽  
Mait Kriipsalu
Keyword(s):  
Municipal Solid Waste ◽  
Solid Waste ◽  
Calorific Value ◽  
Ash Content ◽  
Fuel Production ◽  
Heating Value ◽  
Refuse Derived Fuel ◽  
Morphological Composition ◽  
The Mean

AbstractThe authors determined the morphological composition of refuse derived fuel (RDF) produced in Latvia and Lithuania by manually sorting. The parameters of RDF (moisture, net calorific value, ash content, carbon, nitrogen, hydrogen, sulphur, chlorine, metals) was determined using the EN standards. Comparing obtained results with data from literature, authors have found that the content of plastic is higher but paper and cardboard is lower than typical values. Results also show that the mean parameters for RDF can be classified with the class codes: Net heating value (3); chlorine (3); mercury (1), and responds to limits stated for 3rd class of solid recovered fuel. It is recommended to separate biological waste at source to lower moisture and ash content and increase heating value for potential fuel production from waste.

Experimental of Wood Gasification in Suction Biomass Gasifier

2012 ◽  
Vol 626 ◽  
pp. 1020-1026
Author(s):  
Muhammad Iqbal Ahmad ◽  
Zainal Alimuddin Zainal Alauddin ◽  
Shahril Nizam Mohamed Soid ◽  
Mohamed Mazlan ◽  
Mohd Huzaifah Yusoff
Keyword(s):  
Experimental Work ◽  
Feeding Rate ◽  
Stable Condition ◽  
Producer Gas ◽  
Carbon Conversion ◽  
Heating Value ◽  
Gasification Process ◽  
Result Show ◽  
Widespread Availability ◽  
Gas Conversion

Biomass is one of the alternatives energy which are abundant, relatively cheap, and widespread availability. This paper is aim to show the process finding according experimental work of wood using suction biomass gasifier. Energy can be extracted from biomass through gasification process. The experiment focuses on woody gasification. A suction biomass gasifier has been built and operated under stable condition which fueled from wood waste and air as gasifying agent. The biomass feeding rate was varied from 3 to 5.5kg/hr. Result show that producer gas contains CO in 20-30% in volume and H2 found to be varying between 14 and16% vol. The low heating value (LHV) from this woody gasification around 4-5 MJ/Nm3. Carbon conversion efficiency also measured as a parameter to indicate biomass-gas conversion.

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