scholarly journals Cassava starch-chitosan-sorghum micro-fibrillated cellulose biocomposite wrapping film to prevent COVID-19 outspread

2021 ◽  
Vol 914 (1) ◽  
pp. 012075
Author(s):  
K W Prasetiyo ◽  
F A Syamani ◽  
Y R Amalia ◽  
R Ermawati ◽  
D Fatimah ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Acetic Anhydride ◽  
Modulus Of Elasticity ◽  
Cassava Starch ◽  
The Other ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Raw Starch ◽  
Soda Pulping ◽  
Virus Spreading

Abstract To prevent virus spreading, the corpse or the coffin of COVID-19 patients need to be wrapped in plastic. Low-density polyethylene (LDPE), a crude oil-based wrapping plastic, is difficult to decompose in nature after use. In this study, biocomposite wrapping film was developed from cassava starch and chitosan, with the addition of sorghum Micro-Fibrillated Cellulose (MFC) by levels of 1%, 2%, 3%, 4% and 5%. Cassava starch (raw starch) was modified by acetic anhydride to produce acetylated cassava starch (acetylated starch) which is less hydrophilic thus enhance the compounding ability with LDPE. The sorghum MFC was obtained from sorghum fibers after following processes: soda pulping, bleaching and fibrillation with a super grinder. The addition of 1% sorghum MFC into raw starch-chitosan increased the tensile strength and modulus of elasticity by 33% and 17%, respectively. On the other hand, the addition of 2% sorghum MFC into acetylated starch-chitosan increased the elongation by 38%. Wrapping film needs to have good elongation ability so that it can be stretched during application. Based on elongation characteristic, acetylated cassava starch-chitosan with addition of 2% sorghum MFC can be developed to be a candidate for biocomposite wrapping film to prevent COVID-19 outspread.

Characterization of Gamma Irradiated PP/LDPE Blend

2014 ◽  
Vol 353 ◽  
pp. 90-95
Author(s):  
Tatiana Mayumi Moori ◽  
Mauro Cesar Terence ◽  
Nilson Casimiro Pereira ◽  
Sonia Braunstein Faldini ◽  
Leila Figueiredo de Miranda
Keyword(s):  
Tensile Strength ◽  
Gamma Rays ◽  
The Other ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Average Increase ◽  
Polymeric Chains ◽  
Before And After ◽  
Gamma Irradiated

This study analyzed nine polypropylene (PP) and low-density polyethylene (LDPE) blends where the mass concentrations of each sample were changed, proportionally. The aim was to investigate the tensile strength by means of these polymers best combination, before and after its exposal to gamma rays. The results showed that the 20/80 - PP/LDPE blend had a better performance concerning mechanical properties after irradiation, where the maximums tensile stress had an average increase of 30% in 30 and 50 kGy doses and 33% in the 200 kGy dose. On the other hand, it was verified that the higher blend's PP concentration, the higher its tensile strength will be (except for 100 kGy and 200 kGy doses which PP concentration over 70% can cause eventual degradation in the polymeric chains of the blend).

scholarly journals Improvement of Tensile Properties of Recycled Low-Density Polyethylene by Incorporation of Calcium Carbonate Particles

2018 ◽  
Vol 8 (3) ◽  
Author(s):  
Raed Ma’ali ◽  
Shadi Sawalha ◽  
Omar Surkhi ◽  
Amani Hamarsheh ◽  
Sabreen Yacoub ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Calcium Carbonate ◽  
Tensile Properties ◽  
Modulus Of Elasticity ◽  
Degree Of Crystallinity ◽  
Low Density Polyethylene ◽  
Carbonate Content ◽  
Low Density ◽  
Filler Particles ◽  
Recycled Low Density Polyethylene

Plastics are used in versatile applications including automobile, packaging, piping and house goods, these huge uses attribute in the consumption of the oil reserves and the emerged waste harm the environment when it disposed irregularly. Recycling of plastics is one of the realistic solutions to the aforementioned problems and to reduce production cost. However, the reduction in mechanical properties of recycled plastics limit their use and thus reinforced plastics become popular because of their high mechanical, physical and thermal properties. The effects of calcium carbonate content from 0 to 15 wt.% on the tensile properties of recycled low-density polyethylene (RLDPE) were tested, the addition of calcium carbonate particles up to 15 wt.% was found to enhance the tensile strength and modulus of elasticity of RLDPE samples. Three calcium carbonate particle sizes (80, 200 and 500 µm) were mixed with RLDPE to investigate the effect of particles size on the tensile properties of RLDPE, it was found that the addition of small filler particles resulted in a noticeable improvement of tensile strength and modulus of elasticity of RLDPE compared with large filler particles. It was also observed that the addition of stearic acid slightly improves tensile properties of RLDPE which may be related to improvement of the interfacial adhesion between the filler and RLDPE. The crystallization temperature and the degree of crystallinity of RLDPE were increased by the addition of 7.5 wt.% calcium carbonate particles because they act as nucleating agents.

scholarly journals Properties of Low-Cost WPCs Made from Alien Invasive Trees and rLDPE for Interior Use in Social Housing

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2436
Author(s):  
Abubakar Sadiq Mohammed ◽  
Martina Meincken
Keyword(s):  
Tensile Strength ◽  
Water Absorption ◽  
Social Housing ◽  
Low Cost ◽  
Production Costs ◽  
Low Density Polyethylene ◽  
Low Grade ◽  
Low Density ◽  
Invasive Trees ◽  
Recycled Low Density Polyethylene

Low-cost wood–plastic composites (WPCs) were developed from invasive trees and recycled low-density polyethylene. The aim was to produce affordable building materials for low-cost social housing in South Africa. Both raw materials are regarded as waste materials, and the subsequent product development adds value to the resources, while simultaneously reducing the waste stream. The production costs were minimised by utilising the entire biomass of Acacia saligna salvaged from clearing operations without any prior processing, and low-grade recycled low-density polyethylene to make WPCs without any additives. Different biomass/plastic ratios, particle sizes, and press settings were evaluated to determine the optimum processing parameters to obtain WPCs with adequate properties. The water absorption, dimensional stability, modulus of rupture, modulus of elasticity, tensile strength, and tensile moduli were improved at longer press times and higher temperatures for all blending ratios. This has been attributed to the crystallisation of the lignocellulose and thermally induced cross-linking in the polyethylene. An increased biomass ratio and particle size were positively correlated with water absorption and thickness swelling and inversely related with MOR, tensile strength, and density due to an incomplete encapsulation of the biomass by the plastic matrix. This study demonstrates the feasibility of utilising low-grade recycled polyethylene and the whole-tree biomass of A. saligna, without the need for pre-processing and the addition of expensive modifiers, to produce WPCs with properties that satisfy the minimum requirements for interior cladding or ceiling material.

Effect of fillers on mechanical properties of recycled low density polyethylene composites under weathered condition

2020 ◽  
Vol 15 (3) ◽  
pp. 44-49
Author(s):  
Ibiyemi A. Idowu ◽  
Olutosin O. Ilori
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Pure Water ◽  
Mechanical Tests ◽  
Filler Loading ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Hardness Property ◽  
Recycled Low Density Polyethylene ◽  
Polyethylene Composites

The study examined the effect of fillers on the mechanical properties of the recycled low density polyethylene composites under weathered condition with a view of managing the generation and disposal of plastic wastes. Discarded pure water sachets and fillers (glass and talc) were sourced and recycled. Recycled low density polyethylene (RLDPE) and preparation of RLDPE/glass, RLDPE/talc and RLDPE/glass/talc composites were carried out using a furnace at compositions of 0 – 40% in steps of 10% by weight. The mixtures were poured into hand-laid mould. The samples produced were exposed to sunlight for eight (8) weeks and their mechanical properties were studied. The results of mechanical tests revealed that tensile strength decreased with increasing filler loading while impact strength and hardness property increased marginally and considerably with increasing filler loading for all the composites respectively. The study concluded that glass and talc were able to reinforce recycled low density polyethylene under weathered condition. Keywords: Recycled Low Density Polyethylene (RLDPE); Fillers; Glass, Talc; Weathering condition; Sunlight; and Mechanical properties; Tensile strength, Impact and hardness

Effect of Functionalized MWCNTs with Surfactant and Coupling Agent on Properties of LDPE/POE Blends

2011 ◽  
Vol 43 (6) ◽  
pp. 543-558 ◽  
Author(s):  
Z. Chen ◽  
S. Chen ◽  
J. Zhang
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Tensile Strength ◽  
Multiwalled Carbon Nanotubes ◽  
Crystallization Behavior ◽  
Low Density Polyethylene ◽  
Favorable Effect ◽  
Low Density ◽  
Multiwalled Carbon ◽  
Polyolefin Elastomer

The surfactant, sodium dodecylbenzenesulfonate (NaDDBS) and coupling agents, γ-aminopropyltriethoxy sliane (KH550) and isopropyl dioleic(dioctylphosphate) titanate (NDZ101) were used to treat multiwalled carbon nanotubes in this work. The effects of surface modification of multiwalled carbon nanotubes on crystallization behavior, mechanical properties, and electrical properties of low density polyethylene/polyolefin elastomer/multiwalled carbon nanotubes composites were studied. The results showed that NaDDBS, KH550, and NDZ101 had a favorable effect of improving the dispersion of multiwalled carbon nanotubes, but it cannot improve the interfacial interactionbetween multiwalled carbon nanotubes and the matrix. The improvement in dispersion favored the crystallization behavior and mechanical properties. Modified multiwalled carbon nanotubes had a better acceleration nucleation effect than raw multiwalled carbon nanotubes on low density polyethylene/polyolefin elastomer blends at low content (≤1 wt%). The tensile strength of low density polyethylene/polyolefin elastomer/multiwalled carbon nanotubes composites with modified multiwalled carbon nanotubes increased with lower multiwalled carbon nanotubes content (≤1 wt%), and KH550 and NDZ101 led low density polyethylene/polyolefin elastomer/multiwalled carbon nanotubes composites to possess a higher tensile strength than that of NaDDBS with 1 wt% content. NaDDBS, KH550, and NDZ101 had a minor influence on the dielectric properties of the composites and even caused a decrease in the dielectric loss of composites with 10 wt% multiwalled carbon nanotubes content.

Effect of the blow-up ratio on morphology and engineering properties of three-layered linear low-density polyethylene blown films

2017 ◽  
Vol 34 (1) ◽  
pp. 27-42 ◽  
Author(s):  
Suthakarn Auksornkul ◽  
Siriwat Soontaranon ◽  
Chonthicha Kaewhan ◽  
Pattarapan Prasassarakich
Keyword(s):  
Electron Microscopy ◽  
Tensile Strength ◽  
Transverse Direction ◽  
Blow Up ◽  
Engineering Properties ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Film Morphology ◽  
Linear Low Density Polyethylene ◽  
Machine Direction

A series of linear low-density polyethylene films were produced using a three-layer co-extrusion machine. How the blow-up ratio and resin characteristics affected the final film morphology and engineering properties were studied. The crystalline morphology and orientation during the blown film process of the low-density polyethylene film were investigated using small-angle X-ray scattering, transmission electron microscopy and scanning electron microscopy. Increasing the blow-up ratio increased the transverse direction molecular orientation and decreased the machine direction orientation. The resulting low-density polyethylene morphology was a regular lamellar stacking parallel to the machine direction. The film morphology strongly influenced the mechanical properties. Increasing the blow-up ratio from 1.7 to 2.8 decreased the machine direction tensile strength by 14% and increased the transverse direction tensile strength up to 27% for both the low-density polyethylene/1-butene and low-density polyethylene/1-octene co-monomers, while the machine direction tear strength increased up to 36% and the transverse direction decreased by 16%. Moreover, the first and second heating characteristics from differential scanning calorimeter showed the inherent crystallinity change with increasing blow-up ratio for both the low-density polyethylene/1-octene and the low-density polyethylene/1-butene copolymer. The crystalline orientation changes induced with increasing blow-up ratio affected the film water vapor and oxygen permeability.

Investigation of Novel Polymer Composites Based on Recycled Multilayer Combined Packaging Materials

2020 ◽  
Vol 299 ◽  
pp. 94-99
Author(s):  
Vasily Ovchinnikov ◽  
Elena E. Mastalygina ◽  
Petr Pantyukhov
Keyword(s):  
Tensile Strength ◽  
Composite Material ◽  
High Density Polyethylene ◽  
Elasticity Modulus ◽  
Low Density Polyethylene ◽  
Packaging Materials ◽  
Low Density ◽  
Destruction Process ◽  
Hard Particles ◽  
Blended Polymer

Polymer composite based on multilayer combined packaging wastes was prepared and investigated. The composite was made of tetrahedral package wastes, where cardboard part was removed. It was found that obtained composite material has blended polymer matrix that consists of low-density polyethylene, high-density polyethylene and polypropylene. Melting temperature of individual polymers in composite shifts to lower temperatures than that of the initial components. It is the evidence of destruction process or interaction between polymers. The hard particles of aluminum and cellulose are uniformly distributed in the composite. For that reason, these particles do not reduce melt fluidity significantly. The tensile strength and elasticity modulus are higher for the obtained material compared to pure polyethylene. The results show a high potential for the use of the developed composite material.

scholarly journals Effect of Heat Drawing Process on Mechanical Properties of Dry-Jet Wet Spun Fiber of Linear Low Density Polyethylene/Carbon Nanotube Composites

2017 ◽  
Vol 2017 ◽  
pp. 1-9
Author(s):  
Jong Won Kim ◽  
Joon Seok Lee
Keyword(s):  
Mechanical Properties ◽  
Plastic Deformation ◽  
Tensile Strength ◽  
Polymer Materials ◽  
Degree Of Crystallinity ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Drawing Process ◽  
Linear Low Density Polyethylene ◽  
Crystallinity Degree

Polyethylene is one of the most commonly used polymer materials. Even though linear low density polyethylene (LLDPE) has better mechanical properties than other kinds of polyethylene, it is not used as a textile material because of its plastic behavior that is easy to break at the die during melt spinning. In this study, LLDPE fibers were successfully produced with a new approach using a dry-jet wet spinning and a heat drawing process. The fibers were filled with carbon nanotubes (CNTs) to improve the strength and reduce plastic deformation. The crystallinity, degree of orientation, mechanical properties (strength to yield, strength to break, elongation at break, and initial modulus), electrical conductivity, and thermal properties of LLDPE fibers were studied. The results show that the addition of CNTs improved the tensile strength and the degree of crystallinity. The heat drawing process resulted in a significant increase in the tensile strength and the orientation of the CNTs and polymer chains. In addition, this study demonstrates that the heat drawing process effectively decreases the plastic deformation of LLDPE.

The Properties of Linear Low Density Polyethylene/Cyperus Odoratus (LLDPE/CY) Blends: Effect of Sodium Hydroxide

2015 ◽  
Vol 815 ◽  
pp. 69-73 ◽  
Author(s):  
Nik Ahmad Faris Nik Abdullah ◽  
Nik Noriman Zulkepli ◽  
Sam Sung Ting ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Kamarudin Hussin ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Sodium Hydroxide ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Natural Fibers ◽  
Biodegradable Plastics ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Linear Low Density Polyethylene ◽  
Naoh Solution

The purpose of this study was to determine the effect of treated Cyperus Odoratus (CY) with sodium hydroxide (NaOH) on the properties of biodegradable plastics made from linear low density polyethylene (LLDPE)/CY blends. Alkali treatments for natural fibers can increased adhesion between the hydrophilic fibers and hydrophobic matric. After CY was treated with 5% NaOH solution, it can be seen that the tensile strength and Young’s modulus of the LLDPE/CY blends significantly increased. Therefore, alkali treatments can be considered in modifying the properties of natural fibers.

Investigation of Epoxidized Natural Rubber (ENR 50) as a Compatibilizer on Cogon Grass Filled Low Density Polyethylene/Soya Spent Flour

2014 ◽  
Vol 803 ◽  
pp. 310-316 ◽  
Author(s):  
S.T. Sam ◽  
Nurul Hani ◽  
H. Ismail ◽  
Nik Noriman ◽  
S. Ragunathan
Keyword(s):  
Tensile Strength ◽  
Fourier Transform ◽  
Natural Rubber ◽  
Water Absorption ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Fourier Transform Infrared ◽  
Epoxidized Natural Rubber ◽  
Low Density Polyethylene ◽  
Low Density

Natural fiber reinforced composites are increasingly being used in various applications area. Therefore, the processing method and physical properties of these composites are very important parameters in product quality and quaranty. This paper focused on the tensile properties, Fourier transform infrared (FTIR) and water absorption of cogon grass (CG) with low density polyethylene (LDPE)/soya spent flour (SSF) composites. The tensile strength and elongation at break (Eb) of uncompatibilized CG with LDPE/ SSF decreased significantly with increasing of fiber content. However, the Young’s modulus increased with increasing of CG loading. The presence of epoxidized natural rubber (ENR 50) as a compatibilizer increased the tensile strength, Eband Young’s modulus of the composites when compared to uncompatibilized composites. Fourier transform infrared results show distinguishable peaks for compatibilized and uncompatibilized composites. The water absorption for both uncompatibilized and compatibilized composites increased from day 1 until day 21. The presence of ENR 50 as compatibilizer showed lower water absorption percentage compared to uncompatibilized composites.

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