scholarly journals Mechanical Performance of High-Density Polyethylene (HDPE) Composites Containing Quarry Dust Filler

2021 ◽  
Vol 945 (1) ◽  
pp. 012075
Author(s):  
Fu Yee Xuen ◽  
Kwan Wai Hoe ◽  
Yamuna Munusamy

Abstract An innovative thermoplastic composite was produced using quarry dust which is an industrial waste from quarry industries. The quarry dust was added into high-density polyethylene (HDPE) using melt blending technique in an internal mixer at different mixing loading ratios. The quarry dust filled HDPE (QD-HDPE) composites were then characterized in terms of morphological and mechanical properties. Analysis on processing torque to produce QD-HDPE composites was conducted and the results showed that the optimum quarry dust loading in HDPE composites is at 30wt%. The results from mechanical test such as ultimate tensile strength (UTS), E-modulus, elongation at break, and flexural strength justify this. Scanning Electron Microscopy (SEM) analysis shows that quarry dust had a rough surface with sharp edges and it can be successfully added into HDPE matrix as a filler. In conclusion, performance of the HDPE composites is enhanced by the incorporation of quarry dust. This indicates that quarry dust is a potential filler to be used in thermoplastic composite industries in order to reduce the production cost and relax the pollution problems.

Author(s):  
Joshua Bachert ◽  
A. H. M. E. Rahman ◽  
Ma'moun Abu-Ayyad

Both high corrosion costs and an over-abundance of plastic waste have significant global impacts. This research seeks to help in both areas by utilizing recycled plastic as an anticorrosive coating. Many plastic-based coatings, especially those developed in more recent years, already contain recycled content. This research, which utilizes 100% recycled high density polyethylene (HDPE) as a powder coat, will add to the increasingly sustainable catalog of anti-corrosive coatings. The HDPE was applied to mild steel samples with traditional electrostatic powder coating equipment. The coating thickness was measured using scanning electron microscope (SEM) characterized and was found to be roughly 116 μm. The SEM analysis did not reveal any porosity in the coating. The immersion corrosion test in 5% H2SO4 for 2–3 days showed corrosion products at the bottom of the beaker. The maximum corrosion obtained was 424.4 mills/year (mpy) after 70.45 hours of immersion and the minimum corrosion obtained was 0.0 mpy after 5.58 hours of immersion. The acid immersion tests indicated that the corrosion started from the edges and advanced towards the inner surfaces. The coating on the edges was not uniform and may be porous. The salt immersion test in 5% NaCl solution by mass showed the sign of corrosion products after 5.5 hours and increased with time. A few samples showed corrosion over 25% of the surface after 70.5 hours of immersion. This is again attributed to the fact that the edges were not coated completely. The corrosion resistance can be improved by avoiding the sharp edges on the part.


2019 ◽  
Vol 54 (14) ◽  
pp. 1831-1845 ◽  
Author(s):  
Abu Sadat Muhammad Sayem ◽  
Julfikar Haider ◽  
MM Alamgir Sayeed

The bast fibres, a subgroup of natural fibre family, have emerged as a strong competitor of widely used man-made glass fibre for use as fillers or reinforcing materials in certain types of composite materials, which do not require very high mechanical resistance. This paper investigates the manufacturing of multi-layered jute fabric-reinforced thermoplastic composite and its mechanical performance. Hessian jute fabrics in two, four and six layers without any pre-treatment were sandwiched in 0° orientation into seven layers of high-density polyethylene sheets and pressed at high temperature and pressure to form composite laminates having three different structural designs. The laminates with two, four and six layers contain approximately 6.70 wt%, 12.90 wt% and 18.50 wt% of jute fibres, respectively. Mechanical performance of the composite laminates having four and six layers of jute fabric was found to have improved significantly when compared to the pure high-density polyethylene laminates. Within a given sample thickness of 6.5 mm, the laminate with six layers of jute fabric exhibited the best mechanical performance. Optical microscopic analysis revealed that the yarn orientation of the fabrics within the composites remained stable, and there was no visible void in the laminate structure. Fracture morphology of the composite investigated by a scanning electron microscope showed good adhesion of the jute fabrics with the high-density polyethylene matrix.


2019 ◽  
Vol 69 (4) ◽  
pp. 313-321
Author(s):  
Xiaoxia Hu ◽  
Zhenghao Chen ◽  
Yang Cao ◽  
Zhangjing Chen ◽  
Shuangbao Zhang ◽  
...  

Abstract The focus of this study was to observe the properties of bamboo plastic composites modified with a self-made modifier, 18 acyl-dopamine (0, 0.25, 0.50, 0.75, 1.00, and 1.25 weight percent [wt%] based on the dry weight of bamboo powder). The effects of the modifier were demonstrated by measures of mechanical properties, water absorption, thermal stability, and scanning electron microscopy (SEM). The results revealed that 18 acyl-dopamine could be used as an effective modifier of bamboo powder/high-density polyethylene composites. When the modifier was increased, the toughness of the composite deteriorated, and the strength and rigidity improved. This indicated that when the dosage became higher, the compatibilization became stronger, and the toughening effect became worse. Based on the experimental data, a small dosage modifier acted as a toughening agent; as the dosage increased to 1.0 wt%, the compatibility began to appear. The modifier reacted with the hydroxyl groups on the surface of the bamboo powder, which caused the bamboo powder to absorb less water, so the thickness expansion rate was lowest at 1.25 wt%. The pyrolysis peak of bamboo powder and plastic showed a tendency to be close to each other, indicating that the interface was improving. Based on the equation of Flynn-Wall-Ozawa, as the dosage of the modifier increased from 0.50 to 1.25 wt%, the apparent activation energy also increased. The SEM analysis showed the binding between bamboo powder and the plastic matrix was strongest when the modifier dosage was 1.25 wt%.


2021 ◽  
Vol 9 (1) ◽  
pp. 248-256
Author(s):  
J.A. dos Santos ◽  
R.C. Tucunduva ◽  
J.R.M. D’Almeida

Polymer pipes are being widely used by many industrial segments. Although not affected by corrosion, the mechanical performance of these pipes can be reduced due to exposure to temperature, UV radiation and by contact with various fluids. Depending on the deterioration process, embrittlement or plasticization may occur, and the service life of the pipe can be severely reduced. In this work, the combined action of temperature and water upon the mechanical performance of polyamide 12 and high-density polyethylene pipes is evaluated. Destructive and non-destructive techniques were used and the performance of both materials was compared. Both polymers were platicized by the effect of water. However, for high density polyethylene the effect of temperature was more relevant than for polyamide. This behavior was attributed to the dependence of the free volume with the markedly different glass transition temperature of the polymers and the temperatures of testing.


2020 ◽  
Vol 10 ◽  
pp. 48-55
Author(s):  
H. V. Allakhverdiyeva ◽  
◽  
N. T. Kakhramanov ◽  
I. I. Ismayilov ◽  
◽  
...  

The paper presents the results of a study of the effect of aluminum content on the physic-mechanical properties of composites based on high density polyethylene and low density polyethylene. The properties of metal-filled composites, such as ultimate tensile stress, elongation at break, elastic module, melt flow rate, and heat resistance, were studied. According to the data obtained, the loading of aluminum into the composition of low density polyethylene contributes to a monotonic increase in the ultimate tensile stress and the elastic module. When aluminum is loading into the composition of high density polyethylene, on the contrary, a natural decrease in the ultimate tensile stress and elongation at break of the composites is observed. It is shown that when using a compatibilizer, which is polyethylene modified with maleic anhydride, a significant increase in the ultimate tensile stress of high-density polyethylene composites is observed. A schematic representation of the structure of composites with an interpretation of the probable mechanism of hardening of the material in the presence of a compatibilizer is given. It is shown that the crystallinity of the initial polyethylene has a significant effect on the hardening effect of composites. Electron microscopic micrographs of the structure of a filled composite without and with compatibilizer are given. A comparative assessment shows that in the presence of a compatibilizer, aluminum particles are in the bulk of the polymer matrix, i.e. are not in an isolated state. It is assumed that HDPE macrochains free of maleic anhydride (MA) are involved in the formation of crystalline formations, and small sections of macrosegments containing polar groups of MA are concentrated mainly in amorphous regions and in defects in crystalline structures in the form of passage chains. The concentration of PEMA macrosegments containing MA in the narrow amorphous space of HDPE favorably affects the increase in the adhesive forces of interaction on the surface of aluminum particles, which affects the preservation of the ultimate tensile stress at a relatively high level over a wide range of aluminum concentrations.


2015 ◽  
Vol 754-755 ◽  
pp. 201-204
Author(s):  
Ragunathan Santiagoo ◽  
Sam Sung Ting ◽  
Azlinda Abdul Ghani ◽  
Hanafi Ismail ◽  
Awiezan Mislan

The compatibilizer effect of ENR-50 on the tensile properties of high density polyethylene (HDPE)/recycled acrylonitrile butadiene rubber (NBRr)/banana skin powder (BSP)/ composites has been studies. HDPE/NBRr/BSP composites were prepared by melt mixing technique using twin-screw at 180 °C for 9 minutes at rotor speed 50 rpm. The six different composites studied were 100/0/5, 80/20/5, 70/30/5, 60/40/5, 50/50/5, and 40/60/5. As for compatibilized composite a fix 5 wt% of ENR-50 was evaluated. The specimens were analysed for tensile strength and elongation at break (Eb). The results showed that tensile strength and the elongation at break were decreases with the increasing of NBRr loading. However for ENR-50 compatibilized composites, higher tensile strength and elongation at break was recorded. The ENR-50 was found to be an excellent compatibilizer for HDPE/NBRr/BSP composites.


2012 ◽  
Vol 178-181 ◽  
pp. 897-900
Author(s):  
Ming Shan Yang ◽  
Lin Kai Li

The modification process of recycled melamine-formaldehyde(MF) plastic on high-density polyethylene(HDPE) has been studied, and the optimal compounding parameters were obtained by twin extruding system in this paper. The results showed that with increasing of recycled MF plastic in PE, the tensile strength, elongation at break, molding shrinkage and impact strength decreased, the modulus, heat distortion temperature(HDT) and melt flow rate(MFR) increased, which indicates that the addition of recycled MF plastic can improve rigidity, heat resistance, size stability and flowability of HDPE. More importantly, the oxygen index(OI) of HDPE was increased with the addition of recycled MF plastic, which indicates that recycled MF plastic can improve the flame-retardant property of HDPE.


2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Henry C. Obasi

Blends of nonbiodegradable and biodegradable polymers can promote a reduction in the volume of plastic waste when they undergo partial degradation. In this study, properties of raphia palm interspersed fibre (RPIF) filled high density polyethylene (HDPE) have been investigated at different levels of filler loadings, 0 to 60 wt.%. Maleic anhydride-graft polyethylene was used as a compatibilizer. Raphia palm interspersed fibre was prepared by grinding and sieved to a particle size of 150 µm. HDPE blends were prepared in a corotating twin screw extruder. Results showed that the tensile strength and elongation at break of the blends decreased with increase in RPI loadings and addition of MA-g-PE was found to improve these properties. However, the Young’s modulus increased with increase in the amount of RPI into HDPE and compatibilization further increased the Young’s modulus. The water absorption indices and weight loss for RPI/HDPE composites were found to increase with RPI loadings but were decreased on addition of MA-g-PE.


2014 ◽  
Vol 34 (9) ◽  
pp. 813-821 ◽  
Author(s):  
Gaurav Madhu ◽  
Haripada Bhunia ◽  
Pramod K. Bajpai ◽  
Veena Chaudhary

Abstract Polyblend films were prepared from high-density polyethylene (HDPE) and poly(l-lactic acid) (PLLA) up to 20% PLLA by the melt blending method in an extrusion mixer with post-extrusion blown film attachment. The 80/20 (HDPE/PLLA) blend was compatibilized with maleic anhydride grafted polyethylene (PE-g-MA) in varying ratios [up to 8 parts per hundred of resin (phr)]. Tensile properties of the films were evaluated to obtain optimized composition for packaging applications of both non-compatibilized and compatibilized blends. The compositions HDPE80 (80% HDPE and 20% PLLA) and HD80C4 (80% HDPE, 20% PLLA and 4 phr compatibilizer) were found to be optimum for packaging applications. However, better tensile strength (at yield) and elongation (at break) of 80/20 (HDPE/PLLA) blend were noticed in the presence of PE-g-MA. Further, thermal properties and morphologies of these blends were evaluated. Differential scanning calorimetry (DSC) study revealed that blending does not much affect the crystalline melting point of HDPE and PLLA, but heat of fusion of 80/20 (HDPE/PLLA) blend was decreased as compared to that of neat HDPE. Spectroscopy studies showed evidence of the introduction of some new groups in the blends and gaining compatibility in the presence of PE-g-MA. The compatibilizer influenced the morphology of the blends, as apparent from scanning electron microscopy (SEM) and supported by Fourier transform infrared (FTIR).


2015 ◽  
Vol 754-755 ◽  
pp. 215-219
Author(s):  
Ismail Yuhaida ◽  
Husseinsyah Salmah ◽  
Hanafi Ismail ◽  
Zainuddin Firuz

Wollastonite is one type of inorganic filler. The effects of wollastonite loading on tensile properties of wollastonite (WS) filled high density polyethylene (HDPE)/Natural Rubber (NR) composites was studied. The HDPE/NR/WS composites were prepared by using Brabender EC Plus at a temperature of 180 °C with rotor speed of 50 rpm for 10 min. It was found that the increasing of wollastonite loading had decreased the tensile strength and elongation at break, whereas the Young’s modulus of the HDPE/NR/WS composites had increased with the increasing of wollastonite loading.


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