The direct measurement of the isothermal Joule-Thomson coefficient for gases

1953 ◽  
Vol 218 (1132) ◽  
pp. 133-143 ◽  
Keyword(s):  
Carbon Dioxide ◽  
Nitrous Oxide ◽  
Direct Measurement ◽  
Direct Measurements ◽  
New Apparatus ◽  
Thomson Coefficient

A new apparatus is described for measuring the isothermal Joule-Thomson coefficient. The results obtained agree well with other direct measurements and also with adiabatic Joule-Thomson and compressibility data. The gases which have been investigated are nitrogen, ethylene, carbon dioxide and nitrous oxide, in the range 0 to 45° C and 0 to 45 atm.

The isothermal Joule-Thomson coefficient of some binary gas mixtures

1955 ◽  
Vol 230 (1182) ◽  
pp. 354-358 ◽  
Keyword(s):  
Carbon Dioxide ◽  
Nitrous Oxide ◽  
Statistical Theory ◽  
Binary Mixtures ◽  
Pressure Coefficient ◽  
Gas Mixtures ◽  
Thomson Coefficient ◽  
Mixed Gases ◽  
Limiting Value

The limiting value at zero pressure of the isothermal Joule -Thomson coefficient has been measured from 0 to 45° C for the mixtures carbon dioxide + nitrous oxide, carbon dioxide + ethylene, nitrous oxide + ethylene, and nitrous oxide + nitrogen. These measurements are compared with a statistical theory of mixed gases composed of non-spherical molecules. The change of the zero-pressure coefficient with composition in the binary mixtures is shown to agree better with the calculated values for mixtures of non-spherical molecules than those for mixtures of spherical molecules.

Tidal rewetting in salt marshes triggers pulses of nitrous oxide emissions but slows carbon dioxide emission

2021 ◽  
Vol 156 ◽  
pp. 108197
Author(s):  
Hollie E. Emery ◽  
John H. Angell ◽  
Akaash Tawade ◽  
Robinson W. Fulweiler
Keyword(s):  
Carbon Dioxide ◽  
Nitrous Oxide ◽  
Salt Marshes ◽  
Carbon Dioxide Emission ◽  
Nitrous Oxide Emissions

scholarly journals Greenhouse gas emissions from the water–air interface of a grassland river: a case study of the Xilin River

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Xue Hao ◽  
Yu Ruihong ◽  
Zhang Zhuangzhuang ◽  
Qi Zhen ◽  
Lu Xixi ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Land Use ◽  
Nitrous Oxide ◽  
Greenhouse Gas Emissions ◽  
Greenhouse Gas ◽  
Ghg Emissions ◽  
Nitrous Oxide Emissions ◽  
Gas Emissions ◽  
Sand Land ◽  
Very High

AbstractGreenhouse gas (GHG) emissions from rivers and lakes have been shown to significantly contribute to global carbon and nitrogen cycling. In spatiotemporal-variable and human-impacted rivers in the grassland region, simultaneous carbon dioxide, methane and nitrous oxide emissions and their relationships under the different land use types are poorly documented. This research estimated greenhouse gas (CO2, CH4, N2O) emissions in the Xilin River of Inner Mongolia of China using direct measurements from 18 field campaigns under seven land use type (such as swamp, sand land, grassland, pond, reservoir, lake, waste water) conducted in 2018. The results showed that CO2 emissions were higher in June and August, mainly affected by pH and DO. Emissions of CH4 and N2O were higher in October, which were influenced by TN and TP. According to global warming potential, CO2 emissions accounted for 63.35% of the three GHG emissions, and CH4 and N2O emissions accounted for 35.98% and 0.66% in the Xilin river, respectively. Under the influence of different degrees of human-impact, the amount of CO2 emissions in the sand land type was very high, however, CH4 emissions and N2O emissions were very high in the artificial pond and the wastewater, respectively. For natural river, the greenhouse gas emissions from the reservoir and sand land were both low. The Xilin river was observed to be a source of carbon dioxide and methane, and the lake was a sink for nitrous oxide.

Cross-bridge blocker BTS permits direct measurement of SR Ca2+ pump ATP utilization in toadfish swimbladder muscle fibers

2003 ◽  
Vol 285 (4) ◽  
pp. C781-C787 ◽  
Author(s):  
Iain S. Young ◽  
Claire L. Harwood ◽  
Lawrence C. Rome
Keyword(s):  
Sarcoplasmic Reticulum ◽  
Direct Measurement ◽  
Motor Behavior ◽  
Force Generation ◽  
Skinned Fibers ◽  
Control Value ◽  
Cross Bridge ◽  
Direct Measurements ◽  
Hill Coefficients ◽  
Cross Bridges

Because the major processes involved in muscle contraction require rapid utilization of ATP, measurement of ATP utilization can provide important insights into the mechanisms of contraction. It is necessary, however, to differentiate between the contribution made by cross-bridges and that of the sarcoplasmic reticulum (SR) Ca2+ pumps. Specific and potent SR Ca2+ pump blockers have been used in skinned fibers to permit direct measurement of cross-bridge ATP utilization. Up to now, there was no analogous cross-bridge blocker. Recently, N-benzyl- p-toluene sulfonamide (BTS) was found to suppress force generation at micromolar concentrations. We tested whether BTS could be used to block cross-bridge ATP utilization, thereby permitting direct measurement of SR Ca2+ pump ATP utilization in saponin-skinned fibers. At 25 μM, BTS virtually eliminates force and cross-bridge ATP utilization (both <4% of control value). By taking advantage of the toadfish swimbladder muscle's unique right shift in its force-Ca2+ concentration ([Ca2+]) relationship, we measured SR Ca2+ pump ATP utilization in the presence and absence of BTS. At 25 μM, BTS had no effect on SR pump ATP utilization. Hence, we used BTS to make some of the first direct measurements of ATP utilization of intact SR over a physiological range of [Ca2+]at 15°C. Curve fits to SR Ca2+ pump ATP utilization vs. pCa indicate that they have much lower Hill coefficients (1.49) than that describing cross-bridge force generation vs. pCa (∼5). Furthermore, we found that BTS also effectively eliminates force generation in bundles of intact swimbladder muscle, suggesting that it will be an important tool for studying integrated SR function during normal motor behavior.

Nitrous oxide and carbon dioxide emissions from monoculture and rotational cropping of corn, soybean and winter wheat

2008 ◽  
Vol 88 (2) ◽  
pp. 163-174 ◽  
Author(s):  
C F Drury ◽  
X M Yang ◽  
W D Reynolds ◽  
N B McLaughlin
Keyword(s):  
Carbon Dioxide ◽  
Nitrous Oxide ◽  
Winter Wheat ◽  
Carbon Dioxide Emissions ◽  
Crop Residue ◽  
Agricultural Land ◽  
Application Rate ◽  
Climatic Conditions ◽  
Growing Seasons ◽  
Previous Crop

It is well established that nitrous oxide (N2O) and carbon dioxide (CO2) emissions from agricultural land are influenced by the type of crop grown, the form and amount of nitrogen (N) applied, and the soil and climatic conditions under which the crop is grown. Crop rotation adds another dimension that is often overlooked, however, as the crop residue being decomposed and supplying soluble carbon to soil biota is usually from a different crop than the crop that is currently growing. Hence, the objective of this study was to compare the influence of both the crop grown and the residues from the preceding crop on N2O and CO2 emissions from soil. In particular, N2O and CO2 emissions from monoculture cropping of corn, soybean and winter wheat were compared with 2 -yr and 3-yr crop rotations (corn-soybean or corn-soybean-winter wheat). Each phase of the rotation was measured each year. Averaged over three growing seasons (from April to October), annual N2O emissions were about 3.1 to 5.1 times greater in monoculture corn (2.62 kg N ha-1) compared with either monoculture soybean (0.84 kg N ha-1) or monoculture winter wheat (0.51 kg N ha-1). This was due in part to the higher inorganic N levels in the soil resulting from the higher N application rate with corn (170 kg N ha-1) than winter wheat (83 kg N ha-1) or soybean (no N applied). Further, the previous crop also influenced the extent of N2O emissions in the current crop year. When corn followed corn, the average N2O emissions (2.62 kg N ha-1) were about twice as high as when corn followed soybean (1.34 kg N ha-1) and about 60% greater than when corn followed winter wheat (1.64 kg N ha-1). Monoculture winter wheat had about 45% greater CO2 emissions than monoculture corn or 51% greater emissions than monoculture soybean. In the corn phase, CO2 emissions were greater when the previous crop was winter wheat (5.03 t C ha-1) than when it was soybean (4.20 t C ha-1) or corn (3.91 t C ha-1). Hence, N2O and CO2 emissions from agricultural fields are influenced by both the current crop and the previous crop, and this should be accounted for in both estimates and forecasts of the emissions of these important greenhouse gases. Key words: Denitrification, soil respiration, rotation, crop residue

scholarly journals Pineapple Residue Ash Reduces Carbon Dioxide and Nitrous Oxide Emissions in Pineapple Cultivation on Tropical Peat Soils at Saratok, Malaysia

2021 ◽  
Vol 13 (3) ◽  
pp. 1014
Author(s):  
Liza Nuriati Lim Kim Choo ◽  
Osumanu Haruna Ahmed ◽  
Nik Muhamad Nik Majid ◽  
Zakry Fitri Abd Aziz
Keyword(s):  
Carbon Dioxide ◽  
Nitrous Oxide ◽  
Peat Soil ◽  
Nitrous Oxide Emissions ◽  
N2o Emissions ◽  
Peat Soils ◽  
Closed Chamber ◽  
Npk Fertilizers ◽  
Npk Fertilizer ◽  
Carbon Dioxide Co2

Burning pineapple residues on peat soils before pineapple replanting raises concerns on hazards of peat fires. A study was conducted to determine whether ash produced from pineapple residues could be used to minimize carbon dioxide (CO2) and nitrous oxide (N2O) emissions in cultivated tropical peatlands. The effects of pineapple residue ash fertilization on CO2 and N2O emissions from a peat soil grown with pineapple were determined using closed chamber method with the following treatments: (i) 25, 50, 70, and 100% of the suggested rate of pineapple residue ash + NPK fertilizer, (ii) NPK fertilizer, and (iii) peat soil only. Soils treated with pineapple residue ash (25%) decreased CO2 and N2O emissions relative to soils without ash due to adsorption of organic compounds, ammonium, and nitrate ions onto the charged surface of ash through hydrogen bonding. The ability of the ash to maintain higher soil pH during pineapple growth primarily contributed to low CO2 and N2O emissions. Co-application of pineapple residue ash and compound NPK fertilizer also improves soil ammonium and nitrate availability, and fruit quality of pineapples. Compound NPK fertilizers can be amended with pineapple residue ash to minimize CO2 and N2O emissions without reducing peat soil and pineapple productivity.

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