A model for the simultaneous heterogeneous and homogeneous nucleation of gas bubbles

1979 ◽  
Vol 368 (1734) ◽  
pp. 331-343 ◽  
Keyword(s):  
Heterogeneous Nucleation ◽  
Homogeneous Nucleation ◽  
Bubble Nucleation ◽  
Rate Theory ◽  
Rare Gases ◽  
Bubble Density ◽  
Competitive Mechanism ◽  
The Matrix ◽  
Arrhenius Energy ◽  
First Time

Electron microscope observations of cavities in steels have shown that they are often associated with microstructural features as well as occurring randomly in the matrix. Previous theoretical studies of gas bubble nucleation have concentrated on either homogeneous or heterogeneous nucleation. In the present work we extend the homogeneous nucleation rate theory for rare gases in solids to include, for the first time, the competitive mechanism of heterogeneous nucleation. The model indicates that the temperature dependence of the bubble density varies as the binding energy between a trap and a single gas atom is changed, and provides an interpretation of the high Arrhenius energy found from observed cavity densities.

Bubbles and element clusters in rock melts: A chicken and egg problem

2021 ◽  
Author(s):  
Renelle Dubosq ◽  
Pia Pleše ◽  
Brian Langelier ◽  
Baptiste Gault ◽  
David Schneider
Keyword(s):  
Heterogeneous Nucleation ◽  
Homogeneous Nucleation ◽  
Growth Dynamics ◽  
Gas Bubbles ◽  
Atom Probe ◽  
Bubble Nucleation ◽  
Interface Element ◽  
Rich Cluster ◽  
Heterogeneous Distribution ◽  
Rapid Decompression

<p>The nucleation and growth dynamics of gas bubbles and crystals play a vital function in determining the eruptive behaviour of a magma. Their rate and relative timing, among other factors, are controlled by the magma’s ascent rate. Investigating the kinetics of decompression-induced degassing and crystallization processes can thus give us insight into the rheology of magmas. For example, the rapid decompression of magmas inhibits microlite crystallization and bubble nucleation during ascent leading to crystallization and degassing at shallow levels. This results in a drastic increase in viscosity and an over pressured system, which can lead to violent eruptions. Although many experiments and numerical simulations of magma decompression have been carried out, nascent and initial bubble nucleation remain poorly understood. It is widely accepted that there are two ways bubbles can nucleate within a melt: heterogeneous (on a pre-existing surface) and homogeneous nucleation (within the melt), where homogeneous nucleation requires a higher volatile supersaturation. It has since been tentatively suggested that homogeneous nucleation is simply a variety of heterogeneous nucleation where nucleation occurs on the surface of submicroscopic crystals. However, evidence of these crystals is equivocal. Thus, we have combined novel 2D and 3D structural and chemical microscopy techniques including scanning transmission electron microscopy (STEM), electron energy-loss spectroscopy (EELS) mapping, and atom probe tomography (APT) to investigate the presence of sub-nanometer scale chemical heterogeneities in the vicinity of gas bubbles within an experimental andesitic melt. The combined STEM and EELS data reveal a heterogeneous distribution of bubbles within the melt ranging between 20-100 nm in diameter, some of which have Fe and/or Ca element clusters at the bubble-melt interface. Element clusters enriched in Fe, Ca, and Na are also observed heterogeneously distributed within the melt. The reconstructed APT data reveals bubbles as low ionic density regions overlain by a Na-, Ca-, and K-rich cluster and heterogeneously distributed Fe clusters within the bulk of the melt. Based on these observations, our data demonstrate the existence of nano-scale chemical heterogeneities within the melt and at the bubble-melt interface of bubbles that were previously interpreted to be nucleated homogeneously within the melt, therefore contributing to the proposed hypothesis that homogeneous nucleation could in fact be a variety of heterogeneous nucleation. These results highlight the need to redefine homogeneous nucleation and revisit whether bubbles or crystals occur first within volcanic melts. </p>

Lattice imaging of precipitates in Al-Zn-Mg alloy

1986 ◽  
Vol 44 ◽  
pp. 412-413
Author(s):  
C. K. Wu
Keyword(s):  
Grain Boundaries ◽  
Homogeneous Nucleation ◽  
Alloy System ◽  
Mg Alloy ◽  
List Type ◽  
Lattice Structures ◽  
Type Number ◽  
Orientation Relationships ◽  
Lattice Imaging ◽  
The Matrix

The precipitation phenomenon in Al-Zn-Mg alloy is quite interesting and complicated and can be described in the following categories:(i) heterogeneous nucleation at grain boundaries;(ii) precipitate-free-zones (PFZ) adjacent to the grain boundaries;(iii) homogeneous nucleation of snherical G.P. zones, n' and n phases inside the grains. The spherical G.P. zones are coherent with the matrix, whereas the n' and n phases are incoherent. It is noticed that n' and n phases exhibit plate-like morpholoay with several orientation relationship with the matrix. The high resolution lattice imaging techninue of TEM is then applied to study precipitates in this alloy system. It reveals the characteristics of lattice structures of each phase and the orientation relationships with the matrix.

Amorphous silica coating on α-alumina particles

1995 ◽  
Vol 53 ◽  
pp. 210-211
Author(s):  
J. W. Mellowes ◽  
C. M. Chun ◽  
I. A. Aksay
Keyword(s):  
Amorphous Silica ◽  
Heterogeneous Nucleation ◽  
Homogeneous Nucleation ◽  
Silica Coating ◽  
Full Density ◽  
Optimal Conditions ◽  
Fine Grained ◽  
Alumina Particles ◽  
Complete Mullitization ◽  
Powder Compacts

Mullite (3Al2O32SiO2) can be fabricated by transient viscous sintering using composite particles which consist of inner cores of a-alumina and outer coatings of amorphous silica. Powder compacts prepared with these particles are sintered to almost full density at relatively low temperatures (~1300°C) and converted to dense, fine-grained mullite at higher temperatures (>1500°C) by reaction between the alumina core and the silica coating. In order to achieve complete mullitization, optimal conditions for coating alumina particles with amorphous silica must be achieved. Formation of amorphous silica can occur in solution (homogeneous nucleation) or on the surface of alumina (heterogeneous nucleation) depending on the degree of supersaturation of the solvent in which the particles are immersed. Successful coating of silica on alumina occurs when heterogeneous nucleation is promoted and homogeneous nucleation is suppressed. Therefore, one key to successful coating is an understanding of the factors such as pH and concentration that control silica nucleation in aqueous solutions. In the current work, we use TEM to determine the optimal conditions of this processing.

Optimization of thermal conductivity in composites loaded with the solid-solid phase-change materials

2018 ◽  
Vol 25 (6) ◽  
pp. 1157-1165
Author(s):  
Taoufik Mnasri ◽  
Adel Abbessi ◽  
Rached Ben Younes ◽  
Atef Mazioud
Keyword(s):  
Thermal Conductivity ◽  
Phase Change ◽  
Phase Change Materials ◽  
Solid Phase ◽  
Spherical Inclusions ◽  
First Case ◽  
The Matrix ◽  
Composite Conductivity ◽  
First Time

AbstractThis work focuses on identifying the thermal conductivity of composites loaded with phase-change materials (PCMs). Three configurations are studied: (1) the PCMs are divided into identical spherical inclusions arranged in one plane, (2) the PCMs are inserted into the matrix as a plate on the level of the same plane of arrangement, and (3) the PCMs are divided into identical spherical inclusions arranged periodically in the whole matrix. The percentage PCM/matrix is fixed for all cases. A comparison among the various situations is made for the first time, thus providing a new idea on how to insert PCMs into composite matrices. The results show that the composite conductivity is the most important consideration in the first case, precisely when the arrangement plane is parallel with the flux and diagonal to the entry face. In the present work, we are interested in exploring the solid-solid PCMs. The PCM polyurethane and a wood matrix are particularly studied.

Direct Nucleation of Crystalline SiGe on Substrates by Reactive Thermal CVD with Si2H6 and GeF4

1997 ◽  
Vol 467 ◽  
Author(s):  
Fumio Yoshizawa ◽  
Kunihiro Shiota ◽  
Daisuke Inoue ◽  
Jun-ichi Hanna
Keyword(s):  
Growth Rate ◽  
Gas Phase ◽  
Heterogeneous Nucleation ◽  
Homogeneous Nucleation ◽  
Film Growth ◽  
Early Stage ◽  
Gaseous Mixture ◽  
The Other ◽  
Thermal Cvd ◽  
Initial Deposition

ABSTRACTPolycrystalline SiGe (poly-SiGe) film growth by reactive thermal CVD with a gaseous mixture of Si2H6 and GeF4 was investigated on various substrates such as Al,Cr, Pt, Si, ITO, ZnO and thermally grown SiO2.In Ge-rich film growth, SEM observation in the early stage of the film growth revealed that direct nucleation of crystallites took place on the substrates. The nucleation was governed by two different mechanisms: one was a heterogeneous nucleation on the surface and the other was a homogeneous nucleation in the gas phase. In the former case, the selective nucleation was observed at temperatures lower than 400°C on metal substrates and Si, where the activation of adsorbed GeF4 on the surface played a major role for the nuclei formation, leading to the selective film growth.On the other hand, the direct nucleation did not always take place in Si-rich film growth irrespective of the substrates and depended on the growth rate. In a growth rate of 3.6nm/min, the high crystallinity of poly-Si0.95Ge0.05in a 220nm-thick film was achieved at 450°C due to the no initial deposition of amorphous tissue on SiO2 substrates.

scholarly journals LMI-Based Stability Criterion of Impulsive T-S Fuzzy Dynamic Equations via Fixed Point Theory

2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
Ruofeng Rao ◽  
Zhilin Pu
Keyword(s):  
Fixed Point ◽  
Stability Criterion ◽  
High Efficiency ◽  
Fixed Point Theory ◽  
Point Theory ◽  
Linear Matrix ◽  
The Matrix ◽  
Matrix Exponential Function ◽  
Takagi Sugeno ◽  
First Time

By formulating a contraction mapping and the matrix exponential function, the authors apply linear matrix inequality (LMI) technique to investigate and obtain the LMI-based stability criterion of a class of time-delay Takagi-Sugeno (T-S) fuzzy differential equations. To the best of our knowledge, it is the first time to obtain the LMI-based stability criterion derived by a fixed point theory. It is worth mentioning that LMI methods have high efficiency and other advantages in largescale engineering calculations. And the feasibility of LMI-based stability criterion can efficiently be computed and confirmed by computer Matlab LMI toolbox. At the end of this paper, a numerical example is presented to illustrate the effectiveness of the proposed methods.

scholarly journals Controlling Condensation of Water Using Hybrid Hydrophobic-Hydrophilic Surfaces

2010 ◽  
Author(s):  
Kripa K. Varanasi ◽  
Tao Deng
Keyword(s):  
Nucleation Rate ◽  
Heterogeneous Nucleation ◽  
Energy Barrier ◽  
Superhydrophobic Surfaces ◽  
Industrial Processes ◽  
Spatial Control ◽  
Hydrophilic Surfaces ◽  
Wide Range ◽  
First Time ◽  
Control Water

Heterogeneous nucleation of water plays an important role in wide range of natural and industrial processes. Though heterogeneous nucleation of water is ubiquitous and everyday experience, spatial control of this important phenomenon is extremely difficult. Here we show, for the first time, that spatial control in the heterogeneous nucleation of water can be achieved by manipulating the local nucleation energy barrier and nucleation rate via the modification of the local intrinsic wettability of a surface by patterning hybrid hydrophobic-hydrophilic regions on a surface. Such ability to control water nucleation could address the condensation-related limitations of superhydrophobic surfaces, and has implications for efficiency enhancements in energy and desalination systems.

Graphite/UPE Nanocomposite: Transport, Thermal, Mechanical and Viscoelastic Properties

2019 ◽  
Vol 23 ◽  
pp. 201-212
Author(s):  
Shivkumari Panda ◽  
Dibakar Behera ◽  
Tapan Kumar Bastia
Keyword(s):  
Transport Properties ◽  
Unsaturated Polyester ◽  
Homogeneous Distribution ◽  
Thermo Gravimetric ◽  
New Class ◽  
The Matrix ◽  
Novel Method ◽  
Water Transport Properties ◽  
First Time

This chapter presents the preparation and characterization of some unique properties of nanocomposites by dispersing graphite flakes in commercial unsaturated polyester (UPE) matrix. The composite was prepared by a novel method with the use of solvent swelling technique. Three different specimens of UPE/graphite nanocomposites were fabricated with addition of 1, 2 and 3 wt% of graphite flakes. Except mechanical, viscoelastic and thermo gravimetric properties, transport properties like electrical conductivity, thermal conductivity and water transport properties were studied for the first time. Graphite flakes propose enhanced properties to the composites suggesting homogeneous distribution of the nanofiller in the matrix and strong interaction with the matrix. 2wt% nanofiller loading showed superior essential characteristics and after that the properties reduced may be due to the nucleating tendency of the nanofiller particles. The XRD pattern showed the compatibility of the graphite flakes by introducing a peak around 26.550 in the nanocomposites. SEM Properties are also in agreement with the compatibility. Nanocomposite with 2wt% graphite also showed remarkable enhancement in transport, mechanical, viscoelastic and thermo gravimetric properties. So by introduction of a small quantity of graphite endow the new class of multiphase nanocomposites with inimitable structure and tremendous application.

scholarly journals Explore the Effects of Fertilization on Polyphenols Content in Autumn of Forages from Hill Permanent Grassland by Principal Component & Classifications Analysis

2011 ◽  
Vol 68 (1) ◽  
Author(s):  
Monica HARMANESCU
Keyword(s):  
Colorimetric Method ◽  
Principal Component ◽  
Floristic Composition ◽  
Classification Analysis ◽  
Permanent Grassland ◽  
Different Types ◽  
The Matrix ◽  
Chemometric Techniques ◽  
First Time

Principal Components and Classification Analysis (PC&CA) represents one of the most utilised multivariate chemometric techniques, having the advantage to use many measurements for a single sample in the same time, being recommended for understanding better the complexity of one phenomenon. The aim of this paper was to use PC&CA to study the effects of different types of fertilizers on polyphenols content of forages harvested in autumn from permanent grassland. Gravimetrically was established the matrix of floristic composition. The experimental field was fertilized first time in 2003, organic and/or NPK mineral. The determination of polyphenols contents was made using UV-VIS SPECORD 205 spectrophotometer, in conformity to chemical Folin and Ciocalteu colorimetric method. The highest polyphenols content was identified in forages from unfertilized variant (108 µM gallic acid/g). PC&CA can be a useful tool in describing the modification of polyphenols contents of forages under the effects of organic and/or mineral fertilisation of permanent grassland.

Crystal Nucleation in Submicron Droplets of Pure Elements

1993 ◽  
Vol 321 ◽  
Author(s):  
Louis M. Holzman ◽  
Thomas F. Kelly ◽  
W. N. G. Hitchon
Keyword(s):  
Heterogeneous Nucleation ◽  
Homogeneous Nucleation ◽  
Crystal Nucleation ◽  
Droplet Radius ◽  
Electrohydrodynamic Atomization ◽  
Submicron Droplets ◽  
Diffraction Patterns

ABSTRACTLiquid-to-crystal nucleation has been studied extensively through droplet experiments to locate examples of homogeneous nucleation. However, prior to this work very few examples have been found, which implies that the experiments have not been able to isolate heterogeneous nucleants in a small percentage of the droplets as is required. In this research, electrohydrodynamic atomization (EHD) is used to produce sub-Micron droplets of pure elements that are largely free of heterogeneous nucleants.Diffraction patterns of individual EHD-produced droplets are viewed to determine the fraction of crystalline droplets produced as a function of droplet radius. These results are compared to theories for surface and volume heterogeneous nucleation and for homophase nucleation. It is found that Si and Ge nucleate through either homogeneous nucleation or nucleation by homophase impurities. Nucleation results for vanadium and iron were not conclusive.

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