The relation between porosity, microstructure and strength, and the approach to advanced cement-based materials

1983 ◽  
Vol 310 (1511) ◽  
pp. 139-153 ◽  
Keyword(s):  
Elastic Modulus ◽  
Fracture Energy ◽  
Cement Paste ◽  
Compression Strength ◽  
Bending Strength ◽  
Cement Pastes ◽  
Cement Based Materials ◽  
Mdf Cements

A theory is formulated to connect the strength of cement paste with its porosity. The theory shows that bending strength is largely dictated by the length of the largest pores, as in the Griffith (1920) model, but there is also an influence of the volume of porosity, which affects toughness through changing elastic modulus and fracture energy. Verification of this theory was achieved by observing the large pores in cement, and then relating bending strength to the measured defect length, modulus and fracture energy. The argument was proved by developing processes to remove the large pores from cement pastes, thereby raising the bending strength to 70 MPa. Further removal of colloidal pores gave a bending strength of 150 MPa and compression strength up to 300 MPa with improved toughness. Re-introduction of controlled pores into these macro-defect-free (mdf) cements allowed Feret’s law (1897) to be explained.

Preparation of MgO- and CaO-Bearing Expansive Agent Used for Cement-Based Materials

2013 ◽  
Vol 539 ◽  
pp. 211-214 ◽  
Author(s):  
Li Wu Mo ◽  
Yang Deng ◽  
An Qun Lu ◽  
Min Deng
Keyword(s):  
Cement Paste ◽  
Rapid Expansion ◽  
Curing Temperature ◽  
Cement Pastes ◽  
Expansive Agent ◽  
Mineral Phases ◽  
Mix Proportion ◽  
Cement Based Materials

Blended expansive agents consisting of MgO and CaO were prepared by calcining the mixtures of dolomite and magnesite. The mineral phases and microstructures of expansive agent were examined by XRD and SEM. The expansion properties of cement pastes containing 5% and 6% of expansive agent as well as the microstructure of hydrated expansive agent in cement paste were investigated. Results indicated that the contents of MgO and CaO in the blended expansive agent could be adjusted by changing the mix proportion of dolomite and magnesite. All the cement pastes containing expansive agent produced rapid expansion. At the same addition dosage, irrespective of curing temperature, expansive agent containing higher content of MgO produced greater expansion in cement pastes, particularly at late age, which probably ascribes to the relatively slow hydration of MgO.

Prediction of Elastic Modulus of Cement-Based Materials Based on Power’s Volume Model

2012 ◽  
Vol 253-255 ◽  
pp. 474-477 ◽  
Author(s):  
Lang Wu ◽  
Bing Yan ◽  
Bin Lei
Keyword(s):  
Elastic Modulus ◽  
Elastic Properties ◽  
Cement Paste ◽  
Cement Ratio ◽  
Water Cement Ratio ◽  
Micromechanics Model ◽  
Volume Model ◽  
Cement Based Materials ◽  
Hydrated Products ◽  
Multi Phase

The hydrated products, unhydrated cement and water (capillary pores) in the cement paste are seen as matrix, inclusion, Equivalent medium respectively, We used the micromechanics theories and Power’s Volume model to develop a multi-phase micromechanics model capable of simulating the elastic properties of cement-based materials, and the evolution of elastic properties in the hydration process was calculated at different water-cement ratio. The final experimental results show that this model can be used to predict the elastic properties of cement-based materials.

Application of a-SiO2 Rich Additives in Cement Paste

2015 ◽  
Vol 749 ◽  
pp. 362-367 ◽  
Author(s):  
Jaroslav Pokorný ◽  
Milena Pavlíková ◽  
Eva Navrátilová ◽  
Pavla Rovnaníková ◽  
Zbyšek Pavlík ◽  
...  
Keyword(s):  
Cement Paste ◽  
Bending Strength ◽  
Setting Time ◽  
Chemical Properties ◽  
Xrd Analysis ◽  
Fast Reaction ◽  
Cement Pastes ◽  
Matrix Density ◽  
Physical And Chemical ◽  
And Chemical Properties

The effect of a-SiO2 of various origin on the properties of cement paste with incorporated different silica containing materials is experimentally studied in the paper. For the applied a-SiO2 materials, basic physical and chemical properties are accessed, together with their chemical composition. Amount of amorphous phase of SiO2 in particular siliceous materials is determined using XRD analysis. Matrix density, bulk density, total open porosity, compressive and bending strength are measured for all developed pastes with incorporated a-SiO2 containing materials, together with initial and final setting time of fresh mixtures. The obtained data give evidence on a high and fast reaction activity of tested siliceous materials which results in a significant improvement of porosity and mechanical strength of a-SiO2 modified cement pastes.

Fracture Properties of Ultra-High Strength Cement-Based Materials

2017 ◽  
Vol 726 ◽  
pp. 553-557
Author(s):  
Qing Bi ◽  
Wu Yao
Keyword(s):  
Fracture Toughness ◽  
Elastic Modulus ◽  
Bending Strength ◽  
Strain Energy Release ◽  
High Strength ◽  
Defect Size ◽  
Theoretical Derivation ◽  
Fracture Properties ◽  
Working Stress ◽  
Cement Based Materials

By combining the three-point bending beam test with theoretical derivation, the elastic modulus, fracture toughness, surface energy and the maximum defect size permissible under certain working stress of ultra-high strength cement-based materials were obtained. The fracture properties were studied with the water to binder ratios (W/B) from 0.18 to 0.14. Test results showed that the ultra-high strength cement-based materials are quasi-brittle and the net bending strength of specimen decreased substantially when there was a notch. The elastic modulus of ultra-high strength cement-based materials can be up to 74.0 GPa, obviously higher than that of ordinary cement-based materials, showing greater elastic deformation resistance. Moreover, with decrease of W/B ratio, the compressive strength, fracture toughness, critical strain energy release rate as well as the maximum defect size permissible under certain working stress of ultra-high strength cement-based materials increased significantly, indicating that the anti-cracking ability increased with the decrease of W/B ratio.

Influences of Latex and Mixing Procedure on Mechanical Properties of Hardened Cement Paste(II)

2015 ◽  
Vol 1129 ◽  
pp. 538-545
Author(s):  
D. Han ◽  
W. Chen ◽  
S. Zhong
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Elastic Modulus ◽  
Flexural Strength ◽  
Fracture Energy ◽  
Cement Paste ◽  
Apparent Density ◽  
Hardened Cement ◽  
Hardened Cement Paste

In this study,influences of latex and mixing procedure on flexural strength, compressive strength, elastic modulus and apparent fracture energy of hardened cement paste mixed with polycarboxylate (PC) as superplasticizer were analyzed. The results show that, the apparent density of fresh latex modified cement paste (LMCP) and the compressive strength of the hardened LMCP were reduced 1%-8% and 0-28% respectively compared with the control, while the flexural strength and apparent fracture energy were increased 11%-70% and 22%-157% respectively. In generally, the mixing procedure had gentle effect on the mechanical properties of harden LMCP with the same mp/mc, while the different mp/mc and latex types had greater impact. The amounts of polymer adsorbed changed by mixing procedure and had significantly effect on the properties fresh LMCP while very little on the harden LMCP.

scholarly journals Effect of Calcium Nitrate on the Properties of Portland–Limestone Cement-Based Concrete Cured at Low Temperature

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1611
Author(s):  
Gintautas Skripkiūnas ◽  
Asta Kičaitė ◽  
Harald Justnes ◽  
Ina Pundienė
Keyword(s):  
Compressive Strength ◽  
Cement Paste ◽  
Setting Time ◽  
Calcium Nitrate ◽  
Curing Temperature ◽  
Hardened Concrete ◽  
Cement Pastes ◽  
Initial Setting Time ◽  
Initial Setting ◽  
Early Strength

The effect of calcium nitrate (CN) dosages from 0 to 3% (of cement mass) on the properties of fresh cement paste rheology and hardening processes and on the strength of hardened concrete with two types of limestone-blended composite cements (CEM II A-LL 42.5 R and 42.5 N) at different initial (two-day) curing temperatures (−10 °C to +20 °C) is presented. The rheology results showed that a CN dosage up to 1.5% works as a plasticizing admixture, while higher amounts demonstrate the effect of increasing viscosity. At higher CN content, the viscosity growth in normal early strength (N type) cement pastes is much slower than in high early strength (R type) cement pastes. For both cement-type pastes, shortening the initial and final setting times is more effective when using 3% at +5 °C and 0 °C. At these temperatures, the use of 3% CN reduces the initial setting time for high early strength paste by 7.4 and 5.4 times and for normal early strength cement paste by 3.5 and 3.4 times when compared to a CN-free cement paste. The most efficient use of CN is achieved at −5 °C for compressive strength enlargement; a 1% CN dosage ensures the compressive strength of samples at a −5 °C initial curing temperature, with high early strength cement exceeding 3.5 MPa but being less than the required 3.5 MPa in samples with normal early strength cement.

Quantitative Characterization of Hydration of Cement Pastes by Rietveld Phase Analysis and Thermoanalysis

2013 ◽  
Vol 539 ◽  
pp. 19-24 ◽  
Author(s):  
Yong Qi Wei ◽  
Wu Yao
Keyword(s):  
Phase Analysis ◽  
Cement Paste ◽  
Rietveld Method ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Quantitative Characterization ◽  
Cement Pastes ◽  
Hydration Mechanism ◽  
Spot Check

The quantitative characterization of hydration of cement pastes has always been one of focuses of researchers’ attention. Rietveld phase analysis (RPA), a combination of quantitative X-ray diffraction (QXRD) and the Rietveld method, supplies a tool of an enormous potential for that. Although a few of related researches were conducted by RPA, the reported attention was not paid to the neat cement paste with a low w/c ratio. Therefore, this work aimed at the quantitative study on hydration of such a cement paste chiefly by this method, meanwhile, cooperated with the hyphenated technique of thermogravimetry with differential scanning calorimetry (TG-DSC), as a spot check. Results indicated that RPA was a reliable method in quantitatively characterizing hydration of cement pastes, and gave a clear decription of evolution of all main crystal phases in cement pastes; and that the evolution of monosulphate(Afm_12) was also able to be tracked quantitatively. This will help to understand better the hydration mechanism of cement pastes, as well as to investigate quantitatively effects of mineral and chemical admixtures on hydration of composite cementitious systems.

The Influence of Various Gypsum Dosage, Specific Area of Cement and Water Reducers on Bleeding of Fresh Cement Paste Using Low-Field NMR

2021 ◽  
Vol 1036 ◽  
pp. 255-262
Author(s):  
Yan Liang Ji ◽  
Zhen Ping Sun ◽  
Min Pang
Keyword(s):  
Cement Paste ◽  
Specific Area ◽  
High Water ◽  
Low Permeability ◽  
Cement Pastes ◽  
Bleeding Rate ◽  
Low Field ◽  
Low Field Nmr ◽  
Type Water ◽  
Hot Zone

Based on the low-field NMR, this study inveitigated bleeding property of the fresh cement pastes mixed with various gypsum dosage, specific area of cement and water reducers. Results showed that the gypsum dosage between 3 % and 5 % will cause an decrease bleeding and a lower bleeding velocity, while a 1 % gypsum dosage will increase the bleeding as a function of time. The increase of the cement surface will lead to a less bleeding rate. This can be explained that the finer particle will contribute to the packing which will form a low permeability of the cement paste, as a result less bleeding water is observed. The PCEs-made sample has smaller hot zone area which indocated the PCEs has good bleeding stability when varing water cement ratio. Furthermore, bying comparing with the NPE, it was found the ACS type water reducer has higher bleeding sensitivity when high water cement ratios were used.

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