Self-repairing CFRPs targeted towards structural aerospace applications

2016 ◽  
Vol 7 (5) ◽  
pp. 656-670 ◽  
Author(s):  
Marialuigia Raimondo ◽  
Felice De Nicola ◽  
Ruggero Volponi ◽  
Wolfgang Binder ◽  
Philipp Michael ◽  
...  

Purpose The purpose of this paper is to describe the first experiments to manufacture self-healing carbon fiber reinforced panels (CFRPs) for the realization of structural aeronautic components in order to address their vulnerability to impact damage in the real service conditions. Design/methodology/approach The developed self-healing system is based on ring-opening metathesis polymerizations reaction of microencapsulated 5-ethylidene-2-norbornene/dicyclopentadiene cyclic olefins using Hoveyda-Grubbs’ first generation catalyst as initiator. In this work, the self-healing resin is infused into a carbon fiber dry preform using an unconventional bulk film infusion technique that has allowed to minimize the filtration effects via a better compaction and reduced resin flow paths. Infrared spectroscopy provides a useful way to identify metathesis products and therefore catalyst activity in the self-healing panel after damage. The damage resistance of the manufactured CFRPs is evaluated through hail and drop tests. Findings The self-healing manufactured panels show, after damage, catalyst activity with metathesis product formation, as evidenced by an infrared peak at 966 cm−1. The damage response of CFRPs, detected in accord to the requirements of hail impact for the design of a fuselage in composite material, is very good. The results are very encouraging and can constitute a solid basis for bringing this new technology to the self-healable fiber reinforced resins for aerospace applications. Originality/value In this paper, autonomically healing CFRPs with damage resistance and self-healing function are proposed. In the development of self-healing aeronautic materials it is critical that self-healing activity functions in adverse weather conditions and at low working temperatures which can reach values as low as −50°C.

2018 ◽  
Vol 9 (6) ◽  
pp. 723-736 ◽  
Author(s):  
Elisa Calabrese ◽  
Pasquale Longo ◽  
Carlo Naddeo ◽  
Annaluisa Mariconda ◽  
Luigi Vertuccio ◽  
...  

PurposeThe purpose of this paper is to highlight the relevant role of the stereochemistry of two Ruthenium catalysts on the self-healing efficiency of aeronautical resins.Design/methodology/approachHere, a very detailed evaluation on the stereochemistry of two new ruthenium catalysts evidences the crucial role of the spatial orientation of phenyl groups in the N-heterocyclic carbene ligands in determining the temperature range within the curing cycles is feasible without deactivating the self-healing mechanisms (ring-opening metathesis polymerization reactions) inside the thermosetting resin. The exceptional activity and thermal stability of the HG2MesPhSyncatalyst, with the syn orientation of phenyl groups, highlight the relevant potentiality and the future perspectives of this complex for the activation of the self-healing function in aeronautical resins.FindingsThe HG2MesPhSyncomplex, with the syn orientation of the phenyl groups, is able to activate metathesis reactions within the highly reactive environment of the epoxy thermosetting resins, cured up to 180°C, while the other stereoisomer, with the anti-orientation of the phenyl groups, does not preserve its catalytic activity in these conditions.Originality/valueIn this paper, a comparison between the self-healing functionality of two catalytic systems has been performed, using metathesis tests and FTIR spectroscopy. In the field of the design of catalytic systems for self-healing structural materials, a very relevant result has been found: a slight difference in the molecular stereochemistry plays a key role in the development of self-healing materials for aeronautical and aerospace applications.


2004 ◽  
Vol 261-263 ◽  
pp. 295-300
Author(s):  
Han Ki Yoon ◽  
Jae Hyup Lee ◽  
Yi Hyun Park ◽  
J.S. Park

Carbon fiber reinforced aluminum layer laminate (CARALL), which were consisted of various numbers of CFRP prepregs, adhesive films and aluminum sheets, were fabricated by an autoclave. Impact damage behaviors of carbon fiber reinforced plastic (CFRP) and CARALL were investigated. The impact damage resistance of CARALL was significantly higher than that of CFRP. Compression after impact (CAI) tests was conducted to investigate the effect of impact damage on the compression strength of CARALL and CFRP specimens. The CAI strength of CFRP and CARALL decreased with increase of impact energy. However, CAI strength of CARALL is higher than that of CFRP, which can be attributed to the excellent impact damage absorbability of aluminum sheet in CARALL.


2011 ◽  
Vol 66-68 ◽  
pp. 683-687 ◽  
Author(s):  
Li Zhang ◽  
Yan Jue Gong ◽  
Shuo Zhang

By designing the different formulations of the composites and adopting optimized technology including extrusion and molding, the effects of the Micro-capsules on the properties of nylon composites are analyzed by the impact property test. The mechanical impact property of the glass fiber reinforced nylon composites is influenced little if the content of the self-healing microcapsules added is less than 3.5%, and the technology of self-healing microcapsules used in the polymer composite gear is feasible.


2016 ◽  
Vol 68 (2) ◽  
pp. 212-219 ◽  
Author(s):  
Juan Wu ◽  
Ziming Kou ◽  
Gongjun Cui

Purpose – The purpose of this paper is to prepare carbon fiber-reinforced polyimide matrix composites and to investigate the single role of carbon fiber in polyimide composites on tribological performance under distilled water condition. Design/methodology/approach – Three carbon fiber-reinforced polyimide matrix composites were fabricated by using a hot press molding technique. The tribological behaviors of carbon fiber-reinforced polyimide matrix composites sliding against steel ball were evaluated with a ball-on-disk tribotester under distilled water condition. Meanwhile, the effect of different length of carbon fiber on the wear resistance of polyimide matrix composites was investigated during the sliding process. Findings – The friction coefficients and specific wear rates of polyimide composites containing 100 μm carbon fibers were lower than those of other specimens. The wear mechanism of carbon fiber-reinforced composites was delamination under distilled water condition. The interfacial combination between the carbon fiber and matrix became worse with the increase of length of carbon fiber. Originality/value – This paper reported the effect of the different length of carbon fiber on polyimide matrix composites to prepare mechanical parts in mining industrial fields.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Mervin Ealiyas Mathews ◽  
Anand N ◽  
Diana Andrushia A ◽  
Tattukolla Kiran ◽  
Khalifa Al-Jabri

PurposeBuilding elements that are damaged by fire are often strengthened by fiber wrapping techniques. Self-compacting concrete (SCC) is an advanced building material that is widely used in construction due to its ability to flow and pass through congested reinforcement and fill the required areas easily without compaction. The aim of the research work is to examine the flexural behavior of SCC subjected to elevated temperature. This research work examines the effect of natural air cooling (AC) and water cooling (WC) on flexural behavior of M20, M30, M40 and M50 grade fire-affected retro-fitted SCC. The results of the investigation will enable the designers to choose the appropriate repair technique for improving the service life of structures.Design/methodology/approachIn this study, an attempt has been made to evaluate the flexural behavior of fire exposed reinforced SCC beams retrofitted with laminates of carbon fiber reinforced polymer (CFRP), basalt fiber reinforced polymer (BFRP) and glass fiber reinforced polymer (GFRP). Beam specimens were cast with M20, M30, M40 and M50 grades of SCC and heated to 925ºC using an electrical furnace for 60 min duration following ISO 834 standard fire curve. The heated SCC beams were cooled by either natural air or water spraying.FindingsThe reduction in the ultimate load carrying capacity of heated beams was about 42% and 55% for M50 grade specimens that were cooled by air and water, respectively, in comparison with the reference specimens. The increase in the ultimate load was 54%, 38% and 27% for the specimens retrofitted with CFRP, BFRP and GFRP, respectively, compared with the fire-affected specimens cooled by natural air. Water-cooled specimens had shown higher level of damage than the air-cooled specimens. The specimens wrapped with carbon fiber could able to improve the flexural strength than basalt and glass fiber wrapping.Originality/valueSCC, being a high performance concrete, is essential to evaluate the performance under fire conditions. This research work provides the flexural behavior and physical characteristics of SCC subjected to elevated temperature as per ISO rate of heating. In addition attempt has been made to enhance the flexural strength of fire-exposed SCC with wrapping using different fibers. The experimental data will enable the engineers to choose the appropriate material for retrofitting.


2019 ◽  
Vol 25 (10) ◽  
pp. 1624-1636 ◽  
Author(s):  
Hongbin Li ◽  
Taiyong Wang ◽  
Sanjay Joshi ◽  
Zhiqiang Yu

Purpose Continuous fiber-reinforced thermoplastic composites are being widely used in industry, but the fundamental understanding of their properties is still limited. The purpose of this paper is to quantitatively study the effects of carbon fiber content on the tensile strength of continuous carbon fiber-reinforced polylactic acid (CCFRPLA) fabricated through additive manufacturing using the fused deposition modeling (FDM) process. Design/methodology/approach The strength of these materials is highly dependent on the interface that forms between the continuous fiber and the plastic. A cohesive zone model is proposed as a theoretical means to understand the effect of carbon fiber on the tensile strength properties of CCFRPLA. The interface formation mechanism is explored, and the single fiber pulling-out experiment is implemented to investigate the interface properties of CCFRPLA. The fracture mechanism is also explored by using the cohesive zone model. Findings The interface between carbon fiber and PLA plays the main role in transferring external load to other fibers within CCFRPLA. The proposed model established in this paper quantitatively reveals the effects of continuous carbon fiber on the mechanical properties of CCFRPLA. The experimental results using additively manufacturing CCFRPLA provide validation and explanation of the observations based on the quantitative model that is established based on the micro-interface mechanics. Research limitations/implications The predict model is established imagining that all the fibers and PLA form a perfect interface. While in a practical situation, only the peripheral carbon fibers of the carbon fiber bundle can fully infiltrate with PLA and form a transmission interface. These internal fibers that cannot contract with PLA fully, because of the limit space of the nozzle, will not form an effective interface. Originality/value This paper theoretically reveals the fracture mechanism of CCFRPLA and provides a prediction model to estimate the tensile strength of CCFRPLA with different carbon fiber contents.


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