Lubricant and tribological properties of zinc compound in palm oil

2019 ◽  
Vol 71 (10) ◽  
pp. 1177-1185 ◽  
Author(s):  
Muhammad Aizat Md Alias ◽  
Mohd Fadzli Bin Abdollah ◽  
Hilmi Amiruddin
Keyword(s):  
Tribological Properties ◽  
Palm Oil ◽  
Friction And Wear ◽  
Viscosity Index ◽  
Acid Number ◽  
Friction Test ◽  
Content Type ◽  
Base Oil ◽  
Digital Microscope ◽  
Zinc Compound

Purpose This paper aims to investigate the composition of lubricant and the enhancement of tribological properties using palm oil as a parent base oil mixed with an organo-zinc compound as an additive. Design/methodology/approach The oil samples were prepared by mixing organo-zinc compound additive, zinc dioctyldithiophosphate (ZnDoDP) and zinc diamyldithiocarbamate (ZDDC), at 0 to 3.0 Wt.% concentrations with commercialised palm oil which were then homogenised using an ultrasonic homogeniser. The oil samples were then tested for their oil properties through elemental analysis, their viscosity index, flashpoint and acid number. Next, the friction test was performed using a four-ball tribometer, and the worn surfaces of the balls were observed using a digital microscope. Findings The results showed that commercialised palm oil with 2.0 Wt.% of ZnDoDP had excellent characteristics regarding its lubricant properties, such as its viscosity index, coefficient of friction and wear compared to commercialised palm oil with the addition of 2.0 Wt.% of ZDDC. Originality/value To the best of the authors’ knowledge, this is the first study to compare the effect of the concentration of ZnDoDP and ZDDC on the lubricant and triological properties of vegetable oil (palm).

scholarly journals Effect of The Ratio of H-Zeolite Catalyst and Temperature in The Opening Ring Reaction in Bio Lube Base Oil Production from Palm Oil

METANA ◽  
2020 ◽  
Vol 16 (1) ◽  
pp. 1-10
Author(s):  
Abdillah Iman Izzan ◽  
Ary Octaviani ◽  
Purwanto Purwanto
Keyword(s):  
Palm Oil ◽  
Ring Opening ◽  
Zeolite Catalyst ◽  
Viscosity Index ◽  
Weight Ratio ◽  
Acid Number ◽  
Lubricating Oil ◽  
Future Research ◽  
Base Oil ◽  
Ring Opening Reaction

Lubricants are materials that can reduce friction between two components. Lubricants are very important to keep the engine from being damaged quickly. Currently lubricants on the market generally comes from petroleum derivatives with limited availability. Therefore, technology needs to be developed to look for other raw materials as a substitute for petroleum based lubricating oil, namely by utilizing the potential of existing vegetable oils, one of which is palm oil. Biolubricant made from palm oil will be made using the method of transesterification, epoxidation and ring opening reaction. To increase yield and high product quality, a catalyst in the form of H-Zeolite is used. So that this study aims to determine the effect of the ratio of H-Zeolite catalyst to ring opening reactions. The quality of lube base oil could be indicated from density, viscosity index and acid number. Acid number will smaller in presence higher content in 10% weight ratio of H-Zeolite as catalyst and EPOME also higher temperature of ring-opening reaction because the catalyst H-Zeolit will work more effective in temperature 75oC. Other evidence is of density and viscosity index would show good value than smaller amount of H-Zeolit and lower temperature of reaction. Advices for the future research are the purification needs to be done not only physically but also chemically to maximize the results obtained. Preferably on the reaction of opening the epoxides rings used a long chain alcohol compounds that have a high viscosity and boiling point to obtain a better viscosities value

scholarly journals Pengaruh Penambahan Minyak Kelapa dan Sawit Terhadap Sifat Fisik dan Tribologi Pelumas SAE 40

Jurnal METTEK ◽  
2019 ◽  
Vol 5 (1) ◽  
pp. 1
Author(s):  
Dedison Gasni ◽  
KM Abdul Razak ◽  
Ahmad Ridwan ◽  
Muhammad Arif
Keyword(s):  
Fatty Acids ◽  
Coefficient Of Friction ◽  
Tribological Properties ◽  
Palm Oil ◽  
Boundary Lubrication ◽  
Viscosity Index ◽  
Coconut Oil ◽  
High Viscosity ◽  
Mineral Oil ◽  
Lubricating Oil

Penelitian ini bertujuan untuk mengetahui efek dari penambahan minyak kelapa dan sawit terhadap sifat fisik dan tribologi pelumas SAE 40. Vegetabel oil, seperti; minyak kelapa dan sawit, memiliki nilai viskositas indek yang tinggi dan sifat pelumasan yang baik terutama didaerah boundary lubrication jika dibandingkan dengan mineral oil (SAE 40). Hal ini disebabkan karena vegetabel oil memiliki kandungan fatty acids yang tidak dimiliki oleh mineral oil. Keunggulan lain dari minyak kelapa dan sawit adanya sifat yang ramah lingkungan karena mudah terurai di alam dan dapat diperbaharui. Pada penelitian ini sifat yang baik dari minyak kelapa dan sawit ini akan dimanfaatkan sebagai zat aditif pada minyak pelumas SAE 40. Pengujian dilakukan terhadap sifat fisik dan tribology dengan penambahan 5%, 10%, 15%, dan 20% berat dari minyak kelapa dan sawit ke dalam minyak pelumas SAE 40. Pengujian sifat fisik terdiri dari pengukuran viskositas pada temperatur 400C dan 1000C dan viskositas index. Pengujian sifat tribologi untuk menentukan keausan dan koefisien gesek berdasarkan ASTM G99 dengan menggunakan alat uji pin on disk. Dari hasil pengujian diperoleh bahwa dengan penambahan minyak kelapa dan sawit kedalam minyak pelumas SAE 40 terjadi peningkatan viskositas indeks. Peningkatan viskositas indeks sebanyak  17% dengan penambahan 20% minyak sawit. Terjadi perubahan sifat tribologi dengan penambahan minyak sawit, berupa penurunan keausan dan nilai koefisien gesek dibandingkan dengan penambahan minyak kelapa. This study aims to determine the effect of coconut and palm oils as additives to physical and tribological properties of SAE 40 lubricating oil . Vegetable oils, such as; coconut oil and palm oil, have high viscosity index and good lubrication properties, especially in boundary lubrication compared to mineral oil. This is due to vegetable oil having fatty acids that are not owned by mineral oil. The advantages of coconut oil and palm oil are environmentally friendly properties because they are biodegradable and renewable. In this study, the good properties of coconut and palm oils will be used as additives in SAE 40 lubricating oil. Tests are carried out on the physical and tribological properties with the addition of 5%, 10%, 15%, and 20% by weight of coconut and palm oils into SAE 40 lubricating oil. Physical properties testing consists of measuring viscosity at temperatures of 400C and 1000C and viscosity index. The tribological test is to determine wear and coefficient of friction based on ASTM G99 using a pin on disc test equipment. From the test results,  it was found that coconut and palm oils as additives into SAE 40 lubricating oil could increase in viscosity index. The increase of  the viscosity index was 17% by adding 20% of palm oil. There was a change of tribological properties in the form of decreasing on the wear and the coefficient of friction with the addition of palm oil compare to addition of coconut oil.

Tribological properties of beef tallow as lubricating grease

2017 ◽  
Vol 69 (5) ◽  
pp. 645-654 ◽  
Author(s):  
Juozas Padgurskas ◽  
Raimundas Rukuiža ◽  
Ihor Mandziuk ◽  
Arturas Kupcinskas ◽  
Katerina Prisyazhna ◽  
...  
Keyword(s):  
Critical Load ◽  
Tribological Properties ◽  
Beef Tallow ◽  
Friction And Wear ◽  
Load Level ◽  
Synthesis Process ◽  
Polymer Additives ◽  
Lubricating Grease ◽  
Content Type ◽  
Thermally Processed

Purpose The purpose of this paper is to report on the tribological properties of beef tallow grease and improvements therein through modification with special processing, polymeric compounds and additives. Design/methodology/approach Pure original beef tallow grease was used as a biological lubricating grease reference material for the tribological research. Beef tallow was modified and synthesized by adding special biological anti-oxidant additives, LZ anti-wear additives, waste polyethylene terephthalate (PET) polymer compounds and thermally processed graphite. Findings Rheometric measurements indicate that the beef tallow grease modification technology used in this study enables control of the synthesis process to produce lubricants with the required microstructure. Investigation results of the tribological properties of differently modified greases show that beef tallow synthesized with polymer additives efficiently operates together with anti-wear additives to reduce friction and wear. The grease compound with thermally processed graphite has good tribological properties at 300 N load levels. The critical load level of lubricating greases could be significantly increased through the use of anti-wear additives and thermally processed graphite. Originality/value Investigation results of the tribological properties of differently modified beef tallow greases show that beef tallow synthesized with polymer additives efficiently operates together with anti-wear additives to reduce friction and wear. The critical load level of lubricating beef tallow greases could be significantly increased using anti-wear additives and thermally processed graphite.

Tribological properties of the epoxy resin-based solid lubricant coating modified by Kevlar fibers

2018 ◽  
Vol 70 (9) ◽  
pp. 1706-1713 ◽  
Author(s):  
Guotao Zhang ◽  
Yanguo Yin ◽  
Ting Xie ◽  
Dan Li ◽  
Ming Xu ◽  
...  
Keyword(s):  
Wear Resistance ◽  
Epoxy Resin ◽  
Tribological Properties ◽  
Dry Friction ◽  
Friction And Wear ◽  
Solid Lubricant ◽  
Transfer Film ◽  
Wear Properties ◽  
Content Type ◽  
Friction And Wear Properties

Purpose This paper aims to obtain high mechanical and good tribological properties of epoxy resin-based coatings under dry friction conditions. Design/methodology/approach Bonded solid lubricant coatings containing Kevlar fibres were prepared by a spraying method. The friction and wear properties of the coatings were experimentally investigated with a face-to-face tribometre under dry friction conditions. Scanning electron microscopy, energy dispersive X-ray spectroscopy and 3D laser scanning technologies were used to characterise the tribological properties. The action mechanism of the Kevlar fibres on a solid lubricant transfer film was also analysed. Findings Adding Kevlar fibres can significantly improve the wear resistance of the coatings. When the Kevlar fibre content increases, the tribological properties of the coatings improve and then worsen. Superior properties are obtained with 0.03 g of Kevlar fibres. Appropriately increasing the load or speed is beneficial to the removal of the outer epoxy resin and the formation of a lubricant film. During friction, the solid lubricants wrapped in the epoxy resin accumulate on the surface to form a transfer film that shows a good self-lubricating performance. In the later friction stage, fatigue cracks occur on the solid lubricant film but cannot connect to one another because of the high wear resistance and the entanglement of the rod-like Kevlar fibres. Thus, no large-area film falls from the matrix, thereby ensuring the long-term functioning of solid lubricant coatings. Originality/value Epoxy resin-based solid lubricant coatings modified by Kevlar fibres were prepared, and their friction and wear properties were investigated. Their tribological mechanisms were also proposed. This work provided a basis for the analysis of the tribological properties and design of bonded solid lubricant coatings containing Kevlar fibres.

Experimental Research on Tribological Properties of Mn0.78Zn0.22Fe2O4 Magnetic Fluids

2008 ◽  
Vol 130 (3) ◽  
Author(s):  
Wang Li-jun ◽  
Guo Chu-wen ◽  
Ryuichiro Yamane
Keyword(s):  
Tribological Properties ◽  
Friction And Wear ◽  
Chemical Properties ◽  
Friction Reduction ◽  
Experimental Investigations ◽  
Wear Scar Diameter ◽  
Base Oil ◽  
Turbine Oil ◽  
Physical And Chemical ◽  
And Chemical Properties

The synthesis and application of nanometer-sized particles have received considerable attention in recent years because of their different physical and chemical properties from those of the bulk materials or individual molecules; however, few experimental investigations on the tribological properties of lubricating oils with and without nanoferromagnetic particles have been performed. This work investigates the tribological properties of Mn0.78Zn0.22Fe2O4 nanoferromagnetic as additive in 46# turbine oil using a four-ball friction and wear tester. It is shown that the 46# turbine oil containing Mn0.78Zn0.22Fe2O4 nanoparticles has much better friction reduction and antiwear abilities than the base oil. The 46# turbine oil doped with 6wt%Mn0.78Zn0.22Fe2O4 nanoparticles show the best tribological properties among the tested oil samples, and PB value is increased by 26%, and the decreasing percentage of wear scar diameter is 25.45% compared to base oil.

Tribological and physical properties of PTFE-NBR self-lubricating composites under water lubrication

2020 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Wei Feng ◽  
Lei Yin ◽  
Yanfeng Han ◽  
Jiaxu Wang ◽  
Ke Xiao ◽  
...  
Keyword(s):  
Physical Properties ◽  
Peer Review ◽  
Tribological Properties ◽  
Water Lubrication ◽  
Butadiene Rubber ◽  
Friction Test ◽  
Bearing Material ◽  
Content Type ◽  
Lubricating Film ◽  
Self Lubricating Composites

Purpose This paper aims to explore the possibility of converting the nitrile butadiene rubber (NBR) water-lubricated bearing material into a self-lubricating bearing material by the action of polytetrafluoroethylene (PTFE) particles and water lubrication. Design/methodology/approach A group of experimental studies was carried out on a ring-on-block friction test. The physical properties, tribological properties and interface structure of PTFE-NBR self-lubricating composites filled with different percentages of PTFE particles were investigated. Findings The experimental results indicated that the reduction in friction and wear is a result of the formation of the lubricating film on the surface of the composites. The lubricating film was formed of a large amount of PTFE particles continuously supplied under water lubrication conditions and the PTFE particles here can greatly enhance the load capacity and lubrication performance. Originality/value In this study, the tribological properties of PTFE particles added to the NBR water-lubricated bearing materials under water lubrication were investigated experimentally, and the research was carried out by a ring-on-block friction test. It is believed that this study can provide some guidance for the application of PTFE-NBR self-lubricating. Peer review The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-05-2020-0187/

The tribological performance of engineered micro-surface topography by picosecond laser on PEEK

2019 ◽  
Vol 72 (1) ◽  
pp. 172-179 ◽  
Author(s):  
Meiling Wang
Keyword(s):  
Tribological Properties ◽  
Design Methodology ◽  
Friction And Wear ◽  
Picosecond Laser ◽  
Wear Property ◽  
Content Type ◽  
Friction Curve ◽  
Micro Structures ◽  
Wear Tests ◽  
Friction And Wear Tests

Purpose The purpose of this study is to investigate the effect of engineered micro-structures on the tribological properties of metal-polyetheretherketone (PEEK) surface. Design/methodology/approach Circular dimples with diameters of 25 and 50 µm were designed and manufactured on PEEK plate specimens using picosecond laser. Reciprocating friction and wear tests on a ball-on-flat configuration were performed to evaluate the tribological properties of the designed micro-structures in dry contacts. The loading forces of 0.9 and 3 N were applied. Findings As a result, obvious fluctuations of coefficient of friction curve were observed in tribosystems consisting of non-textured and textured PEEK with circular dimples of 25 µm in diameter. GCr15 ball/textured PEEK plate specimens with circular dimples of 50 µm in diameter revealed a superior friction and wear property. Originality/value Different to the existing studies in which the tribopairs consist of hard bearing couples, this study investigated the tribological properties of the engineered micro-structures on the hard-on-soft bearing couples.

scholarly journals Effect of temperature and mating pair on tribological properties of DLC and GLC coatings under high pressure lubricated by MoDTC and ZDDP

Friction ◽  
2020 ◽  
Author(s):  
Kang Liu ◽  
Jia-jie Kang ◽  
Guang-an Zhang ◽  
Zhi-bin Lu ◽  
Wen Yue
Keyword(s):  
Tribological Properties ◽  
Friction And Wear ◽  
Effect Of Temperature ◽  
Wear Properties ◽  
Dlc Coatings ◽  
Base Oil ◽  
Two Temperatures ◽  
Friction And Wear Properties ◽  
Lubrication Conditions ◽  
Better Than

AbstractDiamond-like carbon (DLC) and graphite-like carbon (GLC) coatings have good prospects for improving the surface properties of engine parts. However, further understanding is needed on the effect of working conditions on tribological behaviors. In this study, GLC and two types of DLC coatings were deposited on GCr15 substrate for investigation. The friction and wear properties of self-mated and steel-mated pairs were evaluated. Two temperatures (25 and 90 °C), three lubrication conditions (base oil, molybdenum dithiocarbamate (MoDTC)-containing oil, MoDTC+zinc dialkyldithiophosphate (ZDDP)-containing oil), and high Hertz contact stress (2.41 GPa) were applied in the experiments. The results showed that high temperature promoted the effect of ZDDP on steel-mated pairs, but increased wear under base oil lubrication. The increased wear for steel-mated pairs lubricated by MoDTC-containing oil was due to abrasive wear probably caused by MoO3 and β-FeMoO4. It was also found that in most cases, the tribological properties of self-mated pairs were better than those of steel-mated pairs.

Synthesis and tribological properties of nanogrease

2018 ◽  
Vol 70 (3) ◽  
pp. 512-518 ◽  
Author(s):  
Alaa Mohamed ◽  
Mohamed Hamdy ◽  
Mohamed Bayoumi ◽  
Tarek Osman
Keyword(s):  
Electron Microscopy ◽  
Tribological Properties ◽  
Power Efficiency ◽  
New Technologies ◽  
Mechanical Equipment ◽  
Content Type ◽  
Base Oil ◽  
X Ray ◽  
Transmission Electron ◽  
Steel Balls

Purpose To enhance the tribological properties of nanogrease, one of the new technologies was used to synthesize a nanogrease having carbon nanotubes (CNTs) nanoparticles (NPs) with different concentrations. The microstructures of the synthesized NPs were characterized and evaluated by x-ray diffraction spectroscopy (XRD) and transmission electron microscopy (TEM). Tribological properties of the nanogrease were evaluated using a four-ball tester. The worn surface of four steel balls was investigated by scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDX). Design/methodology/approach Grease was dissolved in chloroform (10 Wt.%), at 25 °C for 1 h. In parallel, functionalized CNTs with different volume concentrations (0.5, 1, 2 and 3 Wt.%) were dispersed in N, N-dimethylformamide. The mixture was stirred for 15 min and then sonicated (40 kHz, 150 W) for 30 min. After that, the mixture was added to the grease solution and magnetically stirred for 15 min and then sonicated for 2 h. Findings The results suggested that CNTs can enhance the antiwear and friction properties of nanogrease at 0.5 Wt.% CNTs to about 57 and 48 per cent, respectively. In addition, the weld load of the base oil containing 0.5 Wt.% CNTs was improved by 17 per cent compared with base grease. Originality/value This work describes the inexpensive and simple fabrication of nanogrease for improving the properties of lubricants, which improve power efficiency and extend lifetimes of mechanical equipment.

Synthesis, characterization and tribological behavior of oleic acid-capped core-shell lanthanum borate-SiO2 composites

2014 ◽  
Vol 66 (1) ◽  
pp. 1-8 ◽  
Author(s):  
Zhengfeng Jia ◽  
Yan-qiu Xia ◽  
Xin Shao ◽  
San-ming Du
Keyword(s):  
Oleic Acid ◽  
Tribological Properties ◽  
Friction And Wear ◽  
Thermo Gravimetric Analysis ◽  
Core Shell ◽  
Gravimetric Analysis ◽  
Content Type ◽  
Aisi 1045 Steel ◽  
Aisi 1045 ◽  
1045 Steel

Purpose – The purpose of this paper is to investigate the tribological properties of poly-alpha-olefin (PAO) with nano/microstructure core-shell lanthanum borate-SiO2 composites (OCLS). Design/methodology/approach – Oleic acid-capped core-shell lanthanum borate-SiO2 composites were synthesized by an easy way. The composites were characterized by means of Fourier transform-infrared spectroscopy (FT-IR), transmission electron microscopy (TEM) and thermo gravimetric analysis (TGA). The friction and wear behaviors of the quenched AISI 1045 steel specimens sliding against AISI 52100 steel under the lubrication of PAO containing OCLS were comparatively investigated with PAO containing SiO2 additive on an Optimol SRV reciprocating friction and wear tester. On the other hand, the tribological properties of the PAO containing OCLS were also investigated on four-ball tester. Findings – The diameter of OCLS was about 20 nm, and the thickness of the SiO2 shell was less than 5 nm. The ratio of oleic acid (OA) is about 15 percent. The PAO containing OCLS possesses much better tribological properties than that of pure PAO and PAO containing SiO2 additive. Originality/value – The PAO+OCLS possess a better friction reducing and antiwear properties than pure PAO. The new additive can improve the tribological ability of machinery.

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