Synthesis and evaluation of ashless detergent/dispersant additives for lubricating engine oil

2015 ◽  
Vol 67 (6) ◽  
pp. 622-629 ◽  
Author(s):  
Nehal S. Ahmed ◽  
Hamdy S. Abdel-Hameed ◽  
Ahmed F. El-Kafrawy ◽  
Amal M. Nassar
Keyword(s):  
Organic Acids ◽  
Proton Nuclear Magnetic Resonance ◽  
Engine Oil ◽  
Lubricating Oil ◽  
Total Acid ◽  
Content Type ◽  
Automotive Engines ◽  
Carbonaceous Deposits ◽  
New Compounds

Purpose – The aim of this paper is to solve the problem of carbonaceous deposits in automotive engines by preparing different ashless detergent/dispersant additives based on propylene oxide (PO) and different amines. Carbonaceous deposits in automotive engines are the major problems associated with oil aging. Efficient detergents and dispersants have been used to solve this problem, particularly in lubricating oils. Design/methodology/approach – The structures of the prepared compounds were confirmed using Fourier transform infrared spectroscopy (FT-IR), proton nuclear magnetic resonance (1H-NMR) and gel permeation chromatography (GPC) for determination of molecular weight. This was followed by the evaluation of the prepared compounds such as detergent/dispersant and antioxidants additives for lubricating engine oil using several techniques such as variation of viscosity ratio, change in total acid number, optical density using infrared techniques, spot method, determination of sludge and determination the potential detergent dispersant efficiency (PDDE). Findings – All the prepared compounds were found to be soluble in lubricating oil. The efficiency of the prepared compounds such as antioxidant and detergent/dispersant additives for lubricating oil was investigated. It was found that the additives have excellent power of dispersion, detergency and the most efficient additives such as antioxidant those prepared by using n,n-dimethyloctadecylamine (NDOA) and di-n-butyl dithio phosphoric acid. Practical implications – The paper includes preparation of new compounds from the reaction of propoxylated amines and different organic acids and evaluates them as detergent/dispersant and antioxidants additives by using several techniques. Originality/value – This paper fulfils an identified need to prepare new compounds from the reaction of propoxylated amines and different organic acids and evaluates them as additives by using different methods. All were found to have better efficiency as compared with commercial additives.

Jojoba modified polymers as performance modifiers additives for engine oil

2015 ◽  
Vol 67 (5) ◽  
pp. 425-433 ◽  
Author(s):  
Nehal S. Ahmed ◽  
Amal M. Nassar ◽  
Rabab M. Nasser
Keyword(s):  
Vinyl Acetate ◽  
Pour Point ◽  
Viscosity Index ◽  
Vinyl Pyrrolidone ◽  
Proton Nuclear Magnetic Resonance ◽  
Engine Oil ◽  
Lubricating Oil ◽  
Content Type ◽  
Pour Point Depressants ◽  
Viscosity Index Improvers

Purpose – The purpose of this paper is to prepare novel types of copolymers and terpolymers depending on jojoba, and using them as additives for lubricating oil. Design/methodology/approach – Copolymerization of 1 mole of jojoba with 2 moles of vinyl acetate and copolymerization of 1 mole of jojoba with 2 moles of vinyl pyrrolidone were carried out. Then, two series of terpolymers were prepared by reacting (jojoba: vinyl acetate: alkylacrylate) and (jojoba: vinyl pyrrolidone: alkylacrylate), using free radical chain addition polymerization. Elucidation of the prepared polymers was carried out by using Fourier transform infrared spectroscopy, proton nuclear magnetic resonance and gel permeation chromatography, for determination of weight average molecular weight. The thermal stability of the prepared polymers was determined. The prepared polymers were evaluated as viscosity index improvers and pour point depressants for lubricating oil. Findings – It was found that the viscosity index increases with increasing the alkyl chain length of alkylacrylate. The effect of the monomer type was studied, and it was found that the polymers depending on vinyl acetate have great effect as viscosity index improvers and pour point depressants for lubricating oil. Originality/value – The polymerization of jojoba as different copolymers and terpolymers was carried out. The great influence of the prepared additives on modification of the viscosity properties and pour point of the oil was observed.

Effect of hexagonal boron nitride nanoparticles as an additive on the extreme pressure properties of engine oil

2016 ◽  
Vol 68 (4) ◽  
pp. 441-445 ◽  
Author(s):  
Muhammad Ilman Hakimi Chua Abdullah ◽  
Mohd Fadzli Bin Abdollah ◽  
Noreffendy Tamaldin ◽  
Hilmi Amiruddin ◽  
Nur Rashid Mat Nuri
Keyword(s):  
Diesel Engine ◽  
Boron Nitride ◽  
Hexagonal Boron Nitride ◽  
Experimental Studies ◽  
Engine Oil ◽  
Lubricating Oil ◽  
Extreme Pressure ◽  
Content Type ◽  
Load Carrying ◽  
Sonication Technique

Purpose This paper aims to investigate the effect of hexagonal boron nitride (hBN) nanoparticles on extreme pressure (EP) properties when used as an additive in lubricating oil. Design/methodology/approach The nano-oil was prepared by dispersing an optimal composition of 0.5 vol. per cent of 70 nm hBN in SAE 15W-40 diesel engine oil using a sonication technique. The tribological testing was performed using a four-ball tribometer according to the ASTM standard. Findings It was found that the nano-oil has a potential to decelerate the seizure point on the contact surfaces, where higher EP can be obtained. More adhesive wear was observed on the worn surfaces of ball bearing lubricated with SAE 15W-40 diesel engine oil as compared with the nano-oil lubrication. Originality/value The results of the experimental studies demonstrated the potential of hBN as an additive for improving the load-carrying ability of lubricating oil.

Study on Wear of Piston Rings in Diesel Engines With Exhaust Gas Recirculation

2001 ◽  
Author(s):  
Tokuro Sato ◽  
Hideki Saito ◽  
Koji Korematsu ◽  
Junya Tanaka
Keyword(s):  
Diesel Engines ◽  
Time History ◽  
Acid Number ◽  
Engine Oil ◽  
Lubricating Oil ◽  
Base Number ◽  
Piston Rings ◽  
Total Acid ◽  
Residual Content ◽  
Measured Time

Abstract The wear of piston rings in the diesel engines with EGR system is studied experimentally. In order to clarify the effect of PM on the wear, the wear of the piston rings in the test engine is measured, (1) when the non-soluble in the lubricating oil is removed by the oil filters, (2) when PM in the re-circulating gas is removed by the DPF, (3) when the carbon black is added in the lubricating oil. The experimental results are discussed with the measured time history of kinematic viscosity, total base number, total acid number, ZDTP survival rate, and carbon residual content and its particle size in the engine oil.

The importance of 2 per cent PTFE/FeF3 additives in engine fully formulated oil for reducing friction and wear under boundary lubrication condition

2015 ◽  
Vol 67 (1) ◽  
pp. 75-80 ◽  
Author(s):  
Gabi N Nehme ◽  
Saeed Ghalambor
Keyword(s):  
Boundary Lubrication ◽  
Engine Oil ◽  
Lubricating Oil ◽  
Wear Volume ◽  
Environment Friendly ◽  
Content Type ◽  
Lubricating Oils ◽  
Engine Oils ◽  
Lubrication Condition ◽  
Minimum Wear

Purpose – This paper aims to focus on the topics of phosphorus (P) and sulfur (S) in engine oil. Very reproducible boundary lubrication tests were conducted as part of Design of Experiments software to study the behavior of fluorinated catalyst iron fluoride (FeF3) and polytetrafluoroethylene (PTFE) in the development of environment-friendly (reduced P and S) anti-wear additives for future engine oil formulations. Multi-component fully formulated oils were used with and without the addition of PTFE and fluorinated catalyst to characterize and analyze their performance. Design/methodology/approach – A boundary lubrication protocol was used in the DOE tests to study their tribological behavior. Lubricant additives like PTFE and FeF3 catalyst were used at different concentrations to investigate the wear resistance and the time for a full breakdown under extreme loading conditions. Experiments indicated that new sub-micron FeF3 catalyst plays an important role in preventing the breakdown of the tribofilm. Findings – This paper explores the effect of PTFE and FeF3 catalyst on the performance of fully formulated engine oils. The purpose was to develop equations for minimum wear volume and maximum time for full breakdown. Emphasis was, therefore, given to conditions where the additives were working effectively for minimizing zinc dialkyl dithio phosphate (P per cent). Lubricating oils are normally multi-component additivated systems. They contain different additives such as viscosity improvers, detergents, dispersants and antioxidants. It is known that these additives interact at the surface, affecting the function of the lubricating oil. Therefore, it is important to note that the performance with PTFE and FeF3 catalyst was significantly improved when compared to fully formulated commercial oils used alone. Originality/value – Lubricating oils are normally multi-component additivated systems. They contain different additives such as viscosity improvers, detergents, dispersants and antioxidants. It is known that these additives interact at the surface, affecting the function of the lubricating oil. Therefore, it is important to note that the performance with PTFE and FeF3 catalyst was significantly improved when compared to fully formulated commercial oils used alone.

Experimental studies on the tribological behaviour of engine oil (SAE15W40) with the addition of CuO nanoparticles

2014 ◽  
Vol 66 (2) ◽  
pp. 289-297 ◽  
Author(s):  
Manu V. Thottackkad ◽  
P.K. Rajendrakumar ◽  
K. Prabhakaran Nair
Keyword(s):  
Experimental Studies ◽  
Viscosity Coefficient ◽  
Cuo Nanoparticles ◽  
Engine Oil ◽  
Lubricating Oil ◽  
Tribological Behaviour ◽  
Content Type ◽  
Weight Percentage ◽  
Pin On Disc ◽  
Percentage Basis

Purpose – This manuscript aims to deal with the tribological property variations of engine oil (SAE15W40) by the addition of copper oxide (CuO) nanoparticles on weight percentage basis. Design/methodology/approach – Experimental studies on the influence of CuO nanoparticles utilised as an additive in lubricating oil (SAE15W40) under boundary lubrication conditions have been carried out using a pin-on-disc machine in accordance with ASTM G-99 standard. The variation of viscosity, coefficient of friction, wear and settling of nanoparticles has been studied as a function of particle concentration in the lubricant. Findings – Results show that the frictional force and specific wear rate decrease with an increase in concentration of nanoparticles comes to a minimum at a specific concentration and then increases, showing the presence of an optimum concentration. With the increase in concentration of nanoparticles, the kinematic and dynamic viscosities, and the flash and fire points are found to increase. Originality/value – The use of CuO nanoparticles as additives to a moderate level is a very efficient means of improving the tribological properties of lubricating oils.

Determination of Total Organic Acids in Urine by Extraction with Organic Solvents

1973 ◽  
Vol 19 (6) ◽  
pp. 593-596 ◽  
Author(s):  
Leo Kesner ◽  
Tsai-Tse Yao ◽  
Ralph B Dell
Keyword(s):  
Amino Acids ◽  
Organic Acids ◽  
Inborn Errors Of Metabolism ◽  
Amyl Alcohol ◽  
Rapid Screening ◽  
Metabolic Disturbances ◽  
Total Acid ◽  
Inborn Errors ◽  
Rapid Screening Test

Abstract Metabolic carboxylic acids are extracted, with a mixture of equal volumes of t-amyl alcohol—chloroform, from an acidified sample of as little as 200 µl of urine that has been adsorbed to a short column of silica gel. Total acid in the extract is measured by titration with tetramethylammonium hydroxide (10 mmol/liter) to a phenolphthalein end point. There is no interference from protein, creatinine, creatine, bicarbonate, or amino acids, and no pretreatment of the sample is required. Results compared well (r = 0.94) with those obtained by the Palmer—Van Slyke method for total organic acids. This procedure should prove useful as a simple, rapid screening test for those metabolic disturbances and inborn errors of metabolism characterized by increased excretion of organic acids.

scholarly journals Refining and Reuse of Waste Lube Oil in SI Engines: A Novel Approach for a Sustainable Environment

Energies ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2937
Author(s):  
Muhammad Usman ◽  
Muhammad Kashif Jamil ◽  
Fahid Riaz ◽  
Haris Hussain ◽  
Ghulam Hussain ◽  
...  
Keyword(s):  
Treatment Method ◽  
Acid Number ◽  
Engine Oil ◽  
Lubricating Oil ◽  
Gas Temperature ◽  
Total Acid ◽  
Used Oil ◽  
Novel Approach ◽  
Performance And Emissions ◽  
Improved Performance

The protection of the environment and pollution control are issues of paramount importance. Researchers today are engrossed in mitigating the harmful impacts of petroleum waste on the environment. Lubricating oils, which are essential for the smooth operation of engines, are often disposed of improperly after completing their life. In the experimental work presented in this paper, deteriorated engine oil was regenerated using the acid treatment method and was reused in the engine. The comparison of the properties of reused oil, the engine’s performance, and the emissions from the engine are presented. The reuse of regenerated oil, the evaluation of performance, and emissions establish the usefulness of the regeneration of waste lubricating oil. For the used oil, total acid number (TAN), specific gravity, flash point, ash content, and kinematic viscosity changed by 60.7%, 6.7%, 4.4%, 96%, and 15.5%, respectively, compared with fresh oil. The regeneration partially restored all the lost lubricating oil properties. The performance parameters, brake power (BP), brake specific fuel consumption (BSFC), and exhaust gas temperature (EGT) improved with regenerated oil in use compared with used oil. The emissions CO and NOX contents for acid-treated oil were 9.7% and 17.3% less in comparison with used oil, respectively. Thus, regenerated oil showed improved performance and oil properties along with significantly reduced emissions when employed in an SI engine.

DETERMINATION OF GLYCOL CONTAMINATION IN ENGINE OIL BY INFRARED AND UV-VIS SPECTROSCOPY

2018 ◽  
Author(s):  
Torrey Holland ◽  
Dennis Watson ◽  
P Sivakumar ◽  
Ali Abdul-Munaim ◽  
Robinson Karunanithy
Keyword(s):  
Engine Oil ◽  
Vis Spectroscopy

INFLUENCE OF DICARBOXYLIC ACIDS ON SOWING QUALITY OF SPRING BARLEY

1970 ◽  
pp. 22-25
Author(s):  
N. N. Loy ◽  
S. N. Gulina
Keyword(s):  
Organic Acids ◽  
Spring Barley ◽  
Dose Range ◽  
Dicarboxylic Acids ◽  
Rotary Machine ◽  
Working Solution ◽  
Negative Effect ◽  
Sprouted Seeds

The effect of presowing seed treatment on various concentrations of dicarboxylic (organic) acids on the sowing characteristics of spring barley has been studied. Seeds were treated with organic acids obtained by exposing cuttings to the radiation with a dose of 100 kGy and consequent hydrolysis, in concentrations: 1•10-7 %; 1•10-9; 1•10-11; 1•10-13 and 1•10-15 % on a laboratory rotary machine RVO-64 for one day before laying for germination. Distilled water was used for the control case. The rate of application of the working solution calculated as 10 liters / ton of seeds. Seeds were germinated in filter paper rolls in accordance with GOST 12038-84 requirements. The temperature was maintained at +24 ° C in the thermostat where the glasses with rolls were placed. For determination of germinative power and laboratory germination the sprouted seeds were evaluated after three and seven days, respectively. In laboratory experiments it was established that the treatment of barley seeds of varieties Zazersky 85, Nur and Vladimir with organic acids (OK) in different concentrations had both a stimulating and a negative effect. On the Zazersky 85 variety, in variants with acid concentrations of 1•10-9 and 1•10-11, an increase in germination energy (EP) by 2-4% and a significant decrease (by 3-4%) of laboratory germination (LV) of barley seeds were noted. On the Nur variety, the increase in EP was observed at 4% (concentration 1•10-11), LV and seed growth force (CPC) by 2-7% at a concentration of 1•10-7 and in the dose range 1•10-11 - 1•10-14 compared to the control values. On the grade of Vladimir, an increase in EP, LV, and CPC was found to increase by 1-6% at concentrations OK 1•10-7 and 1•10-13. It was shown that the treatment of seeds with acids led to an increase in the length of the germ in all studied varieties (by 3-9%) and dry biomass of 7-day-old seedlings - by 3-6%. Consequently, the treatment of seeds with a mixture of dicarboxylic acids has a stimulating effect on the sowing quality of spring barley.

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