Effect of hexagonal boron nitride nanoparticles as an additive on the extreme pressure properties of engine oil

2016 ◽  
Vol 68 (4) ◽  
pp. 441-445 ◽  
Author(s):  
Muhammad Ilman Hakimi Chua Abdullah ◽  
Mohd Fadzli Bin Abdollah ◽  
Noreffendy Tamaldin ◽  
Hilmi Amiruddin ◽  
Nur Rashid Mat Nuri

Purpose This paper aims to investigate the effect of hexagonal boron nitride (hBN) nanoparticles on extreme pressure (EP) properties when used as an additive in lubricating oil. Design/methodology/approach The nano-oil was prepared by dispersing an optimal composition of 0.5 vol. per cent of 70 nm hBN in SAE 15W-40 diesel engine oil using a sonication technique. The tribological testing was performed using a four-ball tribometer according to the ASTM standard. Findings It was found that the nano-oil has a potential to decelerate the seizure point on the contact surfaces, where higher EP can be obtained. More adhesive wear was observed on the worn surfaces of ball bearing lubricated with SAE 15W-40 diesel engine oil as compared with the nano-oil lubrication. Originality/value The results of the experimental studies demonstrated the potential of hBN as an additive for improving the load-carrying ability of lubricating oil.

2014 ◽  
Vol 66 (2) ◽  
pp. 289-297 ◽  
Author(s):  
Manu V. Thottackkad ◽  
P.K. Rajendrakumar ◽  
K. Prabhakaran Nair

Purpose – This manuscript aims to deal with the tribological property variations of engine oil (SAE15W40) by the addition of copper oxide (CuO) nanoparticles on weight percentage basis. Design/methodology/approach – Experimental studies on the influence of CuO nanoparticles utilised as an additive in lubricating oil (SAE15W40) under boundary lubrication conditions have been carried out using a pin-on-disc machine in accordance with ASTM G-99 standard. The variation of viscosity, coefficient of friction, wear and settling of nanoparticles has been studied as a function of particle concentration in the lubricant. Findings – Results show that the frictional force and specific wear rate decrease with an increase in concentration of nanoparticles comes to a minimum at a specific concentration and then increases, showing the presence of an optimum concentration. With the increase in concentration of nanoparticles, the kinematic and dynamic viscosities, and the flash and fire points are found to increase. Originality/value – The use of CuO nanoparticles as additives to a moderate level is a very efficient means of improving the tribological properties of lubricating oils.


2020 ◽  
Vol 72 (10) ◽  
pp. 1199-1204
Author(s):  
Hilmi Amiruddin ◽  
Mohd Fadzli Bin Abdollah ◽  
Muhamad Aliff Danial Mohamad Nizar

Purpose This study aims to introduce a novel technique which helped in quantifying the wear performance of a roller chain which was lubricated by using the palm oil-based hexagonal boron nitride (hBN) nanoparticles (nano-biolubricant). Design/methodology/approach The efficiency of the nano-biolubricant was evaluated by using a custom-made roller chain tribometer, at different resistance torque values at a constant speed and running time. Prior to the test, 2 different lubrication conditions were applied. The mass loss and elongation behaviour of a roller chain was selected as a degradation metric for monitoring the amount of the chain wear. The predominant wear mechanism of a roller chain was identified by surface morphological analysis. Findings Regardless of the lubrication conditions, the wear performance of the roller chain was significantly increased, at increasing resistance torque values. Higher wear was noted when the roller chain was lubricated using a nano-biolubricant, however, the wear curve showed a promising high chain life. The predominant wear mechanism involved is abrasive wear. Originality/value Although an increase in the elongation during running is based on the wear between the pins and roller, none of the earlier studies quantified the wear performance of a roller chain under differing lubrication conditions. Hence, for bridging the gap, this study described a new method for measuring the wear performance of the roller chain which was lubricated using the palm oil-based hBN nanoparticles or a nano-biolubricant. Peer review The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-02-2020-0061/


2014 ◽  
Vol 66 (3) ◽  
Author(s):  
Muhammad Ilman Hakimi Chua Abdullah ◽  
Mohd Fadzli Abdollah ◽  
Hilmi Amiruddin ◽  
Noreffendy Tamaldin ◽  
Nur Rashid Mat Nuri

Nanotechnology currently has an important role in reducing engine wear and improving fuel efficiency within engines using nanoparticle additives in engine oil. In this work, the effect of hexagonal boron nitride (hBN) and alumina (Al2O3) nanoparticle additives, on the tribological performance of SAE 15W40 diesel engine oil, was studied. A tribological test was conducted using a four-ball tribotester. The results show that the coefficient of friction (COF) and wear rate of the ball reduced significantly by dispersing hBN nanoparticle additives in SAE 15W40 diesel engine oil; compared to without or with Al2O3 nanoparticle additives. This is in accordance with the significant reduction of wear scar diameter and smoother worn surfaces observed on the balls.


2015 ◽  
Vol 67 (2) ◽  
pp. 139-149 ◽  
Author(s):  
Shibo Wang ◽  
Bo Cao ◽  
Bing Teng

Purpose – The purpose of this paper is to investigate the effect of hexagonal boron nitride (h-BN) and poly (phenyl p-hydroxybenzoate) (PHBA) on improving the torsional tribological behavior of polytetrafluoroethylene (PTFE). Design/methodology/approach – This paper investigates the torsional tribological behavior of PTFE composites filled with h-BN and PHBA under different angular displacements with a plane-on-plane torsional friction tester. The worn surface of PTFE composites was investigated by using a scanning electron microscope. Findings – The shape of T–Θ curves of PTFE composites was influenced by both content fillers and torsional angule. The material with a higher coefficient of sliding friction exhibited the larger torsional angle under which the torsional regime transited from a partial slip to a gross slip. PTFE composites filled with 20 weight per cent PHBA and 10 weight per cent h-BN showed the best anti-wear properties. The specific wear rate of composites exhibits a negative correlation with material hardness. The wear volume loss presents a positive correlation with friction dissipation energy. The specific wear rate of all composites decreased with increasing torsional angle. The dominant wear mechanism of pure PTFE was adhesive wear. The slight plastic flow and plowing occurred on the worn surfaces of PTFE composites because of the higher hardness of composites and the lubrication of h-BN particles with layer crystal structure. Originality/value – This paper put forward a kind of PTFE composite with low torsional wear rate, which can be used in the sliding slewing bearing or the center plate of a bogie.


2014 ◽  
Vol 20 (4) ◽  
pp. 1053-1059 ◽  
Author(s):  
Nicholas L. McDougall ◽  
Rebecca J. Nicholls ◽  
Jim G. Partridge ◽  
Dougal G. McCulloch

AbstractHexagonal boron nitride (hBN) is a promising material for a range of applications including deep-ultraviolet light emission. Despite extensive experimental studies, some fundamental aspects of hBN remain unknown, such as the type of stacking faults likely to be present and their influence on electronic properties. In this paper, different stacking configurations of hBN are investigated using CASTEP, a pseudopotential density functional theory code. AB-b stacking faults, in which B atoms are positioned directly on top of one another while N atoms are located above the center of BN hexagons, are shown to be likely in conventional AB stacked hBN. Bandstructure calculations predict a single direct bandgap structure that may be responsible for the discrepancies in bandgap type observed experimentally. Calculations of the near edge structure showed that different stackings of hBN are distinguishable using measurements of core-loss edges in X-ray absorption and electron energy loss spectroscopy. AB stacking was found to best reproduce features in the experimental B and N K-edges. The calculations also show that splitting of the 1s to π* peak in the B K-edge, recently observed experimentally, may be accounted for by the presence of AB-b stacking faults.


2015 ◽  
Vol 67 (6) ◽  
pp. 622-629 ◽  
Author(s):  
Nehal S. Ahmed ◽  
Hamdy S. Abdel-Hameed ◽  
Ahmed F. El-Kafrawy ◽  
Amal M. Nassar

Purpose – The aim of this paper is to solve the problem of carbonaceous deposits in automotive engines by preparing different ashless detergent/dispersant additives based on propylene oxide (PO) and different amines. Carbonaceous deposits in automotive engines are the major problems associated with oil aging. Efficient detergents and dispersants have been used to solve this problem, particularly in lubricating oils. Design/methodology/approach – The structures of the prepared compounds were confirmed using Fourier transform infrared spectroscopy (FT-IR), proton nuclear magnetic resonance (1H-NMR) and gel permeation chromatography (GPC) for determination of molecular weight. This was followed by the evaluation of the prepared compounds such as detergent/dispersant and antioxidants additives for lubricating engine oil using several techniques such as variation of viscosity ratio, change in total acid number, optical density using infrared techniques, spot method, determination of sludge and determination the potential detergent dispersant efficiency (PDDE). Findings – All the prepared compounds were found to be soluble in lubricating oil. The efficiency of the prepared compounds such as antioxidant and detergent/dispersant additives for lubricating oil was investigated. It was found that the additives have excellent power of dispersion, detergency and the most efficient additives such as antioxidant those prepared by using n,n-dimethyloctadecylamine (NDOA) and di-n-butyl dithio phosphoric acid. Practical implications – The paper includes preparation of new compounds from the reaction of propoxylated amines and different organic acids and evaluates them as detergent/dispersant and antioxidants additives by using several techniques. Originality/value – This paper fulfils an identified need to prepare new compounds from the reaction of propoxylated amines and different organic acids and evaluates them as additives by using different methods. All were found to have better efficiency as compared with commercial additives.


2011 ◽  
Vol 233-235 ◽  
pp. 171-174
Author(s):  
Fu Chuan Huang ◽  
Yun Guo Xie ◽  
Mao Li Yang ◽  
Hui Juan Luo ◽  
Pan Tong ◽  
...  

For high power density diesel engine operating characteristics and its unique compact structure, the development of new high power density diesel engine oil referred to the latest diesel engine oil standard GB 11122-2006. Through the comprehensive assessment of physical and chemical properties, the composite of poly a-olefin (PAO) and polymer esters was determined as base oil,and added high-performance additives. This oil developed has clean dispersion, antioxidation, anti-wear , anti-corrosion and other properties. the lubricating oil can well satisfy the performance requirements of high power density diesel engine.


2016 ◽  
Vol 68 (1) ◽  
pp. 30-34 ◽  
Author(s):  
Laura Peña-Parás ◽  
Demófilo Maldonado-Cortés ◽  
Jaime Taha-Tijerina ◽  
Patricio García-Pineda ◽  
Gerardo Tadeo Garza ◽  
...  

Purpose – The purpose of this paper is to evaluate the extreme pressure properties of CuO and TiO2 nanoparticle additives with the incorporation of a surfactant within a synthetic fluid for metal-forming applications. Design/methodology/approach – The paper studies the effect of CuO and TiO2 nanoparticle additives at various concentrations (0.01, 0.05 and 0.10 wt. per cent) in a synthetic lubricant fluid under extreme pressure conditions. Oleic acid surfactant is added to the nanolubricant to improve dispersion and stability of nanoparticles. Extreme pressure tribological tests are performed on a four-ball T-02 tribotester according to the ITEePib Polish method for testing lubricants under conditions of scuffing. Findings – The results show that the addition CuO and TiO2 nanoparticles under the presence of OA resulted in an increase of the load-carrying capacity (poz) of the lubricant up to 137 and 60 per cent, respectively. The seizure load was also increased by 50 and 15 per cent, respectively. Practical implications – The results show that CuO and TiO2 nanoparticles can be successfully used as additives improving extreme pressure properties of lubricants. Originality/value – This demonstrates the potential of nanoparticle additives using surfactants for improving the extreme pressure properties of lubricants. These nanolubricants can be used for metal-forming applications like deep-drawing, achieving an increased tool life.


2018 ◽  
Vol 70 (1) ◽  
pp. 8-14 ◽  
Author(s):  
Xiao-dong Yu ◽  
Lei Geng ◽  
Xiao-jun Zheng ◽  
Zi-xuan Wang ◽  
Xiao-gang Wu

Purpose Rotational speed and load-carrying capacity are two mutual coupling factors which affect high precision and stable operation of a hydrostatic thrust bearing. The purpose of this paper is to study reasonable matching relationship between the rotational speed and the load-carrying capacity. Design/methodology/approach A mathematical model of relationship between the rotational speed and the load-carrying capacity of the hydrostatic bearing with double-rectangle recess is set up on the basis of the tribology theory and the lubrication theory, and the load and rotational speed characteristics of an oil film temperature field and a pressure field in the hydrostatic bearing are analyzed, reasonable matching relationship between the rotational speed and the load-carrying capacity is deduced and a verification experiment is conducted. Findings By increasing the rotational speed, the oil film temperature increases, the average pressure decreases and the load-carrying capacity decreases. By increasing the load-carrying capacity, the oil film temperature and the average pressure increases and the rotational speed decreases; corresponding certain reasonable matching values are available. Originality/value The load-carrying capacity can be increased and the rotational speed improved by means of reducing the friction area of the oil recess by using low-viscosity lubricating oil and adding more oil film clearance; but, the stiffness of the hydrostatic bearing decreases.


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