Dyeing Properties to Wool Fabrics of Catechu Dye Purified by Micro-Filtration Membrane

2008 ◽  
Vol 12 (1) ◽  
pp. 32-38 ◽  
Author(s):  
Xiuliang Hou ◽  
Li Wei ◽  
Xinlong Zhang ◽  
Huihui Wu ◽  
Qicheng Zhou ◽  
...  

Catechu liquor, which is deep brown-red in color, was purified with a micro-filtration membrane and the stability of catechu dye to different levels of temperatures and pH were investigated in this paper. The effects of the dyeing conditions on color characteristic values and color fastnesses of the dyed wool fabrics were also investigated. The results show that the liquor of catechu dye is stable at pH values of 3-7 and its color changes to a deeper brown-red when its pH value is above 8. The preferable dyeing conditions for wool fabric with refined powder catechu dye are as follows: dyeing temperature of 100±C, pH value of 6.5 for the dye bath and catechu dye of 1-4% (o.w.f). The dyed wool fabric has good color fastnesses to washing, alkali perspiration and dry rubbing. However, its color fastness rating to wet rubbing is poor, ranging from 2-3. Further research will be needed on this aspect.

2017 ◽  
Vol 68 (02) ◽  
pp. 108-115 ◽  
Author(s):  
BENLI HÜSEYIN

In this study, woollen fabrics were dyed with the aqueous extract of fresh red cabbage leaves, containing kaempferol and quercetin as the main colorant species. Brassica vegetables are rich in polyphenols, flavonoids and glucosinolates. The dyeing was carried out with and without metal salts as mordants, such as KAl(SO4)2.12H2O, CuSO4.5H2O, FeSO4.7H2O and K2Cr2O7. Pre-and meta-mordanting methods were used in this study. Mordanted wool fabrics were dyed in a dyebath prepared with different pH values. The pH values of bath were 3, 5, 7, 9 and 11, respectively. Different colors and shades can be obtained within different pH values. The dyed fabrics were evaluated through color measurements and standard wash, perspiration, light and rub fastness tests. The dye absorbed by the fabrics and color properties were measured using a spectrophotometer. The color yield of dyed fabrics is expressed by K/S, and CIELAB (L*, a* and b*) values. The effects of mordant, methods of mordanting and pH value of the dye bath on the color values were studied. Finally, satisfactory results were obtained


2012 ◽  
Vol 454 ◽  
pp. 324-328
Author(s):  
Yan He ◽  
Ya Jing Liu ◽  
Yong Lin Cao ◽  
Li Xia Zhou

Infra-red absorption spectrometry, X-ray diffraction observations and characterization tests based on silicon molybdenum colorimetric method were used to investigate the optimal pH value controlling the stability of the silicic acid form. The experiment process was done by using sodium silicate as raw material. The results showed that the solution of silicate influenced the polymerization. The active silicic acid solution with a certain degree of polymerization was obtained by controlling the pH values.


2011 ◽  
Vol 36 (5) ◽  
pp. 554-562 ◽  
Author(s):  
B Xu ◽  
Q Li ◽  
Y Wang

SUMMARY This study investigated the influence of pH values of bleaching agents on the properties of the enamel surface. Sixty freshly extracted premolars were embedded in epoxy resin and mesiodistally sectioned through the buccal aspect into two parts. The sectioned slabs were distributed among six groups (n=10) and treated using different solutions. Group HCl was treated with HCl solution (pH=3.0) and served as a positive control. Group DW, stored in distilled water (pH=7.0), served as a negative control. Four treatment groups were treated using 30% hydrogen peroxide solutions with different pH values: group HP3 (pH=3.0), group HP5 (pH=5.0), group HP7 (pH=7.0), and group HP8 (pH=8.0). The buccal slabs were subjected to spectrophotometric evaluations. Scanning electron microscopy investigation and Micro-Raman spectroscopy were used to evaluate enamel surface morphological and chemical composition alterations. pH value has a significant influence on the color changes after bleaching (p<0.001). Tukey's multiple comparisons revealed that the order of color changes was HP8, HP7>HP5, HP3>HCl>DW. No obvious morphological alterations were detected on the enamel surface in groups DW, HP7, and HP8. The enamel surface of groups HCl and HP3 showed significant alterations with an erosion appearance. No obvious chemical composition changes were detected with respect to Micro-Raman analysis. Within the limitations of this study, it was concluded that no obvious morphological or chemical composition alterations of enamel surface were detected in the neutral or alkaline bleaching solutions. Bleaching solutions with lower pH values could result in more significant erosion of enamel, which represented a slight whitening effect.


2013 ◽  
Vol 850-851 ◽  
pp. 1197-1201
Author(s):  
Shu Qian Li ◽  
Chang Jiang Liu ◽  
Guang Xin ◽  
Bo Zhang

Polygalacturonase (PG) is key enzyme for softening consenescence mechanism of fruits. In this work, Properties of PG separated and purified from wildActinidia Argutawere studied. The result shows that the optimal reaction temperature is 40°C with a high enzyme activity around 30-50°C. PG keeps a thermo stability at the temperature ranging from 30-40°C, which decreases with increasing of temperature and PG will lose all its activity under 60-70°C for 1h. The optimal reaction pH value for this enzyme is 5.5. As far as the stability in different pH values is concerned, PG is relatively stable for preservation at pH4.5-6.5.The michaelis constant for PG is 27.31. When the concentration for EDTA is higher than 2mmol/L, it is inhibitive for PG . The metal ions of K+, Ca2+, Fe2+, Fe3+, Mg2+can activate the PG enzyme to some extent, the strength of activation:Mg2+Fe3+K+Fe2+Ca2+;The metal ions of Cu2+Zn2+Mn2+Ba2+Al3+can inhibit PG enzyme to some extent, the strength of inhibition:Al3+Ba2+Mn2+Cu2+Zn2+.


1977 ◽  
Vol 30 (7) ◽  
pp. 1417 ◽  
Author(s):  
H Farrah ◽  
WF Pickering

The effect of pH changes and the presence of ligands on the uptake of lead and cadmium ions by three types of clay mineral (kaolinite, illite and montmorillonite) has been investigated. ��� In the absence of ligands, metal ion adsorption increases gradually with increasing pH until a threshold pH value is exceeded, whereupon total precipitation/sorption (attributed to formation of hydroxy species) occurs. With ligands present, the threshold point tends to shift to higher pH values, the magnitude of the effect depending on the stability of the metal complex formed. Adsorption of cationic metal complexes is subject to competition from charged protonated ligand species; anionic complexes are not sorbed.


bionature ◽  
2019 ◽  
Vol 19 (2) ◽  
Author(s):  
M Nurul Qadarullah ◽  
Munir Munir ◽  
Irmayani Irmayani

Abstract. The purpose of this study was to determine the effect of adding lamtoro leaves (leucaenanleucocephale) on pH values and the level of damage at different levels. This study used a completely randomized design (CRD) with 4 treatment levels and 3 replications, namely J0= lamtoro leaf 0%, J1= addition of lamtoro leaves 40%, J2=addition of lamtoro leaves 30%, J3=addition of lamtoroleaves 20%. The results showed that the addition of lamtoro leaves to feed silage has a very real effect. on average the highest to lowest pH value is J0 is (5.16), J1 is (3.83), J2 is (4.67), and J3 is (4.73). Average damage to the highest to lewest is J0 is (6.67), J1 is (1.76), J2 is (4.38), and J3 is (4.78). From the results of the study, it is known that the best treatment and recommended defects are J1 treatment with the addition of lamtoro leaves 40%. Keywords: pH, damage rate, complete feed silage, lamtoro leaf, and rice strawid


2020 ◽  
Vol 2 (61) ◽  
pp. 119-127
Author(s):  
I. Kuzevanova ◽  
◽  
S. Povalchyk ◽  
A. Zulfigarov ◽  
A. Andriiko ◽  
...  

Inner complex compound of cobalt(III) with diaminoethanol, [Co(DetmHdetm)], and polynuclear complex compound 2Co-Ni with diaminoethanol, [Ni(CoDetmHdetm)2](NO3)2, were synthesized. Stabilities of the obtained compounds were investigated in non-aqueous (dimethylformamide) solutions at different values of pH (from acid to alkaline). Methods of potentiometric titration and electron absorption spectra were used to determine the range of pH values where the compounds do not decompose. As a result of these studies, we found that at the upper value of pH=7, the coordination surrounding of the metals (Co(III), Ni(II)) does not change. When the pH value becomes lower than 7 (with adding HCl acide), the inner complex of Co(III) begins to decompose. The ligand H2detm is replaced by Cland partial protonization of diethanolamine occurs. Also, transformation of N,Ncis isomer of inner complex compound of cobalt(III) to N,N-trans isomer takes place, thus reducing the symmetry of the complex. As for the polynuclear complex compound 2Co-Ni, when pH value becomes lower than 7, molecules of solvent begin to react with the products of partially destroyed complex. As a result, new complex compound is formed with the increase of coordination number of nickel(II) from 4 to 6. However, in alkaline solutions where pH values are up to 10, the heterometal complex compound of 2Co-Ni remains stable. Only partial hydrolysis of the solvent occurs in these conditions. The schemes of transformations of [Co(DetmHdetm)] and [Ni(CoDetmHdetm)2](NO3)2 occuring in non-aqueous (dimethylformamide) solutions at different values of pH (from acid to alkaline) are presented in the paper. The results of this study can be used for the preparation of precursor solution for the technology of catalytic materials production. Evidently, the range of pH from 7 to 10 must be maintained in order to avoid the contamination of the final products by the decomposed wastes of complexes and solvent.


2011 ◽  
Vol 332-334 ◽  
pp. 17-22
Author(s):  
Wei Li ◽  
Lei Zhao ◽  
Qian Wen Wang

In this paper,the extraction of rhubarb dye and the stability of rhubarb dye to heat and acetic was investigated. This paper investigated mordant dyeing of the wool fabric with metallic ions Fe2+,Al3+. And the single-factor experiment method and orthogonal experiments were used to study the optimum conditions of pre-mordant dyeing with aluminum ion. As a result, the stability of rhubarb dye to heat and acetic was very good. The optimum conditions of pre-mordant dyeing with aluminum ion was the bath ratio of 1:25, dyeing temperature of 90°C, ph value of 5, and the concentration of aluminum mordant was 5 percent of the fabric and the concentration of the natural dye rhubarb was 60 percent of the fabric.


2020 ◽  
pp. 540-548
Author(s):  
Jan Maarten de Bruijn

The stability of the sucrose molecule throughout processing is of the utmost importance, because in principle any sugar loss will increase the production costs per tonne of the obtained white sugar. Colour in processing is an important technological parameter too, since only an adequate colour control in processing allows the cost-effective production of white sugar crystals of the required quality. For process control of both sugar hydrolysis and colour formation it is necessary to understand the effect of pH value, temperature and retention time on these phenomena. This paper will describe the possible causes of sugar hydrolysis and colour, as well as how to control pH values and temperature in processing in order to limit the technological impact of both reactions in which invert sugar plays a central role.


2017 ◽  
Vol 21 (4) ◽  
pp. 263-275 ◽  
Author(s):  
Xue Zhao

Purpose This paper aims to study microwave pad dyeing process for wool fabric. Influences of various dyeing process conditions including galactomannan dosage, urea dosage, sodium bisulphite dosage, pH value, microwave irradiation power, treating time and cold batching time before microwave fixation on K/S values were analysed. The colour yield, fixation and levelness were compared between microwave fixation and cold batching fixation. Design/methodology/approach Colour yield (K/S values) was calculated using a Datacolor SF650 colour measuring and matching instrument (10° standard observer, CIE D65 light source Measuring; Datacolor, USA) and was used to determine the depth of the shade of dyed wool fabrics. Levelness of dyeing was evaluated also using the Datacolor SF650 colour measuring and matching instrument by measuring average deviation (S), range (P) of the maximum and the minimum for lightness (L), chroma (C) and hue (h), and balanced colour difference (ΔE) at 20 specified uniform locations on the wool fabrics. The colour difference was calculated as per the equation ΔE=(ΔL2+Δa2+Δb2)1/2 as appearing in the Experimental section. Fixation was determined using a Datacolor SF650 colour measuring and matching instrument by measuring ratio the of K/S for wool fabrics that were rinsed, washed, neutralised and then dried, and wool fabrics that were dried after fixation without washing. The pH of the padding solution was evaluated using a PHSJ-4A PH meter (Datacolor, USA). SEM analysis was done on JEOL JSM-5600LV machine (JEOL Ltd, Japan). Findings This study is based on application of microwave technology in the processing of silk. Originality/value It was found in laboratory experiments that uniform dyeing and deeper colour can be achieved throughout the microwave pad dyeing process for wool by using galactomannan. The novel process could reduce the dyeing time and the energy consumption of the traditional cold pad-batch dyeing process for wool fabric.


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