Comparison of Vis-NIR on in situ , intact core and dried, sieved soil to estimate clay content at field to regional scales

2017 ◽  
Vol 68 (4) ◽  
pp. 434-448 ◽  
Author(s):  
M. Poggio ◽  
D. J. Brown ◽  
R. S. Bricklemyer
Keyword(s):  



Geophysics ◽  
1988 ◽  
Vol 53 (12) ◽  
pp. 1556-1564 ◽  
Author(s):  
A. P. Annan ◽  
J. L. Davis ◽  
D. Gendzwill

Dry salt has a very low electrical conductivity which permits radio signals to be transmitted through substantial thicknesses of salt with little attenuation. Radar sounding experiments conducted in several potash mines in Saskatchewan, Canada, confirm that radar is an effective method for probing salt environments. The experiments had two main objectives: namely, to assess the utility of impulse radar for mapping stratigraphy in the salt beds above, below, and beside mining tunnels and to determine the electrical character of the potash beds in situ, since little information was available on the radio‐frequency properties of potash ore. The experiments were conducted with an impulse radar system using antennas which radiated pulses having center frequencies between 100 and 1000 MHz. The higher frequency antennas detected thin clay beds and stress‐relief cracks to depths of several meters. Sounding for deeper structure known to exist at ranges of several tens of meters was not always successful. The lower frequency antenna systems were found most useful for deeper sounding; in some instances known geologic horizons were detected at depths of up to 20 m. Deeper structure was frequently masked by shallow, high‐reflectivity stress‐relief cracks. The potash deposits were found to have a bulk dielectric constant in the range 5 to 6. In many areas, the evaporites have a significant clay content which governed the signal attenuation. Depth of penetration of the radar was generally greater in areas of lower clay content.



2013 ◽  
Vol 67 (8) ◽  
Author(s):  
Seyfullah Madakbaş ◽  
Emrah Çakmakçı ◽  
Memet Kahraman ◽  
Kadir Esmer

AbstractIn this study, polypyrrole-clay (PPy-clay) composites were prepared by the in situ chemical oxidative polymerisation of pyrrole in the presence of clay. The chemical structures of the composites were characterised by FTIR and XRD analysis. The thermal properties of these novel composites were analysed by TGA and DSC measurements. Glass-transition temperatures and char yields increased with the increase in clay content in the nanocomposites. The interactions between PPy and clay were mainly between polypyrrole and the layers of clay. It was observed that, as the amount of clay in the composites increased, the dielectric permittivity decreased while the dielectric conductivity of the composite materials increased.



1990 ◽  
Vol 195 ◽  
Author(s):  
Dominique Marion ◽  
Amos Nur ◽  
Hezhu Yin

ABSTRACTSystematic relations between porosity and compressional velocity Vp in the three component (sand, grains, clay and brine) systems (1) porous sandstone, (2) sands, and (3) suspensions, were obtained using experimental data and models. In Cemented Shaley Sandstones Vp was found to correlate linearly with porosity and clay content. The velocities in clean sandstones are about 7% higher than those predicted by the linear fit, indicating that a small amount of clay significantly reduces the elastic moduli of sandstones.For uncemented shaley sand, a model for the dependence of sonic velocity and porosity on clay content and compaction was developed for sand with clay dispersed in the pore space and for shale with suspened sand grains. The model closely mimics the experimentally observed minimum for porosity and the peak in velocity versus clay content. The results explain much of the scatter in velocity data in-situ. Velocity in suspensions at ϕ = 39% of grains in brine is close to values predicted by the Reuss (Isostress) average. Velocity dispersion, as suggested by Biot (1956 a,b) is calculated and observed in coarser sediments such as sand, whereas velocities in the finer clay and silt follow Biot's low frequency value.In total, our results provide the complete dependence of velocity on porosity in brine saturated sediment with clays, ranging from pure quartz to pure clay and water. Our results also highlight the crucial role of the critical porosity ϕ at about 39%, and the transition from cemented to uncemented sands.



Author(s):  
Khalil Faghihi ◽  
Mostafa Ashouri ◽  
Akram Feyzi

<p>A series of nanocomposites consist of organic polyimide and organo-modified clay content varying from 0 to 5 wt%, were successfully prepared by in situ polymerization. Polyimide used as a matrix of nanocomposite was prepared through the reaction of 1,4-bis [4-aminophenoxy] butane (APB) and 3،3΄،4،4΄-benzophenone tetra carboxylic dianhydride (BTDA) in N,N-dimethylacetamide (DMAc). The resulting nanocomposite films were characterized by FT-IR spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA).</p>



2020 ◽  
Author(s):  
Atmane Lamali ◽  
Lamine Hamai ◽  
Sid Ahmed Mokhtar ◽  
Abdelkrim Yelles-chaouche ◽  
Abdeslam Abtout ◽  
...  

&lt;p&gt;By measuring changes in radioelement concentrations, gamma-ray spectrometry is increasingly emerging as an efficient geophysical method that allows such changes to be geologically mapped according to lithology and soil type. At Ma&amp;#226;dna crater in southern Algeria, this method has been used to monitor any changes in the composition of the target rocks that may be associated with the impact cratering process. For this purpose, several measurements were carried out in situ using a portable field gamma spectrometer. As a result, most predominantly calcareous surface lithologies, exposed on the rim and flanks of the crater, showed a very low emitted radiometric response over the three channels (K, Th, U). However, no more than 90 Cps were counted both inside and outside the crater. Such a rate is indeed expected in sedimentary rocks with low clay content, and this remains valid, as long as other exogenous mineralogical enrichments are excluded. On the other hand, the contoured radioelement concentrations maps, have demonstrated an anomalous enhanced gamma radiation levels of potassium-dominated peaks over the central part of the crater and in the surrounding wadis. Nevertheless, the central potassium anomaly is well correlated with the shallower magnetic one that has been described in previous studies (see e.g. Lamali et al., 2016). Therefore, either near the surrounding wadis or in the central part of this crater, this anomalously high level of radioactivity may be linked to an accumulation of later altered deposits. Consequently, there are no objective criteria to link these results to an impact event occurring at the Ma&amp;#226;dna structure, similar to what was done at the Serra da Cangalha crater (Vasconcelos et al., 2012).&lt;/p&gt;



Geoderma ◽  
2009 ◽  
Vol 150 (3-4) ◽  
pp. 253-266 ◽  
Author(s):  
R.A. Viscarra Rossel ◽  
S.R. Cattle ◽  
A. Ortega ◽  
Y. Fouad


1970 ◽  
Vol 20 (1) ◽  
pp. 71-80 ◽  
Author(s):  
MM Hossain ◽  
ZH Khan ◽  
MS Hussain ◽  
AR Mazumder

Most of the soil samples from four pedons representing some extensive soil series from the Ganges river floodplain of Bangladesh found to be heavy textured with clay content averaging from 43 to 55 per cent up to a depth of one meter. The soils had neutral to alkaline reaction with high percentage of base saturation. Because of seasonal flooding ranging from two - three months the soils have developed redoximorphic features including redox concentration in the middle zone and a redox depletion in the lower zone of the profiles. The seasonal submergence and drying are the most active factors in developing the morphogenetic features in these soils. Smectite was the dominant clay mineral followed by mica and kaolinite with small quantities of vermiculites and interstratified minerals. The minerals in the clay fraction of the soils appear to be inherited from alluvial parent materials with very little in situ mineral transformation. The soils were characterized at the family categoric level of USDA soil taxonomy.Key words: Ganges river floodplain; Characterization; Classification; Cultivated soilsDOI: http://dx.doi.org/10.3329/dujbs.v20i1.8870Dhaka Univ. J. Biol. Sci. 20(1): 71-80, 2011 (January)



2003 ◽  
Vol 77 (11) ◽  
pp. 6332-6340 ◽  
Author(s):  
A. J. Malkin ◽  
A. McPherson ◽  
P. D. Gershon

ABSTRACT Vaccinia virus, the basis of the smallpox vaccine, is one of the largest viruses to replicate in humans. We have used in situ atomic force microscopy (AFM) to directly visualize fully hydrated, intact intracellular mature vaccinia virus (IMV) virions and chemical and enzymatic treatment products thereof. The latter included virion cores, core-enveloping coats, and core substructures. The isolated coats appeared to be composed of a highly cross-linked protein array. AFM imaging of core substructures indicated association of the linear viral DNA genome with a segmented protein sheath forming an extended ∼16-nm-diameter filament with helical surface topography; enclosure of this filament within a 30- to 40-nm-diameter tubule which also shows helical topography; and enclosure of the folded, condensed 30- to 40-nm-diameter tubule within the core by a wall covered with peg-like projections. Proteins observed attached to the 30- to 40-nm-diameter tubules may mediate folding and/or compaction of the tubules and/or represent vestiges of the core wall and/or pegs. An accessory “satellite domain” was observed protruding from the intact core. This corresponded in size to isolated 70- to 100-nm-diameter particles that were imaged independently and might represent detached accessory domains. AFM imaging of intact virions indicated that IMV underwent a reversible shrinkage upon dehydration (as much as 2.2- to 2.5-fold in the height dimension), accompanied by topological and topographical changes, including protrusion of the satellite domain. As shown here, the chemical and enzymatic dissection of large, asymmetrical virus particles in combination with in situ AFM provides an informative complement to other structure determination techniques.



Sign in / Sign up

Export Citation Format

Share Document