High Pressure Test Results of a Catalytic Combustor for Gas Turbine

1998 ◽  
Vol 120 (3) ◽  
pp. 509-513 ◽  
Author(s):  
T. Fujii ◽  
Y. Ozawa ◽  
S. Kikumoto ◽  
M. Sato ◽  
Y. Yuasa ◽  
...  

Recently, the use of gas turbine systems, such as combined cycle and cogeneration systems, has gradually increased in the world. But even when a clean fuel such as LNG (liquefied natural gas) is used, thermal NOx is generated in the high temperature gas turbine combustion process. The NOx emission from gas turbines is controlled through selective catalytic reduction processes (SCR) in the Japanese electric industry. If catalytic combustion could be applied to the combustor of the gas turbine, it is expected to lower NOx emission more economically. Under such high temperature and high pressure conditions, as in the gas turbine, however, the durability of the catalyst is still insufficient. So it prevents the realization of a high temperature catalytic combustor. To overcome this difficulty, a catalytic combustor combined with premixed combustion for a 1300°C class gas turbine was developed. In this method, catalyst temperature is kept below 1000°C, and a lean premixed gas is injected into the catalytic combustion gas. As a result, the load on the catalyst is reduced and it is possible to prevent the catalyst deactivation. After a preliminary atmospheric test, the design of the combustort was modified and a high pressure combustion test was conducted. As a result, it was confirmed that NOx emission was below 10 ppm (at 16 percent O2) at a combustor outlet gas temperature of 1300°C and that the combustion efficiency was almost 100 percent. This paper presents the design features and test results of the combustor.

Author(s):  
T. Fujii ◽  
Y. Ozawa ◽  
S. Kikumoto ◽  
M. Sato ◽  
Y. Yuasa ◽  
...  

Recently, use of gas turbine systems such as combined cycle and cogeneration systems has gradually increased in the world. But even when a clean fuel such as LNG (liquefied natural gas) is used, thermal NOx is generated in the high temperature gas turbine combustion process. The NOx emission from gas turbines is controlled through selective catalytic reduction processes (SCR) in the Japanese electric industry. If catalytic combustion could be applied to the combustor of the gas turbine, it is expected to lower NOx emission more economically. Under such high temperature and high pressure conditions as in the gas turbine, however, the durability of the catalyst is still insufficient. So it prevents the realization of a high temperature catalytic combustor. To overcome this difficulty, a catalytic combustor combined with premixed combustion for a 1300°C class gas turbine was developed. In this method, catalyst temperature is kept below 1000°C and a lean premixed gas is injected into the catalytic combustion gas. As a result, the load on the catalyst is reduced and it is possible to prevent the catalyst deactivation. After a preliminary atmospheric test, the design of the combustor was modified and a high pressure combustion test was conducted. As a result, it was confirmed that NOx emission was below 10ppm (at 16% O2) at a combustor outlet gas temperature of 1300°C and that the combustion efficiency was almost 100%. This paper presents the design features and test results of the combustor.


Author(s):  
M. W. Horner ◽  
A. Caruvana

Final component and technology verification tests have been completed for application to a 2600°F rotor inlet temperature gas turbine. These tests have proven the capability of combustor, turbine hot section, and IGCC fuel systems and controls to operate in a combined cycle plant burning a coal-derived gas fuel at elevated gas turbine inlet temperatures (2600–3000°F). This paper presents recent test results and summarizes the overall progress made during the DOE-HTTT Phase II program.


2021 ◽  
Author(s):  
Takashi Nishiumi ◽  
Hirofumi Ohara ◽  
Kotaro Miyauchi ◽  
Sosuke Nakamura ◽  
Toshishige Ai ◽  
...  

Abstract In recent years, MHPS achieved a NET M501J gas turbine combined cycle (GTCC) efficiency in excess of 62% operating at 1,600°C, while maintaining NOx under 25ppm. Taking advantage of our gas turbine combustion design, development and operational experience, retrofits of earlier generation gas turbines have been successfully applied and will be described in this paper. One example of the latest J-Series technologies, a conventional pilot nozzle was changed to a premix type pilot nozzle for low emission. The technology was retrofitted to the existing F-Series gas turbines, which resulted in emission rates of lower than 9ppm NOx(15%O2) while maintaining the same Turbine Inlet Temperature (TIT: Average Gas Temperature at the exit of the transition piece). After performing retrofitting design, high pressure rig tests, the field test prior to commercial operation was conducted on January 2019. This paper describes the Ultra-Low NOx combustor design features, retrofit design, high pressure rig test and verification test results of the upgraded M501F gas turbine. In addition, it describes another upgrade of turbine to improve efficiency and of combustion control system to achieve low emissions. Furthermore it describes the trouble-free upgrade of seven (7) units, which was completed by utilizing MHPS integration capabilities, including handling all the design, construction and service work of the main equipment, plant and control systems.


1999 ◽  
Vol 121 (3) ◽  
pp. 422-428 ◽  
Author(s):  
Y. Ozawa ◽  
Y. Tochihara ◽  
N. Mori ◽  
I. Yuri ◽  
T. Kanazawa ◽  
...  

A catalytically assisted ceramic combustor for a gas turbine was designed to achieve low NOx emission under 5 ppm at a combustor outlet temperature over 1300°C. This combustor is composed of a burner system and a ceramic liner behind the burner system. The burner system consists of 6 catalytic combustor segments and 6 premixing nozzles, which are arranged in parallel and alternately. The ceramic liner is made up of the layer of outer metal wall, ceramic fiber, and inner ceramic tiles. Fuel flow rates for the catalysts and the premixing nozzles are controlled independently. Catalytic combustion temperature is controlled under 1000°C, premixed gas is injected from the premixing nozzles to the catalytic combustion gas and lean premixed combustion over 1300°C is carried out in the ceramic liner. This system was designed to avoid catalytic deactivation at high temperature and thermal and mechanical shock fracture of the honeycomb monolith of the catalyst. A combustor for a 10 MW class, multican type gas turbine was tested under high pressure conditions using LNG fuel. Measurements of emission, temperature, etc. were made to evaluate combustor performance under various combustion temperatures and pressures. This paper presents the design features and the test results of this combustor.


Author(s):  
R. A. Dalla Betta ◽  
J. C. Schlatter ◽  
S. G. Nickolas ◽  
D. K. Yee ◽  
T. Shoji

A catalytic combustion system has been developed which feeds full fuel and air to the catalyst but avoids exposure of the catalyst to the high temperatures responsible for deactivation and thermal shock fracture of the supporting substrate. The combustion process is initiated by the catalyst and is completed by homogeneous combustion in the post catalyst region where the highest temperatures are obtained. This has been demonstrated in subscale test rigs at pressures up to 14 atmospheres and temperatures above 1300°C (2370°F). At pressures and gas linear velocities typical of gas turbine combustors, the measured emissions from the catalytic combustion system are NOx < 1 ppm, CO < 2 ppm and UHC < 2 ppm, demonstrating the capability to achieve ultra low NOx and at the same time low CO and UHC.


Author(s):  
Stéphanie Hoffmann ◽  
Michael Bartlett ◽  
Matthias Finkenrath ◽  
Andrei Evulet ◽  
Tord Peter Ursin

This paper presents the results of an evaluation of advanced combined cycle gas turbine plants with precombustion capture of CO2 from natural gas. In particular, the designs are carried out with the objectives of high efficiency, low capital cost, and low emissions of carbon dioxide to the atmosphere. The novel cycles introduced in this paper are comprised of a high-pressure syngas generation island, in which an air-blown partial oxidation reformer is used to generate syngas from natural gas, and a power island, in which a CO2-lean syngas is burnt in a large frame machine. In order to reduce the efficiency penalty of natural gas reforming, a significant effort is spent evaluating and optimizing alternatives to recover the heat released during the process. CO2 is removed from the shifted syngas using either CO2 absorbing solvents or a CO2 membrane. CO2 separation membranes, in particular, have the potential for considerable cost or energy savings compared with conventional solvent-based separation and benefit from the high-pressure level of the syngas generation island. A feasibility analysis and a cycle performance evaluation are carried out for large frame gas turbines such as the 9FB. Both short-term and long-term solutions have been investigated. An analysis of the cost of CO2 avoided is presented, including an evaluation of the cost of modifying the combined cycle due to CO2 separation. The paper describes a power plant reaching the performance targets of 50% net cycle efficiency and 80% CO2 capture, as well as the cost target of 30$ per ton of CO2 avoided (2006 Q1 basis). This paper indicates a development path to this power plant that minimizes technical risks by incremental implementation of new technology.


Author(s):  
Ralph A. Dalla Betta ◽  
James C. Schlatter ◽  
Sarento G. Nickolas ◽  
Martin B. Cutrone ◽  
Kenneth W. Beebe ◽  
...  

The most effective technologies currently available for controlling NOx emissions from heavy-duty industrial gas turbines are either diluent injection in the combustor reaction zone, or lean premixed Dry Low NOx (DLN) combustion. For ultra low emissions requirements, these must be combined with selective catalytic reduction (SCR) DeNOx systems in the gas turbine exhaust. An alternative technology for achieving comparable emissions levels with the potential for lower capital investment and operating cost is catalytic combustion of lean premixed fuel and air within the gas turbine. The design of a catalytic combustion system using natural gas fuel has been prepared for the GE model MS9OOIE gas turbine. This machine has a turbine inlet temperature to the first rotating stage of over 1100°C and produces approximately 105 MW electrical output in simple cycle operation. The 508 mm diameter catalytic combustor designed for this gas turbine was operated at full-scale conditions in tests conducted in 1992 and 1994. The combustor was operated for twelve hours during the 1994 test and demonstrated very low NOx emissions from the catalytic reactor. The total exhaust NOx level was approximately 12–15 ppmv and was produced almost entirely in the preburner ahead of the reactor. A small quantity of steam injected into the preburner reduced the NOx emissions to 5–6 ppmv. Development of the combustion system has continued with the objectives of reducing CO and UHC emissions, understanding the parameters affecting reactor stability and spatial non-uniformities which were observed at low inlet temperature, and improving the structural integrity of the reactor system to a level required for commercial operation of gas turbines. Design modifications were completed and combustion hardware was fabricated for additional full-scale tests of the catalytic combustion system in March 1995 and January 1996. This paper presents a discussion of the combustor design, the catalytic reactor design and the results of full-scale testing of the improved combustor at MS9OOIE cycle conditions in the March 1995 and January 1996 tests. Major improvements in performance were achieved with CO and UHC emissions of 10 ppmv and 0 ppmv at base load conditions. This ongoing program will lead to two additional full-scale combustion system tests in 1996. The results of these tests will be available for discussion at the June 1996 Conference in Birmingham.


Author(s):  
Colin F. McDonald

With the capability of burning a variety of fossil fuels, giving high thermal efficiency, and operating with low emissions, the gas turbine is becoming a major prime-mover for a wide spectrum of applications. Almost three decades ago two experimental projects were undertaken in which gas turbines were actually operated with heat from nuclear reactors. In retrospect, these systems were ahead of their time in terms of technology readiness, and prospects of the practical coupling of a gas turbine with a nuclear heat source towards the realization of a high efficiency, pollutant free, dry-cooled power plant has remained a long-term goal, which has been periodically studied in the last twenty years. Technology advancements in both high temperature gas-cooled reactors, and gas turbines now make the concept of a nuclear gas turbine plant realizable. Two possible plant concepts are highlighted in this paper, (1) a direct cycle system involving the integration of a closed-cycle helium gas turbine with a modular high temperature gas cooled reactor (MHTGR), and (2) the utilization of a conventional and proven combined cycle gas turbine, again with the MHTGR, but now involving the use of secondary (helium) and tertiary (air) loops. The open cycle system is more equipment intensive and places demanding requirements on the very high temperature heat exchangers, but has the merit of being able to utilize a conventional combined cycle turbo-generator set. In this paper both power plant concepts are put into perspective in terms of categorizing the most suitable applications, highlighting their major features and characteristics, and identifying the technology requirements. The author would like to dedicate this paper to the late Professor Karl Bammert who actively supported deployment of the closed-cycle gas turbine for several decades with a variety of heat sources including fossil, solar, and nuclear systems.


Author(s):  
Eric Chia ◽  
Bruce S. Kang ◽  
Min Zheng ◽  
Yang Li ◽  
Minking Chyu

Current and future designs for advanced turbine systems, such as Integrated Gasification Combined Cycle (IGCC), advanced Natural Gas Combined Cycle (NGCC), and the emerging supercritical CO2 (SCO2) systems require increasing turbine inlet temperature (TIT), which is well beyond the substrate melting temperature. The well-known approach is coating the turbine blade with thermal barrier coatings (TBC) combined with internal cooling channel in the substrate. However, due to thermally grown oxide (TGO) and thermal expansion mismatch stresses, TBC spallation failure is a major concern. Furthermore, neither the ceramic coating layer nor the metallic bond coat in current TBC system can provide structural support to house the internal cooling channels. In this research, a method to fabricate high temperature protective structural coating on top of critical gas turbine components by additive manufacturing (AM) technique using oxide dispersion strengthening (ODS) metal powder is presented. A novel combined mechanochemical bonding (MCB) plus ball milling process is utilized to produce near spherical and uniformly alloyed ODS powders. AM-processed ODS coating by direct energy deposition (DED) method on MAR-247 substrate, with laser powers from 100W to 200W were carried out. The ODS coated samples were then subjected to thermal cyclic loadings for over 2200 cycles. For comparison, in our earlier studies, under the same cyclic testing condition, typical tested TBC coupons showed spallation failure after ∼400 cycles. Correlation of the measured ODS coating Young’s modulus using a unique non-destructive micro-indentation testing method with evolution of the ODS microstructures are studied to identify optimum AM processing parameters for best performance of the ODS samples. In particular, stability of secondary γ′ phase in the ODS coating after thermal cycles is analyzed. Test results revealed a thin steady durable alpha alumina oxide layer on the best performance ODS samples. After 2,200 thermal cycles, strong bonding at ODS/substrate interface is also maintained for most of the ODS coated samples. Test results also showed stable substrate microstructure due to the protective ODS coating even after 2,200 thermal cycles. These preliminary test results showed strong potential for applications of AM-assisted ODS coating on advanced gas turbine components.


Mathematics ◽  
2020 ◽  
Vol 8 (12) ◽  
pp. 2191
Author(s):  
Thanh Dam Mai ◽  
Jaiyoung Ryu

The flow and heat-transfer attributes of gas turbines significantly affect the output power and overall efficiency of combined-cycle power plants. However, the high-temperature and high-pressure environment can damage the turbine blade surface, potentially resulting in failure of the power plant. Because of the elevated cost of replacing turbine blades, damaged blades are usually repaired through modification of their profile around the damage location. This study compared the effects of modifying various damage locations along the leading edge of a rotor blade on the performance of the gas turbine. We simulated five rotor blades—an undamaged blade (reference) and blades damaged on the pressure and suction sides at the top and middle. The Reynolds-averaged Navier–Stokes equation was used to investigate the compressible flow in a GE-E3 gas turbine. The results showed that the temperatures of the blade and vane surfaces with damages at the middle increased by about 0.8% and 1.2%, respectively. This causes a sudden increase in the heat transfer and thermal stress on the blade and vane surfaces, especially around the damage location. Compared with the reference case, modifications to the top-damaged blades produced a slight increase in efficiency about 2.6%, while those to the middle-damaged blades reduced the efficiency by approximately 2.2%.


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