Consideration on Thermal Decomposition of Calcium Hydroxide Pellets for Energy Storage

1989 ◽  
Vol 111 (3) ◽  
pp. 245-250 ◽  
Author(s):  
I. Fujii ◽  
K. Tsuchiya ◽  
Y. Shikakura ◽  
M. S. Murthy
Keyword(s):  
Heat Transfer ◽  
Thermal Decomposition ◽  
Calcium Hydroxide ◽  
Thermal Stresses ◽  
Zinc Powder ◽  
Solar Thermal Energy ◽  
Mechanism Of Decomposition ◽  
Effect Of Additives ◽  
Nucleation Sites ◽  
Reversible Chemical Reaction

The reversible chemical reaction of Ca(OH)2/CaO appears to be attractive for storage of solar thermal energy, in view of the nonpolluting and nontoxic nature of the reactants. This paper presents some data on thermal decomposition of calcium hydroxide pellets along with its additives of aluminum, aluminum hydroxide, zinc, and copper. The addition of aluminum and zinc powder enhanced the rate of decomposition considerably at 450° C, but copper had no effect. Considerations on the effect of additives are also discussed in some detail, though their effects are not established with certainty. There is some evidence that heat transfer into the pellet, and the number of potential nucleation sites due to thermal stresses, influence the kinetics and mechanism of decomposition.

scholarly journals The use of a solution of the inverse heat conduction problem to monitor thermal stresses

2019 ◽  
Vol 108 ◽  
pp. 01003
Author(s):  
Jan Taler ◽  
Piotr Dzierwa ◽  
Magdalena Jaremkiewicz ◽  
Dawid Taler ◽  
Karol Kaczmarski ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Heat Transfer Coefficient ◽  
Transfer Coefficient ◽  
Power Plants ◽  
Thermal Stresses ◽  
Thermal Power ◽  
Temperature Fields ◽  
Thick Wall ◽  
Fluid Temperature ◽  
Unsteady Temperature

Thick-wall components of the thermal power unit limit maximum heating and cooling rates during start-up or shut-down of the unit. A method of monitoring the thermal stresses in thick-walled components of thermal power plants is presented. The time variations of the local heat transfer coefficient on the inner surface of the pressure component are determined based on the measurement of the wall temperature at one or six points respectively for one- and three-dimensional unsteady temperature fields in the component. The temperature sensors are located close to the internal surface of the component. A technique for measuring the fastchanging fluid temperature was developed. Thermal stresses in pressure components with complicated shapes can be computed using FEM (Finite Element Method) based on experimentally estimated fluid temperature and heat transfer coefficient

Identification of three-dimensional transient temperature fields in thick-walled elements using the inverse method

2018 ◽  
Vol 28 (1) ◽  
pp. 138-150 ◽  
Author(s):  
Magdalena Jaremkiewicz
Keyword(s):  
Heat Transfer ◽  
Heat Transfer Coefficient ◽  
Transfer Coefficient ◽  
Inverse Method ◽  
Thermal Stresses ◽  
Computing Time ◽  
Transient Temperature ◽  
Content Type ◽  
Inner Surface ◽  
The Heat Transfer Coefficient

Purpose The purpose of this paper is to propose a method of determining the transient temperature of the inner surface of thick-walled elements. The method can be used to determine thermal stresses in pressure elements. Design/methodology/approach An inverse marching method is proposed to determine the transient temperature of the thick-walled element inner surface with high accuracy. Findings Initially, the inverse method was validated computationally. The comparison between the temperatures obtained from the solution for the direct heat conduction problem and the results obtained by means of the proposed inverse method is very satisfactory. Subsequently, the presented method was validated using experimental data. The results obtained from the inverse calculations also gave good results. Originality/value The advantage of the method is the possibility of determining the heat transfer coefficient at a point on the exposed surface based on the local temperature distribution measured on the insulated outer surface. The heat transfer coefficient determined experimentally can be used to calculate thermal stresses in elements with a complex shape. The proposed method can be used in online computer systems to monitor temperature and thermal stresses in thick-walled pressure components because the computing time is very short.

Thermal Analysis of Cooling System in a Gas Turbine Transition Piece

2011 ◽  
Author(s):  
Jun Su Park ◽  
Namgeon Yun ◽  
Hokyu Moon ◽  
Kyung Min Kim ◽  
Sin-Ho Kang ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Gas Turbine ◽  
Thermal Stresses ◽  
Cooling System ◽  
Structural Information ◽  
Thermal Analyses ◽  
Thermal Design ◽  
Transfer Coefficients ◽  
Transition Piece ◽  
Inlet Conditions

This paper presents thermal analyses of the cooling system of a transition piece, which is one of the primary hot components in a gas turbine engine. The thermal analyses include heat transfer distributions induced by heat and fluid flow, temperature, and thermal stresses. The purpose of this study is to provide basic thermal and structural information on transition piece, to facilitate their maintenance and repair. The study is carried out primarily by numerical methods, using the commercial software, Fluent and ANSYS. First, the combustion field in a combustion liner with nine fuel nozzles is analyzed to determine the inlet conditions of a transition piece. Using the results of this analysis, pressure distributions inside a transition piece are calculated. The outside of the transition piece in a dump diffuser system is also analyzed. Information on the pressure differences is then used to obtain data on cooling channel flow (one of the methods for cooling a transition piece). The cooling channels have exit holes that function as film-cooling holes. Thermal and flow analyses are carried out on the inside of a film-cooled transition piece. The results are used to investigate the adjacent temperatures and wall heat transfer coefficients inside the transition piece. Overall temperature and thermal stress distributions of the transition piece are obtained. These results will provide a direction to improve thermal design of transition piece.

Numerical and Experimental Investigation of Interface Bonding Via Substrate Remelting of an Impinging Molten Metal Droplet

1996 ◽  
Vol 118 (1) ◽  
pp. 164-172 ◽  
Author(s):  
C. H. Amon ◽  
K. S. Schmaltz ◽  
R. Merz ◽  
F. B. Prinz
Keyword(s):  
Heat Transfer ◽  
Numerical Model ◽  
Molten Metal ◽  
Thermal Stresses ◽  
Initial Conditions ◽  
Metal Droplet ◽  
Solid Substrate ◽  
Numerical Results ◽  
Operating Conditions ◽  
Analytical Approaches

A molten metal droplet landing and bonding to a solid substrate is investigated with combined analytical, numerical, and experimental techniques. This research supports a novel, thermal spray shape deposition process, referred to as microcasting, capable of rapidly manufacturing near netshape, steel objects. Metallurgical bonding between the impacting droplet and the previous deposition layer improves the strength and material property continuity between the layers, producing high-quality metal objects. A thorough understanding of the interface heat transfer process is needed to optimize the microcast object properties by minimizing the impacting droplet temperature necessary for superficial substrate remelting, while controlling substrate and deposit material cooling rates, remelt depths, and residual thermal stresses. A mixed Lagrangian–Eulerian numerical model is developed to calculate substrate remelting and temperature histories for investigating the required deposition temperatures and the effect of operating conditions on remelting. Experimental and analytical approaches are used to determine initial conditions for the numerical simulations, to verify the numerical accuracy, and to identify the resultant microstructures. Numerical results indicate that droplet to substrate conduction is the dominant heat transfer mode during remelting and solidification. Furthermore, a highly time-dependent heat transfer coefficient at the droplet/substrate interface necessitates a combined numerical model of the droplet and substrate for accurate predictions of the substrate remelting. The remelting depth and cooling rate numerical results are also verified by optical metallography, and compare well with both the analytical solution for the initial deposition period and the temperature measurements during droplet solidification.

Conjugated Heat Transfer in Skirt Hot Box in Pressure Vessels

2006 ◽  
Author(s):  
Hossein Shokouhmand ◽  
Manoochehr Bozorgmehrian
Keyword(s):  
Heat Transfer ◽  
Natural Convection ◽  
Temperature Gradient ◽  
Thermal Stresses ◽  
Weld Line ◽  
Pressure Vessels ◽  
Conductive Heat ◽  
Air Pocket ◽  
Cyclic Operation ◽  
Conjugated Heat Transfer

Pressure vessels are common equipment in oil, gas and petrochemical industries. In a hot containing fluid vessel, excessive temperature gradient at junction of skirt to head (weld line), can cause unpredicted high thermal stresses; Thereby fracture of the vessel may occur as a result of cyclic operation. Providing a hot box (air pocket) in crotch space is a economical, applicable and easy mounted method in order to reduce the intensity of thermal stresses. Natural convection due to temperature difference between the wall of pocket, will absorb heat near the hot wall (head of the vessel) and release that near the cold wall (skirt of the vessel), then the skirt wall conducts heat to the earth as a fin. This conjugated heat transfer removes the temperature gradient boundary at welded junction. This phenomena will lead the temperature gradient on the weld line from a sudden to smooth behavior, thereby the skirt-head junction, that is a critical region, could be protected from excessive thermal stresses. In this paper the profit of hot box and conjugated heat transfer in cavity has been demonstrated experimentally. As a result it is shown that the conductive heat transfer through the skirt (which acts as a fin) ensures the continuation of natural convection in the box. Also the governing equations has been solved numerically and compared with experimental results.

Modelling of Convective Melt Flow and Interface Shape in Commercial Bridgman-Stockbarger Growth of CdZnTe

2000 ◽  
Author(s):  
Toby D. Rule ◽  
Ben Q. Li ◽  
Kelvin G. Lynn
Keyword(s):  
Heat Transfer ◽  
Thermal Stress ◽  
Solute Transport ◽  
Latent Heat ◽  
Thermal Stresses ◽  
Radiation Detector ◽  
Time History ◽  
High Quality ◽  
Melt Convection ◽  
The Impact

Abstract CdZnTe single crystals for radiation detector and IR substrate applications must be of high quality and controlled purity. The growth of such crystals from a melt is very difficult due to the low thermal conductivity and high latent heat of the material, and the ease with which dislocations, twins and precipitates are introduced during crystal growth. These defects may be related to solute transport phenomena and thermal stresses associated with the solidification process. As a result, production of high quality material requires excellent thermal control during the entire growth process. A comprehensive model is being developed to account for radiation and conduction within the furnace, thermal coupling between the furnace and growth crucible, and finally the thermal stress fields within the growing crystal which result from the thermal conditions imposed on the crucible. As part of this effort, the present work examines the heat transfer and fluid flow within the crucible, using thermal boundary conditions obtained from experimental measurements. The 2-D axisymetric numerical model uses the deforming finite element method, with allowance made for melt convection, solidification with latent heat release and conjugate heat transfer between the solid material and the melt. Results are presented for several stages of growth, including a time-history of the solid-liquid interface (1365 K isotherm). The impact of melt convection, thermal end conditions and furnace temperature gradient on the growth interface is evaluated. Future work will extend the present model to include radiation exchange within the furnace, and a transient analysis for studying solute transport and thermal stress.

scholarly journals FINITE ELEMENT ANALYSIS OF THE HEAT TRANSFER IN A PISTON

2020 ◽  
Vol 4 (1) ◽  
pp. 45-51
Author(s):  
Aisha Muhammad ◽  
Shanono Ibrahim Haruna
Keyword(s):  
Heat Transfer ◽  
Finite Element ◽  
Numerical Simulations ◽  
Internal Combustion Engines ◽  
Thermal Stresses ◽  
Maximum Temperature ◽  
Cylinder Wall ◽  
Fe Model ◽  
Piston Cylinder ◽  
Piston Head

The gas expansion process that takes place in a piston cylinder assembly have been used in numerous applications. However, the time-dependent process of heat transfer is still not fully apprehended as the expansion processes are complex and difficult due to the unsteady property of the turbulent flow process. Internal combustion Engines(ICE) designs are conducted with the aim of achieving higher efficiency in the thermal characteristics. To optimize these designs, numerical simulations are conducted. However, modelling of the process in terms of heat transfer and combustion is complex and challenging. For a designer to understand, calculate and quantify the thermal stresses and heat losses at different sections of the structure, understanding the piston-cylinder wall is needed. This study carried out a numerical simulations based on Finite Element Method (FEM) to investigatethe stresses in the piston, and temperature after loading. Appropriate boundary conditions were set on different surfaces for FE model. The study includes the effects of the thermal conductivity of the material of piston, cylinder wall, and connecting rod. Results show the maximum Von-misses stress occurs on the piston head with a value of 3486. 1MPa. The maximum temperature of the piston head and cylinder wall stands at 68.252 and 42.704 degree Celsius respectively.

The thermal decomposition of RDX at temperatures below the melting point. V. The evolution of occluded volatile matter prior to the decomposition, and the influence of past history of the sample on the rate of decomposition

1972 ◽  
Vol 25 (11) ◽  
pp. 2337 ◽  
Author(s):  
JJ Batten
Keyword(s):  
Thermal Decomposition ◽  
Reaction Time ◽  
Melting Point ◽  
Ambient Temperature ◽  
Ultraviolet Light ◽  
Past History ◽  
Volatile Matter ◽  
Post Irradiation ◽  
Mechanism Of Decomposition ◽  
History Of

It is fist demonstrated that the occluded solvents and gases which are often present in RDX are expelled prior to zero reaction time of thermal decomposition. Thus they do not seriously interfere with the use of pressure increase as a measure of the extent of thermal decomposition. The rate of thermal decomposition of sublimed RDX at 195�C is then compared with the rate after the following treatments, (i) preliminary grinding of the crystals, (ii) preparation of the crystals by different techniques, (iii) mixing RDX with various solid additives, (iv) interruption of the reaction by cooling, and (v) pre-irradiation with ultraviolet light. The results indicated that treatments (i), (ii), and (iv) had little effect on the rate, whereas (iii) and (v) could markedly influence the rate. Their effects are discussed in terms of the mechanism of decomposition. The results also indicated that there was a post-irradiation reaction of RDX at ambient temperature.

Sign in / Sign up

Export Citation Format

Share Document