The Comparison of Membrane Blocking Process and Yeast Membrane Filtration Data

Author(s):  
Aklilu T. G. Giorges ◽  
John A. Pierson

Membrane filtration systems are used in a variety of processing industries where their performance meet and exceed the requirements in cost and quality. However, it is a challenge to design a small pore-size membrane system that treats very concentrated, large-volume streams within a reasonable time period. In the processing industries, several membrane technologies are used to separate various fluid streams where the concentrate or filtrate contains high-value products. Nevertheless, pore blocking is one of the major factors determining the applicability, efficiency and performance of the membrane filtration and separation system. Inside and outside membrane pore blockages lead to concentration polarization and cake buildup that reduces the flux rate and increases losses in system efficiency. There are four pore blocking mechanisms identified and modeled (complete, standard, intermediate and cake). Several experimental and theoretical works exist that describe the pore flow and blocking process. Depending on the processing fluid and membrane characteristics, all or some of the blocking mechanisms will be exhibited during the filtration process. Understanding the fluid and membrane size and characteristics in addition to pore blocking mechanisms is very important to designing effective membrane filtration systems that overcome the drawbacks associated with membrane performance. Furthermore, developing a membrane filtration system with a target cleaning process that controls membrane performance declines and maintains a reasonable flux for an extended period of time requires understanding and identifying the cause of membrane blocking. In this study, the membrane blocking during the filtration process was investigated experimentally. The experiment was designed to simulate the characteristics of a fluid stream encountered in food processing. The higher concentration was selected to manage the experiment time as well as to address worst-case scenarios, while the lower concentrations were selected to manage the filter area reduction. Dead-end filtration of two yeast solution concentrations were filtered through two different filter areas. In addition, the dynamic tests were conducted with shear generated using an impeller operated at various rotational speeds. Several tests were performed and the filtrate volume, time, pressure and agitation rate were recorded. The volume was measured with a graduated cylinder and the time measured in seconds. The results show the membrane blocking process is significantly affected by the membrane and fluid characteristics. The plots of pore blocking models and the experimental membrane filtrate data show the dominant pore blocking observed for both filters and flow process is cake filtration. The side-by-side comparison also indicates that the dominant pore blocking mechanisms depend on time. Thus, the initial and final pore blocking may not be attributed to the same pore blocking mechanism. Although it cannot be clearly shown from the current study, some part of the experimental flux profile may also be shaped by the combined pore blocking effects.

Fluids ◽  
2020 ◽  
Vol 5 (3) ◽  
pp. 121
Author(s):  
Shi Yue Liu ◽  
Zhengyi Chen ◽  
Pejman Sanaei

Membrane filtration fouling is a very complex process and is determined by many properties such as the membrane internal morphology, membrane pore structure, flow rate and contaminant properties. In a very slow filtration process or during the late stage of filtration, when the flow rate is naturally low and Péclet number is small, particle diffusion is essential and cannot be neglected, while in typical filtration models, especially in moderate and fast filtration process, the main contribution stems from the particle advection. The objectives of this study is to formulate mathematical models that can (i) investigate how filtration process varies under possible effects of particles diffusion; and (ii) describe how membrane morphology evolves and investigate the filtration performance during the filtration process. We also compare the results with the case that diffusion is less important and make a prediction about what kind of membrane filter pore structure should be employed to achieve a particular optimum filtration performance. According to our results, the filtrate and efficiency of particle separation are found to be under the trade-off relationship, and the selection of the membrane properties depends on the requirement of the filtration.


Membranes ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 171 ◽  
Author(s):  
Hao Xu ◽  
Kang Xiao ◽  
Jinlan Yu ◽  
Bin Huang ◽  
Xiaomao Wang ◽  
...  

Membrane fouling is a complicated issue in microfiltration and ultrafiltration. Clearly identifying the dominant fouling mechanisms during the filtration process is of great significance for the phased and targeted control of fouling. To this end, we propose a semi-empirical multiple linear regression model to describe flux decline, incorporating the five fouling mechanisms (the first and second kinds of standard blocking, complete blocking, intermediate blocking, and cake filtration) based on the additivity of the permeate volume contributed by different coexisting mechanisms. A piecewise fitting protocol was established to distinguish the fouling stages and find the significant mechanisms in each stage. This approach was applied to a case study of a microfiltration membrane filtering a model foulant solution composed of polysaccharide, protein, and humic substances, and the model fitting unequivocally revealed that the dominant fouling mechanism evolved in the sequence of initial adaptation, fast adsorption followed by slow adsorption inside the membrane pores, and the gradual growth of a cake/gel layer on the membrane surface. The results were in good agreement with the permeate properties (total organic carbon, ultraviolet absorbance, and fluorescence) during the filtration process. This modeling approach proves to be simple and reliable for identifying the main fouling mechanisms during membrane filtration with statistical confidence.


Author(s):  
A Bergen ◽  
P M Wild ◽  
N Djilali ◽  
G W Vickers

A new membrane filtration process which uses the dynamic environment created on board a centrifuge rotor to enhance the performance of the separation process is described. Centrifugal membrane separation (CMS) combines the energy savings associated with centrifugal reverse osmosis (CRO) with the natural alleviation of concentration polarization and fouling due to the dynamic environment. A research centrifuge was constructed to compare the CMS process directly with a conventional process. An experimental investigation was conducted to determine the effects of centripetal and Coriolis acceleration on membrane performance. A description of the apparatus and the experimental results for various membrane orientations are presented. Significant reduction in the fouling rate and virtual elimination of concentration polarization have been shown.


2011 ◽  
Vol 63 (12) ◽  
pp. 2846-2852 ◽  
Author(s):  
J. W. Hatt ◽  
S. J. Judd ◽  
E. Germain

An automatic backflush pre-filter used for pre-treatment for secondary wastewater re-use was evaluated and optimised at two different mesh sizes over an 18 month period. The filter was initially run with a 500 μm rating mesh size, as recommended by the supplier of the downstream membrane filtration process, and then at 100 μm to investigate any change in water quality produced and associated improved membrane performance. With the 500 μm mesh in place, the filter fouling rate was low and a backflush was initiated every 3.5 h. For the 100 μm mesh the fouling rate was extremely rapid. Fouling was found to be caused by reverse side blockage of the pre-filter due to biofilm growth, and not by improved solids capture; there was no improvement in water quality with the smaller mesh size, since particle unloading from the biofilm took place. The pre-filter fouling rate was found to be related to turbidity. At a turbidity of 5 NTU the filter backflushed around 200 times per day, while at 10 NTU this increased to over 300 times. Further analysis enabled the backflush water volume to be decreased by reducing the backflush duration and increasing the backflush cycle time (i.e. the time between backflushes).


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Miquel Gomez ◽  
Elisenda Bañon-Maneus ◽  
Marta Arias-Guillén ◽  
Francisco Maduell

Abstract Adsorption properties of hemodialyzers are traditionally retrieved from diffusive treatments and mainly focused on inflammatory markers and plasma proteins. The possible depurative enhancement of middle and high molecular weight solutes, as well as protein-bound uremic toxins by adsorption in convective treatments, is not yet reported. We used discarded plasma exchanges from uremic patients and out-of-date erythrocytes as a novel in vitro uremic precursor matrix to assess removal and adsorption patterns of distinct material and structure but similar surface hemodialyzers in hemodialysis and on-line hemodiafiltration treatments. We further related the obtained results to the possible underlying membrane pore blocking mechanisms. Convection improved removal but slightly enhanced adsorption in the cellulosic and synthetic dialyzers tested. The polymethylmethacrylate hemodialyzer obtained the highest extracted ($$M_{ext}$$ M ext ) and adsorbed ($$M_{ads}$$ M ads ) mass values when submitted to hemodiafiltration for all molecules analyzed including albumin ($$M_{ext}=15.8\pm 3.9$$ M ext = 15.8 ± 3.9  g, $$M_{ads}=44.3\pm 11.5$$ M ads = 44.3 ± 11.5  mg), whereas the polyamide membrane obtained substantial lower results even for this molecule ($$M_{ext}=2.2\pm 1.2$$ M ext = 2.2 ± 1.2  g, $$M_{ads}=4.2\pm 0.7$$ M ads = 4.2 ± 0.7  mg) under the same treatment parameters. Hemodiafiltration in symmetric and enlarged pore hemodialyzers enhances removal and adsorption by internal pore deposition (intermediate pore-blocking) for middle and high molecular weight toxins but leads to substantial and deleterious albumin depuration.


Author(s):  
Rosiah Rohani ◽  
Izzati Izni Yusoff ◽  
Nadiah Khairul Zaman ◽  
Arshid Mahmood Ali ◽  
Nadiatul Atalia Balqis Rusli ◽  
...  

Water SA ◽  
2017 ◽  
Vol 43 (4) ◽  
pp. 573 ◽  
Author(s):  
Mónica L Salazar-Peláez ◽  
Juan Manuel Morgan-Sagastume ◽  
Adalberto Noyola

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