Effect Analysis of Various Gradient Particle Size Distribution on Electrical Performance of Anode-Supported SOFCs With Gradient Anode

Author(s):  
Pei Fu ◽  
Yuansheng Song ◽  
Jian Yang ◽  
Qiuwang Wang

Abstract Gradient particle size anode has shown great potential in improving the electrical performance of anode-supported solid oxide fuel cells (SOFCs). In the present study, a 3-D comprehensive model is established to study the effect of various gradient particle size distribution on the cell electrical performance for the anode microstructure optimization. The effect of homogeneous particle size on the cell performance is studied first. The maximum current density of homogeneous anode SOFC is obtained for the comparison with the electrical performance of gradient anode SOFC. Then the effect of various gradient particle size distribution on the cell molar fraction and polarization losses distribution is analyzed and discussed in detail. Increasing the particle diameter gradient can effectively reduce the anodic concentration overpotential. Decreasing the particle diameter of AFL2 is beneficial to reducing the activation and ohmic overpotentials. On these bases, the comprehensive electrical performances of SOFCs with gradient particle size anode and homogeneous anode are compared to highlight the optimal gradient particle diameter distribution. In the studied cases of the present work, the gradient particle diameter of 0.7 μm, 0.4 μm and 0.1 μm at ASL, AFL1 and AFL2 (Case 3) is the optimal particle size distribution.

2020 ◽  
Vol 142 (7) ◽  
Author(s):  
Pei Fu ◽  
Yuansheng Song ◽  
Jian Yang ◽  
Qiuwang Wang

Abstract Gradient particle size anode has shown great potential in improving the electrical performance of anode-supported solid oxide fuel cells (SOFCs). In this study, a 3D comprehensive model is established to study the effect of various gradient particle size distribution on the cell electrical performance for the anode microstructure optimization. The effect of homogeneous particle size on the cell performance is studied first. The maximum current density of homogeneous anode SOFC is obtained for the comparison with the electrical performance of gradient anode SOFC. Then the effect of various gradient particle size distribution on the cell molar fraction, polarization losses, and electronic current density distribution is analyzed and discussed in detail. Results show that increasing the particle diameter gradient can effectively reduce the anodic concentration overpotential. Decreasing the particle diameter of anode functional layer 2 is beneficial for reducing the activation and ohmic overpotentials. On these bases, the comprehensive electrical performance of SOFCs with gradient particle size anode and homogeneous anode is compared to highlight the optimal gradient particle diameter distribution. In the studied cases of this work, the gradient particle diameter of 0.7 μm, 0.4 μm, and 0.1 μm at anode support layer (ASL), anode functional layer 1, and anode functional layer 2 (case 3) is the optimal particle size distribution.


Author(s):  
S. Cazares ◽  
J. A. Barrios ◽  
C. Maya ◽  
G. Velásquez ◽  
M. Pérez ◽  
...  

Abstract An important physical property in environmental samples is particle size distribution. Several processes exist to measure particle diameter, including change in electrical resistance, blocking of light, the fractionation of field flow and laser diffraction (these being the most commonly used). However, their use requires expensive and complex equipment. Therefore, a Digital Microscopic Imaging Application (DMIA) method was developed adapting the algorithms used in the Helminth Egg Automatic Detector (HEAD) software coupled with a Neural Network (NN) and Bayesian algorithms. This allowed the determination of particle size distribution in samples of waste activated sludge (WAS), recirculated sludge (RCS), and pretreated sludge (PTS). The recirculation and electro-oxidation pre-treatment processes showed an effect in increasing the degree of solubilization (DS), decreasing particle size and breakage factor with ranges between 44.29%, and 31.89%. Together with a final NN calibration process, it was possible to compare results. For example, the 90th percentile of Equivalent Diameter (ED) value obtained by the DMIA with the corresponding result for the laser diffraction method. DMIA values: 228.76 μm (WAS), 111.18 μm (RCS), and 84.45 μm (PTS). DMIA processing has advantages in terms of reducing complexity, cost and time, and offers an alternative to the laser diffraction method.


2020 ◽  
Vol 57 (11) ◽  
pp. 1684-1694
Author(s):  
Shijin Li ◽  
Adrian R. Russell ◽  
David Muir Wood

Internal erosion (suffusion) is caused by water seeping through the matrix of coarse soil and progressively transporting out fine particles. The mechanical strength and stress–strain behavior of soils within water-retaining structures may be affected by internal erosion. Some researchers have set out to conduct triaxial erosion tests to study the mechanical consequences of erosion. Prior to conducting a triaxial test they subject a soil sample, which has an initially homogeneous particle-size distribution and density throughout, to erosion by causing water to enter one end of a sample and wash fine particles out the other. The erosion and movement of particles causes heterogeneous particle-size distributions to develop along the sample length. In this paper, a new soil sample formation procedure is presented that results in homogeneous particle-size distributions along the length of an eroded sample. Triaxial tests are conducted on homogeneous samples formed using the new procedure as well as heterogeneous samples created by the more commonly used approach. Results show that samples with homogeneous post-erosion particle-size distributions exhibit slightly higher peak deviator stresses than those that were heterogeneous. The results highlight the importance of ensuring homogeneity of post-erosion particle-size distributions when assessing the mechanical consequences of erosion. Forming samples using the new procedure enables the sample’s response to triaxial loading to be interpreted against a measure of its initially homogenous state.


2010 ◽  
Vol 21 (6) ◽  
pp. 676-680 ◽  
Author(s):  
Masatoshi Akashi ◽  
Tsukasa Otani ◽  
Atsuko Shimosaka ◽  
Yoshiyuki Shirakawa ◽  
Jusuke Hidaka

2014 ◽  
Vol 70 (11) ◽  
pp. 1873-1879 ◽  
Author(s):  
G. Garofalo ◽  
M. Carbone ◽  
P. Piro

The study analyzed the particle size distribution of particulate matter (PM) retained in two catch basins located, respectively, near a parking lot and a traffic intersection with common high levels of traffic activity. Also, the treatment performance of a filter medium was evaluated by laboratory testing. The experimental treatment results and the field data were then used as inputs to a numerical model which described on a qualitative basis the hydrological response of the two catchments draining into each catch basin, respectively, and the quality of treatment provided by the filter during the measured rainfall. The results show that PM concentrations were on average around 300 mg/L (parking lot site) and 400 mg/L (road site) for the 10 rainfall-runoff events observed. PM with a particle diameter of <45 μm represented 40–50% of the total PM mass. The numerical model showed that a catch basin with a filter unit can remove 30 to 40% of the PM load depending on the storm characteristics.


2011 ◽  
Vol 399-401 ◽  
pp. 828-833
Author(s):  
Xiao Su Cheng ◽  
Meng Qi Peng ◽  
Yu Fa Zhong

The centrifugal spray drying process of bauxite slurry was studied to investigate the influence of slurry solid content on the particle size distribution and the sphericity of the microspheres, and so was operation technology on average diameter and the sphericity of the microspheres. The optimal operation parameters are obtained to prepare high spherical microspheres bauxite with the diameter distribution of 100 μm and whose particle size distribution is narrow: the slurry solid content is 70 wt%, the dry air temperature is 250 °C, the rotation rate of spray head is 6000 rpm and the feed flow rate is 1 L/h in the experiments.


2017 ◽  
Vol 899 ◽  
pp. 95-100
Author(s):  
Kássia Graciele dos Santos ◽  
L.V. Ferreira ◽  
Ricardo Correa Santana ◽  
Marcos Antonio de Souza Barrozo

Spouted bed simulations are usually performed using only one granular phase with a mean particle diameter representing the entire particle mixture, instead of a particle size distribution. In this study, the effect of the particle size distribution is accounted through the simulation of a mixture with five granular phases. The results showed that the particle segregation occurs. Larger particles are more concentrated in the upper region, while the smaller particles are preferably positioned in the lower region of the bed. Computational simulation using CFD method reproduced well the segregation experiments with different participle sizes of sand.


2020 ◽  
Vol 205 ◽  
pp. 03010
Author(s):  
Tiancheng Liang ◽  
Jinwei Zhang ◽  
Chuanyou Meng ◽  
Nailing Xiu ◽  
Bo Cai ◽  
...  

The conductivity of the proppant-packs is critical in the productivity of hydraulically fractured wells. Proppants are also the best medium for studying particle packing. Sand and ceramic media are two most common proppants used for hydraulic fracturing. This study focuses on investigate the relation between conductivity and properties of proppant-packs, the particle-size distribution, porosity and mean particle diameter have been measured. The porosity of the proppant pack under zero pressure is determined from bulk density and apparent density. To accurately measure the porosity under variable closed stress conditions, the compressed width was taken into consideration. The particle size distribution was measured from sieve analysis. The paper presents results obtained by conducting routine conductivity test on a variety of proppants. The conductivity-porosity relationships are nonlinear. The conductivity is most sensitive to mean grain size, followed by closed stress, and then sorting. Larger median diameter always correlates to higher conductivity at low stress. Loss of conductivity with stress is more severe for large particles sands than small particles. The binomial method can be used to calculate the conductivity of different types and mesh proppants, which is shown to fit conductivity-mean diameter data successfully. The research is of guiding significance to choose the proper size distribution proppants in hydraulic fracturing. Meanwhile, the binomial method is a better predictor of proppant-packs conductivity based on particle size distribution.


2013 ◽  
Vol 275-277 ◽  
pp. 2411-2414 ◽  
Author(s):  
Song Lin Yi ◽  
Zhi Ming Wang ◽  
Xian Zhong Yi ◽  
Wei Chang

The properties of particle size distribution of rock cuttings and its shape characteristics are the most important parameters to petroleum drilling engineering. The samples of rock drill-cuttings are collected from 7 wells within the depths of 3500 m in Liaohe Oilfield of China. The particle size distribution laws of these rock samples with the average diameter over 74 μm are analyzed. The result shows that the drill cuttings feature obvious sheet shape and the size distribution curve of the particles is mainly related to the formation rocks and drilling bits. While drilling at the well depths of between 0 and 2000m by the cone bits, particle size distribution of drill cuttings has a form of approximately power function, the probability particle diameter being 8.50~9.27 mm. Drilling at the depths of between 2000 and 2800 m by the cone bits, the size distribution of cuttings has a form of nearly function, the probability particle diameter being 3.04~4.67 mm. Drilling at the depths under 2800m by PDC bits, the size distribution has a form of nearly the Rayleigh distribution, the probability rock diameter being 0.91~0.94 mm.


2002 ◽  
Vol 46 (6-7) ◽  
pp. 191-198 ◽  
Author(s):  
J. German ◽  
G. Svensson

During recent years the interest in street sweeping as a pollutant control measure has increased. For planning of street sweeping programs and disposal of street sweeping waste there is a need to investigate the composition of street sweeping waste and the effect of street sweeping on the remaining sediments on the street. Particle size distribution and heavy metal concentration has been measured for street sweeping waste, street sediments before sweeping and remaining sediments after sweeping. The results show that the concentrations of heavy metals are a function of particle diameter and proportional to the inverse of the particle diameter, i.e. the highest concentrations are found in finest fractions. Regression equations for metal concentrations as a function of particle diameter are presented. According to Swedish guidelines for environmental quality of contaminated sites, heavy metal concentration in the sweeping waste can not be considered as a serious problem. The largest amount of metals and sediment is found in the sandy fractions (0.125-0.5mm). The street sweeper is more effective in removing coarse sediments than fine. This means that the street sediments after sweeping are finer than the sediments before.


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