Archean mafic metavolcanics from the Rouyn–Noranda district, Abitibi Greenstone Belt, Quebec. 1. Mobility of the major elements

1982 ◽  
Vol 19 (12) ◽  
pp. 2258-2275 ◽  
Author(s):  
Léopold Gélinas ◽  
Michel Mellinger ◽  
Pierre Trudel

In a suite of Archean mafic pillows from the Rouyn–Noranda region of Quebec's Abitibi Greenstoné Belt, including both tholeiitic and calc-alkaline varieties spanning the prehnite–pumpellyite to upper greenschist metamorphic facies, three types of alteration can be defined: (I) chlorite–epidote–actinolite; (II) chlorite–epidote; and (III) chlorite ± sericite; the number of mineral phases decreases as a result of progressive hydration from type I to type III alteration. Albitization, resulting from substitution of [Formula: see text], in calcic plagioclase, is highly variable in type I alteration, but in types II and III the plagioclase is totally albitized and in some cases silicified. Chloritization is closely linked to increasing hydration and Ca leaching with MgO and FeO substituting for CaO in ferromagnesian minerals.Calcium was mobilized and carried by solutions, as evidenced by the variable concentration of epidote at the margins of pillows. This calcium leaching generated an excess of Al2O3 with respect to the combined molecular proportions of Na2O, K2O, and CaO, and is shown by the presence of corundum in CIPW norm calculations. In some pillows showing substitution of [Formula: see text], the fo2 of the invading fluid appears to have remained constant, being buffered by the pillow composition; this would be favored by a low water/rock mass ratio. As a result, the initial pillow Fe2O3/FeO ratio remained constant. In other pillows, the fo2 appears to have been imposed by the invading fluid rather than by the mineral assemblage: the FeO/MgO ratios are thus no longer representative of the magmatic composition whereas the ΣFeO/MgO is still representative of the pristine magmatic value.Two types of substitution of CaO by FeO and (or) MgO have been observed: (1) preferential substitution restricted to type I alteration, of FeO over MgO, similar to low-temperature substitution in modern-day sea-floor alteration; and (2) the more common substitution in type II and III alterations in which MgO predominates over FeO, similar to the high-temperature substitution taking place at great depth on the ocean floor.Although the samples were collected to test mineral heterogeneities caused by chemical degradation, more than 40% of the pillows sampled retained their pristine ΣFeO/MgO ratios. The various alteration patterns are independent of the initial tholeiitic or calc-alkaline lineage; this was confirmed using rare earth elements (REE) and inert trace elements such as Zr, Y, and Ti. The chemical changes in the mafic metavolcanic rocks do not obliterate their tholeiitic or calc-alkaline chemical affinities.


1993 ◽  
Vol 30 (7) ◽  
pp. 1521-1531 ◽  
Author(s):  
David Morin ◽  
Michel Jébrak ◽  
Marc Bardoux ◽  
Normand Goulet

The McWatters metavolcanic rocks are structurally bounded lenses within the Cadillac tectonic zone on the southern boundary of the Abitibi greenstone belt. They comprise komatiite, tholeiitic basalt and gabbro, and calc-alkaline andesitic lavas and volcaniclastic rocks cut by calc-alkaline dioritic and lamprophyric dykes. The McWatters basalts are mid-ocean-ridge basalt type tholeiites exhibiting low incompatible trace element contents and [La/Yb]N < 1. They may have formed via relatively high degree partial melting of a rare-earth element depleted mantle source. The andesites exhibit chondrite-normalized trace-element patterns with light-rare-earth and large-ion lithophile element enrichments and negative Nb and Ti anomalies, comparable to those of subduction-related calc-alkaline andesites. McWatters units are distinct from nearby Blake River Group rocks, despite comparable lithological assemblages and some common geochemical characteristics. The McWatters basalts exhibit lower Ti/Y, Zr/Y, and La/Yb than the Blake River tholeiites, whereas the McWatters andesites display lower Ti/Zr and higher Zr/Y than the Blake River calc-alkaline units. The McWatters tholeiites can be correlated with northern Pontiac Group tholeiitic units based on similar trace-element ratios and parallel rare-earth-element patterns. Thus, the McWatters tholeiites represent Pontiac rocks, underthrust beneath the southern Abitibi belt and appearing as isolated and retrograded lenses in the Cadillac tectonic zone. They may represent the remnants of an ocean basin that once separated the southern Abitibi greenstone belt from the Pontiac Subprovince.



2021 ◽  
Author(s):  
D. Yergeau ◽  
P. Mercier-Langevin ◽  
B. Dubé ◽  
V. McNicoll ◽  
S. E. Jackson ◽  
...  

Abstract The Westwood deposit, located in the Archean Doyon-Bousquet-LaRonde mining camp in the southern Archean Abitibi greenstone belt, contains 4.5 Moz (140 metric t) of gold. The deposit is hosted in the 2699–2695 Ma submarine, tholeiitic to calc-alkaline volcanic, volcaniclastic, and intrusive rocks of the Bousquet Formation. The deposit is located near the synvolcanic (ca. 2699–2696 Ma) Mooshla Intrusive Complex that hosts the Doyon epizonal intrusion-related Au ± Cu deposit, whereas several Au-rich volcanogenic massive sulfide (VMS) deposits are present east of the Westwood deposit. The Westwood deposit consists of stratigraphically stacked, contrasting, and overprinting mineralization styles that share analogies with both the intrusion-related and VMS deposits of the camp. The ore zones form three distinct, slightly discordant to stratabound corridors that are, from north (base) to south (top), the Zone 2 Extension, the North Corridor, and the Westwood Corridor. Syn- to late-main regional deformation and upper greenschist to lower amphibolite facies regional metamorphism affect the ore zones, alteration assemblages, and host rocks. The Zone 2 Extension consists of Au ± Cu sulfide (pyrite-chalcopyrite)-quartz veins and zones of disseminated to semimassive sulfides. The ore zones are spatially associated with a series of calc-alkaline felsic sills and dikes that crosscut the mafic to intermediate, tholeiitic to transitional, lower Bousquet Formation volcanic rocks. The metamorphosed proximal alteration consists of muscovite-quartz-pyrite ± gypsum-andalusite-kyanite-pyrophyllite argillic to advanced argillic-style tabular envelope that is up to a few tens of meters thick. The North Corridor consists of auriferous semimassive to massive sulfide veins, zones of sulfide stringers, and disseminated sulfides that are hosted in intermediate volcaniclastic rocks at the base of the upper Bousquet Formation. The Westwood Corridor consists of semimassive to massive sulfide lenses, veins, zones of sulfide stringers, and disseminated sulfides that are located higher in the stratigraphic sequence, at or near the contact between calc-alkaline dacite domes and overlying calc-alkaline rhyodacite of the upper Bousquet Formation. A large, semiconformable distal alteration zone that encompasses the North Corridor is present in the footwall and vicinity of the Westwood Corridor. This metamorphosed alteration zone consists of an assemblage of biotite-Mn garnet-chlorite-carbonate ± muscovite-albite. A proximal muscovite-quartz-chlorite-pyrite argillic-style alteration assemblage is associated with both corridors. The Zone 2 Extension ore zones and associated alteration are considered synvolcanic based on crosscutting relationships and U-Pb geochronology and are interpreted as being the distal expression of an epizonal magmatic-hydrothermal system that is centered on the upper part of the synvolcanic Mooshla Intrusive Complex. The North and Westwood corridors consist of bimodal-felsic Au-rich VMS-type mineralization and alteration produced by the convective circulation of modified seawater that included a magmatic contribution from the coeval epizonal Zone 2 Extension magmatic-hydrothermal system. The Westwood Au deposit represents one of the very few documented examples of an Archean magmatic-hydrothermal system—or at least of such systems formed in a subaqueous environment. The study of the Westwood deposit resulted in a better understanding of the critical role of magmatic fluid input toward the formation of Archean epizonal intrusion-related Au ± Cu and seafloor/subseafloor Au-rich VMS-type mineralization.



1990 ◽  
Vol 27 (4) ◽  
pp. 582-589 ◽  
Author(s):  
S. L. Jackson ◽  
R. H. Sutcliffe

Published U–Pb geochronological, geological, and petrochemical data suggest that there are late Archean ensialic greenstone belts (GB) (Michipicoten GB and possibly the northern Abitibi GB), ensimatic greenstone belts (southern Abitibi GB and Batchawana GB), and possibly a transitional ensimatic–ensialic greenstone belt (Swayze GB) in the central Superior Province. This lateral crustal variability may preclude simple correlation of the Michipicoten GB and its substrata, as exposed in the Kapuskasing Uplift, with that of the southern Abitibi GB. Furthermore, this lateral variability may have determined the locus of the Kapuskasing Uplift. Therefore, although the Kapuskasing Uplift provides a useful general crustal model, alternative models of crustal structure and tectonics for the southern Abitibi GB warrant examination.Thrusting of a juvenile, ensimatic southern Abitibi GB over a terrane containing evolved crust is consistent with (i) the structural style of the southern Abitibi GB; (ii) juvenile southern Abitibi GB metavolcanic rocks intruded by rocks having an isotopically evolved, older component; and (iii) Proterozoic extension that preserved low-grade metavolcanic rocks within the down-dropped Cobalt Embayment, which is bounded by higher grade terranes to the east and west.



2021 ◽  
Author(s):  
D. Yergeau ◽  
P. Mercier-Langevin ◽  
B. Dubé ◽  
M. Malo ◽  
A. Savoie

Abstract The Westwood deposit (4.5 Moz Au) is hosted in the 2699–2695 Ma Bousquet Formation volcanic and intrusive rocks, in the eastern part of the Blake River Group, southern Abitibi greenstone belt. The Bousquet Formation is divided in two geochemically distinct members: a mafic to intermediate, tholeiitic to transitional lower member and an intermediate to felsic, transitional to calc-alkaline upper member. The Bousquet Formation is cut by the synvolcanic (2699–2696 Ma) polyphase Mooshla Intrusive Complex, which is cogenetic with the Bousquet Formation. The deposit contains three strongly deformed (D2 flattening and stretching), steeply S-dipping mineralized corridors that are stacked from north to south: Zone 2 Extension, North Corridor, and Westwood Corridor. The North and Westwood corridors are composed of Au-rich polymetallic sulfide veins and stratabound to stratiform disseminated to massive sulfide ore zones that are spatially and genetically associated with the calcalkaline, intermediate to felsic volcanic rocks of the upper Bousquet Formation. The formation of the disseminated to semimassive ore zones is interpreted as strongly controlled by the replacement of porous volcaniclastic rocks at the contact with more impermeable massive cap rocks that helped confine the upflow of mineralizing fluids. The massive sulfide lenses are spatially associated with dacitic to rhyolitic domes and are interpreted as being formed, at least in part, on the paleoseafloor. The epizonal, sulfide-quartz vein-type ore zones of the Zone 2 Extension are associated with the injection of subvolcanic, calc-alkaline felsic sills and dikes within the lower Bousquet Formation. These subvolcanic intrusive rocks, previously interpreted as lava flows, are cogenetic and coeval with the intermediate to felsic lava flows and domes of the upper Bousquet Formation. The change from fractional crystallization to assimilation- and fractional crystallization-dominated processes and transitional to calc-alkaline magmatism is interpreted to be responsible for the development of the auriferous ore-forming system. The Westwood deposit is similar to some Phanerozoic Au ± base metal-rich magmatic-hydrothermal systems, both in terms of local volcano-plutonic architecture and inferred petrogenetic context. The complex volcanic evolution of the host sequence at Westwood, combined with its proximity to a polyphase synvolcanic intrusive complex, led to the development of one of the few known large Archean subaqueous Au-rich magmatic-hydrothermal systems.



1980 ◽  
Vol 17 (9) ◽  
pp. 1292-1299 ◽  
Author(s):  
I. E. M. Smith

In well exposed, well developed greenstone belts of the Superior Province there is a clear progression from stratigraphically lower, geochemically primitive volcanic rock types (komatiites, tholeiites) to overlying geochemically evolved calc-alkaline volcanic rock types. In the western Blake River Group of the Abitibi Greenstone Belt the change from tholeiitic to calc-alkaline volcanics represents a geochemical discontinuity defined by an increase in incompatible elements and light/heavy rare-earth element fractionation in the overlying rocks. Quantitative modelling of the parameters of the discontinuity indicates that it can be explained by a change to very small amounts of melting of unmodified mantle lherzolite, although this is not a unique solution. In calc-alkaline suites showing high degrees of rare-earth element fractionation the calculated melt fraction required of unmodified mantle becomes unrealistically low and models involving a geochemically evolved source may have to be considered.



1990 ◽  
Vol 27 (5) ◽  
pp. 649-656 ◽  
Author(s):  
A. Turek ◽  
R. Keller ◽  
W. R. Van Schmus

The Mishibishu greenstone belt, located 40 km west of Wawa, is a typical Archean greenstone belt and is probably an extension of the Michipicoten belt. This belt is composed of basic to felsic metavolcanic rocks of tholeiitic to calc-alkaline affinity and of metasedimentary rocks ranging from conglomerate to argillite. Granitoids, diorites, and gabbros intrude and embay supracrustal rocks as internal and external plutons.Six U–Pb zircon ages have been obtained on rocks in this area. The oldest is 2721 ± 4 Ma for the Jostle Lake tonalite. The bulk of the volcanic rocks formed by 2696 ± 17 Ma, which is the age of the Chimney Point porphyry at the top of the volcanic pile. The Pilot Harbour granite has a similar age of 2693 ± 7 Ma. The age of the Tee Lake tonalite is 2673 ± 12 Ma, and the age of the Iron. Lake gabbro is 2671 ± 4 Ma. The youngest age for volcanics in this part of the Superior Province is 2677 ± 7 Ma, obtained from, the David Lakes pyroclastic breccia. these ages agree with those reported for the adjacent Michipicoten and Gamitagama belts.





1975 ◽  
Vol 12 (12) ◽  
pp. 2080-2085 ◽  
Author(s):  
D. E. Vogel

Chloritoid- and kyanite-bearing acid metavolcanic rocks of the Abitibi Greenstone belt have acquired an aluminum surplus by weathering prior to metamorphism. The weathering increases from the top of the volcanic unit downwards, as shown by increasing values for both Niggli-t and the Zr/P ratio. The depositional environment of these rocks is postulated to be either shallow marine or terrestrial.



1982 ◽  
Vol 19 (11) ◽  
pp. 2100-2113 ◽  
Author(s):  
Ann M. Tasillo-Hirt ◽  
John W. Geissman ◽  
David W. Strangway ◽  
Larry S. Jensn

A paleomagnetic study (159 samples, 30 sites) was done on calc-alkaline volcanics of the Blake River Group, dated at 2703 ± 2 Ma and occupying the central portion of a major synclinorium in the Abitibi Greenstone Belt. Magnetically stable single- and multi-vectorial components of magnetization were resolved in demagnetization; however, there was poor consistency of directions linearly decaying to the origin in vector analysis on the site, sample, and subsample levels (e.g., D = 190.0°, I = −29.2°, k = 1.5, α95 = 25.0°, n = 21 specimens from N = 21 samples). Preliminary results from a conglomerate test performed on the Chaput–Hughes Member of the overlying Timiskaming Group suggest that a pre-depositional remanence was retained and that there was not a widespread regional metamorphic event after the sediments were deposited. Cobbles derived from alkali volcanics of the Timiskaming Group and Kinojevis (tholeiites) and Blake River volcanics display dispersed directions of magnetization between cobbles. Preliminary magnetization data from the matrix of the conglomerate are well grouped, and correction for regional structure results in a direction similar to the characteristic one of Matachewan dikes. Paleomagnetic data from a downfaulted block of Timiskaming volcanics cut by Matachewan diabase dike may be interpreted to suggest that the fault block has been rotated clockwise (80°+) and subsequently tilted to the west (80°).



1984 ◽  
Vol 117 ◽  
pp. 1-26
Author(s):  
A Rehkopff

The Marranguit-Kangilerssua supracrustals constitute a sequence of variable supracrustallithologies intensely folded into surrounding orthogneisses and metamorphosed under granulite facies conditions. No field or petrographic evidence indicates the original nature of the individual supracrustal rock types. Fortynine samples from the quartzo-feldspathic part of the supracrustals have been analysed for major elements and the trace elements Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr and Ba. Ten different geochemical discrimination methods indicate that both metasedimentary and metaigneous material are present. The metaigneous rocks possess typical calc-alkaline differentiation trends and were originally extrusives. Mixing-zones between metasedimentary and metavolcanic material are interpreted as reflecting a pyroclastic nature of some of the metavolcanic rocks. The quartzo-feldspathic part of the M-K supracrustals is dominated by greywacke/lithic arenite with subordinate intercalations of mudstone and single layers or lensoid bodies of subarkose and sublithic arenite. The greywacke/lithic arenite grade into calc-alkaline pyroclastics, which vary in composition from rhyodacite to rhyolite. Associated quartz-andesitic and dacitic extrusives occur throughout the supracrustal formation, which in addition contains thin layers af limestone, basic and ultrabasic rocks. The supracrustals may be either Archaean or Proterozoic in age.



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