Geochemical exploration for buried sandstone-hosted uranium mineralisation using mobile U and Pb isotopes: case study of the REB deposit, Great Divide Basin, Wyoming

2021 ◽  
pp. geochem2021-043
Author(s):  
M.Z. Abzalov

Mobile radiogenic lead isotopes (206Pb, 207Pb, 208Pb, and 210Pb) represent products of radioactive decay of their parental uranium and thorium isotopes (238U, 235U, 232Th), and are considered potential geochemical pathfinders of the buried sandstone-type uranium deposits. Soil samples collected along a geochemical traverse intersecting buried uranium roll front mineralisation at the REB deposit in the Great Divide Basin, Wyoming, USA were studied. Mineralisation of this deposit is hosted in weakly lithified arkosic sands, at a depth of 120 - 200 metres, without a strong surficial expression of its presence at depth which makes discovery of this deposit type difficult, slow, and expensive. All soil samples have been analysed for ratios of the mobile long-lived Pb isotopes and their parental U and Th isotopes, determined from partial leach products obtained using a weak acid leaching technique. The samples were also analysed for trace elements, assayed both in the partial leach products and using conventional whole soil sample assays. Ratios of the mobile radiogenic Pb isotopes to their parental U and Th isotopes (206Pb/238U, 207Pb/235U and 208Pb/232Th) determined in the partial leach products exhibit anomalous contents in the soil samples collected above the uranium rolls. The anomalous values are several times greater than background values, to lateral distances of 350-400m outside of the roll fronts. Notably, conventional whole soil assays have failed to detect the anomalies which were detected using mobile Pb isotopes. Supplementary material:https://doi.org/10.6084/m9.figshare.c.5610980

Minerals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 512
Author(s):  
David Quirt ◽  
Antonio Benedicto

Pb-isotopes have been proposed as pathfinders for sandstone-hosted unconformity-related U deposits, with isotope ratios providing information on mineralization timing and element remobilization and migration. Pb-isotopes proximal to mineralization display radiogenic signatures, often with ‘excess Pb’ suggestive of derivation from greater U concentrations than are currently present. The U deposits in the Kiggavik project area (west of Baker Lake, NU, Canada) are basement-hosted, contain several generations of pitchblende mineralization, display a strong structural control, and are located in fault-related fracture systems and foliation-parallel veinlets. Drill core samples were analysed by Inductively-Coupled Plasma-Mass Spectrometer (ICP-MS) for Pb isotopes following multi-acid total-digestion, reverse Aqua Regia partial-digestion, and weak-acid-leach attacks, to evaluate the utility of the respective dissolution methods in Pb-isotope pathfinder geochemistry. Partial-digestion results are similar to weak-acid-leach results, indicating that interpretation of Pb-isotope signatures can be carried out from partial-digestion data if weak-acid-leach data are unavailable. Application of this pathfinder method at Kiggavik shows that Pb-isotope ratios display systematic trends useful for exploration vectoring. Uranium-content-adjusted 206Pb/204Pb ratios and 206Pb/204Pb ‘excess-lead’ data highlight anomalous isotopic values. 207Pb/206Pb ratios display downhole trends complementary to location of mineralization. Three-dimensional (3D) distributions of Pb-isotope data at the Contact U prospect show systematic trends and form halos around the mineralization. Isotopic footprints are limited to <50 m from the mineralization outline, reflecting host-rock and structural control, but indicate areas with elevated potential for U mineralization and provide vectoring information within basement lithologies.


2021 ◽  
pp. SP520-2021-144
Author(s):  
Marie-Noëlle Guilbaud ◽  
Corentin Chédeville ◽  
Ángel Nahir Molina-Guadarrama ◽  
Julio Cesar Pineda-Serrano ◽  
Claus Siebe

AbstractThe eruption of the ∼10 km3 rhyolitic Las Derrumbadas twin domes about 2000 yrs ago has generated a wide range of volcano-sedimentary deposits in the Serdán-Oriental lacustrine basin, Trans-Mexican Volcanic Belt. Some of these deposits have been quarried, creating excellent exposures. In this paper we describe the domes and related products and interpret their mode of formation, reconstructing the main phases of the eruption as well as syn-and-post eruptive erosional processes. After an initial phreatomagmatic phase that built a tuff ring, the domes grew as an upheaved plug lifting a thick sedimentary pile from the basin floor. During uplift, the domes collapsed repeatedly to form a first-generation of hetero-lithologic hummocky debris avalanche deposits. Subsequent dome growth produced a thick talus and pyroclastic density currents. Later, the hydrothermally-altered over-steepened dome peaks fell to generate 2nd generation, mono-lithologic avalanches. Subsequently, small domes grew in the collapse scars. From the end of the main eruptive episode onwards, heavy rains remobilized parts of the dome carapaces and talus, depositing lahar aprons. Las Derrumbadas domes are still an important source of sediments in the basin, and ongoing mass-wasting processes are associated with hazards that should be assessed, given their potential impact on nearby populations.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5752296


2021 ◽  
pp. jgs2021-035
Author(s):  
Wanchese M. Saktura ◽  
Solomon Buckman ◽  
Allen P. Nutman ◽  
Renjie Zhou

The Jurassic–Cretaceous Tsoltak Formation from the eastern borderlands of Ladakh Himalaya consists of conglomerates, sandstones and shales, and is intruded by norite sills. It is the oldest sequence of continent-derived sedimentary rocks within the Shyok Suture. It also represents a rare outcrop of the basement rocks to the voluminous Late Cretaceous–Eocene Ladakh Batholith. The Shyok Formation is a younger sequence of volcaniclastic rocks that overlie the Tsoltak Formation and record the Late Cretaceous closure of the Mesotethys Ocean. The petrogenesis of these formations, ophiolite-related harzburgites and norite sill is investigated through petrography, whole-rock geochemistry and U–Pb zircon geochronology. The youngest detrital zircon grains from the Tsoltak Formation indicate Early Cretaceous maximum depositional age and distinctly Gondwanan, Lhasa microcontinent-related provenance with no Eurasian input. The Shyok Formation has Late Cretaceous maximum depositional age and displays a distinct change in provenance to igneous detritus characteristic of the Jurassic–Cretaceous magmatic arc along the southern margin of Eurasia. This is interpreted as a sign of collision of the Lhasa microcontinent and the Shyok ophiolite with Eurasia along the once continuous Shyok–Bangong Suture. The accreted terranes became the new southernmost margin of Eurasia and the basement to the Trans-Himalayan Batholith associated with the India-Eurasia convergence.Supplementary material:https://doi.org/10.6084/m9.figshare.c.5633162


2021 ◽  
pp. geochem2021-074
Author(s):  
Godson Godfray

Successful gold exploration projects depend on a piece of clear information on the association between gold, trace elements, and mineralization controlling factors. The use of soil geochemistry has been an important tool in pinpointing exploration targets during the early stage of exploration. This study aimed to establish the gold distribution, the elemental association between gold and its pathfinder elements such as Cu, Zn, Ag, Ni, Co, Mn, Fe, Cd, V, Cr, Ti, Sc, In, and Se and identify lithologies contributing to the overlying residual soils. From cluster analysis, a high similarity level of 53.93% has been shown with Ag, Cd, and Se at a distance level of 0.92. Au and Se have a similarity level of 65.87% and a distance level of 0.68, hence is proposed to be the most promising pathfinder element. PCA, FA, and the Pearson's correlation matrix of transformed data of V, Cu, Ni, Fe, Mn, Cr, and Co and a stronger correlation between Pb and U, Th, Na, K, Sn, Y, Ta and Be shows that source gold mineralization might be associated with both hornblende gneisses interlayered with quartzite, tonalite, and tonalitic orthogneiss. From the contour map and gridded map of Au and its pathfinder elements, it has been noted that their anomalies and target generated are localized in the Northern part of the area. The targets trend ESE to WNW nearly parallel to the shear zones as a controlling factor of Au mineralization emplacement.Supplementary material:https://doi.org/10.6084/m9.figshare.c.5721965


2021 ◽  
pp. SP521-2021-141
Author(s):  
Chang-Fu Zhou ◽  
Xinyue Wang ◽  
Jiahao Wang

AbstractCtenochasmatid pterosaurs flourished and diversified in the Early Cretaceous Jehol Biota. Here, a partial mandible of Forfexopterus is described based on a three-dimensional reconstruction using high-resolution X-ray Computed Tomography (CT) data. The first nine pairs of functional teeth of the rostral dentition revealed along with their replacements. The functional teeth are evenly arranged with a tooth density of 2.2 teeth/cm. The tooth crown is distinctly reduced from its base to the tip, and framed by two weak ridges, possibly as a pair of vestigial carinae. The replacement teeth are sharp and pointed, and have erupted slightly against the medial surface of the functional teeth. Surprisingly, tooth wear is observed in this specimen, the first record of tooth-tooth occlusion in ctenochasmatids. The wear facets exhibit high-angled lingual and lower-angled labial facets, implying a tooth-tooth occlusion in pterosaur clade. This discovery indicates that the Jehol ctenochasmatids possibly employed a more active feeding strategy than other filter-feeding pterosaurs (e.g. Ctenochasma, Pterodaustro, Gnathosaurus).Supplementary material at https://doi.org/10.6084/m9.figshare.c.5722060


2021 ◽  
pp. jgs2021-109
Author(s):  
Igor V. Kemkin ◽  
Andrei V. Grebennikov ◽  
Xing-Hua Ma ◽  
Ke-Ke Sun

We present new U–Pb age data for granitoids in the Central Sikhote–Alin orogenic belt in SE Russia, which refute the established opinion about the absence of the Late Cretaceous magmatism at the eastern margin of the Paleo-Asian continent. It was previously thought that a period of magmatic quiescence occurred from 88 to 50 Ma, related to subduction of the Paleo-Pacific Plate under the eastern margin of the Paleo-Asian continent, although this is inconsistent with evidence from the Sikhote–Alin, Sakhalin, and Japan regions. Three suites of plutonic rocks with different ages were identified in this study. The first suite has ages of 105–92 Ma and formed in a syn-orogenic setting. The second (86–83 Ma) and third (ca. 73 Ma) suites formed during the post-orogenic stage of the Sikhote–Alin orogenic belt. The second and third suites were coeval with Late Cretaceous granitoids that formed in a suprasubduction continental arc known as the Eastern Sikhote–Alin volcanic–plutonic belt (ESAVPB). However, the studied rocks are located far inland from the ESAVPB. The ages of the studied granitoids coincide with the timing of a change in the angle of convergence between the Paleo-Pacific Plate and eastern margin of the Paleo-Asian continent. This change in motion of the oceanic plate with respect to the continental plate was probably caused by a rupture in the subducted slab (i.e., a slab tear), followed by asthenospheric upwelling and partial melting of the overlying crust, which ultimately generated post-orogenic intrusive magmatism.Supplementary material:https://doi.org/10.6084/m9.figshare.c.5738616


2021 ◽  
pp. jgs2021-027
Author(s):  
Valeria Boyko ◽  
Jürgen Pätzold ◽  
Alexey Kamyshny

High fluxes of iron minerals associated with aeolian dry deposition may result in anomalously high reactive iron content and fast reoxidation of hydrogen sulphide in the sediments that prevents pyrite formation and results in “cryptic” sulphur cycle. In this work, we studied cycling of iron and sulphur in the deep-water (> 800 m water depth) sediments of the Red Sea and its northern extension, Gulf of Aqaba. We found that reactive iron content in the surface sediments of the Gulf of Aqaba and the Red Sea is high, while the content of sulphur-bound iron is very low and decreases with water depth. The presence of pyrite traces and zero-valent sulfur as well as isotopic compositions of sulphate and pyrite, which are consistent with sulphate reduction under substrate-limiting conditions, suggest that cryptic sulfur cycling is likely to be a result of fast reoxidation of hydrogen sulfide rather than microbial sulfate reduction suppression. In the sediments of Shaban Deep, which are overlain with hyper-saline hydrothermal brine, low reactive iron and high organic carbon contents result in a non-cryptic sulphur cycle characterized by preservation of pyrite in the sediments.Thematic collection: This article is part of the Sulfur in the Earth system collection available at: https://www.lyellcollection.org/cc/sulfur-in-the-earth-systemSupplementary material:https://doi.org/10.6084/m9.figshare.c.5508155


2011 ◽  
Vol 77 (11) ◽  
pp. 3663-3668 ◽  
Author(s):  
Valeria Guidi ◽  
Nicola Patocchi ◽  
Peter Lüthy ◽  
Mauro Tonolla

ABSTRACTRecurrent treatments withBacillus thuringiensissubsp.israelensisare required to control the floodwater mosquitoAedes vexansthat breeds in large numbers in the wetlands of the Bolle di Magadino Reserve in Canton Ticino, Switzerland. Interventions have been carried out since 1988. In the present study, the spatial distribution of restingB. thuringiensissubsp.israelensisspores in the soil was measured. TheB. thuringiensissubsp.israelensisconcentration was determined in soil samples collected along six transects covering different elevations within the periodically flooded zones. A total of 258 samples were processed and analyzed by quantitative PCR that targeted an identical fragment of 159 bp for theB. thuringiensissubsp.israelensis cry4Aaandcry4Bagenes.B. thuringiensissubsp.israelensisspores were found to persist in soils of the wetland reserve at concentrations of up to 6.8 log per gram of soil. Continuous accumulation due to regular treatments could be excluded, as the decrease in spores amounted to 95.8% (95% confidence interval, 93.9 to 97.7%). The distribution of spores was correlated to the number ofB. thuringiensissubsp.israelensistreatments, the elevation of the sampling point, and the duration of the flooding periods. The number ofB. thuringiensissubsp.israelensistreatments was the major factor influencing the distribution of spores in the different topographic zones (P< 0.0001). These findings indicated thatB. thuringiensissubsp.israelensisspores are rather immobile after their introduction into the environment.


2011 ◽  
Vol 77 (10) ◽  
pp. 3443-3450 ◽  
Author(s):  
Evelien M. Adriaenssens ◽  
Pieter-Jan Ceyssens ◽  
Vincent Dunon ◽  
Hans-Wolfgang Ackermann ◽  
Johan Van Vaerenbergh ◽  
...  

ABSTRACTPantoea agglomeransis a common soil bacterium used in the biocontrol of fungi and bacteria but is also an opportunistic human pathogen. It has been described extensively in this context, but knowledge of bacteriophages infecting this species is limited. Bacteriophages LIMEzero and LIMElight ofP. agglomeransare lytic phages, isolated from soil samples, belonging to thePodoviridaeand are the firstPantoeaphages of this family to be described. The double-stranded DNA (dsDNA) genomes (43,032 bp and 44,546 bp, respectively) encode 57 and 55 open reading frames (ORFs). Based on the presence of an RNA polymerase in their genomes and their overall genome architecture, these phages should be classified in the subfamily of theAutographivirinae, within the genus of the “phiKMV-like viruses.” Phylogenetic analysis of all the sequenced members of theAutographivirinaesupports the classification of phages LIMElight and LIMEzero as members of the “phiKMV-like viruses” and corroborates the subdivision into the different genera. These data expand the knowledge ofPantoeaphages and illustrate the wide host diversity of phages within the “phiKMV-like viruses.”


2021 ◽  
pp. SP523-2021-76
Author(s):  
Robert W. Dalrymple

AbstractThis study reviews the morphology, hydrodynamics and sedimentology of 33 modern straits, including examples from diverse tectonic and climatic settings. Strait morphology ranges from short, simple straits to long, tortuous passages many 100s of kilometers long; depths range from 10 m to >1 km. The morphological building block of strait sedimentation is a constriction flanked by open basins; a single strait can contain one or several of these. Currents accelerate through the constrictions and decelerate in the basins, leading to a spatial alternation of high- and low-energy conditions. Currents in a strait can be classified as either ‘persistent’ (oceanic currents or density-driven circulation) or ‘intermittent’ (tidally or meteorologically generated currents). Constrictions tend to be bedload partings, with the development of transport paths that diverge outward. Deposition occurs where the flow decelerates, generating paired subaqueous ‘constriction-related deltas’ that can be of unequal size. Cross-bedding predominates in high-energy settings; muddy sediment waves and contourite drifts are present in some straits. In shallow straits that were exposed during the sea-level lowstand, strait deposits typically occur near or at the maximum flooding surface, and can overlie estuarine and fluvial deposits. The most energetic deposits need not occur at the time of maximum inundation.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5746061


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