scholarly journals Special Distribution of Crude Oil in the Lucaogou Formation in Jimusaer Sag and Genetic Analysis of Its Physical Difference

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-15
Author(s):  
Ming Wang ◽  
Shiju Liu ◽  
Ji Li ◽  
Gang Gao ◽  
Julei Mi ◽  
...  
Keyword(s):  
Physical Properties ◽  
Crude Oil ◽  
Source Rocks ◽  
Crude Oils ◽  
Sweet Spot ◽  
Material Source ◽  
The Poor ◽  
Lucaogou Formation ◽  
The Difference ◽  
Sweet Spots

The shale oil of the Lucaogou Formation in the Jimusaer Sag of the Junggar Basin was divided into two sweet spots for exploration and development. Crude oil in the upper and lower sweet spots comes from the upper and lower source rocks. After years of exploration, it has been found that the crude oil in the lower sweet spot has worse physical properties than that of the upper sweet spot. In this study, through the physical and geochemical analysis of crude oil in the upper and lower sweet spots, combined with the organic petrological observation of the upper and lower source rocks, the cause of the poor physical properties of the crude oil in the lower sweet spot has been identified. n-Alkanes in the saturated hydrocarbons of crude oil in the upper and lower sweet were complete while odd-to-even predominance was evident, indicating that the poor physical properties of the crude oil are unrelated to biodegradation. In addition, the correlation between the biogenic parameters and the physical properties of crude oil was analyzed, finding that the difference in crude oil is mainly related to the composition of biogenic precursors of upper and lower source rocks. Combined with organic petrological observation, the lower source rock was found to be rich in telalginite (green algae), which is therefore the primary reason for the difference in physical properties. In comparing results from the characteristics of crude oil biomarkers from both the upper and lower sweet spots, crude oils in the upper sweet spot are similar to each other, indicating that the enrichment of crude oil has experienced a certain migration. In contrast, the differences in biomarkers between the crude oils of the lower sweet spot were relatively large and changed regularly with depth, suggesting the self-generated and self-stored characteristics of crude oil enrichment. At the same time, it was found that the crude oil in the lower sweet spot is also affected by the maturity of adjacent source rocks under the condition of a consistent parent material source. Overall, it was determined that the lower the maturity of source rocks, the poorer the physical property of the crude oil produced.

STABLE HYDROGEN ISOTOPE RATIOS OF SEDIMENTARY HYDROCARBONS: A POTENTIAL METHOD FOR ASSESSING THERMAL MATURITY?

2005 ◽  
Vol 45 (1) ◽  
pp. 253
Author(s):  
D. Dawson ◽  
K. Grice ◽  
R. Alexander
Keyword(s):  
Vitrinite Reflectance ◽  
Potential Method ◽  
Source Rocks ◽  
Crude Oils ◽  
Thermal Maturity ◽  
Peak Oil ◽  
Data Set ◽  
High Maturity ◽  
The Difference ◽  
Hydrogen Isotope Ratios

A relationship has been identified between the maturity level of source rocks and the stable hydrogen isotopic compositions (δD) of extracted saturated hydrocarbons, based on the analysis of nine sediments and five crude oils from the Perth Basin (WA). The sediments cover the immature to late mature range. Distinct δD signatures are observed for the immature sediments where pristane and phytane are significantly depleted in deuterium (D) relative to the n-alkanes. With increasing maturity the difference between the δD values of n-alkanes and isoprenoids reduces as pristane and phytane become progressively enriched in D. The n-alkane–isoprenoid δD signature of the crude oils, including one from a different source facies, is similar to mature–late mature sediments representative of the peak oil–generative window. Enrichment of D in isoprenoids is attributed to isotopic exchange associated with thermal maturation. Average δD values of pristane and phytane correlate well with vitrinite reflectance, as does the biomarker maturity parameter Ts/Tm. The limited data set suggests that δD values of aliphatic hydrocarbons may be useful for establishing thermal maturity, particularly when other maturity parameters are not appropriate. Furthermore, we suggest δD values may be useful over a wider maturity range than traditional parameters, particularly at very high maturity where biomarker parameters are no longer effective.

scholarly journals Geochemical Characteristics of Gas and Flowback Water in Lake Facies Shale: A Case Study From the Junggar Basin, China

2021 ◽  
Vol 9 ◽  
Author(s):  
Lin Zhang ◽  
Dan Liu ◽  
Yongjin Gao ◽  
Min Zhang
Keyword(s):  
Carbon Isotope ◽  
Shale Gas ◽  
Isotope Composition ◽  
Ordos Basin ◽  
Junggar Basin ◽  
Source Rocks ◽  
Flowback Water ◽  
Lucaogou Formation ◽  
The Difference

The chemical and isotopic compositions of the natural gas and the co-produced flowback water from the XJC 1 well in Junggar Basin, China, were analyzed to determine the origin of gases in the Permian Lucaogou Formation (P2l) and the Triassic Karamay Formation (T2k) in the Bogda Mountain periphery area of the Southern Junggar Basin. The value of carbon isotope composition of the P2l lacustrine shale gas in the Junggar Basin was between the shale gas in Chang 7 Formation of Triassic (T1y7) in the Ordos Basin and that in the Xu 5 Formation of Triassic (T3x5) in the Sichuan Basin. The difference in gas carbon isotope is primarily because the parent materials were different. A comparison between compositions in the flowback water reveals that the P2l water is of NaHCO3 type while the T2k water is of NaCl type, and the salinity of the latter is higher than the former, indicating a connection between P2l source rock and the T2k reservoir. In combination with the structural setting in the study area, the gas filling mode was proposed as follows: the gas generated from the lacustrine source rocks of the Permian Lucaogou Formation is stored in nearby lithological reservoirs from the Permian. Petroleum was also transported along the faults to the shallow layer of the Karamay Formation over long distances before it entered the Triassic reservoir.

scholarly journals An experimentally investigate the effect of physical properties on the production of lubricating materials from crude oils

2019 ◽  
Vol 3 (1) ◽  
pp. 30-47
Author(s):  
Hazim Al-Jewaree ◽  
Omar M.Ali
Keyword(s):  
Physical Properties ◽  
Crude Oil ◽  
Vacuum Distillation ◽  
Research Effort ◽  
Lubricating Oil ◽  
Crude Oils ◽  
Final Conclusion ◽  
Lubricating Oils ◽  
Atmospheric Distillation ◽  
Oil Derivatives

Abstract One of the most important oil derivatives in our time, which all the world seeks to obtain and produce a lot is lubricating oils, which are used for several important purposes and the most important is to keep the thermal engines from damage or collapse due to the phenomenon of friction of the moving parts mechanically at a high temperatures and pressure is relatively high as well as the wear phenomenon This research effort focuses on a comparative study of five types of mix crude Libyan oils (El-Feel Field, Al Wafa Field, Amina Field, Brega Field and Al-Sedra Field) for produced the lubricated oil experimentally . Test carried out on the production the lubrication oil by measuring the physical properties include: normal boiling point, pour point, specific gravity (Sp. gr.), standard density (API), dynamic viscosity , kinematics viscosity , Acentric factor and Watson factor (K or Kw). It’s found from the practical results of the production the lubricating oil from crude oil for atmospheric distillation of crude oil practically depends on measurement two physical properties very accurately Watson factor first and then the API. The results from the tests showed that, mix crude oil of Amena, El-Sedra and El-Feel fields suitable than others for production the lubricated oil at atmospheric and then use the vacuum distillation columns. Other results observation, that’s two others types are impossible to produce the lubricated oil. Also, the results observed that’s the useful mole percentage of lubricated oil cutoff has range very small from 2 to 17 % for these types of Libyan crude oils, this percentage will be increase when use vacuum distillation with added some additives materials. In addition, practical results have been found that not all the cutoff produced from atmospheric distillation within the range of temperatures between 370 and 550 oC are lubricating oils, but other compounds are oil derivatives suitable for different fuel depending on the chemical structure of these extracts. The final conclusion of this work is that any crude oil with a light Arabic class (has a relative density API less than 38 and a Kw lower than 12.1) is suitable for the production of lubricated oils from the crude oil. Keyword: physical properties of crude oil, lubricated oil, Libyan crude oil

scholarly journals Aromatic Hydrocarbons as Indicators of Maturation and Source: Correlative Geochemical Evaluation of Commingled Niger Delta Crude Oils

2020 ◽  
Vol 4 (2) ◽  
pp. 1-9
Author(s):  
Onyema MO
Keyword(s):  
Crude Oil ◽  
Aromatic Hydrocarbons ◽  
Niger Delta ◽  
Higher Plants ◽  
Source Rocks ◽  
Crude Oils ◽  
Relative Distribution ◽  
Geochemical Parameters ◽  
The Individual ◽  
Maturity Parameters

Two Niger Delta crude oils from Rivers and Delta States (samples A and F) and their compositional mixtures (samples B, C, D and E) where evaluated using a range of geochemical parameters derived from aromatic hydrocarbons and aromatic sulphur compounds to determine their source and maturity. The relative distribution of various plant markers in crude oil samples A and F which were retained in their compositional mixes suggests the contribution of angiosperm higher plants and coniferous higher plants to the source rocks that generated the crude oils. The various maturity parameters computed for the oil samples revealed that both the Rivers and Delta crude oils lie in the high maturity state with sample F significantly more matured than sample A. All alkynaphthalene maturity parameters suggested a peak to late oil generation window for the crude oil samples except the methyl naphthalene ratio (MNR) whose maturity sequence lacks sufficient variation to distinguish maturity differences in the crude oil samples. The maturity characters of TNR-1 and TNR-2 (trimethylnaphthalene ratio) showed a strong correlation between the individual crude oil samples and their mixtures. However, all the other maturity parameters showed moderate or weak correlation between the individual crude oil samples and their mixtures.

scholarly journals Light Hydrocarbon Geochemistry: Insight into Mississippian Crude Oil Sources from the Anadarko Basin, Oklahoma, USA

Geofluids ◽  
2019 ◽  
Vol 2019 ◽  
pp. 1-15 ◽  
Author(s):  
Ibrahim Atwah ◽  
Stephen Sweet ◽  
John Pantano ◽  
Anthony Knap
Keyword(s):  
Crude Oil ◽  
Fluid Dynamic ◽  
Northern Region ◽  
Source Rocks ◽  
Crude Oils ◽  
Variable Degree ◽  
Woodford Shale ◽  
Reservoir Water ◽  
Water Washing ◽  
Geochemical Parameters

The Mississippian limestone is a prolific hydrocarbon play in the northern region of Oklahoma and the southern part of Kansas. The Mississippian reservoirs feature variations in produced fluid chemistry usually explained by different possible source rocks. Such chemical variations are regularly obtained from bulk, molecular, and isotopic characteristics. In this study, we present a new geochemical investigation of gasoline range hydrocarbons, biomarkers, phenols, and diamondoids in crude oils produced from Mississippian carbonate and Woodford Shale formations. A set of oil samples was examined for composition using high-performance gas-chromatography and mass-spectrometry techniques. The result shows a distinct geochemical fingerprint reflected in biomarkers such as the abundance of extended tricyclic terpanes, together with heptane star diagrams, and diamantane isomeric distributions. Such compounds are indicative of the organic matter sources and stages of thermal maturity. Phenolic compounds varied dramatically based on geographic location, with some oil samples being depleted of phenols, while others are intact. Based on crude oil compositions, two possible source rocks were identified including the Woodford Shale and Mississippian mudrocks, with a variable degree of mixing reported. Variations in phenol concentrations reflect reservoir fluid dynamic and water interactions, in which oils with intact phenols are least affected by water-washing conversely and crude oils depleted in phenols attributed to reservoir water-washing. These geochemical parameters shed light into petroleum migration within Devonian-Mississippian petroleum systems and mitigate geological risk in exploring and developing petroleum reservoirs.

Application of Nonlinear Parameters Predictive Model Based on LS-SVM in Pipeline of Mixed Transportation

2020 ◽  
Author(s):  
Xue Li ◽  
Lei Shi
Keyword(s):  
Prediction Model ◽  
Physical Properties ◽  
Crude Oil ◽  
Raw Materials ◽  
Crude Oils ◽  
Nonlinear Parameters ◽  
Reliability Modeling ◽  
Model Based ◽  
Sample Data ◽  
Mixed Crude

Abstract In order to meet the refinery’s requirements on the properties of raw materials, improve the hydraulic stability of pipeline transporting process, and reduce the energy consumption, it’s necessary to mix up different crude oils transported in pipeline. The traditional method to obtain the physical properties of mixed crude oil, especially the nonlinear parameters such as viscosity and pour point, is experiment test or empirical formula, but the disadvantage is the heavy workload or limited use conditions. In this paper, a nonlinear parameters prediction model based on LS-SVM is put forward for transporting mixed crude oil in pipeline. The modeling method of the nonlinear parameters prediction based on LS-SVM : 1 normalize the different batch sample data; 2 the kernel function of SVM is Gaussian RBF; 3 regress coefficients by genetic algorithm; 4 train parameters and then obtain the nonlinear parameters prediction model. The nonlinear parameters prediction model based on LS-SVM has superiority in aspects of reliability, modeling efficiency, universality and adaptability. It can adapt to the dynamic requirements of refinery on crude oil properties, make full use of the accumulated mixed crude oils’ physical properties and their mixing ratio. The prediction accuracy of non-linear parameters model can be improved continuously. And then, the rationality and efficiency of online mixed transportation in pipeline can be improved effectively.

Oil–source rock correlation for tight oil in tuffaceous reservoirs in the Permian Tiaohu Formation, Santanghu Basin, northwest China

2015 ◽  
Vol 52 (11) ◽  
pp. 1014-1026 ◽  
Author(s):  
Jian Ma ◽  
Zhilong Huang ◽  
Xiaoyu Gao ◽  
Changchao Chen
Keyword(s):  
Organic Matter ◽  
Crude Oil ◽  
Source Rock ◽  
Stable Carbon Isotope ◽  
Northwest China ◽  
Source Rocks ◽  
Tight Oil ◽  
Stable Carbon ◽  
Lucaogou Formation ◽  
Oil Source

Tight oil in the Permian Tiaohu Formation in the Santanghu Basin, northwest China, has a peculiar property such that the reservoir is sedimentary organic matter-bearing tuff characterized by high porosity (10%–25%) and very low permeability, mainly in the range of 0.01–0.50 mD. Biomarker and stable carbon isotope compositions of selected crude oils and source-rock extracts were analyzed to determine the source rock of the tight oil. Source rocks in the Lucaogou Formation consist of various rock types dominated by mudstones containing organic matter with intense yellow–green fluorescence. Mudstones in the Lucaogou Formation have total organic carbon (TOC) values mainly in the range of 1.0–8.0 wt%, hydrocarbon generation potential (S1 + S2) mostly >6 mg/g, and chloroform extractable bitumen “A” generally >0.1%. The maceral composition is predominantly fluorescing amorphinite. The hydrogen index (HI) varies from 300 to 900 mg HC/g TOC, indicating dominant Type I and Type II kerogen. Compared with the mudstones and tuffs in the Tiaohu Formation, the mudstones in the Lucaogou Formation are the best source rocks. The biomarker characteristics of mudstone extracts in the Lucaogou Formation differ from those in the Tiaohu Formation, based on the gammacerane index, β-carotane content, and the relative contents of C27, C28, and C29 regular steranes. Crude oil samples in the tuff show low pristane/phytane (Pr/Ph) ratios, high gammacerane indices, high β-carotane, and a dominance of the C29 regular sterane followed by C28 and C27 steranes, as well as depleted stable carbon isotope compositions. Oil–source correlation with biomarkers and δ13C values shows that the crude oil in the tuffs mainly originates from underlying source rocks in the Lucaogou Formation. The sedimentary organic matter in the tuffs also makes a small contribution to the tuffaceous reservoir. Therefore, the tuffaceous tight reservoir in the Tiaohu Formation is unusual in that the oil is not indigenous; rather, it migrates a long distance to accumulate in the upper reservoir.

Study of the Effect of Crude Oils on the Metallic Corrosion

2018 ◽  
Vol 5 (1) ◽  
pp. 43-54
Author(s):  
Suresh Aluvihara ◽  
Jagath K Premachandra
Keyword(s):  
Crude Oil ◽  
Sulfur Content ◽  
Salt Content ◽  
Ferrous Metal ◽  
Relative Weight ◽  
Oil Refining ◽  
Crude Oils ◽  
Hardness Tester ◽  
Corrosion Rates ◽  
Ferrous Metals

Corrosion is a severe matter regarding the most of metal using industries such as the crude oil refining. The formation of the oxides, sulfides or hydroxides on the surface of metal due to the chemical reaction between metals and surrounding is the corrosion that  highly depended on the corrosive properties of crude oil as well as the chemical composition of ferrous metals since it was expected to investigate the effect of Murban and Das blend crude oils on the rate of corrosion of seven different ferrous metals which are used in the crude oil refining industry and investigate the change in hardness of metals. The sulfur content, acidity and salt content of each crude oil were determined. A series of similar pieces of seven different types of ferrous metals were immersed in each crude oil separately and their rates of corrosion were determined by using their relative weight loss after 15, 30 and 45 days. The corroded metal surfaces were observed under the microscope. The hardness of each metal piece was tested before the immersion in crude oil and after the corrosion with the aid of Vicker’s hardness tester. The metallic concentrations of each crude oil sample were tested using atomic absorption spectroscopy (AAS). The Das blend crude oil contained higher sulfur content and acidity than Murban crude oil. Carbon steel metal pieces showed the highest corrosion rates whereas the stainless steel metal pieces showed the least corrosion rates in both crude oils since that found significant Fe and Cu concentrations from some of crude oil samples. The mild steel and the Monel showed relatively intermediate corrosion rates compared to the other types of ferrous metal pieces in both crude oils. There was a slight decrease in the initial hardness of all the ferrous metal pieces due to corrosion.

scholarly journals Effective source rock selection and oil–source correlation in the Western Slope of the northern Songliao Basin, China

2021 ◽  
Vol 18 (2) ◽  
pp. 398-415
Author(s):  
He Bi ◽  
Peng Li ◽  
Yun Jiang ◽  
Jing-Jing Fan ◽  
Xiao-Yue Chen
Keyword(s):  
Organic Matter ◽  
Source Rock ◽  
Thermal Evolution ◽  
Songliao Basin ◽  
Source Rocks ◽  
Crude Oils ◽  
Western Slope ◽  
Geochemical Parameters ◽  
Group I ◽  
Oil Source

AbstractThis study considers the Upper Cretaceous Qingshankou Formation, Yaojia Formation, and the first member of the Nenjiang Formation in the Western Slope of the northern Songliao Basin. Dark mudstone with high abundances of organic matter of Gulong and Qijia sags are considered to be significant source rocks in the study area. To evaluate their development characteristics, differences and effectiveness, geochemical parameters are analyzed. One-dimensional basin modeling and hydrocarbon evolution are also applied to discuss the effectiveness of source rocks. Through the biomarker characteristics, the source–source, oil–oil, and oil–source correlations are assessed and the sources of crude oils in different rock units are determined. Based on the results, Gulong and Qijia source rocks have different organic matter primarily detrived from mixed sources and plankton, respectively. Gulong source rock has higher thermal evolution degree than Qijia source rock. The biomarker parameters of the source rocks are compared with 31 crude oil samples. The studied crude oils can be divided into two groups. The oil–source correlations show that group I oils from Qing II–III, Yao I, and Yao II–III members were probably derived from Gulong source rock and that only group II oils from Nen I member were derived from Qijia source rock.

Sign in / Sign up

Export Citation Format

Share Document