scholarly journals Ground-Based DOAS Measurements of Stratospheric Trace Gases at Two Antarctic Stations during the 2002 Ozone Hole Period

2005 ◽  
Vol 62 (3) ◽  
pp. 765-777 ◽  
Author(s):  
U. Frieß ◽  
K. Kreher ◽  
P. V. Johnston ◽  
U. Platt

Abstract Compared to recent years, the development of the Antarctic ozone hole in 2002 showed very unusual dynamical features. The midwinter polar vortex was one of the smallest observed during the past decade. Driven by planetary waves, the vortex showed a strong asymmetry in early spring. A large air mass separated in late September, leaving what was previously a small vortex even smaller. Furthermore, stratospheric temperatures exceeded the polar stratospheric cloud (PSC) threshold earlier than in previous years, leading to a decrease in halogen activation by heterogeneous surface reactions. Ground-based observation of stratospheric trace gases in austral spring of 2001 and 2002 using passive Differential Optical Absorption Spectroscopy (DOAS) observations of zenith-scattered sunlight in the UV and visible wavelength region (320–650 nm) are presented. Using DOAS measurements of ozone, NO2, BrO, and OClO at two different Antarctic sites, Neumayer Station (70°S, 8°W) and Arrival Heights (78°S, 167°E), the chemical composition of the stratosphere is investigated under the unusual conditions of the 2002 ozone hole period and compared to the more typical observations of the previous year (2001).

2019 ◽  
Vol 69 (1) ◽  
pp. 57
Author(s):  
Oleksandr Evtushevsky ◽  
Andrew R. Klekociuk ◽  
Volodymyr Kravchenko ◽  
Gennadi Milinevsky ◽  
Asen Grytsai

Quasi-stationary planetary wave activity in the lower Antarctic stratosphere in the late austral winter was an important contributor to the preconditioning of the ozone hole in spring 2017. Observations show that the ozone hole area (OHA) in spring 2017 was at the level of 1980s, that is, almost half the maximum size in 2000s. The observed OHA was close to that forecasted based on a least-squares linear regression between wave amplitude in August and OHA in September–November. We show that the key factor which contributed to the preconditioning of the Antarctic stratosphere for a relatively small ozone hole in the spring of 2017 was the development of large-amplitude stratospheric planetary waves of zonal wave numbers 1 and 2 in late winter. The waves likely originated from tropospheric wave trains and promoted the development of strong mid-latitude anticyclones in the lower stratosphere which interacted with the stratospheric polar vortex and strongly eroded the vortex in August and September, mitigating the overall level of ozone loss.


2022 ◽  
pp. 1-63

Abstract Motivated by the strong Antarctic sudden stratospheric warming (SSW) in 2019, a survey on the similar Antarctic weak polar events (WPV) is presented, including their life cycle, dynamics, seasonality, and climatic impacts. The Antarctic WPVs have a frequency of about four events per decade, with the 2002 event being the only major SSW. They show a similar life cycle to the SSWs in the Northern Hemisphere but have a longer duration. They are primarily driven by enhanced upward-propagating wavenumber 1 in the presence of a preconditioned polar stratosphere, i.e., a weaker and more contracted Antarctic stratospheric polar vortex. Antarctic WPVs occur mainly in the austral spring. Their early occurrence is preceded by an easterly anomaly in the middle and upper equatorial stratosphere besides the preconditioned polar stratosphere. The Antarctic WPVs increase the ozone concentration in the polar region and are associated with an advanced seasonal transition of the stratospheric polar vortex by about one week. Their frequency doubles after 2000 and is closely related to the advanced Antarctic stratospheric final warming in recent decades. The WPV-resultant negative phase of the southern annular mode descends to the troposphere and persists for about three months, leading to persistent hemispheric scale temperature and precipitation anomalies.


2021 ◽  
Author(s):  
Jezabel Curbelo ◽  
Gang Chen ◽  
Carlos R. Mechoso

<div>The evolution of the Northern Hemisphere stratosphere during late winter and early spring of 2020 was punctuated by outstanding events both in dynamics and tracer evolution. It provides an ideal case for study of the Lagrangian properties of the evolving flow and its connections with the troposphere. The events ranged from an episode of polar warming at upper levels in March, a polar vortex split into two cyclonic vortices at middle and lower levels in April, and a remarkably deep and persistent mass of ozone poor air within the westerly circulation throughout the period. The latter feature was particularly remarkable during 2020, which showed the lowest values of stratospheric ozone on record.</div><div> </div><div>We focus on the vortex split in April 2020 and we examine this split at middle as well as lower stratospheric levels, and the interactions that occurred between the resulting two vortices which determined the distribution of ozone among them. We also examine the connections among stratospheric and tropospheric events during the period.</div><div> </div><div>Our approach for analysis will be based on the application of Lagrangian tools to the flow field, based on following air parcels trajectories, examining barriers to the flow, and the activity and propagation of planetary waves. Our findings confirm the key role for the split played by a flow configuration with a polar hyperbolic trajectory and associated manifolds. A trajectory analysis illustrates the transport of ozone between the vortices during the split. We argue that these stratospheric events were linked to strong synoptic scale disturbances in the troposphere forming a wave train from the north Pacific to North America and Eurasia.</div><div><strong> </strong></div><div><strong>Reference:</strong><strong> </strong>J. Curbelo, G. Chen,  C. R. Mechoso. Multi-level analysis of the northern polar vortex split in April 2020 during development of the Arctic ozone hole. Earth and Space Science Open Archive. doi: 10.1002/essoar.10505516.1</div><div> </div><div><strong>Acknowledgements:</strong> NSF Grant AGS-1832842, RYC2018-025169 and EIN2019-103087.</div>


2005 ◽  
Vol 5 (3) ◽  
pp. 2989-3046 ◽  
Author(s):  
P. Krecl ◽  
C. S. Haley ◽  
J. Stegman ◽  
S. M. Brohede ◽  
G. Berthet

Abstract. The first vertical profiles of stratospheric OClO retrieved from Odin/OSIRIS limb-scattered sunlight radiances are presented. The retrieval method is based on a two-step approach, using differential optical absorption spectroscopy combined with the maximum a posteriori estimator. The details of the spectral window selection, spectral corrections and inversion technique are discussed. The results show that OClO can be detected inside the South polar vortex region between about 12 and 20 km altitude with a 2–5 km height resolution and an estimated retrieval error better than 60% at the peak. OClO concentrations are consistent with chemical transport model simulations and show the expected relation to the atmospheric conditions in the lower stratosphere in the austral spring 2002. This unique data set of OClO profiles is very promising to study the stratospheric chlorine activation in both polar regions.


2021 ◽  
Author(s):  
Markus Jesswein ◽  
Heiko Bozem ◽  
Hans-Christoph Lachnitt ◽  
Peter Hoor ◽  
Thomas Wagenhäuser ◽  
...  

Abstract. Inorganic chlorine (Cly) is the sum of the degradation products of long-lived chlorinated source gases. These include the reservoir species (HCl and ClONO2) and active chlorine species (i.e. ClOx). The active chlorine species drive catalytic cycles that deplete ozone in the polar winter stratosphere. This work presents calculations of inorganic chlorine (Cly) derived from chlorinated source gas measurements on board the High Altitude and Long Range Research Aircraft (HALO) during the Southern hemisphere Transport, Dynamic and Chemistry (SouthTRAC) campaign in late winter and early spring 2019. Results are compared to Cly of the Northern Hemisphere derived from measurements of the POLSTRACC-GW-LCYCLE-SALSA (PGS) campaign in the Arctic winter of 2015/2016. A scaled correlation was used for PGS data, since not all source gases were measured. Cly from a scaled correlation was compared to directly determined Cly and agreed well. An air mass classification based on in situ N2O measurements allocates the measurements to the vortex, the vortex boundary region, and mid-latitudes. Although the Antarctic vortex was weakened in 2019 compared to previous years, Cly reached 1687 ± 20 ppt at 385 K, therefore up to around 50 % of total chlorine could be found in inorganic form inside the Antarctic vortex, whereas only 15 % of total chlorine could be found in inorganic form in the southern mid-latitudes. In contrast, only 40 % of total chlorine could be found in inorganic form in the Arctic vortex during PGS and roughly 20 % in the northern mid-latitudes. Differences inside the respective vortex reaches up to 565 ppt more Cly in the Antarctic vortex 2019 than in the Arctic vortex 2016 (at comparable distance to the local tropopause). As far as is known, this is the first comparison of inorganic chlorine within the respective polar vortex. Based on the results of these two campaigns, the difference of Cly inside the respective vortex is significant and larger than reported inter annual variations.


2021 ◽  
Vol 21 (2) ◽  
pp. 617-633
Author(s):  
Martin Dameris ◽  
Diego G. Loyola ◽  
Matthias Nützel ◽  
Melanie Coldewey-Egbers ◽  
Christophe Lerot ◽  
...  

Abstract. Ozone data derived from the Tropospheric Monitoring Instrument (TROPOMI) sensor on board the Sentinel-5 Precursor satellite show exceptionally low total ozone columns in the polar region of the Northern Hemisphere (Arctic) in spring 2020. Minimum total ozone column values around or below 220 Dobson units (DU) were seen over the Arctic for 5 weeks in March and early April 2020. Usually the persistence of such low total ozone column values in spring is only observed in the polar Southern Hemisphere (Antarctic) and not over the Arctic. These record low total ozone columns were caused by a particularly strong polar vortex in the stratosphere with a persistent cold stratosphere at higher latitudes, a prerequisite for ozone depletion through heterogeneous chemistry. Based on the ERA5, which is the fifth generation of the European Centre for Medium-Range Weather Forecasts (ECMWF) atmospheric reanalysis, the Northern Hemisphere winter 2019/2020 (from December to March) showed minimum polar cap temperatures consistently below 195 K around 20 km altitude, which enabled enhanced formation of polar stratospheric clouds. The special situation in spring 2020 is compared and discussed in context with two other Northern Hemisphere spring seasons, namely those in 1997 and 2011, which also displayed relatively low total ozone column values. However, during these years, total ozone columns below 220 DU over several consecutive days were not observed in spring. The similarities and differences of the atmospheric conditions of these three events and possible explanations for the observed features are presented and discussed. It becomes apparent that the monthly mean of the minimum total ozone column value for March 2020 (221 DU) was clearly below the respective values found in March 1997 (267 DU) and 2011 (252 DU), which highlights the special evolution of the polar stratospheric ozone layer in the Northern Hemisphere in spring 2020. A comparison with a typical ozone hole over the Antarctic (e.g., in 2016) indicates that although the Arctic spring 2020 situation is remarkable, with total ozone column values around or below 220 DU observed over a considerable area (up to 0.9 million km2), the Antarctic ozone hole shows total ozone columns typically below 150 DU over a much larger area (of the order of 20 million km2). Furthermore, total ozone columns below 220 DU are typically observed over the Antarctic for about 4 months.


2014 ◽  
Vol 27 (19) ◽  
pp. 7462-7474 ◽  
Author(s):  
William J. M. Seviour ◽  
Steven C. Hardiman ◽  
Lesley J. Gray ◽  
Neal Butchart ◽  
Craig MacLachlan ◽  
...  

Abstract Using a set of seasonal hindcast simulations produced by the Met Office Global Seasonal Forecast System, version 5 (GloSea5), significant predictability of the southern annular mode (SAM) is demonstrated during the austral spring. The correlation of the September–November mean SAM with observed values is 0.64, which is statistically significant at the 95% confidence level [confidence interval: (0.18, 0.92)], and is similar to that found recently for the North Atlantic Oscillation in the same system. Significant skill is also found in the prediction of the strength of the Antarctic stratospheric polar vortex at 1 month average lead times. Because of the observed strong correlation between interannual variability in the strength of the Antarctic stratospheric circulation and ozone concentrations, it is possible to make skillful predictions of Antarctic column ozone amounts. By studying the variation of forecast skill with time and height, it is shown that skillful predictions of the SAM are significantly influenced by stratospheric anomalies that descend with time and are coupled with the troposphere. This effect allows skillful statistical forecasts of the October mean SAM to be produced based only on midstratosphere anomalies on 1 August. Together, these results both demonstrate a significant advance in the skill of seasonal forecasts of the Southern Hemisphere and highlight the importance of accurate modeling and observation of the stratosphere in producing long-range forecasts.


2021 ◽  
Author(s):  
Myojeong Gu ◽  
Carl-Fredrik Enell ◽  
Janis Pukite ◽  
Ulrich Platt ◽  
Uwe Raffalski ◽  
...  

<p>Recent research on stratospheric ozone indicates signs of ozone recovery, but on the other hand, ozone recovery is also expected to be delayed by many aspects (e.g climate change). Therefore, it is important to monitor continuously stratospheric trace gases to predict the future evolution of the Arctic ozone and other trace gases which are involved in the ozone depletion chemistry. OClO is well known as an indicator of the stratospheric chlorine activation and can be measured using remote sensing techniques.</p><p>In this study, we present long-term measurements of OClO slant column densities at Kiruna, Sweden (67.84°N, 20.41°E) which were obtained from the ground-based zenith sky DOAS instruments since 1997. The measurement site is located north of the polar circle in which the variability of the OClO abundance depends on the state of stratospheric chlorine activation but also whether the polar vortex is located above the measurement site.</p><p>The aim of this study is to give an overview of the measured stratospheric OClO abundance for 19 years, and to investigate the dominant parameters affecting ozone and OClO during periods of stratospheric chlorine activation. One particular focus is on the parameters which trigger the activation and de-activation at the beginning and the end of the polar winter.</p><p>To do so, we compare the general dependencies of OClO on other trace gases and meteorological conditions.</p>


1992 ◽  
Vol 19 (18) ◽  
pp. 1819-1822 ◽  
Author(s):  
T. Deshler ◽  
A. Adriani ◽  
G. P. Gobbi ◽  
D. J. Hofmann ◽  
G. Di Donfrancesco ◽  
...  

2019 ◽  
Vol 69 (1) ◽  
pp. 29
Author(s):  
Andrew R. Klekociuk ◽  
Matthew B. Tully ◽  
Paul B. Krummel ◽  
Oleksandr Evtushevsky ◽  
Volodymyr Kravchenko ◽  
...  

We review the 2017 Antarctic ozone hole, making use of various meteorological reanalyses, and in-situ, satellite and ground-based measurements of ozone and related trace gases, and ground-based measurements of ultraviolet radiation. The 2017 ozone hole was associated with relatively high-ozone concentrations over the Antarctic region compared to other years, and our analysis ranked it in the smallest 25% of observed ozone holes in terms of size. The severity of stratospheric ozone loss was comparable with that which occurred in 2002 (when the stratospheric vortex exhibited an unprecedented major warming) and most years prior to 1989 (which were early in the development of the ozone hole). Disturbances to the polar vortex in August and September that were associated with intervals of anomalous planetary wave activity resulted in significant erosion of the polar vortex and the mitigation of the overall level of ozone depletion. The enhanced wave activity was favoured by below-average westerly winds at high southern latitudes during winter, and the prevailing easterly phase of the quasi-biennial oscillation (QBO). Using proxy information on the chemical make-up of the polar vortex based on the analysis of nitrous oxide and the likely influence of the QBO, we suggest that the concentration of inorganic chlorine, which plays a key role in ozone loss, was likely similar to that in 2014 and 2016, when the ozone hole was larger than that in 2017. Finally, we found that the overall severity of Antarctic ozone loss in 2017 was largely dictated by the timing of the disturbances to the polar vortex rather than interannual variability in the level of inorganic chlorine.


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