Corrosion, optimization and surface analysis of Fe-Al2O3-CeO2 metal matrix nanocomposites

Author(s):  
Pallav Gupta ◽  
Naseem Ahamad ◽  
Jimmy Mehta ◽  
Devendra Kumar ◽  
Mumtaz A Quraishi ◽  
...  

In the present work, metal matrix nanocomposites are being prepared using Fe as base material reinforced with Al2O3 and doped with CeO2. Nanocomposite specimens were synthesized using powder metallurgy technique. Tafel Polarization, Corrosion Behavior and its optimization using Analysis of Variance (ANOVA) as well as Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS) along with Phase and Microstructure of prepared samples have been investigated. It was observed that corrosion rate and corrosion current density was highest for pure Fe samples whereas 1.0% CeO2 doped Fe-Al2O3 metal matrix nanocomposite system showed the formation of nano amorphous layer on the specimen surface. Analysis of Variance shows that the different compositions of samples have changed outcome on corrosion behavior. Technique for Order of Preference by Similarity to Ideal Solution analysis shows ordered preference of sample as per the readings of corrosion rate.

Author(s):  
S. Jayalakshmi ◽  
R. Arvind Singh

The chapter highlights the various processing/synthesizing routes of Light Metal Matrix Nanocomposites (LMMNCs), their microstructural characteristics, mechanical behaviour, and tribological properties. LMMNCs are advanced materials, in which nano-sized ceramic particles are reinforced into Al/Mg matrices. In conventional Metal Matrix Composites (MMCs), the incorporation of micron sized reinforcements in the matrix usually results in a considerable improvement in hardness and ultimate strength when compared to the unreinforced base material. However, most of these composites do not show plastic deformation (little or no yield) and exhibit drastic reduction in ductility. This poses a major limitation for MMCs to be used in real-time applications. In order to overcome this drawback, Al/Mg composites with nano-scale reinforcements have been developed. Based on numerous research works, it has been established that LMMNCs are better materials that possess superior properties, wherein both strength and ductility improvements along with excellent wear resistance can be achieved.


Author(s):  
S. Jayalakshmi ◽  
R. Arvind Singh

The chapter highlights the various processing/synthesizing routes of Light Metal Matrix Nanocomposites (LMMNCs), their microstructural characteristics, mechanical behaviour, and tribological properties. LMMNCs are advanced materials, in which nano-sized ceramic particles are reinforced into Al/Mg matrices. In conventional Metal Matrix Composites (MMCs), the incorporation of micron sized reinforcements in the matrix usually results in a considerable improvement in hardness and ultimate strength when compared to the unreinforced base material. However, most of these composites do not show plastic deformation (little or no yield) and exhibit drastic reduction in ductility. This poses a major limitation for MMCs to be used in real-time applications. In order to overcome this drawback, Al/Mg composites with nano-scale reinforcements have been developed. Based on numerous research works, it has been established that LMMNCs are better materials that possess superior properties, wherein both strength and ductility improvements along with excellent wear resistance can be achieved.


Metals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 125
Author(s):  
Seyed Kiomars Moheimani ◽  
Mehran Dadkhah ◽  
Mohammad Hossein Mosallanejad ◽  
Abdollah Saboori

Metal matrix nanocomposites (MMNCs) with high specific strength have been of interest for numerous researchers. In the current study, Mg matrix nanocomposites reinforced with AlN nanoparticles were produced using the mechanical stirring-assisted casting method. Microstructure, hardness, physical, thermal and electrical properties of the produced composites were characterized in this work. According to the microstructural evaluations, the ceramic nanoparticles were uniformly dispersed within the matrix by applying a mechanical stirring. At higher AlN contents, however, some agglomerates were observed as a consequence of a particle-pushing mechanism during the solidification. Microhardness results showed a slight improvement in the mechanical strength of the nanocomposites following the addition of AlN nanoparticles. Interestingly, nanocomposite samples were featured with higher electrical and thermal conductivities, which can be attributed to the structural effect of nanoparticles within the matrix. Moreover, thermal expansion analysis of the nanocomposites indicated that the presence of nanoparticles lowered the Coefficient of Thermal Expansion (CTE) in the case of nanocomposites. All in all, this combination of properties, including high mechanical strength, thermal and electrical conductivity, together with low CTE, make these new nanocomposites very promising materials for electro packaging applications.


Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1034
Author(s):  
Massoud Malaki ◽  
Alireza Fadaei Tehrani ◽  
Behzad Niroumand ◽  
Manoj Gupta

Metal matrix composites (MMCs) have been developed in response to the enormous demand for special industrial materials and structures for automotive and aerospace applications, wherein both high-strength and light weight are simultaneously required. The most common, inexpensive route to fabricate MMCs or metal matrix nanocomposites (MMNCs) is based on casting, wherein reinforcements like nanoceramics, -carbides, -nitrides, elements or carbon allotropes are added to molten metal matrices; however, most of the mentioned reinforcements, especially those with nanosized reinforcing particles, have usually poor wettability with serious drawbacks like particle agglomerations and therefore diminished mechanical strength is almost always expected. Many research efforts have been made to enhance the affinity between the mating surfaces. The aim in this paper is to critically review and comprehensively discuss those approaches/routes commonly employed to boost wetting conditions at reinforcement-matrix interfaces. Particular attention is paid to aluminum matrix composites owing to the interest in lightweight materials and the need to enhance the mechanical properties like strength, wear, or creep resistance. It is believed that effective treatment(s) may enormously affect the wetting and interfacial strength.


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