This chapter starts with the importance of composite materials over single-phase materials and further explores the importance of natural fiber reinforced composites over synthetic fiber reinforced composites followed by chemical and physical modifications of the fiber surface to enhance the adhesion between the fiber and the matrix. The chapter also focuses on the different types of wear mechanisms that lead to shutting down the industries and types of different wear test rings to measure the wear rate of a material. Current work also represents a comprehensive literature study on tribological characterisation of composite materials. In addition, it focuses composites as TRIBO material in engineering systems. The effect of tribological operating parameters like load, sliding velocity, sliding distance, temperature, and other influential parameters like fiber length, fiber volume fraction, fiber orientation, and surface treatment on friction and wear rate of composites are also described. Over the past few years composites have been dominant in the emerging materials. The applications areas of composite materials have grown steadily in the various systems of Mechanical Engineering, Civil Engineering, Electrical Engineering, Medical Engineering, and Automobile Engineering. In engineering systems, failure of parts may occur due to different types of wear mechanisms. The availability of a range of fiber reinforcements, fillers, matrices, and processing techniques offers ample scope for tailoring properties in composites as required for specific applications.