scholarly journals Fabrication and Characterization of the Modified EV31-Based Metal Matrix Nanocomposites

Metals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 125
Author(s):  
Seyed Kiomars Moheimani ◽  
Mehran Dadkhah ◽  
Mohammad Hossein Mosallanejad ◽  
Abdollah Saboori

Metal matrix nanocomposites (MMNCs) with high specific strength have been of interest for numerous researchers. In the current study, Mg matrix nanocomposites reinforced with AlN nanoparticles were produced using the mechanical stirring-assisted casting method. Microstructure, hardness, physical, thermal and electrical properties of the produced composites were characterized in this work. According to the microstructural evaluations, the ceramic nanoparticles were uniformly dispersed within the matrix by applying a mechanical stirring. At higher AlN contents, however, some agglomerates were observed as a consequence of a particle-pushing mechanism during the solidification. Microhardness results showed a slight improvement in the mechanical strength of the nanocomposites following the addition of AlN nanoparticles. Interestingly, nanocomposite samples were featured with higher electrical and thermal conductivities, which can be attributed to the structural effect of nanoparticles within the matrix. Moreover, thermal expansion analysis of the nanocomposites indicated that the presence of nanoparticles lowered the Coefficient of Thermal Expansion (CTE) in the case of nanocomposites. All in all, this combination of properties, including high mechanical strength, thermal and electrical conductivity, together with low CTE, make these new nanocomposites very promising materials for electro packaging applications.

Author(s):  
Mohammad K Hassanzadeh-Aghdam

Understanding the structure–property relations for metal matrix nanocomposites reinforced with nanoparticles is a key factor for a reliable and optimal design of such new material systems. In the present study, coefficient of thermal expansion of silicon carbide (SiC) nanoparticle-reinforced aluminum (Al) matrix nanocomposites is predicted using a three-dimensional unit cell based micromechanical approach. The model takes into account the aluminum carbide (Al4C3) interphase region formed due to the reaction between SiC nanoparticles and surrounding Al matrix. The effects of some critical parameters, including volume fraction and diameter of SiC nanoparticles, interphase features such as geometry and material properties on the coefficient of thermal expansion of Al nanocomposite are extensively investigated. The obtained results clearly reveal the high influence of the interphase region on the coefficient of thermal expansion of Al nanocomposite. Based on the simulation results, the coefficient of thermal expansion of Al nanocomposite nonlinearly decreases with the increase in the interphase thickness or decreasing SiC nanoparticles diameter. Furthermore, the role of interphase in the thermal expansion behavior of Al nanocomposite becomes more prominent with the reduction in the nanoparticle diameter. Also, the coefficient of thermal expansion of Al nanocomposite linearly decreases as SiC nanoparticle volume fraction increases.


Author(s):  
S. Jayalakshmi ◽  
R. Arvind Singh

The chapter highlights the various processing/synthesizing routes of Light Metal Matrix Nanocomposites (LMMNCs), their microstructural characteristics, mechanical behaviour, and tribological properties. LMMNCs are advanced materials, in which nano-sized ceramic particles are reinforced into Al/Mg matrices. In conventional Metal Matrix Composites (MMCs), the incorporation of micron sized reinforcements in the matrix usually results in a considerable improvement in hardness and ultimate strength when compared to the unreinforced base material. However, most of these composites do not show plastic deformation (little or no yield) and exhibit drastic reduction in ductility. This poses a major limitation for MMCs to be used in real-time applications. In order to overcome this drawback, Al/Mg composites with nano-scale reinforcements have been developed. Based on numerous research works, it has been established that LMMNCs are better materials that possess superior properties, wherein both strength and ductility improvements along with excellent wear resistance can be achieved.


Symmetry ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 537
Author(s):  
Chandrashekar A. ◽  
B. V. Chaluvaraju ◽  
Asif Afzal ◽  
Denis A. Vinnik ◽  
Abdul Razak Kaladgi ◽  
...  

Nano aluminum oxide was prepared by the combustion method using aluminum nitrate as the oxidizer and urea as a fuel. Characterization of synthesized materials was performed using SEM (scanning electron microscope), powder XRD (X-ray diffraction), FTIR (Fourier transform infrared spectroscopy), and TEM (transmission electron microscope). Al-Mg/Al2O3 (2, 4, 6, and 8 wt%) metal matrix nanocomposites were prepared by liquid metallurgy route-vertex technique. The homogeneous dispersion of nano Al2O3 particles in Al-Mg/Al2O3 metal matrix nanocomposites (MMNCs) was revealed from the field emission SEM analysis. The reinforcement particles present in the matrix were analyzed through energy-dispersive X-ray spectroscopy method. The properties (corrosion and mechanical) of the fabricated composites were evaluated. The mechanical and corrosion properties of the prepared nanocomposites initially increased and then decreased with the addition of nano Al2O3 particles in Al-Mg Matrix. The studies show that, the presence of 6 wt% of nano Al2O3 particles in the matrix improved the properties of other combinations of nano Al2O3 in the Al-Mg matrix material. Further, the Al-Mg/Al2O3 (6 wt%) MMNCs are joined by friction stir welding and evaluated for microstructural, mechanical, and corrosion properties. Al-Mg/Al2O3 MMNCs may find applications in the marine field. The response surface method (RSM) was used for the optimization of tensile strength, Young’s modulus, and microhardness of the synthesized material which resulted in a 95% of statistical confidence level. Artificial neural network (ANN) analysis was also carried out which perfectly predicted these two properties. The ANN model is optimized to obtain 99.9% accurate predictions by changing the number of neurons in the hidden layer.


2021 ◽  
Author(s):  
F. A. Mirza ◽  
Daolun Chen

Lightweighting in the transportation industry is today recognized as one of the most important strategies to improve fuel efficiency and reduce anthropogenic climate-changing, environment-damaging, and human death-causing emissions. However, the structural applications of lightweight alloys are often limited by some inherent deficiencies such as low stiffness, high wear rate and inferior strength. These properties could be effectively enhanced by the addition of stronger and stiffer reinforcements, especially nano-sized particles, into metal matrix to form composites. In most cases three common strengthening mechanisms (load-bearing effect, mismatch of coefficients of thermal expansion, and Orowan strengthening) have been considered to predict the yield strength of metal matrix nanocomposites (MMNCs). This study was aimed at developing a unified model by taking into account the matrix grain size and porosity (which is unavoidable in the materials processing such as casting and powder metallurgy) in the prediction of the yield strength of MMNCs. The Zener pinning effect of grain boundaries by the nano-sized particles has also been integrated. The model was validated using the experimental data of magnesium- and titanium-based nanocomposites containing different types of nano-sized particles (namely, Al2O3, Y2O3, and carbon nanotubes). The predicted results were observed to be in good agreement with the experimental data reported in the literature.


2011 ◽  
Vol 264-265 ◽  
pp. 663-668 ◽  
Author(s):  
B. Karthikeyan ◽  
S. Ramanathan ◽  
V. Ramakrishnan

The demand of today’s and future spacecrafts for a stable platform for critical payloads is the driving force behind the coefficient of thermal expansion (CTE) measurement of different aerospace materials. The CTE of a composite is different from that given by a simple rule of mixtures. This is because of the presence of reinforcement. The expansion coefficient of reinforcement is less than that of the matrix which introduces a mechanical constraint on the matrix. The degree of constraint is also dependent on the nature of the reinforcement. It is important to point out that interface can exert some influence on the value of CTE, especially for very small particle size. In addition to the interface, the CTE of particle reinforced metal matrix composites (MMCs) is affected by several other factors. To cater the needs of various requirements in a spacecraft making, a wide variety of materials are used. Besides, the indigenization efforts and development of new materials for space-use emphasizes the measurement of CTE before their actual use. Stir casting technique was used to fabricate composites containing Si Cp as reinforcements and special thermo physical properties of the material are found. CTE of the composites are measured by TMA. The experiments have been carried out in the temperature range -1400 C to 5750 C.


2021 ◽  
Author(s):  
F. A. Mirza ◽  
Daolun Chen

Lightweighting in the transportation industry is today recognized as one of the most important strategies to improve fuel efficiency and reduce anthropogenic climate-changing, environment-damaging, and human death-causing emissions. However, the structural applications of lightweight alloys are often limited by some inherent deficiencies such as low stiffness, high wear rate and inferior strength. These properties could be effectively enhanced by the addition of stronger and stiffer reinforcements, especially nano-sized particles, into metal matrix to form composites. In most cases three common strengthening mechanisms (load-bearing effect, mismatch of coefficients of thermal expansion, and Orowan strengthening) have been considered to predict the yield strength of metal matrix nanocomposites (MMNCs). This study was aimed at developing a unified model by taking into account the matrix grain size and porosity (which is unavoidable in the materials processing such as casting and powder metallurgy) in the prediction of the yield strength of MMNCs. The Zener pinning effect of grain boundaries by the nano-sized particles has also been integrated. The model was validated using the experimental data of magnesium- and titanium-based nanocomposites containing different types of nano-sized particles (namely, Al2O3, Y2O3, and carbon nanotubes). The predicted results were observed to be in good agreement with the experimental data reported in the literature.


2011 ◽  
Vol 239-242 ◽  
pp. 759-763
Author(s):  
Saheb Nouari

Agglomeration and poor distribution/dispersion of carbon nanotubes (CNTs) within the matrix remains a major problem in processing homogeneous CNT reinforced metal matrix nanocomposites. In this work, we examine the effect of processing on the dispersion of CNTs in Al6061 and Al2124 alloy based Nanocomposites. Three methods were used to prepare the nanocomposite powders. In the first, CNTs were mixed with the prealloyed powder through dry ball milling. In the second, CNTs were sonicated then the prealloyed powder was added followed by sonication of the mixture and wet milling. In the third, the CNTs were functionalized, sonicated, and then the prealloyed powder was added followed by sonication of the mixture and wet milling. The effect of functionaliztion, sonication and type of milling on the dispersion of CNTs was evaluated.


2021 ◽  
Vol 06 ◽  
Author(s):  
Hong Yang ◽  
Jayesh B Patel ◽  
Xinliang Yang ◽  
Sarkis Gavras ◽  
Hajo Dieringa

: Metal Matrix Nanocomposites (MMNCs) often show excellent properties compared to their non-reinforced alloys due to either the achieved grain refinement or Orowan strengthening. Especially in light metals such as aluminium and magnesium as the matrix has the potential to be significantly improved in relation to mechanical properties. Functionalisation can also be achieved in some cases. However, the challenge lies in the homogeneous distribution of the ceramic nanoparticles in the melt, if MMNCs are processed via melt metallurgical processes. The large surface area of the nanoparticles generates large van der Waals forces which have to be overcome. Furthermore, the wettability of the particles with molten metal is difficult. Additional forces can be applied by ultrasound, electromagnetic stirring or even high-shearing. In this paper properties of MMNCs with a light metal matrix will be presented, which were produced with the High-Shearing Dispersion Technique. First, the process with its different characteristics and the underlying theory is presented and then property improvements are discussed by comparing MMNCs to their matrix materials.


Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1426
Author(s):  
Íris Carneiro ◽  
José Valdemar Fernandes ◽  
Sónia Simões

The strengthening effect of carbon nanotubes (CNTs) in metal matrix nanocomposites occurs due to several mechanisms that act simultaneously. The possible strengthening mechanisms for metal matrix nanocomposites reinforced with CNTs consist of: (1) load transfer, (2) grain refinement and texture strengthening, (3) second phase strengthening, and (4) strain hardening. The main focus of this work is to identify the strengthening mechanisms that play a role in the case of the Ni-CNT nanocomposite produced by powder metallurgy. For the dispersion and mixing of the metallic powders with CNTs, two different routes were performed by ultrasonication and ball milling. The results indicated that four different strengthening mechanisms are present in the nanocomposites and had a different contribution to the final mechanical properties. The load transfer and the increase in dislocation density seem to strongly affect the properties and microstructure of the nanocomposite. The grain refinement and the presence of second phase particles have a small contribution in the strengthening of this nanocomposite, since the introduction of CNTs in the Ni matrix slightly affects the size and orientation of the grains in the matrix and a few nanometric particles of Ni3C were identified.


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