Iron-bearing smectites: a revised relationship between structural Fe, b cell edge lengths and refractive indices

Clay Minerals ◽  
2013 ◽  
Vol 48 (1) ◽  
pp. 97-103 ◽  
Author(s):  
M. Heuser ◽  
P. Andrieux ◽  
S. Petit ◽  
H. Stanjek

AbstractStructural iron in smectites correlates with the cell edge length b and increases the refractive index. The cell edge length b is usually obtained from the position of the (060) reflection, but in this work we show that such b values differ from the values obtained from Rietveld fits because contributions from (hkl) reflections shift the position of the (060) reflection. The correlation between Fe and cell edge length b was significant (r2 > 0.99); the relationship is b [Å] = 8.9977(0.0035) + 0.1117(0.0032) × Fetot. Furthermore, we present for the first time measurements of the refractive index n of Fe-bearing smectites, applying a recently published turbidity method (Weidler & Friedrich, 2007). The refractive index correlates both with structural iron (r2 = 0.64) and with b (r2 = 0.94).

1954 ◽  
Vol 35 (2) ◽  
pp. 56-59 ◽  
Author(s):  
D. L. Randall

This study was made to investigate the relationship of surface meteorological data and corresponding surface refractive indices to radio field strengths in the FM frequency band. For meteorological observations during which the wind speeds were equal to or greater than 10 mph, and when fronts, low overcast clouds (less than 5000 ft), rain, thunderstorms and fogs were excluded, a 0.70 correlation coefficient was found between hourly surface refractive index and hourly median field strength over a Washington-Richmond path at a frequency of 96.3 Mc.


2017 ◽  
Vol 38 (2) ◽  
Author(s):  
Ruei-Chang Lu ◽  
Keh-Yi Lee

AbstractIn this work, the authors propose a modified type of multi-stage directional couplers and combine it with a wavelength-tunable laser to measure the refractive index of an undetermined biochemical liquid/solution. Tuning the wavelength of the laser incident on the modified multi-stage directional couplers, the relationship between the wavelength corresponding to the maximal output optical power and the refractive index of the unknown fluid has been obtained.


2021 ◽  
Vol 56 ◽  
pp. 134-155
Author(s):  
Yu. M. Shirshov ◽  

The optical properties of blood (spectra of the extinction coefficient, k, refractive index, n, etc.) carry important diagnostic information and are usually monitored using bulk samples. In this work, attention is drawn to the interface between the blood volume and the surface of glass or thin gold films on it, where the refractive index may differ from the bulk one. We draw attention to the relationship between two effects – SPR and TIR. It is shown that if the named effects are measured for two different external media 0 and 1 with different refractive indices, then the values of the angles SPR and TIR will be linearly related by the empirical formula SPR1=SPR0+TIR1- TIR0)*K, where the coefficient K depends on the thickness of the transition layer di between the surface and the volume of the liquid medium (suspension). Numerical calculation of K (di) for gold films shows that K = 1.6 at di = 0 and monotonically decreases to 0.01 with an increase in di to 300 nm (and further to 0). Measurement of the angular dependences of reflection, R(), on (1) 100% hematocrit blood samples, (2) hemolyzed samples and (3) washed erythrocytes with dilutions with a buffer solution. It was shown that all samples exhibit a minimum SPR, but the TIR angle can be measured only for blood samples with destroyed membranes (hemolyzed), buffer solution and plasma. The n-value for hemolyzed blood is 1.3505, which is indicative of a low hemoglobin content in the sample. At the same time, di for a sample of 100% hematocrit was 60-105 nm, which indicates a strong deformation of erythrocytes in the form of polyhedrocytes and their dense packing after centrifugation. Washing the cells with a buffer increases di to 280 nm and more and practically eliminates blood cells from the SPR sensitivity region. The reason for this may be that in the blood of 100% hematocrit, erythrocytes are in the form of polyhedrocytes tightly adhering to the gold surface, while as a result of washing and diluting with a buffer solution, the cells relax back into discocytes. As a result, the containing hemoglobin erythrocyte cytoplasm moves away from the surface at a distance di> 300 nm into the suspension volume and leaves the area of the enhanced plasmon-polariton field.


1960 ◽  
Vol 6 (1) ◽  
pp. 89-105 ◽  
Author(s):  
S. J. Webb

The relationship between cellular water and the death of air-borne cells, and the effect of added substances on these relationships, has been studied. The rate of death of air-stored cells has been correlated with the amount of water bonded to the cellular proteins. Refractive indices of cells, measured by light scatter and interferometry, have suggested that cells suspended in solutions of various compounds contain less water. With the exception of urea, the more able a compound is in displacing water, the less its protectiveness to air-borne cells. Inositol produced the smallest change in the water content and refractive index of cells. This is taken to indicate that, in the absence of water, this compound can form hydrogen bonds with cellular protein which are reversible with water. There appears also to be some relationship between the Gram stain reaction and aerosol stability of the cells. Ribonuclease and lysozyme treatment of air-stable cells rendered them air sensitive, whereas resistance to some antibiotics, and suspension in some antibiotics, afforded stability to air-sensitive cells. It is suggested that the site of damage is the cellular "membranes" which break down on desiccation and result in a loss of differentiation within the cell.


Author(s):  
Walter C. McCrone

An excellent chapter on this subject by V.D. Fréchette appeared in a book edited by L.L. Hench and R.W. Gould in 1971 (1). That chapter with the references cited there provides a very complete coverage of the subject. I will add a more complete coverage of an important polarized light microscope (PLM) technique developed more recently (2). Dispersion staining is based on refractive index and its variation with wavelength (dispersion of index). A particle of, say almandite, a garnet, has refractive indices of nF = 1.789 nm, nD = 1.780 nm and nC = 1.775 nm. A Cargille refractive index liquid having nD = 1.780 nm will have nF = 1.810 and nC = 1.768 nm. Almandite grains will disappear in that liquid when observed with a beam of 589 nm light (D-line), but it will have a lower refractive index than that liquid with 486 nm light (F-line), and a higher index than that liquid with 656 nm light (C-line).


2011 ◽  
Vol 10 (3) ◽  
pp. 139-143 ◽  
Author(s):  
Gazi Islam ◽  
Sarah E. S. Zilenovsky

This note examines the relationship between affirmative action (AA) program perceptions and women’s self-ascribed capacity and desire to become leaders. We propose that women who believe that their organization implements a program of preferential selection toward women will experience negative psychological effects leading to lowered self-expectations for leadership, but that this effect will be moderated by their justice perceptions of AA programs. We test this proposition empirically for the first time with a Latin American female sample. Among Brazilian women managers, desire but not self-ascribed capacity to lead was reduced when they believed an AA policy was in place. Both desire’s and capacity’s relationships with belief in an AA policy were moderated by justice perceptions.


2019 ◽  
pp. 42-44
Author(s):  
I.V. GUSAROV ◽  
V.A. OSTAPENKO ◽  
T.V. NOVIKOVА

Впервые в мире создана популяция зубров на территории 60 градусов северной широты. В новых климатических условиях разведения и сохранения зубров определены и проанализированы факторы существования вида на севере Европейской части РФ. Выявлены признаки, динамика численности, которые являются составной частью системы, предназначенной для управления биоразнообразием. Интродукция, являясь процессом введения в экосистему нехарактерных для нее видов, может усиливать изменения биоценозов как положительно, так и отрицательно. Насколько быстро и успешно проходит процесс адаптации заселенного вида, и усматривается его влияние на окружающую среду зависит дальнейшее существование зубров и в целом биоразнообразия. В статье обсуждаются вопросы взаимоотношения зубров с другими видами копытных и хозяйственной деятельностью человека, а также дальнейшим использованием зубров в сельскохозяйственном производстве. Пластичность зубров, выявление изменений и их анализ при вселении видов в новые условия обитания необходимы не только для определения развития или деградации биоценозов и в целом экосистемы, но и прогноза социально-экономических последствий интродукции как одного из методов сохранения редких и исчезающих видов фауны.For the first time in the world, a bison population has been created in an area of 60 degrees north latitude. In the new climatic conditions of breeding and preservation of bison, the factors of the species existence in the north of the European part of the Russian Federation are identified and analyzed. The signs, dynamics of abundance, which are an integral part of the system designed to manage biodiversity are identified, since the preservation of biological diversity on the planet is one of the main problems of our time. Introduction, being the process of introducing non-typical species into an ecosystem, can enhance changes in biocenoses, both positively and negatively. The question posing sounds especially when it comes to such a large hoofed animal as the European bison. How quickly and successfully the process of adaptation of the universe takes place and its environmental impact is seen depends on the continued existence of bison and biodiversity in general. The article discusses the relationship of bison with other types of ungulates and human activities, as well as the further use of bison in agricultural production. How these issues will be resolved positively depends on the future of these animals. Thus, the plasticity of bison, the identification of changes and their analysis, with the introduction of species into new habitat conditions is necessary not only to determine the development or degradation of biocenoses and the ecosystem as a whole, but also to predict the socio-economic consequences due to the introduction as one of the methods of preserving rare and endangered species of fauna.


Author(s):  
Ole V. Petersen ◽  
Alexander P. Khomyakov ◽  
Henning Sørensen

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Petersen, O. V., Khomyakov, A. P., & Henning. (2001). Natrophosphate from the Ilímaussaq alkaline complex, South Greenland. Geology of Greenland Survey Bulletin, 190, 139-141. https://doi.org/10.34194/ggub.v190.5184 _______________ The rare mineral natrophosphate has been identified for the first time in the Ilímaussaq alkaline complex in a drill core from the Kvanefjeld area. It occurs sparsely in zoned veinlets with cores of natrophosphate and borders of fibrous trona. The natrophosphate is more or less smoky, transparent and unaltered. The refractive index n = 1.448 ± 0.005 is low compared to that given for the material from the type locality, Khibina alkaline complex, Kola Peninsula; the unit cell parameter a = 27.76 ± 0.05 Å is in excellent agreement with that given for the material from the type locality. The veins occur in hyper-agpaitic naujakasite lujavrite; villiaumite is an associated mineral. Only a few water-soluble minerals have so far been found in the Ilímaussaq alkaline complex compared to the wealth of such minerals in the Khibina and Lovozero alkaline complexes. This is possibly at least partly due to lack of necessary precautions during sampling.


1979 ◽  
Vol 44 (7) ◽  
pp. 2064-2078 ◽  
Author(s):  
Blahoslav Sedláček ◽  
Břetislav Verner ◽  
Miroslav Bárta ◽  
Karel Zimmermann

Basic scattering functions were used in a novel calculation of the turbidity ratios for particles having the relative refractive index m = 1.001, 1.005 (0.005) 1.315 and the size α = 0.05 (0.05) 6.00 (0.10) 15.00 (0.50) 70.00 (1.00) 100, where α = πL/λ, L is the diameter of the spherical particle, λ = Λ/μ1 is the wavelength of light in a medium with the refractive index μ1 and Λ is the wavelength of light in vacuo. The data are tabulated for the wavelength λ = 546.1/μw = 409.357 nm, where μw is the refractive index of water. A procedure has been suggested how to extend the applicability of Tables to various refractive indices of the medium and to various turbidity ratios τa/τb obtained with the individual pairs of wavelengths λa and λb. The selection of these pairs is bound to the sequence condition λa = λ0χa and λb = λ0χb, in which b-a = δ = 1, 2, 3; a = -2, -1, 0, 1, 2, ..., b = a + δ = -1, 0, 1, 2, ...; λ0 = λa=0 = 326.675 nm; χ = 546.1 : 435.8 = 1.2531 is the quotient of the given sequence.


Author(s):  
David Willetts

Universities have a crucial role in the modern world. In England, entrance to universities is by nation-wide competition which means English universities have an exceptional influence on schools--a striking theme of the book. This important book first investigates the university as an institution and then tracks the individual on their journey to and through university. In A University Education, David Willetts presents a compelling case for the ongoing importance of the university, both as one of the great institutions of modern society and as a transformational experience for the individual. The book also makes illuminating comparisons with higher education in other countries, especially the US and Germany. Drawing on his experience as UK Minister for Universities and Science from 2010 to 2014, the author offers a powerful account of the value of higher education and the case for more expansion. He covers controversial issues in which he was involved from access for disadvantaged students to the introduction of L9,000 fees. The final section addresses some of the big questions for the future, such as the the relationship between universities and business, especially in promoting innovation.. He argues that the two great contemporary trends of globalisation and technological innovation will both change the university significantly. This is an authoritative account of English universities setting them for the first time in their new legal and regulatory framework.


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