Mg-rich dumortierite in cordierite-orthoamphibole-bearing rocks from the high-grade Bamble Sector, south Norway

1991 ◽  
Vol 55 (381) ◽  
pp. 563-577 ◽  
Author(s):  
Diederik Visser ◽  
Antony Senior
Keyword(s):  
Mineral Chemistry ◽  
Total Iron ◽  
Significant Part ◽  
High Grade ◽  
Alteration Zones ◽  
Tetrahedral Sites ◽  
Titaniferous Magnetite ◽  
Mineral Assemblages ◽  
A Minor ◽  
Bamble Sector

AbstractDumortierite is described from several occurrences of cordierite-orthoamphibole-bearing rocks in the upper-amphibolite facies area of the Bamble Sector, south Norway. Dumortierite occurs with chlorite, muscovite and quartz in late M4 alteration zones or aggregates after M3, peak-metamorphic cordierite and garnet and early M4 vein-cordierite, and intergrown with or replacing orthoamphibole. Late M4P-T conditions, which are interpreted as conditions of dumortierite formation, are estimated from the associated late M4 kyanite-andalusite-chlorite-quartz assemblage and Mg-Fe exchange geothermometry to be 500 ± 50 °C and 3–4 kbar. Retrogression of M3 mineral assemblages is initiated by influx of fluids with XCO2 of 0.3–0.4 during early M4 followed by more water-rich fluids during late M4. Late M4 fluids may show local variations in alkalis and boron. The dumortierites are the most Mg-rich (2.23–3.42 wt. % MgO) ever reported, and contain 0.00–2.05 wt.% TiO2, 0.00–1.08 wt.% Fe2O3, 29.62–32.42 wt.% SiO2 and 55.20–59.71 wt.% Al2O3. Al is the most likely substituent for Si, which shows a minor deficiency at the tetrahedral sites in most dumortierites. The major variations in the mineral chemistry can be described by the coupled substitutions Mg + Ti = 2AlVI, 3Mg = 2AlVI and possibly Mg + H = AlVI. Favoured by low ƒO2 prevailing conditions a significant part of total iron in dumortierites at one locality is present as Fe2+ giving evidence for the Fe2+ + SiIV = AlIV + AlVI tschermakite substitution. FeMg−1 substitution is considered to be limited. Ti-rich dumortierites coexist with rutile, ilmenite or titaniferous magnetite. The development of dumortierite from orthoamphibole correlates with an observed decrease of Al, Mg and Na and increase of Si and Fe in orthoamphibole towards dumortierite.

scholarly journals Rhenium - rich molybdenites in Thracian porphyry Mo±Cu occurrences, NE - Greece

2001 ◽  
Vol 34 (3) ◽  
pp. 1015 ◽  
Author(s):  
Β. ΜΕΛΦΟΣ ◽  
Π. ΒΟΥΔΟΥΡΗΣ ◽  
Κ. ΑΡΙΚΑΣ ◽  
Μ. ΒΑΒΕΛΙΔΗΣ
Keyword(s):  
Chemical Composition ◽  
Hydrothermal Alteration ◽  
Fluid Inclusions ◽  
Mineral Chemistry ◽  
Rare Element ◽  
Alteration Zones ◽  
Porphyry Cu ◽  
Mineral Assemblages ◽  
Host Rocks

The present study correlates both the mineralogy of the hydrothermal alteration and the mineral chemistry of molybdenites from three porphyry Mo ± Cu occurrences in Thrace: Melitena, Pagoni Rachi/Kirki and Ktismata/ Maronia. The mineralisations are genetically related to calcalkaline, subvolcanic bodies of Tertiary age. According to their mineralogical and chemical composition the host rocks are characterized as dacite (Melitena), dacitic andésite (Pagoni Rachi) and porphyry microgranite (Ktismata/Maronia). The molybdenites occur in disseminated form, as fracture fillings, as well within quartz stockworks crosscuting the central alteration zones of the intrusives. They are accompanied by the following mineral assemblages: quartz, sericite, pyrophyllite, diaspore, Ca-Ba-rich alunite, pyrite (Melitena); quartz, albite/K-feldspar, biotite, actinolite, magnetite (Pagoni Rachi); and sericite, kaolinite, pyrophyllite, chlorite (Ktismata). Preliminary microthermometric results showed homogenisation temperatures from 352° to 390 °C for Pagoni Rachi area and from 295° to 363 °C for Melitena area. The salinities range between 4.5 and 6.1 wt% eq. NaCl and between 2.7 and 3.4 wt% eq. NaCl, respectively. Detailed study on over 400 fluid inclusions from the porphyry Cu-Mo deposit in Maronia area revealed formation temperatures from 300° to 420 °C, whereas salinities are distincted in two different groups from 6 to 16 wt% eq. NaCl and from 28 to 55 wt% eq. NaCl. The chemical composition of the molybdenites from the three porphyry Mo±Cu deposits in Thrace was studied with 155 microprobe analyses. The results revealed unusual high and variable Re concentrations in the studied molybdenites. Re content in molybdenite from Melitena area vary from 0.21 to 1.74 wt%, 0.79 wt% on average. The highest values were measured in samples from Pagoni Rachi (0.45-4.21 wt%, 1.98 wt% on average). Finally, microprobe analyses from molybdenite in Ktismata/Maronia showed Re content between 0.12 and 2.88 wt% (0.76 wt% on average). Rhenium is a very rare element with many definite uses, and is mainly associated with molybdenite in porphyry type deposits. According to the data published so far the Re content in molybdenite reaches up to 0.42 wt%. It is obvious therefore that such high Re concentrations (0.12 to 4.22 wt%) from the studied molybdenites in Thrace, are very ineresting for a possible future exploitation.

High-grade Urothelial Carcinoma with Malignant Melanocytic Differentiation

2021 ◽  
pp. 106689692110004
Author(s):  
Hongzhi Xu ◽  
Elizabeth M. Genega ◽  
Liyan Zhuang ◽  
Ming Zhou
Keyword(s):  
Urothelial Carcinoma ◽  
Bladder Wall ◽  
Minor Component ◽  
Asian Woman ◽  
High Grade ◽  
Therapeutic Implications ◽  
Divergent Differentiation ◽  
Rare Cells ◽  
A Minor ◽  
Melanocytic Differentiation

Urothelial carcinoma usually shows divergent differentiation and variant histology with squamous and glandular morphology being most common. In this report, we present a case of divergent malignant melanocytic differentiation in a high-grade urothelial carcinoma. A 98-year-old East Asian woman with an anterior bladder wall mass underwent resection, which revealed a high-grade poorly differentiated tumor. A minor component of high-grade papillary urothelial carcinoma and carcinoma in situ is also present. The majority of the tumor cells are morphologically and immunohistochemically consistent with melanoma, a minority of cells are positive for urothelial markers, and rare cells coexpress both melanocytic and urothelial markers. Cells that express melanocytic markers or urothelial markers are intimately admixed together. Taken together, a diagnosis of high-grade urothelial carcinoma with malignant melanocytic differentiation was rendered. This is the first report in the literature of malignant melanocytic differentiation in a high-grade urothelial carcinoma, a finding that may have important diagnostic and therapeutic implications.

Oxidized and reduced mineral assemblages in greenstone belt rocks of the St. Ives gold camp, Western Australia: vectors to high-grade ore bodies in Archaean gold deposits?

2007 ◽  
Vol 43 (3) ◽  
pp. 363-371 ◽  
Author(s):  
Peter Neumayr ◽  
John Walshe ◽  
Steffen Hagemann ◽  
Klaus Petersen ◽  
Anthony Roache ◽  
...  
Keyword(s):  
Western Australia ◽  
Greenstone Belt ◽  
Gold Deposits ◽  
High Grade ◽  
Ore Bodies ◽  
Mineral Assemblages

scholarly journals PLUMBIAN "ALUNITES" IN HYDROTHERMAL ALTERATION ZONES OF EPITHERMAL AND PORPHYRY TYPE MINERALIZATIONS IN W. THRACE

2004 ◽  
Vol 36 (1) ◽  
pp. 492 ◽  
Author(s):  
Π. Βουδούρης ◽  
Κ. Αρίκας ◽  
Α. Κατερινόπουλος
Keyword(s):  
Hydrothermal Alteration ◽  
Solid Solutions ◽  
Mineral Chemistry ◽  
Alteration Zones ◽  
Hydrothermal Alteration Zones ◽  
Hydrothermal Environment

In this study a new occurrence of Pb-rich members of the alunite supergroup minerals is described. The "alunites" were traced in advanced argilic alteration zones of epithermal and porphyry type mineralizations in W. Thrace/(Greece). These "alunites" are Ca-Sr-Ba-Pb-rich phosphatessulfates and represent solid solutions between members of the alunite, woodhouseite and crandallite group minerals. The highest concentrations of PbO in the Mavrokoryfi and Melitaina alunites are 24.7% and 17.4% respectively. The plumbian phosphates-sulfates occur in the cores of the crystals and are surrounded by common K-Na-rich alunites in Mavrokoryfi and Ba-rich woodhouseite in Melitena, an indication that they were formed in a magmatic-hydrothermal environment after dissolution of apatite and feldspars by phosphate-sulphate rich solutions. The mineral-chemistry of these "alunites" can provide information regarding the genesis of the advanced argilic alteration zones in Greece, and help us in the distinction of the epithermal from deep porphyry style environments.

Glass-bearing felsic nodules from the crystallizing sidewalls of the 1944 Vesuvius magma chamber

2000 ◽  
Vol 64 (3) ◽  
pp. 481-496 ◽  
Author(s):  
P. Fulignati ◽  
P. Marianelli ◽  
A. Sbrana
Keyword(s):  
Magma Chamber ◽  
Melt Inclusions ◽  
Mineral Chemistry ◽  
Glassy Matrix ◽  
Crystal Mush ◽  
Stratigraphic Sequence ◽  
Shallow Magma Chamber ◽  
Mineral Assemblages ◽  
Pressure Crystallization

AbstractIn the 1944 Vesuvius eruption, the shallow magma chamber was disrupted during the highly energetic explosive phases. Abundant cognate xenoliths such as subvolcanic fergusites and cumulates, hornfels, skarns and rare marbles occur in tephra deposits.Mineral chemistry, melt inclusions in minerals and glassy matrix compositions show that fergusites (highly crystalline rocks made of leucite, clinopyroxene, plagioclase, olivine, apatite, oxides and glass) do not correspond to melt compositions but result from combined sidewall accumulation of crystals, formed from K-tephriphonolitic magma resident in the chamber, and in situ crystallization of the intercumulus melt. Very low H2O contents in the intercumulus glass are revealed by FTIR and apatite composition. Whole rock compositions are essentially determined by the bulk mineral assemblages.Glass–bearing fergusites constitute the outer shell of the magma chamber consisting of a highly viscous crystal mush with a melt content in the range 20–50 wt.%. The leucite/(clinopyroxene+olivine) modal ratio, varies with the extraction order of magmas from the chamber, decreasing upwards in the stratigraphic sequence. This reflects a vertical mineralogical zonation of the crystal mush. These data contribute to the interpretation of the subvolcanic low–pressure crystallization processes at the magma chamber sidewalls affecting alkaline potassic magmas.

Compositional variation in högbomites from north Connemara, Ireland

1985 ◽  
Vol 49 (354) ◽  
pp. 649-654 ◽  
Author(s):  
N. S. Angus ◽  
R. Middleton
Keyword(s):  
Chemical Composition ◽  
Regional Metamorphism ◽  
The Other ◽  
Partial Substitution ◽  
Compositional Variation ◽  
Physical Parameters ◽  
Chemical Heterogeneity ◽  
High Grade ◽  
Thermal Metamorphism ◽  
Mineral Assemblages

AbstractHögbomite occurs in two contrasting mineral assemblages within the Currywongaun-Dough-ruagh intrusion of north Connemara: a cordierite-rich pelitic xenolith and an orthopyroxenite. In the latter, högbomite and green spinel form blebs within magnetite-ilmenite grains. The högbomite displays significant compositional variation from grain to grain: TiO2 (3.0–6.3%), FeO (21.6–21.3%), MgO (10.0–7.5%), ZnO (3.6–2.4%). This chemical heterogeneity appears to represent variable degrees of partial substitution of Mg and Zn by Ti, in the replacement of spinel by högbomite. By contrast, in the cordierite-hornfels, the högbomite compositions are more notably enriched in iron: TiO2 (4.7–7.0%), FeO (29.6–24.3%), MgO (4.2–6.2%), ZnO (2.7–2.1%). This iron-rich högbomite appears to have formed primarily by interaction between opaque ore and adjacent cordierite, rather than by replacement of spinel.Two high-grade metamorphic episodes appear to be necessary for högbomite growth, one determining chemical composition and the other appropriate physical parameters. In the Connemara occurrences thermal metamorphism and partial melting, coupled with contamination of the surrounding magma, controlled the formation of mineral assemblages rich in Fe, Mg, Al, Ti, and Zn. Emplacement of the intrusion was accompanied by amphibolite facies regional metamorphism and it is to this metamorphic event that the growth of högbomite may be attributed.

A model for the origin of the Lac St. Jean anorthosite massif

1976 ◽  
Vol 13 (2) ◽  
pp. 389-399 ◽  
Author(s):  
R. A. Frith ◽  
K. L. Currie
Keyword(s):  
Experimental Data ◽  
Partial Melting ◽  
Metamorphic Rocks ◽  
High Grade ◽  
Calc Alkaline ◽  
Grenville Province ◽  
Thermal Event ◽  
Anorthosite Massif ◽  
Mineral Assemblages ◽  
Potassic Rocks

An ancient tonalitic complex becomes migmatitic around the Lac St. Jean massif, ultimately losing its identity in the high grade metamorphic rocks surrounding the anorthosite. Field relations suggest extreme metamorphism and anatexis of tonalitic rocks. Experimental data show that extensive partial melting of the tonalite leaves an anorthositic residue. The same process operating on more potassic rocks would leave monzonitic or quartz syenitic residues. Synthesis of experimental data suggests that the process could operate at pressures of 5–8 kbar and temperatures of 800–1000 °C, which are compatible with mineral assemblages around the anorthosite massif. Slightly higher temperatures at the end of the process could generate magmatic anorthosite.Application of the model to the Grenville province as a whole predicts generation of anorthosite during a long-lived thermal event of unusual intensity. Residual anorthosite would occur as a substratum in the crust, overlain by high-grade metamorphic rocks intruded by anorthosite and syenitic rocks, while higher levels in the crust would display abundant calc-alkaline plutons and extrusives.

Significance of “gneissic” rocks in the Liscomb Complex, Nova Scotia

2010 ◽  
Vol 47 (6) ◽  
pp. 927-940 ◽  
Author(s):  
J. V. Owen ◽  
R. Corney ◽  
J. Dostal ◽  
A. Vaughan
Keyword(s):  
Igneous Rocks ◽  
Metamorphic Rocks ◽  
Low Grade ◽  
High Grade ◽  
Peraluminous Granite ◽  
Isotopic Signatures ◽  
Conventional View ◽  
Basement Rocks ◽  
Mineral Assemblages ◽  
Intrusive Rocks

The Liscomb Complex comprises Late Devonian intrusive rocks (principally peraluminous granite) and medium- to high-grade metamorphic rocks (“gneisses”) that collectively are hosted by low-grade (greenschist facies) metasediments of the Cambro-Ordovician Meguma Group. The conventional view that these “gneisses” contain high-grade mineral assemblages and represent basement rocks has recently been challenged, and indeed, some of the rocks previously mapped as gneisses, particularly metapelites, have isotopic compositions resembling the Meguma Group. Amphibole-bearing enclaves in the Liscomb plutons, however, are isotopically distinct and in this regard resemble xenoliths of basement gneisses in the Popes Harbour lamprophyre dyke, south of the Liscomb area. Metasedimentary enclaves with Meguma isotopic signatures can contain garnets with unzoned cores (implying high temperatures) that host high-grade minerals (prismatic sillimanite, spinel, and (or) corundum) and are enclosed by retrograde-zoned rims. These features are interpreted here as having formed during and following the attainment of peak temperatures related to Liscomb magmatism. The amphibole-bearing meta-igneous rocks described here contain cummingtonite or hornblendic amphibole and occur as enclaves in granodioritic to tonalitic plutons. They are mineralogically, texturally, and isotopically distinct from Meguma metasediments and at least some of the plutonic rocks that enclose them, so remain the most likely candidate for basement rocks in the Liscomb Complex.

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