Geochemical characteristics and petrogenesis of the main granitic intrusions of Greece: an application of trace element discrimination diagrams

1992 ◽  
Vol 56 (385) ◽  
pp. 487-501 ◽  
Author(s):  
E. Baltatzis ◽  
J. Esson ◽  
P. Mitropoulos
Keyword(s):  
High Pressure ◽  
Trace Element ◽  
Partial Melting ◽  
Geochemical Characteristics ◽  
Pressure Fractionation ◽  
Tectonic Zones ◽  
Granitic Intrusions ◽  
Geochemical Investigation ◽  
Of Greece

AbstractGeochemical investigation of samples from 20 granitic intrusions in six tectonic zones of the Hellenides shows that both I-type and S-type granites occur in the region. The I-type granites from four of the zones, namely the Rhodope Massif (RM), the Serbomacedonian Massif (SMM), the Perirhodope Zone (PRZ) and the Attico-cycladic Zone (ACZ), show some systematic differences in their geochemistry. In particular, the Rb, Y, Nb, K and Ti contents increase in the sequence PRZ, SMM, RM and ACZ. The PRZ granites are of Jurassic age, those of the SMM and RM are Eocene to Oligocene and the ACZ ones are Miocene. The differences between zones are attributed to a combination of differences in partial melting and high-pressure fractionation processes. Geochemical differences within zones are explained by variable degrees of amphibole and apatite fractionation and accumulation.

scholarly journals The role of sulphur on the melting of Ca-poor sediment and on trace element transfer in subduction zones: an experimental investigation

2021 ◽  
Author(s):  
Anne-Aziliz Pelleter ◽  
Gaëlle Prouteau ◽  
Bruno Scaillet
Keyword(s):  
Trace Element ◽  
Partial Melting ◽  
Subduction Zones ◽  
Sediment Flux ◽  
Arc Magmas ◽  
Trace Element Contents ◽  
The Stability ◽  
Element Transfer ◽  
High Sediment

Abstract We performed phase equilibrium experiments on a natural Ca-poor pelite at 3 GPa, 750-1000 °C, under moderately oxidizing conditions, simulating the partial melting of such lithologies in subduction zones. Experiments investigated the effect of sulphur addition on phase equilibria and compositions, with S contents of up to ∼ 2.2 wt. %. Run products were characterized for their major and trace element contents, in order to shed light on the role of sulphur on the trace element patterns of melts produced by partial melting of oceanic Ca-poor sediments. Results show that sulphur addition leads to the replacement of phengite by biotite along with the progressive consumption of garnet, which is replaced by an orthopyroxene-kyanite assemblage at the highest sulphur content investigated. All Fe-Mg silicate phases produced with sulphur, including melt, have higher MgO/(MgO+FeO) ratios (relative to S-free/poor conditions), owing to Fe being primarily locked up by sulphide in the investigated redox range. Secular infiltration of the mantle wedge by such MgO and K2O-rich melts may have contributed to the Mg and K-rich character of the modern continental crust. Addition of sulphur does not affect significantly the stability of the main accessory phases controlling the behaviour of trace elements (monazite, rutile and zircon), although our results suggest that monazite solubility is sensitive to S content at the conditions investigated. The low temperature (∼ 800 °C) S-bearing and Ca-poor sediment sourced slab melts show Th and La abundances, Th/La systematics and HFSE signatures in agreement with the characteristics of sediment-rich arc magmas. Because high S contents diminish phengite and garnet stabilities, S-rich and Ca-poor sediment sourced slab melts have higher contents of Rb, B, Li (to a lesser extent), and HREE. The highest ratios of La/Yb are observed in sulphur-poor runs (with a high proportion of garnet, which retains HREE) and beyond the monazite out curve (which retains LREE). Sulphides appear to be relatively Pb-poor and impart high Pb/Ce ratio to coexisting melts, even at high S content. Overall, our results show that Phanerozoic arc magmas from high sediment flux margins owe their geochemical signature to the subduction of terrigenous, sometimes S-rich, sediments. In contrast, subduction of such lithologies during Archean appears unlikely or unrecorded.

Geochemistry and geochronology of OIB-type, Early Jurassic magmatism in the Zhangguangcai range, NE China, as a result of continental back-arc extension

2018 ◽  
Vol 158 (1) ◽  
pp. 143-157 ◽  
Author(s):  
Guangying Feng ◽  
Yildirim Dilek ◽  
Xiaolu Niu ◽  
Fei Liu ◽  
Jingsui Yang
Keyword(s):  
East Asia ◽  
Trace Element ◽  
Partial Melting ◽  
Early Jurassic ◽  
Ne China ◽  
Mafic Rocks ◽  
Asthenospheric Mantle ◽  
Trace Element Contents ◽  
Pacific Slab ◽  
Back Arc

AbstractThe Zhangguangcai Range in the Xing’an Mongolian Orogenic Belt, NE China, contains Early Jurassic (c. 188 Ma) Dabaizigou (DBZG) porphyritic dolerite. Compared with other island-arc mafic rocks, the DBZG dolerite is characterized by high trace-element contents, relatively weak Nb and Ta enrichments, and no Zr, Hf or Ti depletions, similar to OIB-type rocks. Analysed rocks have (87Sr/86Sr)i ratios of 0.7033–0.7044, relatively uniform positive ɛNd(t) values of 2.3–3.2 and positive ɛHf(t) values of 8.5–17.1. Trace-element and isotopic modelling indicates that the DBZG mafic rocks were generated by partial melting of asthenospheric mantle under garnet- to spinel-facies conditions. The occurrence of OIB-like mafic intrusion suggests significant upwelling of the asthenosphere in response to lithospheric attenuation caused by continental rifting. These processes occurred in an incipient continental back-arc environment in the upper plate of a palaeo-Pacific slab subducting W–NW beneath East Asia.

Trace element partitioning during high-P partial melting and melt-rock interaction; an example from northern Fiordland, New Zealand

2004 ◽  
Vol 22 (5) ◽  
pp. 443-457 ◽  
Author(s):  
F. C. Schröter ◽  
J. A. Stevenson ◽  
N. R. Daczko ◽  
G. L. Clarke ◽  
N. J. Pearson ◽  
...  
Keyword(s):  
New Zealand ◽  
Trace Element ◽  
Partial Melting ◽  
Rock Interaction ◽  
Trace Element Partitioning ◽  
Element Partitioning

Phase equilibrium and trace-element modeling of the partial melting of basaltic rocks under low pressure: Implications for plagiogranite generation

2021 ◽  
Author(s):  
Xiao-Fei Xu ◽  
Long-Long Gou ◽  
Xiao-Ping Long ◽  
Yu-Hang Zhao ◽  
Feng Zhou
Keyword(s):  
Trace Element ◽  
Partial Melting ◽  
Low Pressure ◽  
Bulk Rock ◽  
Hydrous Mineral ◽  
Rock Composition ◽  
Bulk Rock Composition ◽  
Element Modeling ◽  
Anhydrous Mineral ◽  
Ree Patterns

Abstract Phase equilibria and trace-element modeling using two previously reported basaltic bulk-rock compositions (samples D11 and 104-16), were carried out in this study, in order to better understand mechanism of low-pressure (LP) partial melting of mafic rocks and associated melt compositions. The T–MH2O pseudosections for both samples at three pressures (i.e. 0.5, 1.0 and 2.0 kbar) display that the H2O-stability field gradually increased with decreasing pressure within the T–MH2O range of 600–1100 °C and 0–12 mol.%. The H2O contents of 10, 5.0, and 0.5 mol.% were selected on the basis of the T–MH2O pseudosections to calculate P–T pseudosections over a P–T window of 0.1–3 kbar and 600–1100 °C, so that the reactions of both the H2O-fluxed and -absent meltings at LP conditions can be investigated. The solidus displays a negative or near-vertical P–T slope, and occurs between 710 and 900 °C at pressure between 0.1 and 3.0 kbar. LP melting of metabasites is attributed to the reactions of the hydrous mineral (hornblende and/or biotite) melting and anhydrous mineral (plagioclase, orthopyroxene, and augite) melting. The hydrous mineral melting is gradually replaced by anhydrous mineral melting as pressure decreasing, as the stability of hornblende decreases with falling pressure. With increasing temperature at a given pressure, the modeled melt compositions are expressed as progressions of the granite-granodiorite-gabbroic diorite fields for sample D11and granite-quartz monzonite-monzonite-gabbroic diorite fields for sample 104-16 on the total alkali–silica diagram. The modeled melts produced through the H2O-fluxed melting display higher Al2O3, CaO, MgO, and lower SiO2 and K2O than those formed by H2O-absent melting at the same P–T conditions. Furthermore, the modeled melts formed by H2O-absent melting, become richer in Al2O3, CaO, MgO, FeO, Na2O, but poorer in SiO2 and K2O as increasing water content. The results of trace-element modeling suggests that the nearly flat REE patterns of modeled bulk-rock composition are inherited by all the modeled melts, and the negative Eu anomalies and Sr depletion of the modeled melts gradually decrease as melting degree increases. Combined with the geochemical characteristics of natural oceanic plagiogranites, which have low K2O contents and flat or slightly LREE-depleted REE patterns, our results imply that a bulk-rock composition with low K2O (<0.17 wt.%) and slightly LREEs depletion is the most likely protolith composition (e.g. basalt D11) for plagiogranites, and the compositions of modeled melts formed by LP H2O-absent partial melting of the basalt D11 at relatively high temperatures (1000–1025 °C) are coincident with those of 1256D tonalites.

Late Eocene post-collisional magmatic rocks from the southern Qiangtang terrane record the melting of pre-collisional enriched lithospheric mantle

2021 ◽  
Author(s):  
Yue Qi ◽  
Qiang Wang ◽  
Gang-jian Wei ◽  
Xiu-Zheng Zhang ◽  
Wei Dan ◽  
...  
Keyword(s):  
Tibetan Plateau ◽  
Trace Element ◽  
Partial Melting ◽  
Early Cretaceous ◽  
Lithospheric Mantle ◽  
Late Eocene ◽  
The Tibetan Plateau ◽  
Mafic Rocks ◽  
Isotopic Compositions ◽  
Qiangtang Terrane

Diverse rock types and contrasting geochemical compositions of post-collisional mafic rocks across the Tibetan Plateau indicate that the underlying enriched lithospheric mantle is heterogeneous; however, how these enriched mantle sources were formed is still debated. The accreted terranes within the Tibetan Plateau experienced multiple stages of evolution. To track the geochemical characteristics of their associated lithospheric mantle through time, we can use mantle-derived magmas to constrain the mechanism of mantle enrichment. We report zircon U-Pb ages, major and trace element contents, and Sr-Nd isotopic compositions for Early Cretaceous and late Eocene mafic rocks in the southern Qiangtang terrane. The Early Cretaceous Baishagang basalts (107.3 Ma) are characterized by low K2O/Na2O (<1.0) ratios, arc-like trace element patterns, and uniform Sr-Nd isotopic compositions [(87Sr/86Sr)i = 0.7067−0.7073, εNd(t) = −0.4 to −0.2]. We suggest that the Baishagang basalts were derived from partial melting of enriched lithospheric mantle that was metasomatized by subducted Bangong−Nujiang oceanic material. We establish the geochemistry of the pre-collisional enriched lithospheric mantle under the southern Qiangtang terrane by combining our data with those from other Early Cretaceous mafic rocks in the region. The late Eocene (ca. 35 Ma) post-collisional rocks in the southern Qiangtang terrane have low K2O/Na2O (<1.0) ratios, and their major element, trace element, and Sr-Nd isotopic compositions [(87Sr/86Sr)i = 0.7042−0.7072, εNd(t) = −4.5 to +1.5] are similar to those of the Early Cretaceous mafic rocks. Based on the distribution, melting depths, and whole-rock geochemical compositions of the Early Cretaceous and late Eocene mafic rocks, we argue that the primitive late Eocene post-collisional rocks were derived from pre-collisional enriched lithospheric mantle, and the evolved samples were produced by assimilation and fractional crystallization of primary basaltic magma. Asthenosphere upwelling in response to the removal of lithospheric mantle induced the partial melting of enriched lithospheric mantle at ca. 35 Ma.

Duobagou Permian–Triassic granites from the Dunhuang orogenic belt, NW China: implications for the tectonic evolution of the southernmost Central Asian Orogenic Belt

2020 ◽  
pp. 1-17
Author(s):  
Zhendong Wang ◽  
Yuanyuan Zhang ◽  
Xiangjiang Yu ◽  
Zhaojie Guo
Keyword(s):  
Partial Melting ◽  
Tectonic Evolution ◽  
Orogenic Belt ◽  
Central Asian Orogenic Belt ◽  
Crustal Growth ◽  
Central Asian ◽  
Granitic Intrusions ◽  
Mantle Component ◽  
Type Granite ◽  
T Values

Abstract The Duobagou Permian–Triassic granites of the Dunhuang orogenic belt are of great importance in understanding the tectonic evolution of the southernmost Central Asian Orogenic Belt. LA-ICP-MS U–Pb zircon ages indicate that Permian–Triassic granitic intrusions from the Duobagou area formed at 276–274 Ma and 246 ± 1 Ma. These granites have high SiO2, Na2O and K2O, but low Al2O3, CaO and MgO contents and belong mainly to the high-K calc-alkaline I-type granite series. Based on whole-rock geochemistry and Sr–Nd and zircon Hf isotopes, the Duobagou Permian–Triassic granites were dominantly derived from the partial melting of lower continental crust formed during late Palaeoproterozoic to Mesoproterozoic times in a post-collisional extensional setting. Permian granites with zircon ϵHf(t) values of −5.4 to +3.1 and Hf model ages of TDM2 = 1.14–1.70 Ga indicate the involvement of a mantle component in their petrogenesis. Triassic granites with higher zircon ϵHf(t) values (+0.5 to +3.8) and TDM2 = 1.08–1.31 Ga suggest more juvenile sources caused by a greater contribution of mantle-derived melts, indicating a significant crustal growth. Regional extension from lithospheric delamination and heating from asthenospheric upwelling were proposed to have triggered the partial melting of lower crust, resulting in the generation of the Permian–Triassic magmatism. This may have been the mechanism for the significant crustal growth during Permian and Triassic times in the southernmost Central Asian Orogenic Belt.

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