Orogenesis, high-T thermal events, and gold vein formation within metamorphic rocks of the Alaskan Cordillera

1993 ◽  
Vol 57 (388) ◽  
pp. 375-394 ◽  
Author(s):  
R. J. Goldfarb ◽  
L. W. Snee ◽  
W. J. Pickthorn

AbstractMesothermal, gold-bearing quartz veins are widespread within allochthonous terranes of Alaska that are composed dominantly of greenschist-facies metasedimentary rocks. The most productive lode deposits are concentrated in south-central and southeastern Alaska; small and generally nonproductive gold-bearing veins occur upstream from major placer deposits in interior and northern Alaska. Oreforming fluids in all areas are consistent with derivation from metamorphic devolatilisation reactions, and a close temporal relationship exists between high-T tectonic deformation, igneous activity, and gold mineralization. Ore fluids were of consistently low salinity, CO2-rich, and had δ18O values of 7‰- 12‰ and δD values between −15‰ and −35‰. Upper-crustal temperatures within the metamorphosed terranes reached at least 450-500°C before onset of significant gold-forming hydrothermal activity. Within interior and northern Alaska, latest Paleozoic through Early Cretaceous contractional deformation was characterised by obduction of oceanic crust, low-T/high-P metamorphism, and a lack of gold vein formation. Mid-Cretaceous veining occurred some 50-100 m.y. later, during a subsequent high-T metamorphic/magmatic event, possibly related to extension and uplift. In southern Alaska, gold deposits formed during latter stages of Tertiary, subduction-related, collisional orogenesis and were often temporally coeval with calc-alkaline magmatism.

1989 ◽  
Vol 26 (1) ◽  
pp. 157-175 ◽  
Author(s):  
Ghislain Tourigny ◽  
Claude Hubert ◽  
Alex C. Brown ◽  
Robert Crépeau

The Bousquet gold deposits are structurally controlled, disseminated and vein type lodes located within a 500 m wide anastomosing deformation zone. Ore is located within narrow zones of high strain surrounded by lozenge-shaped panels of less-deformed rock. Strain characteristics are those of the bulk inhomogeneous flattening style. Ore lenses are spatially related to highly sheared, fractured, and altered mafic and felsic volcanic and volcaniclastic rocks of contrasting rheologic properties. Deformation features can be ascribed to multistage progressive ductile → brittle deformation. Strain markers and kinematic indicators show that the principal displacement within the deformation zone was reverse faulting with a minor sinistral throw. A structural analysis demonstrates that the deformation responsible for the development of a pervasive regional foliation, brittle fractures, and oblique reverse faults can be attributed to a north–south compression.Metamorphic minerals such as andalusite, kyanite, garnet, biotite, chlorite, chloritoid, and calcic plagioclases indicate that upper greenschist metamorphism was attained locally within the ductile deformation zones. Subsequent pervasive retrograde alteration, including carbonatization and hydration of silicates to white mica and chlorite, suggests an important period of hydrothermal activity after peak metamorphism. Native gold is typically closely associated with pyrite and with these hydrothermal assemblages and was probably channelled into ductile and brittle structural zones prior to and after peak metamorphism.Two principal types of steeply dipping auriferous sulphide veins are present in the mine: foliation-oblique veins and foliation-parallel veins. Foliation-oblique veins occur within steeply dipping conjugate shear fractures spatially related to competent protoliths. The main set was emplaced during late stages of the regional tectonic deformation, after the initial development of a pervasive regional foliation and before the end of the progressive deformation. Foliation-parallel veins are located within openings created by decoupling schistosity laminae or by overriding of irregular surfaces such as fault planes and shear zones. These veins are relatively younger and less deformed than the foliation-oblique veins.Pervasive pyritic disseminations along foliation surfaces are earliest and synchronous with the development of foliation and probably continued throughout the progressive deformation. Early disseminated sulphides may also have been remobilized by pressure solution into later vein systems.


2008 ◽  
Vol 72 (4) ◽  
pp. 953-970 ◽  
Author(s):  
T. Oberthür ◽  
T. W. Weiser

AbstractGold mineralization at the Viceroy Mine is hosted in extensional veins in steep shear zones that transect metabasalts of the Archaean Arcturus Formation. The gold mineralization is generally made up of banded or massive quartz carrying abundant coarse arsenopyrite. However, most striking is a distinct suite of Au-Bi-Te-S minerals, namely joseite-A (Bi4TeS2), joseite-B (Bi4Te2S), hedleyite (Bi7Te3), ikunolite (Bi4S3), ‘protojoseite’ (Bi3TeS), an unnamed mineral (Bi6Te2S), bismuthinite (Bi2S3), native Bi, native gold, maldonite (Au2Bi), and jonassonite (AuBi5S4). The majority of the Bi-Te-S phases is characterized by Bi/(Se+Te) ratios of >1. Accordingly, this assemblage formed at reduced conditions at relatively low fS2 and fTe2. Fluid-inclusion thermometry indicates depositional temperatures of the main stage of mineralization of up to 342°C, in the normal range of mesothermal, orogenic gold deposits worldwide. However, melting temperatures of Au-Bi-Te phases down to at least 235°C (assemblage (Au2Bi + Bi + Bi7Te3)) imply that the Au-Bi-Te phases have been present as liquids or melt droplets. Furthermore, the close association of native gold, native bismuth and other Bi-Te-S phases suggests that gold was scavenged from the hydrothermal fluids by Bi-Te-S liquids or melts. It is concluded that a liquid/melt-collecting mechanism was probably active at Viceroy Mine, where the distinct Au-Bi-Te-S assemblage either formed late as part of the main, arsenopyrite-dominated mineralization, or it represents a different mineralization event, related to rejuvenation of the shear system. In either case, some of the gold may have been extracted from pre-existing, gold-bearing arsenopyrite by Bi-Te-S melts, thus leading to an upgrade of the gold ores at Viceroy. The Au-Bi-Te-S assemblage represents an epithermal-style mineralization overprinted on an otherwise mesothermal (orogenic) gold mineralization.


2021 ◽  
Vol 7 (6) ◽  
Author(s):  
T. Yarboboev ◽  
Sh. Sultanov ◽  
I. Ochilov

Analysis of the available information and the results of many years of research on gold deposits in Uzbekistan made it possible to identify the main unconventional types of deposits. Among them, the most interesting are apocarbonate, crustal, sulfide-carbonaceous and apovolcanogenic quartzite (Upper-Kattakashkasai ore occurrence). The apocarbonate type is widespread in Uzbekistan, has been studied in sufficient detail and information is provided on it in this article. The article examines the existence, distribution and genesis of ores of Karlin type gold deposits. The generalizing characteristics of the Karlin type gold mineralization are given. The issues of geochemical specialization of the Paleozoic strata of the Chakylkalyan megablock are considered, the most favorable stratolevel for the localization of mineralized zones is determined, and the features of carbonate rocks in the process of gold deposition during reactions with silicic solutions are characterized. Based on the materials of regional geochemical profiling, the behavior of the main ore-forming elements in the rocks of both carbonate and volcanogenic-terrigenous strata is analyzed. As a result of the analysis, subclarkic contents of the main ore-forming elements (As, Co, Ni, Pb, Cu, Ag, V, Cr, Sc) were revealed, which create increased concentrations in gold-bearing pyrites of both apocarbonate gold mineralization and related formations.


1993 ◽  
Vol 30 (8) ◽  
pp. 1566-1581 ◽  
Author(s):  
R. Craig Ford ◽  
Norman A. Duke

Gold-bearing iron formations are widely distributed within extensive metasedimentary terranes of the Archean Slave Province, situated in the northwestern Canadian Precambrian Shield. Mineralized iron formations occur within thick turbidite sequences overprinted by a protracted history of deformation, metamorphism, and plutonism. Economically significant gold prospects are specifically sited at structural culminations characterized by polyphase folding. Based on garnet–biotite geothermometry on the stable prograde metamorphic assemblage of enveloping metapelites, peak metamorphic conditions are approximated to be 570 °C and 4 kbar (1 kbar = 100 MPa). Diagnostic prograde mineralogy reveals that two facies of silicate iron formation are represented at the five gold occurrences investigated: (1) amphibolitic iron formation (AIF), characterized by quartz + grunerite + hornblende + pyrrhotite ± garnet ± graphite + ilmenite, and (2) pelitic iron formation (PIF), consisting of quartz + biotite + garnet + ilmenite ± grunerite ± hornblende. Textures reveal that grunerite crystallization preceded hornblende and garnet. Within AIF, banded pyrrhotite is in textural equilibrium with prograde metamorphic minerals. Retrograde hornblende, garnet, zoisite, apatite, carbonate, ferroactinolite, and gold-bearing sulphide minerals replace the prograde mineral assemblages on the margins of quartz veins that intensify at AIF fold hinges.It is hypothesized that the iron-formation-hosted gold deposits of the Slave Province are a result of multistage processes. Gold concentrated at high background levels within pyrrhotite-bearing AIF was remobilized during fluid migration into brittle AIF fold hinges in subsequent metamorphic and deformational events. Metamorphic fluid, ponded in fractured AIF hinge domains, caused retrogressive replacement, quartz veining, and gold-bearing sulphide precipitation during waning temperature. Although the mineralized hinge zones commonly display evidence of late chloritization, this alteration did not further affect gold distribution. The gold precipitated with destabilization of thio complexes due to sulphidation prior to low-temperature hydrothermal activity.


2021 ◽  
Author(s):  
Wei Gao ◽  
Ruizhong Hu ◽  
Albert H. Hofstra ◽  
Qiuli Li ◽  
Jingjing Zhu ◽  
...  

Abstract The Youjiang basin on the southwestern margin of the Yangtze block in southwestern China is the world’s second largest Carlin-type gold province after Nevada, USA. The lack of precise age determinations on gold deposits in this province has hindered understanding of their genesis and relation to the geodynamic setting. Although most Carlin-type gold deposits in the basin are hosted in calcareous sedimentary rocks, ~70% of the ore in the Badu Carlin-type gold deposit is hosted by altered and sulfidized dolerite. Although in most respects Badu is similar to other Carlin-type gold deposits in the province, alteration of the unusual dolerite host produced hydrothermal rutile and monazite that can be dated. Field observations show that gold mineralization is spatially associated with, but temporally later than, dolerite. In situ secondary ion mass spectrometry (SIMS) U-Pb dating on magmatic zircon from the least altered dolerite yielded a robust emplacement age of 212.2 ± 1.9 Ma (2σ, mean square of weighted deviates [MSWD] = 0.55), providing a maximum age constraint on gold mineralization. The U-Th/He ages of detrital zircons from hydrothermally mineralized sedimentary host rocks at Badu and four other Carlin-type gold deposits yielded consistent weighted mean ages of 146 to 130 Ma that record cooling from a temperature over 180° to 200°C and place a lower limit on the age of gold mineralization in the basin. Hydrothermal rutile and monazite that are coeval with gold mineralization have been identified in the mineralized dolerite. Rutile is closely associated with hydrothermal ankerite, sericite, and gold-bearing pyrite. It has high concentrations of W, Fe, V, Cr, and Nb, as well as growth zones that are variably enriched in W, Fe, Nb, and U. Monazite contains primary two-phase fluid inclusions and is intergrown with gold-bearing pyrite and hydrothermal minerals. In situ SIMS U-Pb dating of rutile yielded a Tera-Wasserburg lower intercept age of 141.7 ± 5.8 Ma (2σ, MSWD = 1.04) that is within error of the in situ SIMS Th-Pb age of 143.5 ± 1.4 Ma (2σ, MSWD = 1.5) on monazite. These ages are ~70 m.y. younger than magmatic zircons in the host dolerite and are similar to the aforementioned U-Th/He cooling ages on detrital zircons from hydrothermally mineralized sedimentary host rocks. We, therefore, conclude that the Badu Carlin-type gold deposit formed at ca. 144 Ma. The agreement of the rutile and monazite ages with the U-Th-He cooling ages of Badu and four other Carlin-type gold deposits in the Youjiang basin suggests that ca. 144 Ma is representative of a regional Early Cretaceous Carlin-type hydrothermal event formed during back-arc extension.


2020 ◽  
pp. 355-373
Author(s):  
Karen D. Kelley ◽  
Eric P. Jensen ◽  
Jason S. Rampe ◽  
Doug White

Abstract Cripple Creek is among the largest epithermal districts in the world, with more than 800 metric tons (t) Au (>26.4 Moz). The ores are associated spatially, temporally, and genetically with ~34 to 28 Ma alkaline igneous rocks that were emplaced into an 18-km2 diatreme complex and surrounding Proterozoic rocks. Gold occurs in high-grade veins, as bulk tonnage relatively low-grade ores, and in hydrothermal breccias. Pervasive alteration in the form of potassic metasomatism is extensive and is intimately associated with gold mineralization. Based on dating of intrusions and molybdenite and gangue minerals (primarily using 40Ar/39Ar and Re-Os techniques), the region experienced a protracted but intermittent history of magmatism (over a period of at least 5 m.y.) and hydrothermal activity (intermittent over the final ~3 m.y. of magmatic activity). Key factors that likely played a role in the size and grade of the deposit were (1) the generation of alkaline magmas during a transition between subduction and extension that tapped a chemically enriched mantle source; (2) a long history of structural preparation, beginning in the Proterozoic, which created deep-seated structures to allow the magmas and ore fluids to reach shallow levels in the crust, and which produced a fracture network that increased permeability; and (3) an efficient hydrothermal system, including effective gold transport mechanisms, and multiple over-printed hydrothermal events.


2021 ◽  
Vol 21 (1) ◽  
pp. 246-261
Author(s):  
Hongye Feng ◽  
Yiwen Ju ◽  
Bo Chen ◽  
Weixuan Fang ◽  
Hongjian Zhu ◽  
...  

The mineralogical and compositional characteristics of gold-bearing minerals and the occurrence of gold are not only of great significance to exploring the sources of ore-forming materials and their formation mechanisms but also helpful for designing reasonable beneficiations and smelting schemes and achieving remarkable economic benefits. This paper presents an integrated study on the crystal characteristics, elemental composition and distribution of pyrite (the main gold-bearing minerals), on the basis of electron probe microanalysis (EPMA), scanning electron microscopy (SEM), laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) and nano-secondary ion mass spectrometry (NanoSIMS). The occurrence of gold in the Shuiyindong gold deposit and Ashawayi gold deposit has been studied by means of microscopy, SEM, and EPMA images, elemental correlations, S–Fe–As ternary diagrams, logAs–logAu diagrams and Au/As ratios. The gold in pyrite of the Shuiyindong deposit is in the form of nano gold inclusions and lattice gold. The gold in pyrite of the Ashawayi deposit dominantly exists in the form of nano gold inclusions or is present as micro-nano gold particles in the cracks or edges of pyrite, some of which can exist as lattice gold. The ore-forming hydrothermal solution of the Shuiyindong gold deposit is mainly underground hot brine, but it may be reformed by a deep magmatic hydrothermal solution or volcanic-subvolcanic hydrothermal solution. The ore-forming hydrothermal solution of the Ashawayi gold deposit is mainly derived from the metamorphic hydrothermal solution formed during the orogenic process, and the ore-forming process or post-mineralization process may be reformed by the leaching of underground hot brine. Finally, the characteristics of ore-forming fluids and evolution of the two types of deposits are determined via pyrite element surface scanning. This paper shows that micro-nanoscale study of gold-bearing pyrite is of great significance to understanding the gold mineralization process and is worth further study.


2019 ◽  
Vol 20 (2) ◽  
pp. 174-183
Author(s):  
Hani E. Sharafeldin ◽  
Alexander A. Vercheba

Banded ferruginous-siliceous formations (FSF) are confined to the Precambrian basement of the Arabian-Nubian Shield within the central part of the Eastern Desert of Egypt. Gold mineralization is spatially associated with banded ferruginous quartzite, representing one of the most ancient manifestations of gold ore. The Precambrian rocks are combined into deposits complex of the Neoproterozoic Pan-African megacycle of the territory development. Banded iron-silicate rocks occur in sedimentary-volcanogenic rocks that were formed in the subduction trough zones, and are represented by metamorphosed ferruginous quartzites, jaspilites and schists. FSF show tectonic dislocations, shear cracks, and fracture cracks made by gold-quartz-sulphide mineralization. Promising for the identification of gold-bearing mineralization in the rocks of the FSF can be iron-silicate deposits with the occurrence of epigenetic hydrothermal activity as a result of activation of the submarine volcanism of the tholeiitic type.


Author(s):  
K. Derevska ◽  
O. Aleksandrov ◽  
V. Berehovenko ◽  
M. Kovalchuk ◽  
K. Rudenko ◽  
...  

The article clarifies the stratigraphic binding and origin of silicon nodules, which served as the main raw material for the manufacture of tools for mammoth hunters of the Mezhyrich Late Paleolithic site. In archaeological publications, these nodules are often mentioned to be confined to the "Vyrzhikovsky layer" (the Albian layer of the Lower Cretaceous), which was formed under continental conditions and consists of sand-clay (kaolin, in particular) deposits. The analysis of the necessary conditions and possible mechanisms for the formation of silicon nodules indicates the erroneousness of such ideas. Most likely, the source of silicon raw materials was the marine deposits of the Cenomanian (Upper Cretaceous), or, in accordance with the modern stratigraphic division of the Mesozoic-Cenozoic sequence, deposits of the Burim suite (upper Albian – lower Cenomanian). The paleogeographic setting, sedimentological conditions and lithological composition of the "Vyrzhikovsky layer" did not ensure the formation of silicon nodules in it in the form of inclusions. The latter are diagenetic in origin and could only form in the thickness of carbonate rocks, free of clay minerals. The region of Kaniv dislocations was the optimal region from the silicon production point of view, which was determined: firstly, by the tectonic dislocation of the sedimentary sequence, which contributed to the removal of deposits containing silicon nodules in the thickness of younger rocks; secondly,the erosion activity of temporary streams, which brought these deposits to the level of the denudation cut-off. The most convenient place for collecting flints was not the outcrop of bedrock in ravines but the cones of their removal, which overlook the floodplains of the Dnipro and Ros'. The possibility of collecting flint in the immediate vicinity of the Mezhirich site, in the ravines and gullies between the Ros and Rosava rivers, does not find confirmation, since the chalk deposits here lie much lower than the local erosion base and are not exposed by ravines. Therefore, the leading role in the formation of the raw material supply of the Late Paleolithic site of Mezhirich was played by the region adjacent to the Kaniv mountains of the alluvial-proluvial plain.Despite long-term geological study of the Dniester River basin, we still have no clear evidences about gold-bearing potentiality of this area as well as origin of gold. The leading role of geological, geochemical and mineralogical criteria is proved for defining the prospects of substantial gold deposits finding within the Dniester river basin. Gold was found here in the crystalline basement and in the sedimentary cover rocks. Study of mineralogy and lithology of the terraces above the flood-plain and typomorphic peculiarities of native gold shows that palaeogeographic conditions and alimentation zones of debris vary at the different tectonic stages of this area development. Gold-bearing potential of the Pliocene-Quaternary sediments in the Dniester River basin is related to the Pliocene (VI-IX terraces above the flood-plain) and Quaternary (I-V terraces above the flood-plain) terraces complex of the Dniester river, as well as this river and its inflows recent alluvia. Our study of the Mid-flow part of the Dniester river basin allow to conclude that native gold was found in geologocal strata of all ages, from Proterozoic up to the recent alluvium. This fact points the necessity of further prospecting to find the mother lodes of gold. Our field study, samples analyses made as well as publications observation allow highlighting the principal directions of further prospecting and evaluation works. The main among that are: 1) comprehensive study of river Dniester alluvia and its terraces complex (previously VI–VII terraces), that will allow to specify their material composition, to assess real gold-bearing potential and to define the history of denudation areas changes; 2) lithogeochemical prospecting of primary and secondary dispersion haloes to clear the principal gold-bearing regularities; 3) definition of prospect plots within the area described; 4) modern analytical approach study of typomorphic peculiarities of native gold from alluvia and terrace deposits to define its ore formational affinity and mineral type.


Author(s):  
Arifudin Idrus ◽  
Sukamandaru Prihatmoko ◽  
Ernowo Harjanto ◽  
Franz Michael Meyer ◽  
Irzal Nur ◽  
...  

In Indonesia, gold is commonly mined from epithermal-, porphyry-, and skarn-type deposits that are commonly found in volcanic belts along island arcs or active continental margin settings. Numerous gold prospects, however, were recently discovered in association with metamorphic rocks. This paper focuses on metamorphic rock-hosted gold mineralization in Eastern Indonesia, in particular the Bombana (SE Sulawesi) and Buru Island (Maluku) prospects. At Bombana, gold-bearing quartz-veins are hosted by the Pompangeo metamorphic complex. Sheared, segmented veins vary in thickness from 2 cm to 2 m. Gold is mainly present in the form of ‘free gold’ among silicate minerals and closely related to cinnabar, stibnite, tripuhyite, and in places, minor arsenopyrite. The gold distribution is erratic, however, ranging from below detection limit up to 134 g/t. At least three generations of veins are identified. The first is parallel to the foliation, the second crosscuts the first generation of veins as well as the foliation, and the late-stage laminated deformed quartz-calcite vein represents the third mineralization stage. The early veins are mostly massive to crystalline, occasionally brecciated, and sigmoidal, whereas the second-stage veins are narrower than the first ones and less subjected to brecciation. Gold grades in the second- and third-stage veins are on average higher than that in the earlier veins. Microthermometric and Raman spectrometric studies of fluid inclusions indicate abundant H2O-NaCl and minor H2O-NaCl-CO2 fluids. Homogenization temperatures and salinities vary from 114 to 283 ºC and 0.35 to 9.08 wt.% NaCl eq., respectively. Crush-leach analysis of fluid inclusions suggests that the halogen fluid chemistry is not identical to sea water, magmatic or epithermal related fluids, but tends to be similar to fluids in mesothermal-type gold deposits. In Buru Island (Gunung Botak and Gogorea prospects), two distinct generations of quartz veins are identified. Early quartz veins are segmented, sigmoidal discontinuous and parallel to the foliation of the host rock. This generation of quartz veins is characterized by crystalline relatively clear quartz, and weakly mineralized with low sulfide and gold contents. The second type of quartz veins occurs within the ‘mineralized zone’ of about 100 m in width and ~1,000 m in length. Gold mineralization is intensely overprinted by argillic alteration. The mineralization-alteration zone is probably parallel to the mica schist foliation and strongly controlled by N-S or NE-SW-trending structures. Gold-bearing quartz veins are characterized by banded texture particularly following host rock foliation and sulphide banding, brecciated and rare bladed-like texture. Alteration types consist of propylitic (chlorite, calcite, sericite), argillic and carbonation represented by graphite banding and carbon flakes. Ore mineral comprises pyrite, native gold, pyrrhotite, and arsenopyrite. Cinnabar and stibnite are present in association with gold. Ore chemistry indicates that 11 out of 15 samples yielded more than 1 g/t Au, in which 6 of them graded in excess of 3 g/t Au. All high-grade samples are composed of limonite or partly contain limonitic material. This suggests the process of supergene enrichment. Interestingly, most of the high-grade samples contain also high concentrations of As (up to 991ppm), Sb (up to 885ppm), and Hg (up to 75ppm). Fluid inclusions in both quartz vein types consist of 4 phases including L-rich, V-rich, L-V-rich and L1-L2-V (CO2)-rich phases. The mineralizing hydrothermal fluid typically is CO2-rich, of moderate temperature (300-400 ºC), and low salinity (0.36 to 0.54 wt.% NaCl eq). Based on those key features, gold mineralization in Bombana and Buru Island tends to meet the characteristics of orogenic, mesothermal types of gold deposit. Metamorphic rock-hosted gold deposits could represent the new targets for gold exploration particularly in Eastern Indonesia.


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