Ba-rich micas from the Yindongzi-Daxigou Pb-Zn-Ag and Fe deposits, Qinling, northwestern China

1996 ◽  
Vol 60 (400) ◽  
pp. 433-445 ◽  
Author(s):  
Shao-Yong Jiang ◽  
M. R. Palmer ◽  
Yan-He Li ◽  
Chun-Ji Xue
Keyword(s):  
Clay Minerals ◽  
Electron Microprobe ◽  
Carbonate Rocks ◽  
Regional Metamorphism ◽  
Hydrothermal Fluids ◽  
Northwestern China ◽  
Pore Fluids ◽  
Anoxic Conditions ◽  
Sedimentary Environments ◽  
Ore Deposition

AbstractElectron-microprobe analyses of muscovite, biotite, and feldspar are reported for the stratiform Yindongzi—Daxigou Pb—Zn—Ag and Fe deposits of Qinling, northwestern China. The micas are characterized by high Ba levels in banded albite-carbonate rocks that host the deposits. The biotite is also rich in Cl, as is biotite in the nearby Tongmugou Pb-Zn deposit, although biotite and muscovite from this deposit lack Ba enrichment. It is likely that the Ba-rich micas in the Yindongzi-Daxigou deposits formed contemporaneously from the diagenesis and/or regional metamorphism of hydrothermally altered clay minerals, with the barium being derived from entrained pore fluids that may represent relict hydrothermal fluids associated with ore deposition. During the formation of coexisting muscovite and biotite, barium is preferentially partitioned into muscovite and chloride into biotite. Together with the presence of baryte rocks in the bedded ores, these data suggest that ore deposition in the Yindongzi—Daxigou deposits took place in a more oxidising environment than in the nearby Tongmugou deposit. This difference is attributed to the contrasting sedimentary environments of the two deposits, with the Yindongzi—Daxigou deposits having formed under shallow, oxic conditions and the Tongmugou deposit under deeper, anoxic conditions.

scholarly journals Mineral composition of mafic minerals and ore deposition from the Kassiteres (Sappes) and Pagoni Rachi ( Kirki) porphyry Cu-Mo prospects / W. Thrace

2001 ◽  
Vol 34 (3) ◽  
pp. 1005 ◽  
Author(s):  
Π. ΒΟΥΔΟΥΡΗΣ
Keyword(s):  
Mineral Composition ◽  
Chemical Evolution ◽  
Electron Microprobe ◽  
Hydrothermal Fluid ◽  
Major Element ◽  
Fluid Phase ◽  
Hydrothermal Fluids ◽  
Hydrothermal Conditions ◽  
Porphyry Cu ◽  
Ore Deposition

The porphyry Cu-Mo mineralizations at Kassiteres and Pagoni Rachi are genetically related with dioritic to dacitoandesitic subvolcanic rocks that were and preliminary microthermometric data indicate that the hypogene mineralizations were introduced during albitic / potassic alteration of the intrusives and temperatures about 400°C from boiling magmatic-hydrothermal fluids. Electron microprobe major element analyses are presented for magmatic and hydrothermal biotites and amphiboles from both occurences. Hydrothermal biotites in the albitic / potassic zones are more magnesian than their magmatic counterparts and therefore close to phlohopite end - member composition. The amphiboles from Kassiteres range from magnesio - hornblende to actinolite, commonly within the same grain. Moreover the chemical data in both magmatic and hydrothermal biotites and amphiboles from the above two occurences indicate a Mg - and Si - enrichment and a Ti - depletion during crustallization and cooling from magmatic to late magmatic - early hydrothermal conditions. It is likely that an increase in oxyzen fugacity accompanied their chemical evolution. This oxidation trend is associated with the fluid exsolution of the magmas resulting in the development of the studied porphyry type mineralizations. Elements, which are also depleted from Mg - rich (more oxidized) amphiboles and biotites (K, Na, Fe and Ti) are partitioned in the magmatic - hydrothermal fluid phase and are responsible for the albitic / potassic altaration of both occurences.

scholarly journals Upper Jurassic Bedded Limestones and Early Diagenetic Dolomitized Limestones in the Light of Mineralogical, Geochemical and Sedimentological Studies; Kraków Area, Poland

Minerals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 462
Author(s):  
Marcin Krajewski ◽  
Piotr Olchowy
Keyword(s):  
Clay Minerals ◽  
Normal Wave ◽  
Upper Jurassic ◽  
Reef Facies ◽  
Sedimentary Environments ◽  
Storm Wave ◽  
Microscopic Studies ◽  
Silica Alumina ◽  
Characteristic Features ◽  
Facies Types

This paper describes and analyzes the Upper Jurassic (Lower Kimmeridgian) succession exposed in the Zakrzówek Horst, located in the Kraków area. Three distinguished facies types FT 1-FT 3 comprise several limestone varieties: sponge-microbial, pelitic-bioclastic, and partly dolomitized detrital-bioclastic. Their sedimentary environments varied from relatively deeper, attaining storm-wave base, to more shallower, probably close to normal-wave base. Characteristic features of limestones are changes in contents of CaCO3 and insoluble residuum as well as porosity values in vertical transitional zones between facies types. The investigated facies types differ in sediment porosity dependent on development of limestones and its susceptibility to mechanical compaction during the early diagenesis. The studied limestones show high CaCO3 contents and minor insoluble residuum contents comprising quartz, chalcedony and clay minerals. No distinct variability occurs in contents of magnesium, silica, alumina and iron accumulated in clay minerals, iron oxides and oxyhydroxides, as well as in the amounts of amorphous silica. Early diagenetic dolomites, which occur locally within the limestones, were unrelated to fracture systems as possible pathways responsible for transfer of solutions rich in Mg2+ ions. The possible source of Mg2+ ions might have been the pore solutions, which migrated from compacted basinal bedded facies towards reef facies or the grain-supported bedded facies developed in the adjacent areas. Microscopic studies revealed dedolomitization at the surfaces and in the inner parts of dolomite crystals. In many cases, dolomite crystals were replaced by calcite forming pseudomorphs.

Naldrettite (Pd2Sb): A new find in Brazil and comparison with worldwide occurrences

2021 ◽  
Vol 59 (6) ◽  
pp. 1801-1820
Author(s):  
Giorgio Garuti ◽  
Federica Zaccarini
Keyword(s):  
Regional Metamorphism ◽  
Layered Intrusion ◽  
Hydrothermal Fluids ◽  
Maximum Temperature ◽  
Magma Intrusion ◽  
Type Composition ◽  
Before And After ◽  
Magmatic Stage ◽  
New Finding ◽  
Podiform Chromitites

ABSTRACT Naldrettite (Pd2Sb) is a PGM discovered in 2005 in Mesamax Northwest deposit, Ungava region, Quebec, Canada. Before and after its approval, PGM with the naldrettite type composition have been reported from a number of localities worldwide. Most frequently, naldrettite has been documented in magmatic Ni–Cu–PGE sulfide deposits, hydrothermal veins in porphyry coppers of the Cu–Au type, and PGE deposits of Alaskan-type zoned intrusions. Naldrettite has been occasionally found in metasomatic Sb–As sulfide ore, metamorphic Ni–oxide ore, and podiform chromitites, although these occurrences have not been fully constrained by solid chemical analyses or paragenetic reconstruction. In this paper we report the first discovery of naldrettite in Brazil. This new finding occurs in a chromitite sample collected in the Luanga Complex, a Neo-archaean layered intrusion in the Carajás Mineral Province. Paragenetic association with alteration assemblages (ferrianchromite, Fe-hydroxides, chlorite) suggests precipitation of naldrettite from metamorphic hydrothermal fluids. The average composition of the Luanga sample (Pd1.76Pt0.24)Σ2.00(Sb0.57As0.43)Σ1.00 shows major substitution of Pt and As. These elements were derived from the breakdown of primary sperrylite, and were incorporated in naldrettite deposited by percolating fluids, at temperature below 350 °C (maximum temperature registered by the crystallization of associated chlorite). An overview of documented occurrences indicates that naldrettite can form in a variety of igneous rocks (ultramafic, mafic, felsic), even involving minimal concentrations of Pd and Sb. Crystallization of naldrettite generally occurs in the post-magmatic stage due to the activity of hydrothermal fluids containing volatile species Sb, As, Bi, Te, and Pd due to its higher mobility compared with the other PGE. A major issue concerns the origin of fluids that can be: (1) “residual”, after the main crystallization of the host magma, (2) “metamorphic”, during regional metamorphism or serpentinization, and (3) “metasomatic”, emanating from an exotic magma intrusion. The combination of two or three of these factors is the most likely process observed in the naldrettite-bearing complexes.

Volcanogenic clays in Jurassic and Cretaceous strata of England and the North Sea Basin

Clay Minerals ◽  
2000 ◽  
Vol 35 (1) ◽  
pp. 25-55 ◽  
Author(s):  
C. V. Jeans ◽  
D. S. Wray ◽  
R. J. Merriman ◽  
M. J. Fisher
Keyword(s):  
Clay Minerals ◽  
Clay Mineral ◽  
North Sea ◽  
Volcanic Ash ◽  
Hydrothermal Fluids ◽  
Mineral Deposits ◽  
The North ◽  
Clay Deposits ◽  
The North Sea ◽  
Thermal Doming

AbstractThe nature and origin of authigenic clay minerals and silicate cements in the Jurassic and Cretaceous sediments of England and the North Sea are discussed in relation to penecontemporaneous volcanism in and around the North Sea Basin. Evidence, including new REE data, suggests that the authigenic clay minerals represent the argillization of volcanic ash under varying diagenetic conditions, and that volcanic ash is a likely source for at least the early silicate cements in many sandstones. The nature and origin of smectite-rich, glauconite-rich, berthierine-rich and kaolin-rich volcanogenic clay mineral deposits are discussed. Two patterns of volcanogenic clay minerals facies are described. Pattern A is related to ash argillization in the non-marine and marine environments. Pattern B is developed by the argillization of ash concentrated in the sand and silt facies belts in the seas bordering ash-covered islands and massifs. It is associated with regression/ transgression cycles which may be related to thermal doming and associated volcanism, including the submarine release of hydrothermal fluids rich in Fe. The apparent paucity of volcanogenic clay deposits in the Jurasssic and Early Cretaceous sediments of the North Sea is discussed.

scholarly journals Fracture Fillings and Implication of Fluid Activities in Volcanic Rocks: Dixi Area in Kelameili Gas Field, Junggar Basin, Northwestern China

Minerals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 154 ◽  
Author(s):  
Mingyou Feng ◽  
Tian Liu ◽  
Tong Lin ◽  
Xiaohong Liu ◽  
Ningxin Li ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Volcanic Rocks ◽  
Junggar Basin ◽  
Hydrothermal Fluids ◽  
Northwestern China ◽  
Volatile Components ◽  
Gas Field ◽  
Weakly Alkaline ◽  
Quartz Veins ◽  
Calcite Veins

The Carboniferous Batamayineishan Formation of the Kelameili Gas Field is a specific weathered crust-related volcanic reservoir that has a significant production rate in the Junggar Basin, Northwestern China, attributed to debatable processes of fluid evolution. The results suggest that various types of fluids occurring in volcanic rocks lead to the filling of quartz and calcite in fractures and their associated alteration haloes. The silica that formed quartz veins was mainly derived from deep hydrothermal fluids, while the carbon dioxide that formed calcite veins originated from sources characterized by mixing and alteration of deep hydrothermal and hydrocarbon fluids. Siliceous hydrothermal fluids rich in sulphur dioxide and other volatile components were driven by a pressure gradient and buoyancy, and circulated both laterally and vertically along the fractures, forming quartz veins and tension fractures under different temperature conditions. Moreover, changes in salinity, pressure, and carbon dioxide of deep fluids, varying from acidic to weakly alkaline, resulted in earlier calcite precipitation in contraction fractures and weathered fractures. Tectonic uplift resulted in the long-term exposure of volcanic rocks, where fresh water mixed with the partially alkaline fluid escaping the basin to form calcite cements, thus retaining the characteristics of a seepage environment in the weathered fractures. Structural fractures occurred due to tectonic movements during the burial period. Filling and leakage of hydrocarbons caused pore fluids to convert from acidic to alkaline, precipitating late sparry calcite in dissolution fractures. Late hydrothermal fluid metasomatism, brought about by infiltration into the permeable zone, caused partial dissolution of local calcite along cleavage cracks.

The Carboniferous Shikebutai Iron Deposit in Western Tianshan, Northwestern China: Petrology, Fe-O-C-Si Isotopes, and Implications for Iron Pathways

2019 ◽  
Vol 114 (6) ◽  
pp. 1207-1222 ◽  
Author(s):  
Xiuqing Yang ◽  
Jingwen Mao ◽  
Zongsheng Jiang ◽  
M. Santosh ◽  
Zuoheng Zhang ◽  
...  
Keyword(s):  
Iron Ore ◽  
Iron Reduction ◽  
Hydrothermal Fluids ◽  
Northwestern China ◽  
Iron Deposit ◽  
Organic Carbon Content ◽  
Isotope Data ◽  
Western Tianshan ◽  
Dissimilatory Iron Reduction ◽  
Si Isotope

Abstract Submarine volcanic-hosted iron deposits are important sources of iron ore in northwestern China. Here we present the petrological characteristics and coupled Fe-O, C, and Si isotope data of iron ores from the Shikebutai submarine volcanic-hosted hematite deposit in the Western Tianshan region. Several stratiform and lenticular hematite-dominated orebodies occur in Carboniferous submarine volcano-sedimentary sequences in this region. The ores are mainly composed of hematite, quartz, and minor siderite with distinct alternating iron-rich and silica-rich bands. The hematite shows δ56Fe and δ18O values in the range of –0.31 to 0.80‰ and 2.2 to 7.0‰, respectively, and the jasper yields δ30Si values of –1.90 to –1.20‰. Iron and Si were both derived from hydrothermal fluids related to submarine magmatism/volcanism. The Fe-bearing minerals in the Shikebutai deposit define distinct formation pathways. Hematite is the primary dehydrated Fe(III) oxyhydroxide, and the Fe isotope data indicate fractionation resulting from the partial oxidation of Fe(II). The O isotope data reflect inheritance from the submarine hydrothermal fluids source. Jasper was produced during coprecipitation of silica adsorbed onto the Fe(III) oxyhydroxides. The siderite-rich iron ore/volcaniclastic rock samples with a high and variable total organic carbon content (0.14–5.57%) show negative δ13C values (–3.0 to –1.1‰) and light δ56Fe values (–1.11 to –0.84‰). Our isotope data, together with the common occurrence of hematite inclusions in siderite, suggest that siderite was mainly produced by microbial dissimilatory iron reduction during diagenesis. The geologic, petrological, and isotopic data suggest that the Carboniferous Shikebutai deposit was precipitated through chemical and biogenic processes.

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