scholarly journals Widespread Permian granite magmatism in Lower Austroalpine units: significance for Permian rifting in the Eastern Alps

2020 ◽  
Vol 113 (1) ◽  
Author(s):  
Sihua Yuan ◽  
Franz Neubauer ◽  
Yongjiang Liu ◽  
Johann Genser ◽  
Boran Liu ◽  
...  
Keyword(s):  
Tectonic Setting ◽  
Eastern Alps ◽  
Geochemical Data ◽  
Calc Alkaline ◽  
Three Samples ◽  
High K ◽  
Icp Ms ◽  
Granite Magmatism ◽  
Austroalpine Unit ◽  
Granite Suite

Abstract The Grobgneis complex, located in the eastern Austroalpine unit of the Eastern Alps, exposes large volumes of pre-Alpine porphyric metagranites, sometimes associated with small gabbroic bodies. To better understand tectonic setting of the metagranites, we carried out detailed geochronological and geochemical investigations on the major part of the porphyric metagranites. LA–ICP–MS zircon U–Pb dating of three metagranites sampled from the Grobgneis complex provides the first reliable evidence for large volumes of Permian plutonism within the pre-Alpine basement of the Lower Austroalpine units. Concordant zircons from three samples yield ages at 272.2 ± 1.2 Ma, 268.6 ± 2.3 Ma and 267.6 ± 2.9 Ma interpreted to date the emplacement of the granite suite. In combination with published ages for other Permian Alpine magmatic bodies, the new U–Pb ages provide evidence of a temporally restricted period of plutonism (“Grobgneis”) in the Raabalpen basement Complex during the Middle Permian. Comparing the investigated basement with that of the West Carpathian basement, we argue that widespread Permian granite magmatism occurred in the Lower Austroalpine units. They belong to the high-K calc-alkaline to shoshonitic S-type series on the base of geochemical data. Zircon Hf isotopic compositions of the Grobgneis metagranites show εHf(t) values of − 4.37 to − 0.6, with TDM2 model ages of 1.31–1.55 Ga, indicating that their protoliths were derived by the recycling of older continental crust. We suggest that the Permian granitic and gabbroic rocks are considered as rifted-related rocks in the Lower Austroalpine units and are contemporaneous with cover sediments.

Geochemistry, zircon geochronology, and isotopic systematics of the Zhanbuzhale granites in the East Kunlun, Qinghai Province, northwestern China: implications for the tectonic setting

2020 ◽  
Vol 57 (2) ◽  
pp. 275-291
Author(s):  
Hao-Ran Li ◽  
Ye Qian ◽  
Feng-Yue Sun ◽  
Liang Li
Keyword(s):  
Tectonic Setting ◽  
Alkali Feldspar ◽  
Northwestern China ◽  
Geochemical Data ◽  
Calc Alkaline ◽  
Qinghai Province ◽  
East Kunlun ◽  
Initial Stage ◽  
High K ◽  
Tethys Ocean

The Zhanbuzhale region, in the Eastern Kunlun Orogen of northwestern China, is characterized by large volumes of Phanerozoic granitoid rocks and is an ideal region for investigating the tectonic evolution of the Paleo-Tethys system. However, the exact timing of the final closure of the Paleo-Tethys Ocean and initial continental collision remains controversial because of a lack of precise geochronological and detailed geochemical data. In this paper, we report new zircon U–Pb ages and mineralogical, petrographic, and geochemical data for samples of Middle Triassic granodiorite and alkali feldspar granite from the Zhanbuzhale region. The zircon U–Pb ages indicate that the granodiorite and alkali feldspar granite formed at 239 and 236 Ma, respectively. The granodiorites are high-K calc-alkaline, metaluminous, high Sr content, high Sr/Y ratios, low Y content, and show adakite-like affinities. The alkali feldspar granites display high SiO2, extremely low MgO, and low Zr+Nb+Ce+Y contents as well as low Fe2O3t/MgO ratios, showing metaluminous to peraluminous and high-K calc-alkaline features. Geochemical and petrological characteristics of the alkali feldspar granites suggest that they are highly fractionated I-type granites. The granodiorites and alkali feldspar granites have zircon εHf(t) values ranging from –2.26 to –0.18, and from –2.17 to +2.18, respectively. Together with regional geological data, we propose that the Triassic (approximately 239–236 Ma) granitoids were generated during the later stages of northward subduction of the Paleo-Tethys oceanic plate, and that the initial stage of collision between the East Kunlun and the Bayan Har–Songpan Ganzi terrane occurred at approximately 236–227 Ma.

Early Cretaceous crust–mantle interaction linked to rollback of the Palaeo-Pacific flat-subducting slab: constraints from the intermediate–felsic volcanic rocks of the northern Great Xing’an Range, NE China

2021 ◽  
pp. 1-22
Author(s):  
Jia-Hao Jing ◽  
Hao Yang ◽  
Wen-Chun Ge ◽  
Yu Dong ◽  
Zheng Ji ◽  
...  
Keyword(s):  
Early Cretaceous ◽  
Volcanic Rocks ◽  
Geochemical Data ◽  
Calc Alkaline ◽  
Ne China ◽  
Asthenospheric Mantle ◽  
High K ◽  
Wide Range ◽  
Great Xing’An Range ◽  
Subducting Slab

Abstract Late Mesozoic igneous rocks are important for deciphering the Mesozoic tectonic setting of NE China. In this paper, we present whole-rock geochemical data, zircon U–Pb ages and Lu–Hf isotope data for Early Cretaceous volcanic rocks from the Tulihe area of the northern Great Xing’an Range (GXR), with the aim of evaluating the petrogenesis and genetic relationships of these rocks, inferring crust–mantle interactions and better constraining extension-related geodynamic processes in the GXR. Zircon U–Pb ages indicate that the rhyolites and trachytic volcanic rocks formed during late Early Cretaceous time (c. 130–126 Ma). Geochemically, the highly fractionated I-type rhyolites exhibit high-K calc-alkaline, metaluminous to weakly peraluminous characteristics. They are enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs) but depleted in high-field-strength elements (HFSEs), with their magmatic zircons ϵHf(t) values ranging from +4.1 to +9.0. These features suggest that the rhyolites were derived from the partial melting of a dominantly juvenile, K-rich basaltic lower crust. The trachytic volcanic rocks are high-K calc-alkaline series and exhibit metaluminous characteristics. They have a wide range of zircon ϵHf(t) values (−17.8 to +12.9), indicating that these trachytic volcanic rocks originated from a dominantly lithospheric-mantle source with the involvement of asthenospheric mantle materials, and subsequently underwent extensive assimilation and fractional crystallization processes. Combining our results and the spatiotemporal migration of the late Early Cretaceous magmatic events, we propose that intense Early Cretaceous crust–mantle interaction took place within the northern GXR, and possibly the whole of NE China, and that it was related to the upwelling of asthenospheric mantle induced by rollback of the Palaeo-Pacific flat-subducting slab.

Release of Uranium from Uraninite in Granites Through Alteration: Implications for the Source of Granite-Related Uranium Ores

2021 ◽  
Author(s):  
Long Zhang ◽  
Zhenyu Chen ◽  
Fangyue Wang ◽  
Noel C. White ◽  
Taofa Zhou
Keyword(s):  
Uranium Concentration ◽  
Geochemical Data ◽  
Uranium Deposits ◽  
Bulk Rock ◽  
Calc Alkaline ◽  
Alkaline Granite ◽  
Compositional Evolution ◽  
High K ◽  
Backscattered Electron ◽  
Uranium Sources

Abstract Uraninite is the main contributor to the bulk-rock uranium concentration in many U-rich granites and is the most important uranium source for granite-related uranium deposits. However, detailed textural and compositional evolution of magmatic uraninite in granites during alteration and associated uranium mobilization have not been well documented. In this study, textures and geochemistry of uraninites from the Zhuguangshan batholith (South China) were investigated by scanning electron microscopy (SEM) and electron probe microanalysis (EPMA). The geochemical data indicate that the Longhuashan and Youdong plutons are peraluminous leucogranite, the Changjiang pluton is highly fractionated high-K calc-alkaline granite, and the Jiufeng pluton belongs to a high-K calc-alkaline association. Uraninites from the Longhuashan and Youdong granites have lower concentrations of ThO2 (0.9–4.0 wt %) and rare earth elements (REE)2O3 (0.1–1.0 wt %) than those from the Changjiang and Jiufeng granites (ThO2 = 4.4–7.6 wt %, REE2O3 = 0.7–5.1 wt %). Uraninites observed in the Longhuashan, Youdong, Changjiang, and Jiufeng granites yielded chemical ages of 223 ± 3, 222 ± 2, 157 ± 1, and 161 ± 2 Ma, respectively. The samples (including altered and unaltered) collected from the Longhuashan, Youdong, and Changjiang granites are characterized by highly variable whole-rock U concentrations of 6.9 to 44.7 ppm and Th/U ratios of 0.9 to 7.0, consistent with crystallization of uraninite in these granites being followed by uranium leaching during alteration. Alteration of uraninite, indicated by altered domains developing microcracks and appearing darker in backscattered electron (BSE) images compared to unaltered domains, results in the incorporation of Si and Ca and mobilization of U. In contrast, the least altered samples of the unmineralized Jiufeng granite have low U concentrations (5.3–16.4 ppm) and high ΣREE/U (13.6–49.4) and Th/U ratios (2.1–5.6), which inhibit crystallization of uraninite, as its crystallization occurs when the U concentration is high enough to exceed the substitution capacity of other U-bearing minerals. These results indicate that the Longhuashan, Youdong, and Changjiang granites were favorable uranium sources for the formation of uranium deposits in this area. This study highlights the potential of uraninite alteration and geochemistry to assist in deciphering uranium sources and enrichment processes of granite-related uranium deposits.

An early Proterozoic volcanic arc succession in southeastern Wyoming

1984 ◽  
Vol 21 (4) ◽  
pp. 415-427 ◽  
Author(s):  
Kent C. Condie ◽  
Craig A. Shadel
Keyword(s):  
Fractional Crystallization ◽  
Tectonic Setting ◽  
Volcanic Rocks ◽  
Geochemical Data ◽  
Alkaline Basalt ◽  
Calc Alkaline ◽  
Early Proterozoic ◽  
Enriched Mantle ◽  
Sierra Madre ◽  
Felsic Volcanic

The Green Mountain Formation of early Proterozoic age in the Sierra Madre Range of southeastern Wyoming comprises a bimodal mafic and felsic volcanic assemblage. The rocks, which are chiefly breccias, agglomerates, flows, and volcaniclastic sediments, represent both subaerial and submarine eruptions and in part were redeposited in fluvial and nearshore marine environments. Volcanic rocks are clearly calc-alkaline in character and share a large number of geochemical features in common with continental-margin arcs or evolved oceanic-arc systems.The low Mg numbers and Ni contents of the basalts require 30–40% olivine fractional crystallization, and the high contents of the most incompatible elements, high (La/Sm)N ratios, and low Zr/Nb ratios require an undepleted or enriched mantle source. Geochemical data are consistent with an origin for the felsic volcanics and associated Encampment River granodiorite by shallow fractional crystallization of calc-alkaline basalt in a tectonic setting similar to modern arc systems. The near absence of andesites may reflect the retention of andesitic magma in crustal reservoirs during fractional cyrstallization.

scholarly journals Zircon U–Pb geochronology and geochemistry of granitic rocks in central Mongolia

2020 ◽  
Vol 50 ◽  
pp. 23-44
Author(s):  
Boldbaatar Dolzodmaa ◽  
Yasuhito Osanai ◽  
Nobuhiko Nakano ◽  
Tatsuro Adachi
Keyword(s):  
Tectonic Setting ◽  
Granitic Rocks ◽  
Metamorphic Rocks ◽  
Calc Alkaline ◽  
Volcanic Arc ◽  
Central Mongolia ◽  
Central Asian ◽  
High K ◽  
Three Stages ◽  
Late Neoproterozoic

The Central Asian Orogenic Belt had been formed by amalgamation of voluminous subduction–accretionary complexes during the Late Neoproterozoic to the Mesozoic period. Mongolia is situated in the center of this belt. This study presents new zircon U–Pb geochronological, whole-rock major and trace element data for granitoids within central Mongolia and discusses the tectonic setting and evolution of these granitic magmas during their formation and emplacement. The zircon U–Pb ages indicate that the magmatism can be divided into three stages: the 564–532 Ma Baidrag granitoids, the 269–248 and 238–237 Ma Khangai granitoids. The 564–532 Ma Baidrag granitoids are adakitic, have an I-type affinity, and were emplaced into metamorphic rocks. In comparison, the 269–248 Ma granitoids have high-K, calc-alkaline, granodioritic compositions and are I-type granites, whereas the associated the 238–237 Ma granites have an A-type affinity. The 564–532 Ma Baidrag and 269–248 Ma Khangai granitoids also both have volcanic arc-type affinities, whereas the 238–237 Ma granites formed in a post-collisional tectonic setting. These geochronological and geochemical results suggest that arc magmatism occurred at the 564–532 Ma which might be the oldest magmatic activity in central Mongolia. Between the Baidrag and the Khangai, there might be paleo-ocean and the oceanic plate subducted beneath the Khangai and produced voluminous granite bodies during the 269–248 Ma. After the closure of the paleo-ocean, the post collisional granitoids were formed at the 238–237 Ma based on the result of later granitoids in the Khangai area.

scholarly journals Age, origin and tectonic setting of Dulaankhan granitic pluton in northern Mongolia

2019 ◽  
pp. 22-34
Author(s):  
Baatar Gendenjamts ◽  
Baatar Munkhtsengel ◽  
Dashdorjgochoo Odgerel ◽  
Dorjgochoo Sanchir ◽  
Bayaraa Ganbat
Keyword(s):  
Tectonic Setting ◽  
Small Body ◽  
Early Jurassic ◽  
Geochemical Data ◽  
Quartz Syenite ◽  
Granitic Pluton ◽  
Eu Anomaly ◽  
High K ◽  
Northern Mongolia ◽  
Type Granite

Dulaankhan granitic pluton, which is situated in northern Mongolia, the southern portion of the Mongolian-Transbaikalian belt (MTB), is petrographically composed of fine to medium-grained peralkaline granite and is intruded by a small body of quartz syenite. Geochemical data show the Dulaankhan granite and the intruding quartz syenite are both slightly peraluminous and high-K calc-alkaline, and are enriched in LREEs relative to the HREEs, with negative Eu anomaly, and in large ion lithophile elements (LILEs; such as K, Cs and Rb) with respect to high field strength elements (HFSEs; e.g., Nb, Ta and Ti). In terms of relations of Nb, Zr and Y to Ga/Al, however, the Dulaankhan granite and quartz syenite show geochemical features of A-type granites and can be classified into the A2-sub type granite, implying that the pluton formed in an post-collision extensional environment. LA-ICPMS zircon U-Pb dating results suggest that the Dulaankhan granite crystallized at 198±1 Ma, whereas the intruding quartz syenite at 180±1 Ma, consistent with our field observation that the quartz syenite intrudes the granite, attesting that the two granitic bodies were emplaced at different times although both of them formed during the Early Jurassic period. According to these new data, as well as regional ones, we propose that the Dulaankhan granitic pluton was likely generated in the post-collision setting related to the orogenesis of the Mongol-Okhotsk belt that seems to occur prior to Early Jurassic in the northern Mongolian segment.

Stratigraphy, geochemistry, and petrology of the Upper Cretaceous volcanic arc sequence north of Istanbul, Pontides, NW Turkey

2021 ◽  
Author(s):  
Cemre Ay ◽  
Gürsel Sunal ◽  
Aral I. Okay
Keyword(s):  
Black Sea ◽  
Upper Cretaceous ◽  
High Ratio ◽  
Primitive Mantle ◽  
Geochemical Data ◽  
The Black Sea ◽  
Calc Alkaline ◽  
High K ◽  
Nw Turkey ◽  
Pattern Display

<p>Upper Cretaceous arc-related volcanic and volcanoclastic units overlying the Paleozoic sedimentary rocks of the Istanbul Zone are a key unit related to the opening of the Black Sea as a back-arc basin. They formed as a result of north dipping subduction of the Neo-Tethys Ocean beneath Laurasia. We studied the Upper Cretaceous volcanic units north of Istanbul along several stratigraphic sections, and present new geochemical data from the volcanic rocks in order to understand Cretaceous geodynamic evolution of the İstanbul Zone.</p><p>The Upper Cretaceous  volcanic units north of Istanbul are divided into two formations. At the base there is a fore-arc turbidite succession,the İshaklı Formation, which is made up of volcaniclastic sandstone, shale, marl, tuff, debris flow horizons and epiclastic rocks of Turonian age. The İshaklı Formation is conformably overlain by the volcanoclastics,  tuffs, andesite and basalt lavas and agglomerates- the Riva Formation, which represents the arc/ intra-arc series.</p><p>Geochemically, basalts and basaltic andesites of the Riva Formation are low K calc-alkaline to medium-high K calc-alkaline and with magnesium numbers ranging from 32.6% to 51.5% Primitive mantle normalized spider diagram of trace elements show  enrichment in LILE elements (K, Rb, Sr, Cs, Ba, Th and U) and depletion in HFS elements ( Nb,Ta and Ti) . The high ratio of LILE/ HFS and negative Nb-Ta anomalies indicate that the volcanism evolved in subduction setting. Chondirite-normalized REE pattern display slight negative Eu anomalies and the La/Yb ratios of the samples range between 2,76 and 4,89. Our new geochemical, stratigraphical and the regional geological data suggest that north of Istanbul there was a transition from fore-arc deposition to arc volcanism during the Late Cretaceous opening of the Western Black Sea.  Considering the whole Pontide – Sredna-Gora Upper Cretaceous magmatic arc, it can be stated that calc-alkaline volcanism developed in relation to northward subduction of the Neo-Tethys oceanic lithosphere during the Turonian, and may have passed into high-K calc alkaline and shoshonitic magmatism as a result of the progressive extentional tectonism during the Campanian.</p>

scholarly journals Subduction of a rifted passive continental margin: the Pohorje case of Eastern Alps–constraints from geochronology and geochemistry

2020 ◽  
Vol 113 (1) ◽  
Author(s):  
Ruihong Chang ◽  
Franz Neubauer ◽  
Yongjiang Liu ◽  
Johann Genser ◽  
Wei Jin ◽  
...  
Keyword(s):  
Continental Crust ◽  
Rift Zone ◽  
Eastern Alps ◽  
Granitic Magma ◽  
Geochemical Data ◽  
Icp Ms ◽  
Hp Metamorphism ◽  
Two Samples ◽  
Ultramafic Cumulates ◽  
T Values

Abstract This study presents geochronological and geochemical data from newly dated Permian granitic orthogneisses associated with the Eclogite-Gneiss unit (EGU) from the southernmost part of the Austroalpine nappe stack, exposed within the Pohorje Mountains (Slovenia). LA-ICP-MS zircon U–Pb ages of two samples of the augen-gneisses are 255 ± 2.2 Ma and 260 ± 0.81 Ma, which are interpreted as the age of magmatic crystallization of zircon. In contrast, all round zircons from leucogneisses give Cretaceous ages (89.3 ± 0.7 Ma and 90.8 ± 1.2 Ma), considered as the age of UHP/HP metamorphism. The round zircons overgrew older euhedral zircons of Permian and rare older ages tentatively indicating that these rocks are of latest Permian age, too. Zircon εHf(t) values of the four orthogneiss samples are between − 13.7 and − 1.7 with an initial 176Hf/177Hf ratio ranging from 0.282201 to 0.282562; T DM C is Proterozoic. The augen-gneisses show geochemical features, e.g. high (La/Lu)N ratios and strong negative Eu anomalies, of an evolved granitic magma derived from continental crust. The leucogneisses are more heterogeneously composed and are granitic to granodioritic in composition and associated with eclogites and ultramafic cumulates of oceanic affinity. We argue that the Permian granitic orthogneisses might be derived from partial melting of lower crust in a rift zone. We consider, therefore, that segment of the EGU is part of the distal Late Permian rift zone, which finally led to the opening of the Meliata Ocean during Middle Triassic times. If true, the new data also imply that the Permian stretched continental crust was potentially not much wider than ca. 100 km, was subducted and then rapidly exhumed during early Late Cretaceous times.

Middle−Late Triassic southward-younging granitoids: Tectonic transition from subduction to collision in the Eastern Tianshan−Beishan Orogen, NW China

2022 ◽  
Author(s):  
Qigui Mao ◽  
Songjian Ao ◽  
Brian F. Windley ◽  
Zhiyong Zhang ◽  
Miao Sang ◽  
...  
Keyword(s):  
Late Triassic ◽  
Geochemical Data ◽  
Accretionary Complex ◽  
Calc Alkaline ◽  
Eastern Tianshan ◽  
Nw China ◽  
Tectonic Transition ◽  
High K ◽  
Closure Mechanism ◽  
Oceanic Slab

To constrain the closure mechanism and time of the Paleo-Asian Ocean, we report new geochronological and geochemical data for Triassic granites along a NW−SE corridor from Eastern Tianshan to Beishan, NW China. Seven granites have U-Pb ages that young southwards from 245 Ma to 234 Ma in the Kanguer accretionary complex, to 237 Ma to 234 Ma in the eastern Central Tianshan block, to 229 Ma to 223 Ma in the Liuyuan accretionary complex. Granites in the Kanguer accretionary complex formed by fractional crystallization and are peraluminous, high-K, calc-alkaline, and crust-derived. They have very low MgO (Mg# = 6−9), Cr, and Ni contents, and their high εNd(t) (+3.40) and εHf(t) (+4.49 to +11.91) isotopes indicate that the Dananhu arc crust was juvenile. The Huaniushan pluton in the Liuyuan accretionary complex displays the geochemical signatures of both A1- and A2-type granites (Y/Nb = 0.32−3.39). All other granites in the Central Tianshan block and Liuyuan accretionary complex are aluminous A2-types with high K2O+Na2O, Al, rare earth elements (REE), Zr+Nb+Y, Ga, Fe/Mg, and Y/Nb and remarkable depletions of Eu, Ba, Nb, Ta, Sr, P, and Ti. They have a broad range of MgO (Mg# = 9−59), Cr, and Ni contents, Isr (0.70741−0.70945) values, negative εNd (t) (−2.98 to −1.14), and low to moderate εHf(t) (−1.22 to +7.78), which suggests a mixture of mantle and crustal components. These 245−223 Ma granitoids show marked Nb-Ta depletions that point to a subduction origin. Notable enrichments in Nd-Hf isotopes of Late Triassic granites are likely an indication of collision. Integration with previous data enables us to conclude that the delamination of an oceanic slab and mantle upwelling induced partial melting of thickened arc crust during a tectonic transition from a multiple supra-subduction margin to a collisional setting in the Late Triassic.

Petrogenesis of contrasting magmatic suites in the Abu Kharif area, Northern Eastern Desert, Egypt: implications for Pan-African crustal evolution and tungsten mineralization

2021 ◽  
pp. 1-27
Author(s):  
Nora G Abdel Wanees ◽  
Mohamed M El-Sayed ◽  
Khalil I Khalil ◽  
Hossam A Khamis
Keyword(s):  
Partial Melting ◽  
Fractional Crystallization ◽  
Eastern Desert ◽  
Granitic Magma ◽  
Geochemical Data ◽  
Calc Alkaline ◽  
Quartz Veins ◽  
Pan African ◽  
Granite Suite ◽  
Tungsten Mineralization

Abstract The Abu Kharif area in the Northern Eastern Desert consists of contrasting granitic magma suites: a Cryogenian granodiorite suite (850–635 Ma), an Ediacaran monzogranite suite (635–541 Ma) and a Cambrian alkali riebeckite granite suite (541–485 Ma). Tungsten mineralization occurs within W-bearing quartz veins and a disseminated type confined to the monzogranite. Whole-rock geochemical data classify the granodiorite as a late-orogenic I-type with calc-alkaline affinity, while the monzogranite and alkali riebeckite granite represent respectively a post-orogenic highly fractionated I-type with calc-alkaline affinity and an anorogenic A1-subtype with alkaline affinity. Geochemical modelling indicates that the three intrusions represent separate magmatic pulses where the granodiorite was generated by ∼75 % batch partial melting of an amphibolitic source followed by fractional crystallization of hornblende, biotite, apatite and titanite. The monzogranite was formed by 62 % batch partial melting of the normal ‘non-metasomatized’ Pan-African crust of calc-alkaline granite composition followed by fractional crystallization of plagioclase, biotite, K-feldspar, magnetite, ilmenite, with minor apatite and titanite. The alkali riebeckite granite was generated by 65 % batch partial melting of metasomatized Pan-African granite source followed by fractional crystallization of plagioclase, K-feldspar, amphibole and biotite with minor magnetite, apatite and titanite. In general, the parent magmas of the three intrusions were originally enriched in W, but with different concentrations. This W-enrichment would be caused by magmatic-related hydrothermal volatile-rich fluids and concentrated within the monzogranite.

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