scholarly journals Metamorphic gabbro and basalt in ophiolitic and continental nappes of the Zermatt region (Western Alps)

2021 ◽  
Vol 114 (1) ◽  
Author(s):  
Kurt Bucher ◽  
Ingrid Stober

AbstractThe composition of meta-gabbro and meta-basalt occurring abundant and widespread in all nappes of the nappe stack exposed in the Zermatt region of the Western Alp shows distinct patterns related to the geodynamic origin of metamorphic basic rocks. Eclogitic meta-basalts of the ophiolitic Zermatt-Saas Unit (ZSU) show enriched MORB signatures. The meta-basalts (eclogites) of the continental fragment of the Theodul Glacier Unit (TGU) derive from pre-Alpine metamorphic continental intraplate basalts. Meta-basalts (eclogites) from the continental basement of the Siviez-Mischabel nappe (SMN) derive from MORB thus a genetic relation to the TGU eclogites can be excluded. All basic igneous rocks experienced post-magmatic alteration by fluid-rock interaction ranging from processes at the seafloor, in the shallow crust, during subduction zone hydration, in the exhumation channel and late Alpine regional metamorphisms. The consequences of these alteration processes can be identified at various levels in the rock composition data. It was found that the REE data are little affected by fluid-rock alteration. Some trace elements, notably Cs, Rb, and Ba are typically massively altered relative to igneous compositions in all three groups of meta-basalts. Generally, meta-basalts from the TGU and the SMN preserved the features of the original composition whilst the ZSU meta-volcanic rocks experienced massive alteration. For the ZSU meta-volcanic rocks it is evident that Zr was gained and Y lost during high-pressure fluid-rock interaction indicating a mobile behavior of the two elements during HP-metamorphism in contrast to their behavior in hydrothermal near-surface fluid-rock interaction.

2019 ◽  
Vol 36 (3) ◽  
pp. 357-377
Author(s):  
Jorge Aranda Gómez ◽  
Vsevolod Yutsis ◽  
Edgar Juárez-Arriaga ◽  
Carlos Ortega-Obregón ◽  
Norma González-Cervantes ◽  
...  

The Mercurio structural dome is a poorly exposed and complex structure located in the transitional region between the Coahuila Calcareous Platform and the San Pedro El Gallo sector of the Sierra Madre Oriental, Mexico. It is located in the State of Chihuahua, close to the limits with Coahuila and Durango, Mexico. The dome is a circular structure, ~16 km in diameter, that can be seen in air-photos, satellite images, and shaded relief maps, but that has a subtle topographic expression on the ground. As seen in the field, the most conspicuous topographic features in the area are several hills with the morphology of volcanic necks that rise up to 250 m above the surrounding terrain. The deformation fringe of the dome is a series of cuesta-like low hills, less than 30 m high, where a poorly lithified volcano-sedimentary succession (litharenites, polymictic conglomerates, and ignimbrites) is almost completely masked by desert pavement, which is mainly constituted by well-rounded calcareous clasts derived from the Mesozoic sedimentary marine rocks and by less abundant Paleogene volcanic rocks exposed in the region. Inside the dome the following units are exposed: 1) the pre-volcanic basement in a NW-trending, upright, open anticline developed in limestone of the Aurora Formation, 2) a series of hills where is exposed a succession of epiclastic and volcanic rocks, which are similar, in age and lithology, to some facies of the Ahuichila Formation, and 3) a NW-trending dike, exposed at Cerro Dinamita, which is interpreted as an offshoot of the buried subvolcanic body that created the dome. The deformation fringe around the buried intrusive has a quaquaversal array in the bedding and forms a simple monocline-like structure in the NE part of the dome. A set of SE- and NW-trending plunging folds forms the SE and SW portions of the dome, respectively. The NW part of the fringe is nearly completely masked by volcanic rocks, but there is a ~W plunging syncline in the area. Geophysical data show a broad gravimetric high in the region, and there is a distinct aeromagnetic anomaly inside the dome. The morphological expression of the dome lies just east of a NW-trending lineament of gravity and magnetic anomalies, which may be the buried portion of a normal fault shown in geologic maps of the region northwest of the studied area. Another possible cause is an alignment of buried intrusive bodies suggested by the regional aeromagnetic data, a small diorite outcrop south of Sierra El Diablo, and presence of volcanic necks in the northern portion of Sierra Los Alamos. Available geological and geophysical information was used to model a near-surface, irregular intrusive body with variable magnetic susceptibilites. This variation in susceptibilities is consistent with observed differences in rock composition in the exposed volcanic rocks and with evidence that the structure was formed by a bimodal (andesite-rhyolite) magmatic system where mixing/mingling occurred. As a whole, the set of structures is interpreted as a dome formed by forceful magma injection into a previously folded Paleogene volcano-sedimentary succession. U-Pb zircon ages were used to bracket the age of the deformation pulses registered in the rocks. Litharenites from the deformed volcano-sedimentary succession yielded an Ypresian zircon age of ~51 Ma. A tilted, lithic-rich ignimbrite collected near the top of the exposed volcano-sedimentary succession has mean age of 46.4 +0.8/-1.6 Ma, and the Cerro Dinamita dike has a mean age of 29.37 ± 0.24 Ma. Thus, the youngest pulse of Laramide deformation in the area is younger than ~46 Ma and the re-folding, associated with emplacement of the dome occurred at ~29 Ma. Detrital zircon U-Pb ages from Mercurio sandstones suggest dominant sediment sources from plutonic and/or volcanic rocks exposed along western Mexico. Likely subordinate sources are Mesozoic sedimentary rocks in northern and central Mexico. Distribution of detrital zircon U-Pb ages in the studied samples is similar to that documented in sandstones of the Difunta Group at the Parras and La Popa basins, except that older grains (>1.0 Ga), documented in the clastic rocks of these basins, are scarce in the sandstones of the Mercurio area.


Minerals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 411
Author(s):  
Paola Tartarotti ◽  
Silvana Martin ◽  
Andrea Festa ◽  
Gianni Balestro

Ophiolites of the Alpine belt derive from the closure of the Mesozoic Tethys Ocean that was interposed between the palaeo-Europe and palaeo-Adria continental plates. The Alpine orogeny has intensely reworked the oceanic rocks into metaophiolites with various metamorphic imprints. In the Western Alps, metaophiolites and continental-derived units are distributed within two paired bands: An inner band where Alpine subduction-related high-pressure (HP) metamorphism is preserved, and an outer band where blueschist to greenschist facies recrystallisation due to the decompression path prevails. The metaophiolites of the inner band are hugely important not just because they provide records of the prograde tectonic and metamorphic evolution of the Western Alps, but also because they retain the signature of the intra-oceanic tectono-sedimentary evolution. Lithostratigraphic and petrographic criteria applied to metasediments associated with HP metaophiolites reveal the occurrence of distinct tectono-stratigraphic successions including quartzites with marbles, chaotic rock units, and layered calc schists. These successions, although sliced, deformed, and superposed in complex ways during the orogenic stage, preserve remnants of their primary depositional setting constraining the pre-orogenic evolution of the Jurassic Tethys Ocean.


2021 ◽  
Vol 176 (7) ◽  
Author(s):  
Thomas Bovay ◽  
Daniela Rubatto ◽  
Pierre Lanari

AbstractDehydration reactions in the subducting slab liberate fluids causing major changes in rock density, volume and permeability. Although it is well known that the fluids can migrate and interact with the surrounding rocks, fluid pathways remain challenging to track and the consequences of fluid-rock interaction processes are often overlooked. In this study, we investigate pervasive fluid-rock interaction in a sequence of schists and mafic felses exposed in the Theodul Glacier Unit (TGU), Western Alps. This unit is embedded within metaophiolites of the Zermatt-Saas Zone and reached eclogite-facies conditions during Alpine convergence. Chemical mapping and in situ oxygen isotope analyses of garnet from the schists reveal a sharp chemical zoning between a xenomorphic core and a euhedral rim, associated to a drop of ~ 8‰ in δ18O. Thermodynamic and δ18O models show that the large amount of low δ18O H2O required to change the reactive bulk δ18O composition cannot be produced by dehydration of the mafic fels from the TGU only, and requires a large contribution of the surrounding serpentinites. The calculated time-integrated fluid flux across the TGU rocks is 1.1 × 105 cm3/cm2, which is above the open-system behaviour threshold and argues for pervasive fluid flow at kilometre-scale under high-pressure conditions. The transient rock volume variations caused by lawsonite breakdown is identified as a possible trigger for the pervasive fluid influx. The calculated schist permeability at eclogite-facies conditions (~ 2 × 10–20 m2) is comparable to the permeability determined experimentally for blueschist and serpentinites.


2018 ◽  
Vol 37 (2) ◽  
pp. 607-625 ◽  
Author(s):  
Haitao Sun ◽  
Dakang Zhong ◽  
Weijia Zhan

To explain the strong spatial heterogeneity of volcanic reservoirs porosity in the Songliao Basin and provide new ideas for predicting good volcanic reservoirs in other similar basins, the relationship between the pore evolution process and lithology of volcanic reservoirs has been described in this article. With the description and interpretation of core, thin section, scanning electron microscope, and the results of mercury injection experiment, this article clarifies the lithology, pore types, and pore structure features of the volcanic reservoirs in the Songliao Basin. The rocks of volcanic reservoirs in study area contain pyroclastic rock and volcanic lavas. The most common lithologies are rhyolite, volcanic breccia, and volcanic tuff. The pore size, morphology, and structure vary greatly between these three lithologies, the reason of which we think is the different volcanic eruption process as well as rock composition and its structure. The digenetic evolution of rhyolite includes gas dissipation of magmatic condensation; vesicles fulfilling by hydrothermal fluid; kaolinization and sericitization of feldspar phenocrysts; carbonation, devitrification, and recrystallization of felsic matrix; and finally, the dissolution of feldspar phenocrysts and felsic matrix. As for volcanic breccia, it usually go through the compaction, quartz and calcite filling the original pores between volcanic breccias, and dissolution of mineral debris together with tuff matrix. Similar with the rhyolite, volcanic tuff also undergoes the carbonation and kaolinization of felsic matrix, the dissolution of feldspar and felsic matrix, and compaction. Due to these comprehensive processes, a comprehensive analysis of volcanic rock lithology, which can indicate lithology distribution vertically and horizontally, is very necessary during volcanic reservoirs evaluation and prediction. These detailed analyses will help explorers to find potential reservoirs by distinguishing the diagenetic evolution and pore characteristic of volcanic reservoirs.


2017 ◽  
Vol 43 (5) ◽  
pp. 2667
Author(s):  
E. Mposkos ◽  
I. Baziotis

The carbonate-bearing metaperidotite from Sidironero Complex, north of the Xanthi town is composed primarily of olivine and orthopyroxene megacrysts and of Ti-clinohumite, tremolite, chlorite, dolomite, magnesite, talc, antigorite and spinel group minerals. The metaperidotite underwent a prograde HP metamorphism probably isofacial with the neighboring amphibolitized eclogites. Calculated P-T and P(T)-XCO2 phase diagram sections (pseudosections) for the bulk rock composition showed that XCO2 in the fluid phase was extremely low (≤0.008) at the first stages of the metamorphism and increased up to 0.022 at the peak P-T conditions ~1.5 GPa and 690 0C. The prograde metamorphism probably started from a hydrated and carbonated assemblage including talc+chlorite+magnesite+dolomite and proceeded with tremolite and antigorite formation before olivine growth, and orthopyroxene formation after olivine growth (Ol-1). Matrix dolomite, breakdown of chlorite (Chl-1) to Cr spinel+olivine and of Ti-clinohumite to olivine+Mg-ilmenite occurred during decompression. The P-T path is constrained by the absence of clinopyroxene in the metaperidotite.


2021 ◽  
Author(s):  
◽  
João Ricardo Marques Conde da Silva

<p>One of the main issues associated with the exploitation of geothermal energy is the durability of the cement that is used downhole to cement the steel casing to the formation. Cement durability can have a major impact on the lifetime of geothermal wells, which do not usually last as long as desirable. The cement formulations used in the construction of geothermal wells are designed to provide mechanical support to the metallic well casings and protect them against the downhole harsh environment, which often leads to corrosion. This research is focused on the way that these formulations interact with the surrounding rock formation in geothermal environments, and aims to understand whether these are likely to affect the cement durability and, consequently, the geothermal well lifetime. The experimental work in this thesis consists of examining the changes in the interfacial transition zone (ITZ) that forms between geothermal cements and the volcanic rocks, after hydrothermal treatment. Holes were drilled in blocks of volcanic rocks and cement slurries with distinct formulations were poured into the cavities. The assemblages were autoclaved under typical geothermal conditions. The main variables under study were the cement formulation, the temperature of curing (150°C and 290°C), the presence of drilling mud, CO₂ exposure and the type of rock. The results show that with all the Portland cement based systems a series of chemical reactions occur at the interface between the cement and the rock, the ITZ, where migration of Ca²⁺ and OH⁻ ions occurs from the cement into the rock pores. These reactions are ongoing, which occur faster during the first days/few weeks of curing, mostly driven by physical process of cement movement into the rock, followed by a slower second stage, controlled mostly by chemical driving forces. This work highlights the interdependence between the chemical and physical interactions between geothermal cements and volcanic rocks which are complex. Variables such as temperature and time of curing and silica addition affect the cement phases that form, while the amount of amorphous silica and rock permeability dictate the extent of rock interaction. The presence of carbon dioxide influences the extent of rock/cement interaction and this can be controlled by the rock permeability and cement formulation. Consequently, most of the above mentioned variables were found to have an impact on the geothermal cement durability, which depends on the way these factors are combined.</p>


Author(s):  
A.I. Malinovsky ◽  
◽  
V.V. Golozubov ◽  

This paper studies the original results of the material composition analysis of the Early Silurian terrigenous deposits of the Kordonka formation of the Paleozoic – Early Mesozoic Laoeling-Grodekovo terrane of the South Primorye. The research is aimed at reconstructing paleogeodynamic setting of the deposition of sediments of the formation, and determining the type and mother rock composition of the feed sources based on the complex genetic interpretation of the material composition of rocks. It was established that mineralogically and geochemically formation of the rocks correspond to the typical graywackes and represent petrogenic or “first cycle” rocks formed mainly through the source rock failure. They are characterized by a low maturity, low lithodynamic recycling rate of mother rocks and their rapid burial. The interpretation of the results of the complex study of the material composition of the rocks was carried out on the basis of its comparison with the compositions of ancient rocks and modern sediments formed in the well-known geodynamic settings. The obtained data indicate that deposits of the Kordonka formation accumulated in a sedimentary basin connected with an oceanic island arc. Being built by basic and intermediate volcanic rocks as well as by igneous and sedimentary rocks that constituted its base, this island arc was the source area that supplied clastic material to the aforementioned sedimentary basin.


1982 ◽  
Vol 119 (1) ◽  
pp. 77-85 ◽  
Author(s):  
G. Pe-Piper ◽  
A. G. Panagos ◽  
D. J. W. Piper ◽  
C. N. Kotopouli

SummaryThick subaerial volcanic sequences of probable mid Triassic age rest unconformably on Permo-Carboniferous limestones in the ‘Phyllite Series’ within the Gavrovo-Tripolitsa zone of the external Hellenide nappes. The volcanic rocks are varied in character. Pyroclastic rocks (often reddened) predominate, but minor basalt or andesite and rhyolitic hypabyssal intrusions and flows are also found. The rocks have experienced low-grade metamorphism and the only relict primary minerals are pyroxene and rare plagioclase in basic rocks and potash feldspar in acid rocks. The most important metamorphic phases are albite, chlorite, potassium mica, epidote, hematite, quartz and pumpellyite. Twenty-seven whole-rock major-element analyses suggest that there has been some exchange of Na2O and K2O for CaO during metamorphism, but that other elements have been relatively stable. A genetic interpretation of the rocks is attempted using published geochemical discriminator diagrams. The basic rocks are tholeiitic in major element chemistry and pyroxene composition. Trace element (Hf, Ta, Th, Ce, Yb) distribution suggests magma generation at a destructive plate margin.


1981 ◽  
Vol 44 (336) ◽  
pp. 417-423 ◽  
Author(s):  
M. Cathelineau ◽  
J. Leroy

AbstractHydrothermal uranium veins, associated with the Hercynian leucogranites show important variations in their mineralogical, chemical and structural features in relation to the host rock lithology. These are described with particular reference to the Chardon deposit, Vendée where the veins cut granite, basic lithologies, and shales. The following features are described: 1Changes in the thickness of veins near to contact zones, particularly those between granites and basic lithologies, lamprophyres, and shales.2Changes in the gangue mineral assemblage with the preferential development of carbonate in veins cutting basic lithologies, and of silica in veins which cut granite.3Paragenetic zoning in the veins in passing from granites to their metamorphic aureoles.Comparisons between deposits of Vendée, Limousin, and Erzgebirge allow the following generalizations to be made: 1Open faults and subsequent mineralization are concentrated at boundaries between competent and more plastic lithologies.2Mineralizing fluids cause wall-rock alteration characterized by the removal of Si from granite and of Ca, Mg, Fe from metamorphic and basic rocks.3The chemical and structural characteristics of wallrocks are important controls on the mineralization but in acid lithologies the main controls on the pitchblende vein formation are the structural characteristics of the wallrock.


Author(s):  
Hugo W. van Schrojenstein Lantman ◽  
Marco Scambelluri ◽  
Mattia Gilio ◽  
David Wallis ◽  
Matteo Alvaro

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