Modern Lithium and Lithium-Ion Rechargeable Batteries

Author(s):  
Tatiana Kulova ◽  
Alexander Mironenko ◽  
Alexander Rudy ◽  
Alexander Skundin
Author(s):  
Yuhan Wu ◽  
Chenglin Zhang ◽  
Huaping Zhao ◽  
Yong Lei

In next-generation rechargeable batteries, sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs) have been considered as attractive alternatives to lithium-ion batteries due to their cost competitiveness. Anodes with complicated electrochemical mechanisms...


Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1091
Author(s):  
Eva Gerold ◽  
Stefan Luidold ◽  
Helmut Antrekowitsch

The consumption of lithium has increased dramatically in recent years. This can be primarily attributed to its use in lithium-ion batteries for the operation of hybrid and electric vehicles. Due to its specific properties, lithium will also continue to be an indispensable key component for rechargeable batteries in the next decades. An average lithium-ion battery contains 5–7% of lithium. These values indicate that used rechargeable batteries are a high-quality raw material for lithium recovery. Currently, the feasibility and reasonability of the hydrometallurgical recycling of lithium from spent lithium-ion batteries is still a field of research. This work is intended to compare the classic method of the precipitation of lithium from synthetic and real pregnant leaching liquors gained from spent lithium-ion batteries with sodium carbonate (state of the art) with alternative precipitation agents such as sodium phosphate and potassium phosphate. Furthermore, the correlation of the obtained product to the used type of phosphate is comprised. In addition, the influence of the process temperature (room temperature to boiling point), as well as the stoichiometric factor of the precipitant, is investigated in order to finally enable a statement about an efficient process, its parameter and the main dependencies.


1998 ◽  
Vol 21 (2) ◽  
pp. 123-146 ◽  
Author(s):  
G. Campet ◽  
A. Deshayes ◽  
J. C. Frison ◽  
N. Treuil ◽  
J. Portier

We have illustrated the important role played by the nanoscale materials in three-up-to-date energy topics.1/The solar-to-electrical energy conversion in photoelectrochemical cells: we have shown two favorable situations for which photoelectrochemical cells using porous nanocrystalline films have high efficiencies.2/The electrical energy storage in rechargeable rocking-chair lithium batteries: these systems, which use nanocrystalline materials, might be the next generation of rechargeable batteries showing higher capacity, cyclability, and safety than conventional lithium ion batteries.3/The energy saving with efficient electrochromic windows using nanocrystalline materials.


Author(s):  
Sheng Shen ◽  
M. K. Sadoughi ◽  
Xiangyi Chen ◽  
Mingyi Hong ◽  
Chao Hu

Over the past two decades, safety and reliability of lithium-ion (Li-ion) rechargeable batteries have been receiving a considerable amount of attention from both industry and academia. To guarantee safe and reliable operation of a Li-ion battery pack and build failure resilience in the pack, battery management systems (BMSs) should possess the capability to monitor, in real time, the state of health (SOH) of the individual cells in the pack. This paper presents a deep learning method, named deep convolutional neural networks, for cell-level SOH assessment based on the capacity, voltage, and current measurements during a charge cycle. The unique features of deep convolutional neural networks include the local connectivity and shared weights, which enable the model to estimate battery capacity accurately using the measurements during charge. To our knowledge, this is the first attempt to apply deep learning to online SOH assessment of Li-ion battery. 10-year daily cycling data from implantable Li-ion cells are used to verify the performance of the proposed method. Compared with traditional machine learning methods such as relevance vector machine and shallow neural networks, the proposed method is demonstrated to produce higher accuracy and robustness in capacity estimation.


2013 ◽  
Vol 27 (22) ◽  
pp. 1350156 ◽  
Author(s):  
R. J. ZHU ◽  
Y. REN ◽  
L. Q. GENG ◽  
T. CHEN ◽  
L. X. LI ◽  
...  

Amorphous V 2 O 5, LiPON and Li 2 Mn 2 O 4 thin films were fabricated by RF magnetron sputtering methods and the morphology of thin films were characterized by scanning electron microscopy. Then with these three materials deposited as the anode, solid electrolyte, cathode, and vanadium as current collector, a rocking-chair type of all-solid-state thin-film-type Lithium-ion rechargeable battery was prepared by using the same sputtering parameters on stainless steel substrates. Electrochemical studies show that the thin film battery has a good charge–discharge characteristic in the voltage range of 0.3–3.5 V, and after 30 cycles the cell performance turned to become stabilized with the charge capacity of 9 μAh/cm2, and capacity loss of single-cycle of about 0.2%. At the same time, due to electronic conductivity of the electrolyte film, self-discharge may exist, resulting in approximately 96.6% Coulombic efficiency.


2014 ◽  
Vol 596 ◽  
pp. 86-91 ◽  
Author(s):  
Jinbo Wu ◽  
Zhengwang Zhu ◽  
Hongwei Zhang ◽  
Huameng Fu ◽  
Hong Li ◽  
...  

Materials ◽  
2022 ◽  
Vol 15 (1) ◽  
pp. 322
Author(s):  
Ryo Shomura ◽  
Ryota Tamate ◽  
Shoichi Matsuda

Lithium metal anode is regarded as the ultimate negative electrode material due to its high theoretical capacity and low electrochemical potential. However, the significantly high reactivity of Li metal limits the practical application of Li metal batteries. To improve the stability of the interface between Li metal and an electrolyte, a facile and scalable blade coating method was used to cover the commercial polyethylene membrane separator with an inorganic/organic composite solid electrolyte layer containing lithium-ion-conducting ceramic fillers. The coated separator suppressed the interfacial resistance between the Li metal and the electrolyte and consequently prolonged the cycling stability of deposition/dissolution processes in Li/Li symmetric cells. Furthermore, the effect of the coating layer on the discharge/charge cycling performance of lithium-oxygen batteries was investigated.


2019 ◽  
Vol 12 (01) ◽  
pp. 1850104 ◽  
Author(s):  
Jinggao Wu ◽  
Qi Lai ◽  
Canyu Zhong

MoO3@CoMoO4 hybrid is fabricated by a facile one-step hydrothermal method and is used as anode for lithium-ion battery (LIB). Compared to pristine MoO3, galvanostatic charge–discharge tests show that the hybrid electrode delivered a remarkable rate capability of 586.69[Formula: see text]mAh[Formula: see text]g[Formula: see text] at the high current density of 1000[Formula: see text]mA[Formula: see text]g[Formula: see text] and a greatly enhanced cyclic capacity of 887.36[Formula: see text]mA[Formula: see text]h[Formula: see text]g[Formula: see text] after 140 cycles at the current density of 200[Formula: see text]mA[Formula: see text]g[Formula: see text] (with capacity retention, 85.3%). The superior electrochemical properties could be ascribed to the synergistic effect of MoO3 and CoO nanostructure that results in the lower charge transfer resistance and the higher Li[Formula: see text] diffusion coefficient, thus leading to high performance Li[Formula: see text] reversibility storage.


Author(s):  
Haoyu Liu ◽  
Zhen Xu ◽  
Zhenyu Guo ◽  
Jingyu Feng ◽  
Haoran Li ◽  
...  

Waste management is one of the biggest environmental challenges worldwide. Biomass-derived hard carbons, which can be applied to rechargeable batteries, can contribute to mitigating environmental changes by enabling the use of renewable energy. This study has carried out a comparative environmental assessment of sustainable hard carbons, produced from System A (hydrothermal carbonization (HTC) followed by pyrolysis) and System B (direct pyrolysis) with different carbon yields, as anodes in sodium-ion batteries (SIBs). We have also analysed different scenarios to save energy in our processes and compared the biomass-derived hard carbons with commercial graphite used in lithium-ion batteries. The life cycle assessment results show that the two systems display significant savings in terms of their global warming potential impact (A1: −30%; B1: −21%), followed by human toxicity potential, photochemical oxidants creation potential, acidification potential and eutrophication potential (both over −90%). Possessing the best electrochemical performance for SIBs among our prepared hard carbons, the HTC-based method is more stable in both environmental and electrochemical aspects than the direct pyrolysis method. Such results help a comprehensive understanding of sustainable hard carbons used in SIBs and show an environmental potential to the practical technologies. This article is part of the theme issue ‘Bio-derived and bioinspired sustainable advanced materials for emerging technologies (part 2)’.


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