scholarly journals Maturity of dispersed organic matter in bituminous formations of the Ionian Zone (Epirus region, NW Greece)

2017 ◽  
Vol 47 (2) ◽  
pp. 880
Author(s):  
D. Rallakis ◽  
G. Siavalas ◽  
G. Oskay ◽  
D. Tsimiklis ◽  
K. Christanis

The main objective of this paper is to study by means of Organic Petrology techniques, the maturity of the dispersed organic matter from certain sedimentary formations of the Ionian Zone, such as the Bituminous Shale, the Upper Siliceous Vigla Formation and the Bituminous Sandstone. The samples were collected from outcropping sites located in the region of Epirus. Initially they were treated with acids (HCl-HF) to remove most of the carbonate and silicate minerals. Then a ZnCl2 solution was used to concentrate the organic-rich fraction. Total Organic Carbon (TOC) content was determined applying dichromate oxidation. Polished blocks were prepared from the concentrated organic matter mounted in epoxy resin and examined under the coal-petrography microscope. Emphasis was given to maceral identification and vitrinite reflectance (R) measurements, which provide information regarding the quality and the maturity of the organic matter respectively, with implications for the petroleum generation potential regardless the level of alteration. The TOC and Rr values (4.74% and 0.68%, respectively) confirm to the oil potential of the Lower Jurassic Posidonia Shale. Nevertheless, it is suggested that detailed and higher resolution sampling focusing on the Lower Posidonia Shale, as well as organic petrography analyses coupled with Rock-Eval pyrolysis should be carried out in order to accurately determine its quality as petroleum source rocks.

1994 ◽  
Vol 34 (1) ◽  
pp. 692 ◽  
Author(s):  
Roger E. Summons ◽  
Dennis Taylor ◽  
Christopher J. Boreham

Maturation parameters based on aromatic hydrocarbons, and particularly the methyl-phenanthrene index (MPI-1), are powerful indicators which can be used to define the oil window in Proterozoic and Early Palaeozoic petroleum source rocks and to compare maturities and detect migration in very old oils . The conventional vitrinite reflectance yardstick for maturity is not readily translated to these ancient sediments because they predate the evolution of the land plant precursors to vitrinite. While whole-rock geochemical tools such as Rock-Eval and TOC are useful for evaluation of petroleum potential, they can be imprecise when applied to maturity assessments.In this study, we carried out a range of detailed geochemical analyses on McArthur Basin boreholes penetrating the Roper Group source rocks. We determined the depth profiles for hydrocarbon generation based on Rock-Eval analysis of whole-rock, solvent-extracted rock, kerogen elemental H/C ratio and pyrolysis GC. Although we found that Hydrogen Index (HI) and the Tmax parameter were strongly correlated with other maturation indicators, they were not sufficiently sensitive nor were they universally applicable. Maturation measurements based on saturated biomarkers were not useful either because of the low abundance of these compounds in most Roper Group bitumens and oils.


2008 ◽  
Vol 16 ◽  
pp. 1-66 ◽  
Author(s):  
Henrik I. Petersen ◽  
Lars H. Nielsen ◽  
Jørgen A. Bojesen-Koefoed ◽  
Anders Mathiesen ◽  
Lars Kristensen ◽  
...  

The quality, thermal maturity and distribution of potential source rocks within the Palaeozoic–Mesozoic succession of the Danish part of the Norwegian-Danish Basin have been evaluated on the basis of screening data from over 4000 samples from the pre-Upper Cretaceous succession in 33 wells. The Lower Palaeozoic in the basin is overmature and the Upper Cretaceous – Cenozoic strata have no petroleum generation potential, but the Toarcian marine shales of the Lower Jurassic Fjerritslev Formation (F-III, F-IV members) and the uppermost Jurassic – lowermost Cretaceous shales of the Frederikshavn Formation may qualify as potential source rocks in parts of the basin. Neither of these potential source rocks has a basinwide distribution; the present occurrence of the Lower Jurassic shales was primarily determined by regional early Middle Jurassic uplift and erosion. The generation potential of these source rocks is highly variable. The F-III and F-IV members show significant lateral changes in generation capacity, the best-developed source rocks occurring in the basin centre. The combined F-III and F-IV members in the Haldager-1, Kvols-1 and Rønde-1 wells contain 'net source-rock' thicknesses (cumulative thickness of intervals with Hydrogen Index (HI)> 200 mg HC/g TOC) of 40 m, 83 m, and 92 m, respectively, displaying average HI values of 294, 369 and 404 mg HC/g TOC. The Mors-1 well contains 123 m of 'net source rock' with an average HI of 221 mg HC/g TOC. Parts of the Frederikshavn Formation possess a petroleum generation potential in the Hyllebjerg-1, Skagen-2, Voldum-1 and Terne-1 wells, the latter well containing a c. 160 m thick highly oil-prone interval with an average HI of 478 mg HC/g TOC and maximum HI values> 500 mg HC/g TOC.The source-rock evaluation suggests that a Mesozoic petroleum system is the most likely in the study area. Two primary plays are possible: (1) the Upper Triassic – lowermost Jurassic Gassum play, and (2) the Middle Jurassic Haldager Sand play. Potential trap structures are widely distributed in the basin, most commonly associated with the flanks of salt diapirs. The plays rely on charge from the Lower Jurassic (Toarcian) or uppermost Jurassic – lowermost Cretaceous shales. Both plays have been tested with negative results, however, and failure is typically attributed to insufficient maturation (burial depth) of the source rocks. This maturation question has been investigated by analysis of vitrinite reflectance data from the study area, corrected for post-Early Cretaceous uplift. A likely depth to the top of the oil window (vitrinite reflectance = 0.6%Ro) is c. 3050–3100 m based on regional coalification curves. The Frederikshavn Formation had not been buried to this depth prior to post-Early Cretaceous exhumation, and the potential source rocks of the formation are thermally immature in terms of hydrocarbon generation. The potential source rocks of the Fjerritslev Formation are generally immature to very early mature. Mature source rocks in the Danish part of the Norwegian–Danish Basin are thus dependent on local, deeper burial to reach the required thermal maturity for oil generation. Such potential kitchen areas with mature Fjerritslev Formation source rocks may occur in the central part of the study area (central–northern Jylland), and a few places offshore. These inferred petroleum kitchens are areally restricted, mainly associated with salt structures and local grabens (such as the Fjerritslev Trough and the Himmerland Graben).


Geosciences ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 381
Author(s):  
Hunter Green ◽  
Branimir Šegvić ◽  
Giovanni Zanoni ◽  
Silvia Omodeo-Salé ◽  
Thierry Adatte

The use of mineral diagenetic indices and organic matter maturity is useful for reconstructing the evolution of sedimentary basins and critical assessments for potential source rocks for petroleum exploration. In this study, the relationship of clay mineral diagenesis and organic matter thermal indices (Rock-Eval Tmax) and calculated vitrinite reflectance (%Ro) were used to constrain the maximum burial depths and temperatures of three distinct intervals within the northern Permian Basin, USA. X-ray diffraction of clay fractions (<2 µm) consists of illite, chlorite, and illite-smectite intermediates. Primary clay mineral diagenetic changes progressively increase in ordering from R0 to R1 I-S between 2359.5 and 2485.9 m and the appearance of chlorite at 2338.7 m. Rock-Eval pyrolysis data show 0 to 14 wt% TOC, HI values of 40 to 520 mgHC/g TOC, and S2 values of 0 to 62 mg HC/g, with primarily type II kerogen with calculated %Ro within the early to peak oil maturation window. Evaluation of the potential for oil generation is relatively good throughout the Tonya 401 and JP Chilton wells. Organic maturation indices (Tmax, %Ro) and peak burial temperatures correlate well with clay mineral diagenesis (R0–R1 I-S), indicating that maximum burial depths and temperatures were between 2.5 and 4 km and <100 °C and 140 °C, respectively. Additionally, the use of clay mineral-derived temperatures provides insight into discrepancies between several calculated %Ro equations and thus should be further investigated for use in the Permian Basin. Accordingly, these findings show that clay mineral diagenesis, combined with other paleothermal proxies, can considerably improve the understanding of the complex burial history of the Permian Basin in the context of the evolution of the southern margin of Laurentia.


Author(s):  
Koffi Eugene Kouadio ◽  
Selegha Abrakasa ◽  
Sunday S. Ikiensikimama ◽  
Takyi Botwe

The geochemical analysis was performed on twelve (12) core samples from 6 wells of different formations (Akata, Agbada, and Akata/Agbada) of the onshore  Niger Delta Basin. The study was essentially based on the results of the Rock-Eval 6 Pyrolysis to evaluate organic matter abundance, quality, and thermal maturity. The Total Organic Carbon (TOC) varies between 0.6 and 3.06 wt% and the Hydrogen Index (IH) of the studied samples ranges from 38 to 202 mgHC/g TOC, indicating predominantly Type III (gas prone) and mixed type II/III (gas and oil-prone) kerogen. This suggests terrigenous and a mixture of marine and terrigenous organic matter deposited in a paralic marine setting. The organic matter is immature to early mature according to the thermal maturity parameter (414<Tmax<432). The well Isan 9 from Agbada (6760 ft) and Agbada/Akata (8680 ft) shows petroleum generation potential of fair (2,5 < S2 < 5 mg HC/g rock) to good (5 < S2 < 10 mgHC/g rock) and poor for the  other wells. The maturation of the kerogen indicates a very early stage of maturation (Tmax= 432°C). The results indicate that the shales from Agbada and the transition zone between the upper and lower parts of the Akata Shales are more shaly and perhaps the more mature part of the Agbada formation can be the potential source rocks of Niger Delta Basin.


Author(s):  
Sebastian Grohmann ◽  
Susanne W. Fietz ◽  
Ralf Littke ◽  
Samer Bou Daher ◽  
Maria Fernanda Romero-Sarmiento ◽  
...  

Several significant hydrocarbon accumulations were discovered over the past decade in the Levant Basin, Eastern Mediterranean Sea. Onshore studies have investigated potential source rock intervals to the east and south of the Levant Basin, whereas its offshore western margin is still relatively underexplored. Only a few cores were recovered from four boreholes offshore southern Cyprus by the Ocean Drilling Program (ODP) during the drilling campaign Leg 160 in 1995. These wells transect the Eratosthenes Seamount, a drowned bathymetric high, and recovered a thick sequence of both pre- and post-Messinian sedimentary rocks, containing mainly marine marls and shales. In this study, 122 core samples of Late Cretaceous to Messinian age were analyzed in order to identify organic-matter-rich intervals and to determine their depositional environment as well as their source rock potential and thermal maturity. Both Total Organic and Inorganic Carbon (TOC, TIC) analyses as well as Rock-Eval pyrolysis were firstly performed for the complete set of samples whereas Total Sulfur (TS) analysis was only carried out on samples containing significant amount of organic matter (>0.3 wt.% TOC). Based on the Rock-Eval results, eight samples were selected for organic petrographic investigations and twelve samples for analysis of major aliphatic hydrocarbon compounds. The organic content is highly variable in the analyzed samples (0–9.3 wt.%). TS/TOC as well as several biomarker ratios (e.g. Pr/Ph < 2) indicate a deposition under dysoxic conditions for the organic matter-rich sections, which were probably reached during sporadically active upwelling periods. Results prove potential oil prone Type II kerogen source rock intervals of fair to very good quality being present in Turonian to Coniacian (average: TOC = 0.93 wt.%, HI = 319 mg HC/g TOC) and in Bartonian to Priabonian (average: TOC = 4.8 wt.%, HI = 469 mg HC/g TOC) intervals. A precise determination of the actual source rock thickness is prevented by low core recovery rates for the respective intervals. All analyzed samples are immature to early mature. However, the presence of deeper buried, thermally mature source rocks and hydrocarbon migration is indicated by the observation of solid bitumen impregnation in one Upper Cretaceous and in one Lower Eocene sample.


2003 ◽  
Vol 43 (1) ◽  
pp. 117 ◽  
Author(s):  
C.J. Boreham ◽  
J.E. Blevin ◽  
A.P. Radlinski ◽  
K.R. Trigg

Only a few published geochemical studies have demonstrated that coals have sourced significant volumes of oil, while none have clearly implicated coals in the Australian context. As part of a broader collaborative project with Mineral Resources Tasmania on the petroleum prospectivity of the Bass Basin, this geochemical study has yielded strong evidence that Paleocene–Eocene coals have sourced the oil and gas in the Yolla, Pelican and Cormorant accumulations in the Bass Basin.Potential oil-prone source rocks in the Bass Basin have Hydrogen Indices (HIs) greater than 300 mg HC/g TOC. The coals within the Early–Middle Eocene succession commonly have HIs up to 500 mg HC/g TOC, and are associated with disseminated organic matter in claystones that are more gas-prone with HIs generally less than 300 mg HC/g TOC. Maturity of the coals is sufficient for oil and gas generation, with vitrinite reflectance (VR) up to 1.8 % at the base of Pelican–5. Igneous intrusions, mainly within Paleocene, Oligocene and Miocene sediments, produced locally elevated maturity levels with VR up to 5%.The key events in the process of petroleum generation and migration from the effective coaly source rocks in the Bass Basin are:the onset of oil generation at a VR of 0.65% (e.g. 2,450 m in Pelican–5);the onset of oil expulsion (primary migration) at a VR of 0.75% (e.g. 2,700–3,200 m in the Bass Basin; 2,850 m in Pelican–5);the main oil window between VR of 0.75 and 0.95% (e.g. 2,850–3,300 m in Pelican–5); and;the main gas window at VR >1.2% (e.g. >3,650 m in Pelican–5).Oils in the Bass Basin form a single oil population, although biodegradation of the Cormorant oil has resulted in its statistical placement in a separate oil family from that of the Pelican and Yolla crudes. Oil-to-source correlations show that the Paleocene–Early Eocene coals are effective source rocks in the Bass Basin, in contrast to previous work, which favoured disseminated organic matter in claystone as the sole potential source kerogen. This result represents the first demonstrated case of significant oil from coal in the Australian context. Natural gases at White Ibis–1 and Yolla–2 are associated with the liquid hydrocarbons in their respective fields, although the former gas is generated from a more mature source rock.The application of the methodologies used in this study to other Australian sedimentary basins where commercial oil is thought to be sourced from coaly kerogens (e.g. Bowen, Cooper and Gippsland basins) may further implicate coal as an effective source rock for oil.


1982 ◽  
Vol 22 (1) ◽  
pp. 5
Author(s):  
A. R. Martin ◽  
J. D. Saxby

The geology and exploration history of the Triassic-Cretaceous Clarence-Moreton Basin are reviewed. Consideration of new geochemical data ('Rock-Eval', vitrinite reflectance, gas chromatography of extracts, organic carbon and elemental analysis of coals and kerogens) gives further insights into the hydrocarbon potential of the basin. Although organic-rich rocks are relatively abundant, most source rocks that have achieved the levels of maturation necessary for hydrocarbon generation are gas-prone. The exinite-rich oil-prone Walloon Coal Measures are in most parts relatively immature. Some restraints on migration pathways are evident and igneous and tectonic events may have disturbed potentially well-sealed traps. Further exploration is warranted, even though the basin appears gas-prone and the overall prospects for hydrocarbons are only fair. The most promising areas seem to be west of Toowoomba for oil and the Clarence Syncline for gas.


1981 ◽  
Vol 21 (1) ◽  
pp. 187
Author(s):  
M. Smyth ◽  
J. D. Saxby

Sediments from the Permian Pedirka Basin and the overlying Triassic Simpson Desert Basin have been studied to determine their potentials as source rocks for hydrocarbons. Principal techniques used are reflected light microscopy, including vitrinite reflectance, solvent extraction and kerogen isolation.Dispersed organic matter (DOM) occurs through the Permian and Triassic sequences, and is most abundant near the top of the Triassic, constituting up to 2 per cent of the sediments by volume. Of this DOM, 30 to 50 per cent is vitrinite plus exinite. The Permian and Triassic coals have vitrinite reflectivities of up to 0.9 per cent. The geothermal gradient in the vicinity of Poolowanna 1 is probably sufficient to cause the cutinite within the Triassic sediments to break down into petroleum hydrocarbons. In the case of the Poolowanna Jurassic oil show, migration up faults and accumulation in high-temperature reservoirs have been accompanied by the loss of volatile hydrocarbons.


2020 ◽  
Vol 10 (8) ◽  
pp. 3191-3206
Author(s):  
Olusola J. Ojo ◽  
Ayoola Y. Jimoh ◽  
Juliet C. Umelo ◽  
Samuel O. Akande

Abstract The Patti Formation which consists of sandstone and shale offers the best potential source beds in the Bida Basin. This inland basin is one of the basins currently being tested for hydrocarbon prospectivity in Nigeria. Fresh samples of shale from Agbaja borehole, Ahoko quarry and Geheku road cut were analysed using organic geochemical and palynological techniques to unravel their age, paleoecology, palynofacies and source bed hydrocarbon potential. Palynological data suggest Maastrichtian age for the sediments based on the abundance of microfloral assemblage; Retidiporites magdalenensis, Echitriporites trianguliformis and Buttinia andreevi. Dinocysts belonging to the Spiniferites, Deflandrea and Dinogymnium genera from some of the analysed intervals are indicative of freshwater swamp and normal sea conditions. Palynological evidence further suggests mangrove paleovegetation and humid climate. Relatively high total organic carbon TOC (0.77–8.95 wt%) was obtained for the shales which implies substantial concentration of organic matter in the source beds. Hydrocarbon source rock potential ranges from 0.19 to 0.70 mgHC/g.rock except for a certain source rock interval in the Agbaja borehole with high yield of 25.18 mgHC/g.rock. This interval also presents exceptionally high HI of 274 mgHC/g.TOC and moderate amount of amorphous organic matter. The data suggests that in spite of the favourable organic matter quantity, the thermal maturity is low as indicated by vitrinite reflectance and Tmax (0.46 to 0.48 Ro% and 413 to 475 °C, respectively). The hydrocarbon extracts show abundance of odd number alkanes C27–C33, low sterane/hopane ratio and Pr/Ph > 2. We conclude that the source rocks were terrestrially derived under oxic condition and dominated by type III kerogen. Type II organic matter with oil and gas potential is a possibility in Agbaja area of Bida Basin. Thermal maturity is low and little, or no hydrocarbon has been generated from the source rocks.


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