scholarly journals On the Reconstruction of the Mean Positron Lifetime Obtained from the Sequential Chemical Etching Procedure

2020 ◽  
Vol 137 (2) ◽  
pp. 196-200
Author(s):  
J. Dryzek
2012 ◽  
Vol 733 ◽  
pp. 49-52 ◽  
Author(s):  
Jakub Čížek ◽  
Zuzana Barnovská ◽  
Michal Šourek ◽  
Ivan Procházka

Positron lifetime spectroscopy was employed for investigation of the size distribution of free volume holes in Nafion N-1110 membrane. Size distribution of free volume holes was determined in the as-received and dried membrane and in the membrane immersed in water at various temperatures. It was found that absorbed water causes reduction of the mean size of free volume holes and increase of their dispersion and concentration. This indicates that free volumes are split by swollen ionic clusters absorbing water. The kinetics of water uptake and the amount of absorbed solvent was determined by in-situ measurement of the weight increase.


Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7328
Author(s):  
Agnieszka Skoczylas ◽  
Kazimierz Zaleski ◽  
Radosław Zaleski ◽  
Marek Gorgol

The paper presents the results of experimental studies on the impact of impulse shot peening parameters on surface roughness (Sa, Sz, Sp, Sv), surface layer microhardness, and the mean positron lifetime (τmean). In the study, samples made of the Inconel 718 nickel alloy were subjected to impulse shot peening on an originally designed stand. The variable factors of the experiment included the impact energy, the diameter of the peening element, and the number of impacts per unit area. The impulse shot peening resulted in changes in the surface structure and an increase in surface layer microhardness. After the application of impulse shot peening, the analyzed roughness parameters increased in relation to post-milling values. An increase in microhardness was obtained, i.e., from 27 HV 0.05 to 108 HV 0.05 at the surface, while the maximum increase the microhardness occur at the depth from 0.04 mm to 0.08 mm. The changes in the physical properties of the surface layer were accompanied by an increase in the mean positron lifetime τmean. This is probably related to the increased positron annihilation in point defects. In the case of small surface deformations, the increase in microhardness was accompanied by a much lower increase in τmean, which may indicate a different course of changes in the defect structure consisting mainly in modification of the dislocation system. The dependent variables were subjected to ANOVA analysis of variance (it was one-factor analysis), and the effect of independent variables was evaluated using post-hoc tests (Tukey test).


2010 ◽  
Vol 24 (02) ◽  
pp. 151-160 ◽  
Author(s):  
JIE XU ◽  
WEI LIU ◽  
GUO-AN CHENG ◽  
RUI-TING ZHENG

Ordered large-scale alumina nanowire arrays on the surface of porous anodic alumina membranes (AAMs) have been synthesized by chemical etching. The analysis shows that amorphous alumina nanowires directly formed from AAMs have uniform size and shape. The mean length and mean diameter of alumina nanowires are about 6 μm and 24 nm, respectively. It is observed that chemical etching parameters affect the synthesis of alumina nanowires and preferable experimental conditions for the synthesis of alumina nanowire arrays. The intensity of photoluminescence excited from alumina nanowire is affected by post-annealing temperatures. The mechanisms for the synthesis and PL emission of alumina nanowires are discussed.


2010 ◽  
Vol 666 ◽  
pp. 71-74 ◽  
Author(s):  
Yang Yu ◽  
Günter Dlubek ◽  
Reinhard Krause-Rehberg ◽  
Mario Beiner ◽  
Elke Hempel

Positron lifetime annihilation spectroscopy (PALS) was used to study the temperature- dependence of sub-nanometer size local free volumes in two atactic poly(n-octadecyl methacrylate)s (PODMA) with different molecular weight. These materials exhibit short range layered structure with a self-assembly and crystallization of side chains. From the ortho-positronium (o-Ps) lifetime the size of free volume holes and its distribution are calculated. At a temperature Tm=311 ± 5 K, the mean hole volume <vh> shows an abrupt and strong increase from 0.15 nm3 to 0.2 nm3, which comes from the melting of side-chains. The reverse effect, attributed to side chain crystallization, was observed during cooling the samples at slightly lower temperatures. The lifetime result of PODMA is compared with semifluorinated polyesters in which the side chain has an oxydecylperfluorodecyl structure (-O-(CH2)10-(CF2)9-CF3). Long chain polymers without side-chains such as polyethylene and short side-chain poly(n-alkyl methacrylate)s: poly(methyl methacrylate) (PMMA) and poly(n-hexyl methacrylate) (PHMA) are also compared with these polymers.


2017 ◽  
Vol 373 ◽  
pp. 205-208
Author(s):  
Shou Lei Xu ◽  
Er Juan Xie ◽  
Xiu Qing Cao ◽  
Yu Yang Huang ◽  
Ding Kang Xiong ◽  
...  

The positron annihilation techniques and X-ray diffraction have been used to study the microstructure of the La0.67Ca0.33MnO3 ceramics prepared by the solid-state reaction method at different sintered temperatures (T=1573K, 1623K, 1673K, 1723K, 1773K, 1823K). And the electro-magnetic transport behavior of the samples was measured by VSM and Resistivity modular on PPMS. According to these results, all samples show a perovskite structure, the ferromagnetic-paramagnetic and metal-insulator transitions occur at the transition temperature Tc and TMI, respectively, which is almost the same. For La0.67Ca0.33MnO3 sintered at 1673K, the mean positron lifetime is the largest, the maximum value of the magnetization is achieved on the magnetization-temperature curve at H=0.2mT, while the transition temperature occurs at about 244K.


Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4002
Author(s):  
Konrad Skowron ◽  
Ewa Dryzek ◽  
Mirosław Wróbel ◽  
Paweł Nowak ◽  
Marianna Marciszko-Wiąckowska ◽  
...  

Surface mechanical attrition treatment (SMAT) was used to generate a gradient microstructure in commercial grade magnesium. Positron annihilation lifetime spectroscopy and variable energy positron beam measurements, as well as microhardness tests, electron backscatter diffraction, X-ray diffraction, and electrochemical corrosion tests, were used to investigate the created subsurface microstructure and its properties. It was found that SMAT causes an increase in dislocation density and grain refinement which results in increased hardness of the subsurface zone. The mean positron lifetime values indicate trapping of positrons in vacancies associated with dislocations and dislocation jogs. The increase of the SMAT duration and the vibration amplitude influences the depth profile of the mean positron lifetime, which reflects the defect concentration profile. Electrochemical measurements revealed that the structure induced by SMAT increases the susceptibility of magnesium to anodic oxidation, leading to the enhanced formation of hydroxide coverage at the surface and, as a consequence, to the decrease in corrosion current. No significant effect of the treatment on the residual stress was found.


2005 ◽  
Vol 885 ◽  
Author(s):  
Kouji Sakaki ◽  
Yumiko Nakamura ◽  
Yasuharu Shirai ◽  
Robert C Bowman ◽  
Etsuo Akiba

AbstractTo clarify the effect of Sn substitution for Ni of LaNi5 on the lattice defect formation during the hydrogenation and dehydrogenation processes, in-situ positron lifetime measurements were per-formed in LaNi4.93Sn0.27. During the hydrogenation, the mean positron lifetime, τm, monotonically increased up to 175 ps which is almost same as calculated positron lifetime for vacancy. This shows vacancy introduction by hydrogenation. The τm mean positron lifetime decreased down to 135 ps with hydrogen content during the dehydrogenation. It shows that the vacancies are removed from the lattice during the dehydrogenation. These results show that vacancies in LaNi4.93Sn0.27 are intro-duced and removed reversibly during the hydrogenation and dehydrogenation. The concentra-tions of vacancy and dislocation were 1 × 10−5 and 6 × 109 cm−2, respectively. These values are two orders lower than those in LaNi5.


2017 ◽  
Vol 31 (16-19) ◽  
pp. 1744068 ◽  
Author(s):  
Wen Deng ◽  
Zhenying Chen ◽  
Yan Meng ◽  
Xiuqing Cao ◽  
Dingkang Xiong ◽  
...  

The Y3Al5O[Formula: see text] (YAG):Ce ceramic rods and single crystals were prepared by solid state reaction and optical floating zone method, respectively. The XRD results showed that the phases in the YAG:Ce ceramics are mixture of YAG phase and YAlO3 (YAP) phase. There is only a single YAG phase in the single crystals of YAG:Ce. The mean positron lifetime of the YAG:Ce crystal decreases with increasing Ce content, and reaches minimum at 1 at.% Ce, then increases with Ce content. The mean positron lifetime of the YAG:Ce crystal is higher than that of YAG:Ce ceramic with the same chemical composition. The UV–visible absorption spectra of the YAG:Ce crystals indicated that the transmittances of the YAG:Ce crystals are higher than 90% in the wavelength range from 550 nm to 800 nm. The photoluminescence spectra of the YAG:Ce crystals showed wide luminescence emission peaks located in the range of 525–529 nm. A relatively high luminescence intensity is found in the YAG:Ce crystal with 1 at.% Ce. With further increase of Ce content, the luminescence decreases due to the fluorescence quenching effect.


2005 ◽  
Vol 12 (02) ◽  
pp. 197-202
Author(s):  
M. A. ABDEL-RAHMAN ◽  
R. M. ABDEL-LATIF ◽  
M. S. ABDALLAH ◽  
EMAD A. BADAWI

Positron behavior at grain boundaries is characterized by their bulk diffusibility D, their bulk free lifetime τf and their trapped lifetime τt(τt > τf). AlSi 11.35 Mg 0.23, AlSi 10.9 Mg 0.17 Sr 0.06, 7075 and 2024 alloys have been homogenized at 673 K for 12 hours. The mean lifetime, as (indirectly) measured at various strains (degrees of deformation), show a good fitting with a FORTRAN program. τf and τt for the above materials are shown as: (187.3 ± 0.10, 229.7 ± 0.10), (198.0 ± 0.10, 230.3 ± 0.10), (205.4 ± 0.05, 213.4 ± 0.06) and (197.1 ± 0.55, 215.2 ± 0.57) Ps respectively. The mean lifetime was found to vary exponentially with the degree of deformation.


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