scholarly journals New Aromatic Azo-Schiff as Carbon Steel Corrosion Inhibitor in 1 M H2SO4

2018 ◽  
Vol 34 (5) ◽  
pp. 2471-2476 ◽  
Author(s):  
Hamida Edan Salman ◽  
Asim A. Balakit ◽  
Ali Ahmed Abdulridha
Keyword(s):  
Weight Loss ◽  
Carbon Steel ◽  
Corrosion Inhibitor ◽  
Corrosion Inhibition ◽  
Potentiodynamic Polarization ◽  
Inhibition Efficiency ◽  
Steel Corrosion ◽  
Spectroscopic Techniques ◽  
Different Temperatures ◽  
Corrosion Inhibition Efficiency

A new aromatic Schiff base with azo linkage (AS) has been synthesized and characterized by FT-IR, 1H NMR and 13C NMR spectroscopic techniques. The new compound (AS) has been evaluated as carbon steel corrosion inhibitor at different concentrations (0.005, 0.01, 0.02, 0.04 and 0.08 mM) and different temperatures (303 – 333 K). The corrosion inhibition efficiency was studied by potentiodynamic polarization and weight loss measurements. The effects of concentration and temperature on the inhibition efficiency were studied by potentiodynamic polarization studies, the results showed that increasing concentration of AS increases the inhibition efficiency while increasing the temperature decreases it, the highest corrosion inhibition efficiency, 93.9% was recorded with 0.08 mM of AS at 313 K in 1 M H2SO4. Weight loss measurements showed that the inhibition efficiency reached 97.1% in the presence of AS (0.08 mM) at 313 K. The adsorption process was found to obey Langmuir isotherm, and the adsorption thermodynamic parameters were studied. Scanning electron microscope (SEM) was used to confirm the results.

Rhizophora apiculata Extract as Corrosion Inhibitor in 3.5% NaCl for API 5L Steel

2018 ◽  
Vol 791 ◽  
pp. 83-87
Author(s):  
Femiana Gapsari ◽  
Putu Hadi Setyarini ◽  
Andita N.F. Ganda
Keyword(s):  
Weight Loss ◽  
Fourier Transform ◽  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Functional Groups ◽  
Inhibition Efficiency ◽  
Steel Corrosion ◽  
Polarization Method ◽  
Infra Red ◽  
Corrosion Inhibition Efficiency

The corrosion inhibition efficiency of Rhizophora acipulata(RA) extract was investigated for API 5L Steel corrosion in 3.5% NaCl using weight loss and polarization method. Fourier Transform Infra-Red (FTIR) was used toanalyze the characteristics of extract RA functional groups. The weight loss and polarization result indicated that extract RA inhibited API 5L steel corrosion rate. Based on the polarization result, the inhibition efficiency reached up 97.52% with addition 100ppm of RA extract.

Surface active hyperbranched polyamide-ester as a corrosion inhibitor for carbon steel in both neutral and acidic media

2015 ◽  
Vol 62 (2) ◽  
pp. 95-102 ◽  
Author(s):  
Heba Abdelrazik Mohamed ◽  
Mona Hassan Abdel Rehim
Keyword(s):  
Carbon Steel ◽  
Corrosion Inhibitor ◽  
Corrosion Inhibition ◽  
Inhibition Efficiency ◽  
Plain Carbon Steel ◽  
Water Soluble ◽  
Critical Aggregation Concentration ◽  
Content Type ◽  
Corrosion Inhibition Efficiency ◽  
Hyperbranched Polyamide

Purpose – The purpose of this paper was to protect carbon steel from corrosion with self–aggregated, eco-friendly, water-soluble hyperbranched polyamide-ester (Hb-PAE). Design/methodology/approach – Hb-PAE was synthesized through bulk polycondensation reaction between maleic anhydride and di-isopropanol amine. Complete structural analysis for the obtained polymer was performed using Fourier Transfer Infra-Red Spectroscopy, 1H NMR, Thermal gravimetric analysis (TGA) and differential scanning calorimetry, and the molar mass was measured using gel permeation chromatography/refractive index. For this study, the surface activity of Hb-PAE with hydroxyl end groups was investigated. Surface tension of 1.0 × 10−6 to 0.1M of both Hb-PAE/H2O and Hb-PAE/1N HCl systems was measured, and the critical aggregation concentration (CAC) in both systems was determined. Hb-PAE was examined as a corrosion inhibitor for plain carbon steel in both neutral (distilled water) and acidic (1N HCl) media. The corrosion of the steel was studied quantitatively by measuring its weight loss in both media in the absence and presence of Hb-PAE. The surface morphology of the exposed steel test samples was examined using scanning electron microscopy. Findings – It was found that Hb-PAE inhibited corrosion of steel around the CAC, and its corrosion inhibition efficiency was increased by increasing its concentration. Originality/value – The research can provide a reference for the relationship between the aggregation concentration of the prepared Hb-PAE with its corrosion inhibition efficiency on plain carbon steel. Hb-PAE as a corrosion inhibitor is environmentally acceptable, economical and readily available.

scholarly journals Electrochemical and Surface Morphological Studies of Carbon Steel Corrosion by a Novel Polynuclear Schiff Base in HCl Solution

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
K. S. Shaju ◽  
K. Joby Thomas ◽  
Vinod P. Raphael ◽  
Aby Paul
Keyword(s):  
Weight Loss ◽  
Schiff Base ◽  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Adsorption Isotherm ◽  
Acid Solution ◽  
Corrosion Inhibition ◽  
Hydrochloric Acid Solution ◽  
Inhibition Efficiency ◽  
Morphological Studies

The corrosion inhibition efficiency of a potential polynuclear Schiff base, (s)-2-(anthracene-9 (10H)-ylidene amino)-5-guanidinopentanoic acid (A9Y5GPA), on carbon steel (CS) in 1 M hydrochloric acid solution has been investigated using weight loss measurements, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization studies. The corrosion inhibition efficiencies of parent amine [(s)-2-amino-5-guanidinopentanoic acid] and parent ketone (anthracene-9 (10H)-one) on carbon steel in 1.0 M hydrochloric acid solution have also been investigated using weight loss studies. The electrochemical and weight loss data established that the inhibition efficiency on CS increases with the increase in the concentration of inhibitor, A9Y5GPA. The adsorption of A9Y5GPA obeys the Langmuir adsorption isotherm. Thermodynamic parameters (Kads, ΔGads0) were calculated using the adsorption isotherm. Activation parameters of the corrosion process (Ea, ΔH* and ΔS*) were also calculated from the corrosion rates obtained from temperature studies. Tafel plot analysis revealed that A9Y5GPA acts as a mixed-type inhibitor. A probable inhibition mechanism was also proposed. Surface morphology of the carbon steel specimens in the presence and absence of the inhibitor was evaluated by SEM analysis.

scholarly journals Effect of CO2 Partial Pressure on the Corrosion Inhibition of N80 Carbon Steel by Gum Arabic in a CO2-Water Saline Environment for Shale Oil and Gas Industry

Materials ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 4245
Author(s):  
Gaetano Palumbo ◽  
Kamila Kollbek ◽  
Roma Wirecka ◽  
Andrzej Bernasik ◽  
Marcin Górny
Keyword(s):  
Carbon Steel ◽  
Partial Pressure ◽  
Corrosion Inhibition ◽  
Photoelectron Spectroscopy ◽  
Inhibition Efficiency ◽  
Gum Arabic ◽  
Saline Environment ◽  
X Ray ◽  
Co2 Partial Pressure ◽  
Corrosion Inhibition Efficiency

The effect of CO2 partial pressure on the corrosion inhibition efficiency of gum arabic (GA) on the N80 carbon steel pipeline in a CO2-water saline environment was studied by using gravimetric and electrochemical measurements at different CO2 partial pressures (e.g., PCO2 = 1, 20 and 40 bar) and temperatures (e.g., 25 and 60 °C). The results showed that the inhibitor efficiency increased with an increase in inhibitor concentration and CO2 partial pressure. The corrosion inhibition efficiency was found to be 84.53% and 75.41% after 24 and 168 h of immersion at PCO2 = 40 bar, respectively. The surface was further evaluated by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), grazing incidence X-ray diffraction (GIXRD), and X-ray photoelectron spectroscopy (XPS) measurements. The SEM-EDS and GIXRD measurements reveal that the surface of the metal was found to be strongly affected by the presence of the inhibitor and CO2 partial pressure. In the presence of GA, the protective layer on the metal surface becomes more compact with increasing the CO2 partial pressure. The XPS measurements provided direct evidence of the adsorption of GA molecules on the carbon steel surface and corroborated the gravimetric results.

Corrosion Inhibition of Polyethylene Glycol for Magnesium Alloy AZ91 at Different Temperatures

2014 ◽  
Vol 1015 ◽  
pp. 692-695
Author(s):  
Wei Shang ◽  
Zhou Lan Yin ◽  
Yu Qing Wen ◽  
Xu Feng Wang
Keyword(s):  
Polyethylene Glycol ◽  
Magnesium Alloy ◽  
Corrosion Inhibition ◽  
Inhibition Efficiency ◽  
Nacl Solution ◽  
Alloy Az91 ◽  
Magnesium Alloy Az91 ◽  
Polyethylene Glycol 200 ◽  
Different Temperatures ◽  
Corrosion Inhibition Efficiency

the corrosion inhibition of polyethylene glycol 200 for magnesium alloy AZ91 in 1% NaCl solution at different temperatures are studied. The morphology of the sample at 25°C is analyzed by SEM. And CHI600C electrochemistry workstation is employed to investigate the corrosion inhibition of the samples. The results show that the corrosion inhibition efficiency of polyethylene glycol 200 to the magnesium alloy AZ91 is affected by temperature. Polyethylene glycol 200 has superior corrosion inhibition to the magnesium alloy at the temperature of 25°C.

Corrosion Inhibition of Sodium Hexametaphosphate for Carbon Steel in KCl Solution

2014 ◽  
Vol 886 ◽  
pp. 12-15
Author(s):  
Bin Huang ◽  
Kang Quan Qiao ◽  
Yi Shun Cui
Keyword(s):  
Weight Loss ◽  
Electron Microscope ◽  
Carbon Steel ◽  
Corrosion Inhibition ◽  
Potentiodynamic Polarization ◽  
Polarization Curves ◽  
Sodium Hexametaphosphate ◽  
Anodic Process ◽  
Polarization Measurements ◽  
Potentiodynamic Polarization Curves

The influence of sodium hexametaPhosphate on the corrosion of carbon steel in 0.5 mol•L-1 KCl solution at 25 °C was investigated using weight loss measurements, potentiodynamic polarization curves and Scan electron microscope (SEM). The obtained results show that sodium hexametaPhosphate is an excellent inhibitor and the inhibition efficiencies exceed 87 %. The polarization measurements reveal that sodium hexametaPhosphate is an inhibitor mainly controlled by anodic process.

scholarly journals Improvement in Corrosion Inhibition Efficiency of Molybdate-Based Inhibitors via Addition of Nitroethane and Zinc in Stimulated Cooling Water

2012 ◽  
Vol 2012 ◽  
pp. 1-9 ◽  
Author(s):  
Saeed Mohammadi ◽  
Fatemeh Baghaei Ravari ◽  
Athareh Dadgarinezhad
Keyword(s):  
Electron Microscopy ◽  
Weight Loss ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Inhibition Efficiency ◽  
Cooling Water ◽  
Ac Impedance ◽  
Uniform Corrosion ◽  
Corrosion Inhibition Efficiency ◽  
Zinc Inhibition

An investigation was conducted to improve the corrosion inhibition efficiency of molybdate-based inhibitors for mild steel which is the main construction material of cooling water systems, using nitroethane as an organic compound beside zinc. In this study a new molybdate-based inhibitor was introduced with the composition of 60 ppm molybdate, 20 ppm nitrite, 20 ppm nitroethane, and 10 ppm zinc. Inhibition efficiency of molybdate alone and with nitrite, nitroethane, and zinc on the uniform corrosion of mild steel in stimulated cooling water (SCW) was assessed by electrochemical techniques such as potentiodynamic polarization and electrochemical impedance (AC impedance) measurements. Weight loss measurements were made with coupon testing specimens in the room temperature for 48 h. Studies of electron microscopy, including scanning electron microscopy (SEM) photograph and X-ray energy dispersive spectrometry (EDS) microanalysis, were used. The results obtained from the polarization and AC impedance curves were in agreement with those from the corrosion weight loss results. The results indicate that the new inhibitor is as effective as molybdate alone, though at one-ninth of the concentration range of molybdate, which is economically favorable.

scholarly journals Synthesis of Novel Corrosion Inhibitor N-(1,3-Benzothiazol-2-yl)-4-aminobenzamide in 1 N Hydrochloric Acid Medium

2021 ◽  
Vol 33 (3) ◽  
pp. 622-626
Author(s):  
Senthilkumar Gopal ◽  
Umarani Chinnasamy ◽  
Ramachandran Arumugam
Keyword(s):  
Hydrochloric Acid ◽  
Corrosion Inhibitor ◽  
Acid Medium ◽  
Inhibition Efficiency ◽  
Nmr Studies ◽  
Steel Material ◽  
Hydrochloric Acid Medium ◽  
Different Temperatures ◽  
Corrosion Inhibition Efficiency ◽  
Loss Method

A novel corrosion inhibitor i.e. N-(1,3-benzothiazol-2-yl)-4-aminobenzamide was synthesized and its corrosion inhibitor on controlling the rate of mild steel material in hydrochloric acid medium (1 N) at different temperatures was investigated. Rate of corrosion and inhibition efficiency were analyzed and calculated using mass loss method and electrochemical studies. As the concentration of the inhibitor increase the inhibitor efficiency also increases gradually with decrease in the rate of corrosion. Therefore from this study the efficiency of the inhibitor was good at different temperature in 1 N HCl. The relative corrosion inhibition efficiency of synthesized organic compound has been explained on the basis of its structure dependent-electron donating properties of the inhibitor. Further the structure and compound present in the synthesized organic inhibitor compound was confirmed by FTIR and NMR studies.

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