Analysis of Composite Structure and Primordial Wood Remains in Petrified Wood

2007 ◽  
Vol 61 (8) ◽  
pp. 889-895 ◽  
Author(s):  
J. Nowak ◽  
D. Nowak ◽  
P. Chevallier ◽  
J. Lekki ◽  
R. van Grieken ◽  
...  
Keyword(s):  
Cell Walls ◽  
Central Italy ◽  
Global Scale ◽  
Mineralization Process ◽  
Raman Spectrometry ◽  
X Ray ◽  
The Earth ◽  
Geological Past ◽  
Petrified Wood ◽  
Composite Nature

Among all the fossils, petrified wood belongs to the most impressive and most common of materials. Still, its study has not exceeded the purely phenomenological level. The recognition of the conserved structure of petrified wood seems to be of meaning for understanding the geological past, the complete carbon cycle inside the Earth, and the structure of potential new materials. The first ever published spatial distributions of the remains of the primordial organic material (lignin, cellulose, pectins) in the cells of permineralized wood, from Dunarobba (Central Italy), are presented here. They were collected using μ-Raman spectrometry. The composite nature of the petrified material (calcite located in the lumena of cells and goethite located in the cell walls) was confirmed by electron, proton, and X-ray microprobes. The structure of the cell walls was well preserved. The mineralization process was induced by the tracheidal water flow and was stopped after formation of pipe-like goethite shielding of the cell walls on the cellulose scaffolds. The chemical (Eh and pH ranges) and probable microbial conditions for such a pattern of mineralization were determined. We estimate that substantial amounts of the primordial organic matter were preserved in bodies of petrified wood on a global scale. The wood petrifaction process, if well understood, can be a basis for the production of “everlasting” organic–inorganic composite compounds.

Biogeochemical Cycles and Climate

2019 ◽  
Author(s):  
Han Dolman
Keyword(s):  
Ocean Circulation ◽  
Biogeochemical Cycles ◽  
Integrated System ◽  
General Introduction ◽  
Complex Interplay ◽  
Climate Agreements ◽  
Mitigation And Adaptation ◽  
The Earth ◽  
Geological Past ◽  
Recent Climate

This book describes the interaction of the main biogeochemical cycles of the Earth and the physics of climate. It takes the perspective of Earth as an integrated system and provides examples of both changes in the current climate and those in the geological past. The first three chapters offer a general introduction to the context of the book, outlining the climate system as a complex interplay between biogeochemistry and physics and describing the tools available for understanding climate: observations and models. These chapters describe the basics of the system, the rates and magnitudes and the crucial aspects of biogeochemical cycles needed to understand their functioning. The second part of the book consists of four chapters that describe the physics required to understand the interaction of the climate with biogeochemistry and change. These chapters describe the physics of radiation, and that of the atmosphere, ocean circulation and thermodynamics. The interaction of aerosols with radiation and clouds is addressed in an additional chapter. The third part of the book deals with Earth’s (bio)geochemical cycles. These chapters focus on the stocks and fluxes of the main reservoirs of Earth’s biogeochemical cycles—atmosphere, land and ocean—and their role in the cycles of carbon, oxygen, nitrogen, iron, phosphorus, oxygen, sulphur and water, as well as their interactions with climate. The final two chapters describe possible mitigation and adaptation actions, in relation to recent climate agreements, but always with an emphasis on the biogeochemical aspects.

scholarly journals Visualising Silicon in Plants: Histochemistry, Silica Sculptures and Elemental Imaging

Cells ◽  
2020 ◽  
Vol 9 (4) ◽  
pp. 1066 ◽  
Author(s):  
Gea Guerriero ◽  
Ian Stokes ◽  
Nathalie Valle ◽  
Jean-Francois Hausman ◽  
Christopher Exley
Keyword(s):  
Cell Walls ◽  
Mass Spectrometry Imaging ◽  
Spatial Information ◽  
Cannabis Sativa ◽  
Essential Element ◽  
Molecular Data ◽  
Plant Vigour ◽  
X Ray ◽  
Imaging Approach ◽  
General Improvement

Silicon is a non-essential element for plants and is available in biota as silicic acid. Its presence has been associated with a general improvement of plant vigour and response to exogenous stresses. Plants accumulate silicon in their tissues as amorphous silica and cell walls are preferential sites. While several papers have been published on the mitigatory effects that silicon has on plants under stress, there has been less research on imaging silicon in plant tissues. Imaging offers important complementary results to molecular data, since it provides spatial information. Herein, the focus is on histochemistry coupled to optical microscopy, fluorescence and scanning electron microscopy of microwave acid extracted plant silica, techniques based on particle-induced X-ray emission, X-ray fluorescence spectrometry and mass spectrometry imaging (NanoSIMS). Sample preparation procedures will not be discussed in detail, as several reviews have already treated this subject extensively. We focus instead on the information that each technique provides by offering, for each imaging approach, examples from both silicifiers (giant horsetail and rice) and non-accumulators (Cannabis sativa L.).

scholarly journals Upgrading pyrolytic residue from waste tires to commercial carbon black

2018 ◽  
Vol 36 (5) ◽  
pp. 436-444 ◽  
Author(s):  
Xue Zhang ◽  
Hengxiang Li ◽  
Qing Cao ◽  
Li’e Jin ◽  
Fumeng Wang
Keyword(s):  
Carbon Black ◽  
Value Added ◽  
Pyrolytic Carbon ◽  
Ultrasonic Waves ◽  
Added Value ◽  
Infrared Spectrometry ◽  
Raman Spectrometry ◽  
X Ray ◽  
Waste Tires ◽  
Commercial Carbon

The managing and recycling of waste tires has become a worldwide environmental challenge. Among the different disposal methods for waste tires, pyrolysis is regarded as a promising route. How to effectively enhance the added value of pyrolytic residue (PR) from waste tires is a matter of great concern. In this study, the PRs were treated with hydrochloric and hydrofluoric acids in turn under ultrasonic waves. The removal efficiency for the ash and sulfur was investigated. The pyrolytic carbon black (PCB) obtained after treating PR with acids was analyzed by X-ray fluorescence spectrophotometry, Fourier transform infrared spectrometry, X-ray diffractometry, laser Raman spectrometry, scanning electron microscopy, thermogravimetric (TG) analysis, and physisorption apparatus. The properties of PCB were compared with those of commercial carbon black (CCB) N326 and N339. Results showed PRs from waste tires were mainly composed of carbon, sulfur, and ash. The carbon in PCB was mainly from the CCB added during tire manufacture rather than from the pyrolysis of pure rubbers. The removal percentages for the ash and sulfur of PR are 98.33% (from 13.98 wt % down to 0.24 wt %) and 70.16% (from 1.81 wt % down to 0.54 wt %), respectively, in the entire process. The ash was mainly composed of metal oxides, sulfides, and silica. The surface properties, porosity, and morphology of the PCB were all close to those of N326. Therefore, PCB will be a potential alternative of N326 and reused in tire manufacture. This route successfully upgrades PR from waste tires to the high value-added CCB and greatly increases the overall efficiency of the waste tire pyrolysis industry.

Non-cellulosic structural polysaccharides in algal cell walls I. Xylan in siphoneous green algae

1964 ◽  
Vol 160 (980) ◽  
pp. 293-313 ◽  
Keyword(s):  
Relative Humidity ◽  
Cell Walls ◽  
Marine Algae ◽  
Transverse Section ◽  
Algal Cell ◽  
Repeat Distance ◽  
X Ray ◽  
Face View ◽  
Half Turn ◽  
Parallel Arrays

The cell walls of a number of marine algae, namely species of Bryopsis, Caulerpa, Udotea, Halimeda and Penicillus and of one freshwater alga, Dichotomosiphon , are examined using both chemical and physical techniques. It is shown that, with the possible exception of Bryopsis , cellulose is completely absent and that the walls contain instead β -l,3-linked xylan as the structural polysaccharide. Bryopsis contains, in addition, a glucan which is most abundant in the outer layers of the wall and which stains like cellulose. The xylan is microfibrillar but the microfibrils are more strongly adherent than they are in cellulose, and in some species appear in the electron microscope to be joined by short crossed rod-like bodies. The orientation of the microfibrils is found to vary, ranging from a net tendency to transverse orientation through complete randomness to almost perfect longitudinal alinement. The microfibrils are negatively birefringent, so that all walls seen in optical section, and all parallel arrays of microfibrils whether in face view or in section (except strictly transverse section) are negatively birefringent. With Bryopsis , the negative birefringence in face view is overcompensated by the positive birefringence of the incrusting glucan so that the true birefringence of the crystalline polysaccharide is observed only after the glucan is removed. The X-ray diagram of parallel arrays of microfibrils as found, for instance, in Penicillus dumetosus shows that the xylan chains are helically coiled, in harmony with the negative birefringence. It is deduced that the microfibrils consist of hexagonally packed, double-stranded helices. The diameter of the helices increases with increasing relative humidity, as water is taken into the lattice, from 13.7 Å in material dried over phosphorus pentoxide to a maximum of 1.54 Å at 65 % relative humidity when the xylan contains 30 % of its weight as water. The repeat distance along the helix axis ranges from 5.85 Å (dry) to 6.06 Å (wet), the length of a half turn of each helix containing three xylose residues. The incrusting substances in these walls often include a glucan which is said also to be 1,3-linked. The significance of the extensive differences between this xylan and cellulose are examined both as regards some of the physical properties of the respective cell walls and in relation to the taxonomic position of these plants.

The Strait of Magellan—a Gateway to New Worlds

2021 ◽  
Author(s):  
Mauricio Onetto Pavez
Keyword(s):  
Global Scale ◽  
Modern World ◽  
American Continent ◽  
The Earth ◽  
Starting Point ◽  
Strait Of Magellan ◽  
The World ◽  
The Strait Of Magellan ◽  
History Of ◽  
First Time

The year 2020 marks the five hundredth anniversary of the “discovery” of the Strait of Magellan. The unveiling of this passage between 1519 and 1522 allowed the planet to be circumnavigated for the first time in the history of humanity. All maritime routes could now be connected, and the idea of the Earth, in its geographical, cosmographic, and philosophical dimensions, gained its definitive meaning. This discovery can be considered one of the founding events of the modern world and of the process of globalization that still continues today. This new connectivity awoke an immediate interest in Europe that led to the emergence of a political consciousness of possession, domination, and territorial occupation generalized on a global scale, and the American continent was the starting point for this. This consciousness also inspired a desire for knowledge about this new form of inhabiting the world. Various fields of knowledge were redefined thanks to the new spaces and measurements produced by the discovery of the southern part of the Americas, which was recorded in books on cosmography, natural history, cartography, and manuscripts, circulating mainly between the Americas and Europe. All these processes transformed the Strait of Magellan into a geopolitical space coveted by Europeans during the 16th century. As an interoceanic connector, it was used to imagine commercial routes to the Orient and political projects that could sustain these dynamics. It was also conceived as a space to speculate on the potential wealth in the extreme south of the continent. In addition, on the Spanish side, some agents of the Crown considered it a strategic place for imperial projections and the defense of the Americas.

scholarly journals Geosystemics and Earthquakes

2018 ◽  
Author(s):  
Angelo De Santis ◽  
Gianfranco Cianchini ◽  
Rita Di Giovambattista ◽  
Cristoforo Abbattista ◽  
Lucilla Alfonsi ◽  
...  
Keyword(s):  
Dynamical System ◽  
Solid Earth ◽  
Case Studies ◽  
Central Italy ◽  
Point Of View ◽  
Earth System ◽  
Complex Dynamical System ◽  
The Earth ◽  
Earth’S Interior

Abstract. Geosystemics (De Santis 2009, 2014) studies the Earth system as a whole focusing on the possible coupling among the Earth layers (the so called geo-layers), and using universal tools to integrate different methods that can be applied to multi-parameter data, often taken on different platforms. Its main objective is to understand the particular phenomenon of interest from a holistic point of view. In this paper we will deal with earthquakes, considered as a long term chain of processes involving, not only the interaction between different components of the Earth’s interior, but also the coupling of the solid earth with the above neutral and ionized atmosphere, and finally culminating with the main rupture along the fault of concern (De Santis et al., 2015a). Some case studies (particular emphasis is given to recent central Italy earthquakes) will be discussed in the frame of the geosystemic approach for better understanding the physics of the underlying complex dynamical system.

scholarly journals Sustainable Improvement of Zeolitic Pyroclastic Soils for the Preservation of Historical Sites

2020 ◽  
Vol 10 (3) ◽  
pp. 899
Author(s):  
Manuela Cecconi ◽  
Costanza Cambi ◽  
Stefano Carrisi ◽  
Dimitri Deneele ◽  
Enza Vitale ◽  
...  
Keyword(s):  
Central Italy ◽  
Hydrated Lime ◽  
Thermo Gravimetric ◽  
X Ray ◽  
Beneficial Effects ◽  
Multi Scale ◽  
Sustainable Improvement ◽  
Calcium Silicate Hydrates ◽  
Historical Sites ◽  
Oedometer Tests

Climate changes are inducing a modification of environmental loads on historical sites, requiring new actions towards their conservation. In the paper, the results of an experimental work on sustainable improvement of a pyroclastic soil belonging to the Orvieto cliff (Central Italy) have been investigated in the perspective of its preservation from degradation. The slightly coherent facies of Orvieto Ignimbrite (pozzolana) was treated with hydrated lime and the subsequent chemo-physical evolution was investigated by means of a multi-scale analysis. The beneficial effects obtained from the improvement in terms of mechanical behaviour were interpreted and correlated to the chemo-physical evolution of the system. Microstructural analyses, X-ray diffractometry, thermo-gravimetric analyses (DTG), SEM observations, mercury intrusion porosimetry performed on raw and treated samples, showed that the pozzolanic reactions develop since the very beginning in the system and that the observed mechanical improvement of the treated soil is mainly due to the formation of calcium silicate hydrates (CSH) and calcium aluminate hydrates (CAH). In the paper, the mechanical improvement is put in evidence by comparing the results of oedometer tests performed on both raw and treated samples.

scholarly journals Climate change in the recent geological past and the near future. Predicting its impacts: a Review

2019 ◽  
Vol 55 (1) ◽  
pp. 260
Author(s):  
Constantinos Perisoratis
Keyword(s):  
Climate Change ◽  
Sea Level Rise ◽  
Climatic Change ◽  
Sea Level ◽  
Scientific Community ◽  
Climate Changes ◽  
Late Quaternary ◽  
The Earth ◽  
Geological Past ◽  
Near Future

The climate changes are necessarily related to the increase of the Earth’s temperature, resulting in a sea level rise. Such continuous events, were taking place with minor and greater intensity, during the alternation of warm and cool periods in the Earth during the Late Quaternary and the Holocene periods. However, a particularly significant awareness has taken place in the scientific community, and consequently in the greater public, in the last decades: that a climatic change will take place soon, or it is on-going, and that therefore it is important to undertake drastic actions. However, such a climatic change has not been recorded yet, and hence the necessary actions are not required, for the time being.

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