scholarly journals Studies on the flammability of polypropylene/ammonium polyphosphate and montmorillonite by using the cone calorimeter test

2018 ◽  
Vol 16 (1) ◽  
pp. 108-115 ◽  
Author(s):  
A.A. Hanna ◽  
M.A. Nour ◽  
E.R. Souaya ◽  
M.A. sherief ◽  
A.S. Abdelmoaty
Keyword(s):  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Cone Calorimeter ◽  
Acid Treatment ◽  
Ammonium Polyphosphate ◽  
Fire Performance ◽  
Cone Calorimeter Test ◽  
Peak Heat Release Rate

AbstractFire performance of polypropylene (PP) containing different percentages of ammonium polyphosphate (APP) with montmorillonite (Mt) or treated montmorillonite (MtT) was carried out by using the cone calorimeter test (CCT). Different samples from ammonium polyphosphate and montmorillonite were mixed with 90% polypropylene. The characterization of the prepared samples indicates that there is incorporation between the components of the samples. Heat release rate (HRR), peak heat release rate (PHRR), average heat release rate (Av-HRR), and time to ignition (TTI) of the samples were obtained from the cone calorimeter test. Also, the fire performance index (FPI) and the fire growth rate (FIGRA) were calculated. The interpretation of the curves and the parameters results from the cone calorimeter test which indicates that the addition of montmorillonite to APP increases its action as a flame retardant for PP. Moreover, the samples contain acid treatment montmorillonite showed an increase in the efficiency of ammonium polyphosphate when used. This result may be due to an increase in the SiO2 content by acid treatment.

scholarly journals The effect of intumescent mat on post-fire performance of carbon fibre reinforced composites

2019 ◽  
Vol 37 (3) ◽  
pp. 257-272 ◽  
Author(s):  
Chenkai Zhu ◽  
Jingjing Li ◽  
Mandy Clement ◽  
Xiaosu Yi ◽  
Chris Rudd ◽  
...  
Keyword(s):  
Carbon Fibre ◽  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Reinforced Composites ◽  
Fire Performance ◽  
Total Heat Release ◽  
Reinforced Composite ◽  
Peak Heat Release Rate ◽  
Fibre Reinforced Composites

This study investigated the effect of intumescent mats (M1 and M2) with different compositions on the post-fire performance of carbon fibre reinforced composites. The sandwich structure was designed for composites where M1 (carbon fibre reinforced composite-M1) or M2 (carbon fibre reinforced composite-M2) mats were covered on the composite surface. A significant reduction in the peak heat release rate and total heat release was observed from the cone calorimetric data, and carbon fibre reinforced composite-M1 showed the lowest value of 148 kW/m2 and 29 MJ/m2 for peak heat release rate and total heat release, respectively. In addition, a minor influence on mechanical properties was observed due to the variation of composite thickness and resin volume in the composite. The post-fire properties of composite were characterised, and the M1 mat presented better retention of flexural strength and modulus. The feasibility of two-layer model was confirmed to predict the post-fire performance of composites and reduce the reliance on the large amounts of empirical data.

Flame Retardation of Natural Bamboo Fiber/ Polypropylene Fiber Non-Woven Materials

2011 ◽  
Vol 105-107 ◽  
pp. 1723-1726
Author(s):  
Wei Ma ◽  
Wen Bin Yao
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Heat Release Rate ◽  
Release Rate ◽  
Cone Calorimeter ◽  
Polypropylene Fiber ◽  
Bamboo Fiber ◽  
Peak Heat Release Rate ◽  
Natural Bamboo Fiber ◽  
Flame Retardation

According to Natural Bamboo Fiber/ Polypropylene fiber(PP) non-woven materials encountered the problem that its flame retardation is insufficient, this paper tried to add flame retardant to improve its performance, then the cone calorimeter was used to evaluate its flammability. The results show that Peak-Heat Release Rate and Smoke Release Rate etc significantly improved. In accordance with the UL94 ,the flame retardation meet the level V-0 , consistent with the requirements of enterprise.

Fire Performance of Nylon Nanocomposites Fabricated by Melt Intercalation

2007 ◽  
Vol 334-335 ◽  
pp. 737-740
Author(s):  
Russel J. Varley ◽  
Andrew M. Groth ◽  
Kok Hoong Leong
Keyword(s):  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Fire Performance ◽  
Fire Retardancy ◽  
Cone Calorimetry ◽  
Char Layer ◽  
Transmission Electron ◽  
Peak Heat Release Rate ◽  
In Fire

This paper presents results of a study carried out to evaluate the effects of an organomodified nanoclay, either on its own or in combination with a polyimide, upon the fire performance of a commercially available nylon. The fire performance, as determined using cone calorimetry showed that up to 40% improvement in the peak heat release rate could be achieved at addition levels of only around 5wt% of nanoclay. The level of improvement was shown to be strongly dependent upon nanoscale dispersion with a more highly exfoliated morphology, as determined using transmission electron microscopy, which showed a greater reduction in the peak heat release rate compared to a more ordered intercalated structure. Investigation of the mechanism of fire retardancy showed that the reduction in the heat release rate is due to the nanoclay reinforcing the char layer which prevented combustible products from entering in to the gaseous phase. Generally, though, the time to ignition is unaffected by nanoclay additions. The addition of the polyimide to the nanoclay reinforced nylon was inconclusive showing little evidence of further improvements in fire performance.

Fire performance of continuous glass fibre reinforced polycarbonate composites: The effect of fibre architecture on the fire properties of polycarbonate composites

2018 ◽  
Vol 53 (12) ◽  
pp. 1705-1715 ◽  
Author(s):  
Yousof M Ghazzawi ◽  
Andres F Osorio ◽  
Michael T Heitzmann
Keyword(s):  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Glass Fibre ◽  
Mass Loss Rate ◽  
Fibre Reinforcement ◽  
Fire Performance ◽  
Cone Calorimetry ◽  
Glass Fibre Reinforced ◽  
Fire Properties

The fire performance of polycarbonate resin and the role of glass fibre reinforcement in altering the fire performance was investigated. Three different fibre weaves with comparable surface density, plain, twill, and unidirectional glass fabrics, were used as reinforcements. E-glass fabrics were solution-impregnated with polycarbonate/dichloromethyl, laid up, and compression-moulded to consolidate the glass fibre reinforced polycarbonate composite. Cone calorimetry tests with an incident radiant flux of 35 kW/m2 were used to investigate the fire properties of polycarbonate resin and its composites. Results showed that glass fibre reinforcement improves polycarbonate performance by delaying its ignition, decreasing its heat release rate, and lowering the mass loss rate. The three fibre weave types exhibited similar time to ignition. However, unidirectional fibre had a 35% lower peak heat release rate followed when compared to plain and twill weave fibres.

Synthesis of a phosphorus–nitrogen-containing flame retardant and its application in epoxy resin

2018 ◽  
Vol 31 (2) ◽  
pp. 186-196 ◽  
Author(s):  
Shuang Yang ◽  
Yefa Hu ◽  
Qiaoxin Zhang
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Heat Release Rate ◽  
Flame Retardancy ◽  
Release Rate ◽  
Epoxy Resins ◽  
Proton Nuclear Magnetic Resonance ◽  
Scanning Calorimetry ◽  
Cone Calorimeter Test

In this article, a phosphorus–nitrogen-containing flame retardant (DOPO-T) was successfully synthesized by nucleophilic substitution reaction between 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and cyanuric chloride. The chemical structure of DOPO-T was characterized by Fourier transform infrared spectroscopy, proton nuclear magnetic resonance (NMR) and phosphorous-31 NMR, and elemental analysis. DOPO-T was then blended with diglycidyl ether of bisphenol-A to prepare flame-retardant epoxy resins. Thermal properties, flame retardancy, and combustion behavior of the cured epoxy resins were evaluated by differential scanning calorimetry, thermogravimetric analysis, limited oxygen index (LOI) measurement, UL94 vertical burning test, and cone calorimeter test. The results indicated that the glass transition temperature ( Tg) and temperature at 5% weight loss of epoxy resin (EP)/DOPO-T thermosets were gradually decreased with the increasing content of DOPO-T. DOPO-T catalyzed the decomposition of EP matrix in advance. The flame-retardant performance of EP thermosets was significantly enhanced with the addition of DOPO-T. EP/DOPO-T-0.9 sample had an LOI value of 36.2% and achieved UL94 V-1 rating. In addition, the average of heat release rate, peak of heat release rate, average of effective heat of combustion, and total heat release (THR) of EP/DOPO-T-0.9 sample were decreased by 32%, 48%, 23%, and 31%, respectively, compared with the neat EP sample. Impressively, EP/DOPO-T thermosets acquired excellent flame retardancy under low loading of flame retardant.

Numerical Simulation on Spreading Characteristic of Coach Fire

2012 ◽  
Vol 518-523 ◽  
pp. 1269-1272 ◽  
Author(s):  
Liang Yi ◽  
Jie Chen
Keyword(s):  
Fluid Dynamics ◽  
Numerical Simulation ◽  
Computational Fluid Dynamics ◽  
Heat Release ◽  
Heat Release Rate ◽  
Fire Protection ◽  
Release Rate ◽  
Software Package ◽  
Maximum Temperature ◽  
Peak Heat Release Rate

The aim of this work is to study the burning characteristics of coach fire. With application of computational fluid dynamics (FDS software package), coach fires caused by arson are simulated under different ventilation conditions. Variation of heat release rate (HRR) and distribution of temperature are analyzed. Peak heat release rate of coach fire caused by arson in passenger carriage can reach about 24 MW and maximum temperature in the carriage is over 1000 °C. Results of this study can be referred for fire protection and rescue design of coach.

scholarly journals The formation of charcoal reflectance and its potential use in post-fire assessments

2016 ◽  
Vol 25 (7) ◽  
pp. 775 ◽  
Author(s):  
Claire M. Belcher ◽  
Victoria A. Hudspith
Keyword(s):  
Heat Release ◽  
Release Rate ◽  
Cone Calorimeter ◽  
Fire Severity ◽  
Combustion Process ◽  
Peak Heat Release Rate ◽  
Fire Front ◽  
Char Oxidation ◽  
Reflectance Microscopy ◽  
Potential Use

Charcoal has an exceptional ability to reflect light when viewed using reflectance microscopy. The amount of light reflected is variable depending on the differential ordering of graphite-like phases within the charcoal itself. It has been suggested that this relates to the temperature of formation, whereby higher formation temperatures result in high charcoal reflectance. However, this explanation is derived from oven-based chars that do not well represent the natural combustion process. Here, we have experimentally created charcoals using a cone calorimeter, in order to explore the development of charcoal reflectance during pre-ignition heating and peak heat-release rate, through to the end of flaming and the transition to char oxidation. We find that maximum charcoal reflectance is reached at the transition between pyrolysis and char oxidation, before its conversion to mineral ash, and indicates that our existing understanding of reflectance is in error. We suggest that charcoal reflectance warrants additional study as it may provide a useful quantitative addition to ground-based fire severity surveys, because it may allow exploration of surface heating after the main fire front has passed and the fire transitions to smouldering phases.

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