Polyzwitterionic aqueous solutions – a new class of electrorheological fluids
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AbstractIt has been established that the electroviscosity effect of polyzwitterionic (PZI) aqueous solutions is more considerable than and acts in a direction opposite to that of aqueous polyelectrolyte solutions. Temperature and electric field strength influence the electroviscosity of PZI aqueous solutions in parallel, though the reasons for these effects are quite different. The unusual electroviscosity behaviour of PZI solutions is explained by a ‘core-shell’ model for the structural organization of PZI macromolecules, suggesting that cluster formation is due to intensive dipoledipole interactions between monomer units of the same or of different macromolecules.
2009 ◽
Vol 87-88
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pp. 143-148
2010 ◽
Vol 129-131
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pp. 421-425
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2001 ◽
Vol 15
(06n07)
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pp. 695-703
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2015 ◽
Vol 26
(14)
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pp. 1776-1781
1988 ◽
Vol 92
(17)
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pp. 4994-5001
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2016 ◽
Vol 136
(10)
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pp. 1420-1421
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