scholarly journals The genesis model of carbonate cementation in the tight oil reservoir: A case of Chang 6 oil layers of the Upper Triassic Yanchang Formation in the western Jiyuan area, Ordos Basin, China

2020 ◽  
Vol 12 (1) ◽  
pp. 1105-1115
Author(s):  
Shutong Li ◽  
Shixiang Li ◽  
Xinping Zhou ◽  
Xiaofeng Ma ◽  
Ruiliang Guo ◽  
...  
Keyword(s):  
Profile Analysis ◽  
Sedimentary Environment ◽  
Ordos Basin ◽  
Isotope Analysis ◽  
Thin Sections ◽  
Carbonate Cements ◽  
Carbon And Oxygen Isotope ◽  
Calcite Veins ◽  
Calcium Source ◽  
Carbonate Cementation

AbstractCarbonate cementation is one of the significant tightness factors in Chang 6 reservoir of the western Jiyuan (WJY) area. Based on the observation of core and thin sections, connecting-well profile analysis as well as carbon and oxygen isotope analysis, it is found that ferrocalcite is the main carbonate cements in the Chang 6 reservoir of the WJY area. The single sand body controls the development of carbonate cements macroscopically. Both carbonate cements and calcite veins hold similar diagenetic conditions: the dissolution of plagioclase is the main calcium source and the de-acidification of organic acids is the main carbon source. The diagenetic stage is identified as the mesogenetic A stage. The sedimentary environment is of low salinity. Accordingly, the development model of carbonate cementation in Chang 6 reservoir is summarized into three types: “eggshell pattern,” “cutting pattern,” and “favorable reservoir pattern.” The development degree of carbonate cementation affects the physical properties of reservoir.

Carbon-oxygen isotope analysis of fault rocks in carbonates from different orogenic cycles in the Cantabrian Zone (N Spain): similarities and differences

2021 ◽  
Author(s):  
Sergio Llana-Funez ◽  
Manuel Ignacio de Paz-Álvarez ◽  
Marco Antonio Lopez-Sanchez ◽  
Stefano M. Bernasconi ◽  
Juan Luis Alonso ◽  
...  
Keyword(s):  
Oxygen Isotope ◽  
Isotope Composition ◽  
Isotope Analysis ◽  
Fault Rocks ◽  
Cantabrian Zone ◽  
Geological Processes ◽  
Carbon And Oxygen Isotope ◽  
Calcite Veins ◽  
The Matrix ◽  
Thrust Sheets

<p>The isotopic carbon and oxygen isotope composition of carbonates (δ<sup>13</sup>C and δ<sup>18</sup>O), determined by temperature and the relative abundances of stable isotopes of both elements in water at the time the carbonate is precipitated, can be modified subsequently during geological processes that involve the recrystallization of carbonate. Temperature changes mostly affect δ<sup>18</sup>O, while additional sources of carbon have a greater impact on δ<sup>13</sup>C. Amongst the various processes that may alter the original isotopic signature of carbonate rocks are deformation processes, which can lead the dissolution and reprecipitation of carbonates during deformation, or the involvement of fluids of various origin during younger tectonic events.</p><p>Here, we present the results of isotope analysis in fault rocks from two distinct faults in the Cantabrian Zone (CZ) in northern Spain. It represents the foreland fold and thrust belt of the Variscan orogen in Iberia and is characterized by numerous and large thrust sheets that were emplaced during the Carboniferous. Subsequent rifting episodes in the Mesozoic and more recently Alpine North-South convergence produced the overprinting of some of the earlier Variscan structures. In all cases, brittle processes produced often similar-looking rocks as the fracturing occurred under upper crustal conditions, relatively close to the surface. Fluids involved during deformation on both cycles are likely to differ, so to evaluate alternative tools to distinguish the different cycles of fracturing in carbonates, a stable isotope analysis on carbon and oxygen was undertaken in two well-known structures in the region: the Somiedo nappe and the Ventaniella fault.</p><p>The Somiedo nappe is one of the largest thrust sheets in the Cantabrian Zone, with an estimated offset close to 20 km. The base of the thrust sheet is characterized by well-developed cataclasites and ultracataclasites that formed on Cambrian fine-grained dolostones. It has relatively minor vein activity associated, although the dolostones have been partially recrystallized. The Ventaniella fault is a dextral strike-slip structure cutting obliquely the Cantabrian Mountains. It runs for tens of kilometres inland and has an estimated offset of approximately 5 km. The fault zone in the studied area is characterized by the fracturing and dextral offset of Carboniferous micritic limestones and, more importantly, a relatively strong vein activity that formed a distributed network of calcite veins.</p><p>Cataclasite matrix and fragments, and associated veins were sampled for isotope analysis in the two fault zones. In both cases, the matrix has a signature which is intermediate between the undeformed rock and that of the veins. The fragments have a signature which is indistinguishable from the matrix, suggesting the reworking of the fault rock. The veins have a distinct pattern in both faults, but different from each other. Those related to the Ventaniella fault are mostly hydrothermal, with limited range in δ<sup>18</sup>O and δ<sup>13</sup>C, while the veins from the base of the Somiedo nappe have a larger range of δ<sup>13</sup>C, but limited δ<sup>18</sup>O variation.</p>

scholarly journals Characteristics of Mineralogy, Lithofacies of Fine-Grained Sediments and Their Relationship with Sedimentary Environment: Example from the Upper Permian Longtan Formation in the Sichuan Basin

Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3662
Author(s):  
Hongzhi Yang ◽  
Liangbiao Lin ◽  
Liqing Chen ◽  
Yu Yu ◽  
Du Li ◽  
...  
Keyword(s):  
Mineral Composition ◽  
Sichuan Basin ◽  
Sedimentary Environment ◽  
Organic Matter Content ◽  
Upper Permian ◽  
Carbonaceous Shale ◽  
Carbonate Minerals ◽  
Thin Sections ◽  
Terrestrial Input ◽  
The Sichuan Basin

The Longtan Formation of the Upper Permian in the Sichuan Basin has become a significant target for shale gas exploration in recent years. Multiple methods, including outcrop observations, thin sections, total organic matter content, X-ray diffraction and scanning electron microscopy were used to investigate the mineralogy, shale lithofacies assemblages and their relationships with the deposition environment. The mineral composition of the Longtan Formation has strong mineral heterogeneity. The TOC values of the Longtan Formation have a wide distribution range from 0.07% to 74.67% with an average value of 5.73%. Four types of shale lithofacies assemblages of the Longtan Formation could be distinguished, as clayey mudstone (CLS), carbonaceous shale (CAS), siliceous shale (SS) and mixed shale (MS) on the basis of mineral compositions. The TOC values of various types of shale lithofacies assemblages in the Longtan Formation varied widely. The shore swamp of the Longtan Formation is most influenced by the terrestrial input and mainly develops CLS and MS. The tidal flat is influenced by the terrestrial input and can also deposit carbonate minerals, developing CLS, CAS and MS. The shallow water melanged accumulation shelf develops CAS and MS, dominated by clay and carbonate minerals. The deep water miscible shelf develops CLS and SS, whose mineral composition is similar to that of the shore swamp, but the quartz minerals are mainly formed by chemical and biological reactions, which are related to the Permian global chert event. The depositional environment of the Longtan Formation controls the shale mineral assemblage of the Longtan Formation and also influences the TOC content.

scholarly journals Microscale Pore Throat Differentiation and Its Influence on the Distribution of Movable Fluid in Tight Sandstone Reservoirs

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-7
Author(s):  
Fengjuan Dong ◽  
Xuefei Lu ◽  
Yuan Cao ◽  
Xinjiu Rao ◽  
Zeyong Sun
Keyword(s):  
Ordos Basin ◽  
Pore Throat ◽  
Tight Sandstone ◽  
Throat Radius ◽  
Thin Sections ◽  
Small Pore ◽  
Sandstone Reservoir ◽  
Sandstone Reservoirs ◽  
Classification Evaluation ◽  
Better Than

Tight sandstone reservoirs have small pore throat sizes and complex pore structures. Taking the Chang 6 tight sandstone reservoir in the Huaqing area of the Ordos Basin as an example, based on casting thin sections, nuclear magnetic resonance experiments, and modal analysis of pore size distribution characteristics, the Chang 6 tight sandstone reservoir in the study area can be divided into two types: wide bimodal mode reservoirs and asymmetric bimodal mode reservoirs. Based on the information entropy theory, the concept of “the entropy of microscale pore throats” is proposed to characterize the microscale pore throat differentiation of different reservoirs, and its influence on the distribution of movable fluid is discussed. There were significant differences in the entropy of the pore throat radius at different scales, which were mainly shown as follows: the entropy of the pore throat radius of 0.01~0.1 μm, >0.1 μm, and <0.01 μm decreased successively; that is, the complexity of the pore throat structure decreased successively. The correlation between the number of movable fluid occurrences on different scales of pore throats and the entropy of microscale pore throats in different reservoirs is also different, which is mainly shown as follows: in the intervals of >0.1 μm and 0.01~0.1 μm, the positive correlation between the occurrence quantity of movable fluid in the wide bimodal mode reservoir is better than that in the asymmetric bimodal mode reservoir. However, there was a negative correlation between the entropy of the pore throat radius and the number of fluid occurrences in the two types of reservoirs in the pore throat radius of <0.01 μm. Therefore, pore throats of >0.1 μm and 0.01~0.1 μm play a controlling role in studying the complexity of the microscopic pore throat structure and the distribution of movable fluid in the Chang 6 tight sandstone reservoir. The above results deepen the understanding of the pore throat structure of tight sandstone reservoirs and present guiding significance for classification evaluation, quantitative characterization, and efficient development of tight sandstone reservoirs.

scholarly journals LA-ICP-MS U-Pb dating and geochemical characterization of oil inclusion-bearing calcite cements: Constraints on primary oil migration in lacustrine mudstone source rocks

2021 ◽  
Author(s):  
Ao Su ◽  
Honghan Chen ◽  
Yue-xing Feng ◽  
Jian-xin Zhao
Keyword(s):  
Fluid Inclusion ◽  
Inductively Coupled Plasma ◽  
Homogenization Temperature ◽  
Source Rocks ◽  
Oil Migration ◽  
Carbon And Oxygen Isotope ◽  
Fluorescence Characteristics ◽  
Calcite Veins ◽  
Migration Event

To date, few isotope age constraints on primary oil migration have been reported. Here we present U-Pb dating and characterization of two fracture-filling, oil inclusion-bearing calcite veins hosted in the Paleocene siliciclastic mudstone source rocks in Subei Basin, China. Deposition age of the mudstone formation was estimated to be ca. 60.2−58.0 Ma. The first vein consists of two major phases: a microcrystalline-granular (MG) calcite phase, and a blocky calcite phase, each showing distinctive petrographic features, rare earth element patterns, and carbon and oxygen isotope compositions. The early MG phase resulted from local mobilization of host carbonates, likely associated with disequilibrium compaction over-pressuring or tectonic extension, whereas the late-filling blocky calcite phase was derived from overpressured oil-bearing fluids with enhanced fluid-rock interactions. Vein texture and fluorescence characteristics reveal at least two oil expulsion events, the former represented by multiple bitumen veinlets postdating the MG calcite generation, and the latter marked by blue-fluorescing primary oil inclusions synchronous with the blocky calcite cementation. The MG calcite yields a laser ablation−inductively coupled plasma−mass spectrometry U-Pb age of 55.6 ± 1.4 Ma, constraining the earliest timing of the early oil migration event. The blocky calcite gives a younger U-Pb age of 47.8 ± 2.3 Ma, analytically indistinguishable from the U-Pb age of 46.5 ± 1.7 Ma yielded by the second calcite vein. These two ages define the time of the late oil migration event, agreeing well with the age estimate of 49.7−45.2 Ma inferred from fluid-inclusion homogenization temperature and published burial models. Thermodynamic modeling shows that the oil inclusions were trapped at ∼27.0−40.9 MPa, exceeding corresponding hydrostatic pressures (23.1−26.7 MPa), confirming mild-moderate overpressure created by oil generation-expulsion. This integrated study combining carbonate U-Pb dating and fluid-inclusion characterization provides a new approach for reconstructing pressure-temperature-composition-time points in petroleum systems.

Thermal and hydrocarbon-charge history and the relationship between diagenesis and reservoir connectivity: Venture field, offshore Nova Scotia, eastern Canada1Geological Survey of Canada Contribution 20100418.

2011 ◽  
Vol 48 (9) ◽  
pp. 1293-1306 ◽  
Author(s):  
Atika Karim ◽  
Georgia Pe-Piper ◽  
David J.W. Piper ◽  
Jacob J. Hanley
Keyword(s):  
Nova Scotia ◽  
Fluid Inclusions ◽  
Upper Jurassic ◽  
Gas Reservoirs ◽  
Carbonate Cements ◽  
Migration History ◽  
Carbonate Cementation ◽  
Homogenization Temperatures ◽  
Hydrocarbon Charge ◽  
Reservoir Connectivity

Fluid inclusions in diagenetic cements in Upper Jurassic – Lower Cretaceous sandstones offshore Nova Scotia provide constraints on the fluid migration history in gas reservoirs of the Scotian basin. Diagenetic minerals from six wells in the Venture field were analysed by optical petrography, scanning electron microscopy (SEM), and electron microprobe. A total of 122 primary and secondary fluid inclusions were analysed from different cements. Primary aqueous inclusions in quartz overgrowths have homogenization temperatures (Th) of 111.8 ± 7.1 °C (1σ) and in later carbonate cements 126.5 ± 2.1 °C; inclusions in both cements are highly saline (16–26.1 wt.% NaCl equivalent). Secondary aqueous and hydrocarbon-bearing inclusion trails crosscutting silica cement and detrital quartz have Th of 121.6 ± 13.6 °C and low salinities (8.7 ± 6.0 wt.%). Secondary carbonic inclusions have CO2 melting temperatures (–56.6 ± 0.1 °C) and Th (–9.3 ± 0.8 °C) indicating a high-density carbonic phase. Late carbonate cements in the same sandstone units vary in chemical composition in different wells, and connected reservoirs show similar late carbonate assemblages, suggesting that the late carbonate cementation may be partly controlled by the reservoir fill and spill sequence. Silica and late carbonate cementation involved highly saline fluid flow, likely at about ∼135 Ma. Hydrocarbon migration postdated silica cementation and was associated with secondary fracturing, suggesting that it corresponded to the onset of overpressure.

scholarly journals Sampling and Pretreatment of Tooth Enamel Carbonate for Stable Carbon and Oxygen Isotope Analysis

10.3791/58002 ◽  
2018 ◽  
Author(s):  
Alicia Ventresca Miller ◽  
Ricardo Fernandes ◽  
Anneke Janzen ◽  
Ayushi Nayak ◽  
Jillian Swift ◽  
...  
Keyword(s):  
Oxygen Isotope ◽  
Tooth Enamel ◽  
Isotope Analysis ◽  
Stable Carbon ◽  
Carbon And Oxygen Isotope

Global carbon isotope signal in the Middle Triassic on Svalbard

2021 ◽  
Author(s):  
Victoria S. Engelschiøn ◽  
Øyvind Hammer ◽  
Fredrik Wesenlund ◽  
Jørn H. Hurum ◽  
Atle Mørk
Keyword(s):  
Carbon Isotope ◽  
Depositional Environment ◽  
Middle Triassic ◽  
Barents Sea ◽  
Water Productivity ◽  
Sedimentary Environment ◽  
The Arctic ◽  
Late Triassic ◽  
Triassic Boundary ◽  
Thin Sections

&lt;p&gt;Several carbon isotope curves were recently published for the Early and Middle Triassic in Tethys. Recent work has also been done on the Early Triassic of Svalbard, but not yet for the Middle Triassic. This work is the first to measure &amp;#948;&lt;sup&gt;13&lt;/sup&gt;C for different Middle Triassic localities on Svalbard, which was then part of the Boreal Ocean on northern Pangea. Our aim is to understand the controls on the Svalbard carbon isotope curve and to place them in a global setting.&lt;/p&gt;&lt;p&gt;Correlating Triassic rocks around the world is interesting for several reasons. The Triassic Period was a tumultuous time for life, and the Arctic archipelago of Svalbard has shown to be an important locality to understand the early radiation of marine vertebrates in the Triassic. Much effort is also made to understand the development of the Barents Sea through Svalbard&amp;#8217;s geology.&lt;/p&gt;&lt;p&gt;Carbon isotope curves are controlled by depositional environment and global fluctuations. Global factors such as the carbon cycle control the long-term carbon isotopic compositions, while short-term fluctuations may reflect the origin of organic materials in the sediment (e.g. algal or terrestrial matter), stratification of the water column, and/or surface water productivity. Carbon isotopes can therefore be useful to understand the depositional environment and to correlate time-equivalent rocks globally.&lt;/p&gt;&lt;p&gt;The dataset was collected through three seasons of fieldwork in Svalbard with localities from the islands Spitsbergen, Edge&amp;#248;ya and Bj&amp;#248;rn&amp;#248;ya. Detailed stratigraphic sampling has resulted in high-resolution &amp;#948;&lt;sup&gt;13&lt;/sup&gt;C curves. These show three strong transitions; 1) on the boundary between the Early and Middle Triassic, 2) in the middle of the formation and 3) at the Middle and Late Triassic boundary. Several Tethyan localities show a possibly similar Early-Middle Triassic signal. Current work in progress is sedimentological analysis by thin sections and X-ray fluorescence spectroscopy (XRF) to further understand the sedimentary environment.&lt;/p&gt;

Formation of wide-blocky calcite veins by extreme growth competition

2020 ◽  
pp. jgs2020-104
Author(s):  
Liene Spruženiece ◽  
Michael Späth ◽  
Janos L. Urai ◽  
Estibalitz Ukar ◽  
Michael Selzer ◽  
...  
Keyword(s):  
High Resolution ◽  
Growth Rates ◽  
Polarized Light ◽  
Wall Rock ◽  
Scattered Electron ◽  
Thin Sections ◽  
Content Type ◽  
Calcite Veins ◽  
Supplementary Material ◽  
Electron Back Scattered Diffraction

Liassic limestones on the coast of Somerset in the UK contain dense arrays of calcite microveins with a common, but poorly understood microstructure, characterized by laterally wide crystals that form bridges across the vein. We investigated the mechanisms of formation and evolution of these ‘wide-blocky’ vein microstructures using a combination of high-resolution analytical methods, including virtual petrography, optical cathodoluminescence and scanning electron microscopy techniques (e.g. energy-dispersive X-ray spectrometry, back-scattered electron imaging, cathodoluminescence and electron back-scattered diffraction), laboratory experiments and multiphase field modelling. Our results indicate that the studied veins formed in open, fluid-filled fractures, each in a single opening and sealing episode. As shown by the optical and electron back-scattered diffraction images, the vein crystals grew epitaxially on grains of the wall rock and we hypothesize that their growth rates differed depending on whether the crystals were on a wall rock grain substrate that fractured intergranularly (slow growth rates) or transgranularly (rapid growth rates). Our multiphase field models support this hypothesis, showing that wide, blocky crystals only form where there are significant differences in the growth rate and are dependent on the type of seed grain. These results provide strong evidence for extreme growth competition, a process that we propose controls vein-filling in many micritic carbonate reservoirs, as well as demonstrate that the characteristics of the fracture wall can affect the filling processes in syntaxial veins.Supplementary material: The description and images of the studied thin sections are available at https://doi.org/10.6084/m9.figshare.c.5172371. High-resolution optical microscopy mosaics (under plane-polarized- and crossed polarized light) of the thin section collection in PetroScan file format are available on request from the authors.

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