scholarly journals Peculiarities of doping of ZnO:Mn nanocrystals during their synthesis by the aerosol pyrolysis method

2020 ◽  
Vol 28 (2) ◽  
pp. 91-94
Author(s):  
O. V. Kovalenko ◽  
V. Yu. Vorovsky ◽  
O. V. Khmelenko ◽  
Ye. G. Plakhtii
Keyword(s):  
Heat Treatment ◽  
Surface Layer ◽  
Aqueous Solutions ◽  
Manganese Oxides ◽  
Near Surface ◽  
Zno Nanocrystals ◽  
Pyrolysis Method ◽  
C Decomposition ◽  
Mn Concentrations

Samples of ZnO:Mn nanocrystals with Mn concentrations of 2 and 4 at.% were synthesized by ultrasonic aerosol pyrolysis. The synthesis was carried out at 550°C using aqueous solutions of zinc and manganese nitrates. The samples obtained were subjected to heat treatment at 550°C and 850°C in air for 1 hour. The study of the samples by XRD and EPR methods shows that during the synthesis the process of doping ZnO nanocrystals with manganese occurs only partially, on the surface, in the near-surface layer. Residues of the Mn impurity are located on the surface of nanocrystals and appear during annealing at 550°С in the form of manganese oxides (Mn2O3). During heat treatment at 850°C, decomposition of Mn2O3 and bulk doping of ZnO:Mn nanocrystals occur.

scholarly journals The Effect of Heat Treatment on the Microstructure and Mechanical Properties of 2D Nanostructured Au/NiFe System

Nanomaterials ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 1077 ◽  
Author(s):  
Tatiana Zubar ◽  
Valery Fedosyuk ◽  
Daria Tishkevich ◽  
Oleg Kanafyev ◽  
Ksenia Astapovich ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Surface Layer ◽  
Near Surface ◽  
Force Microscopy ◽  
Thermally Activated ◽  
Atomic Force ◽  
Microstructure And Mechanical Properties ◽  
Internal Volume ◽  
Increasing Temperature

Nanostructured NiFe film was obtained on silicon with a thin gold sublayer via pulsed electrodeposition and annealed at a temperature from 100 to 400 °C in order to study the effect of heat treatment on the surface microstructure and mechanical properties. High-resolution atomic force microscopy made it possible to trace stepwise evolving microstructure under the influence of heat treatment. It was found that NiFe film grains undergo coalescence twice—at ~100 and ~300 °C—in the process of a gradual increase in grain size. The mechanical properties of the Au/NiFe nanostructured system have been investigated by nanoindentation at two various indentation depths, 10 and 50 nm. The results showed the opposite effect of heat treatment on the mechanical properties in the near-surface layer and in the material volume. Surface homogenization in combination with oxidation activation leads to abnormal strengthening and hardening-up of the near-surface layer. At the same time, a nonlinear decrease in hardness and Young’s modulus with increasing temperature of heat treatment characterizes the internal volume of nanostructured NiFe. An explanation of this phenomenon was found in the complex effect of changing the ratio of grain volume/grain boundaries and increasing the concentration of thermally activated diffuse gold atoms from the sublayer to the NiFe film.

Recombination Characteristics of Single-Crystalline Silicon Wafers with a Damaged Near-Surface Layer

2013 ◽  
Vol 58 (2) ◽  
pp. 142-150 ◽  
Author(s):  
A.V. Sachenko ◽  
◽  
V.P. Kostylev ◽  
V.G. Litovchenko ◽  
V.G. Popov ◽  
...  
Keyword(s):  
Surface Layer ◽  
Crystalline Silicon ◽  
Silicon Wafers ◽  
Single Crystalline Silicon ◽  
Near Surface ◽  
Single Crystalline

Single-layer submicron-thick BaTiO3 coatings from poly(vinylpyrrolidone)-containing sols: Gel-to-ceramic film conversion, densification, and dielectric properties

2001 ◽  
Vol 16 (11) ◽  
pp. 3116-3123 ◽  
Author(s):  
Hiromitsu Kozuka ◽  
Atsushi Higuchi
Keyword(s):  
Heat Treatment ◽  
Condensation Reaction ◽  
Single Layer ◽  
Dip Coating ◽  
Single Step ◽  
Dielectric Constants ◽  
Isothermal Heat Treatment ◽  
Coating Films ◽  
Ceramic Film ◽  
C Decomposition

BaTiO3-coating films were prepared from a solution containing poly(vinylpyrrolidone) (PVP) of molar composition Ba(CH3COO)2:Ti(OC2H5)4:PVP:CH3COOH:H2O: C2H5OH = 1:1:0.5:27:4:5, via nonrepetitive, single-step dip-coating. The gel films were found to be converted into BaTiO3 films via evaporation of the solvent and CH3COOH below 210 °C, decomposition of PVP at 210–360 °C, decomposition of CH3COO− below 440 °C, and crystallization at 500–610 °C. The decomposition of PVP was accompanied by the progress of the condensation reaction, which resulted in significant reduction in film thickness. When the gel films were heated isothermally at 700 °C, crack-free BaTiO3 films as thick as 0.9 μm were obtained. When the gel films were heated isothermally at 360 °C and then at 700 °C, the film became denser. Higher dielectric constants around 290 were found for the film that underwent the isothermal heat treatment at 360 °C. A slower rate of PVP decomposition was thought to be the key for the film densification.

scholarly journals Enhanced Diffusion of Dopants in Vacancy Supersaturation Produced by MeV Implantation

1997 ◽  
Vol 469 ◽  
Author(s):  
V. C. Venezia ◽  
T. E. Haynes ◽  
A. Agarwal ◽  
H. -J. Gossmann ◽  
D. J. Eaglesham
Keyword(s):  
Surface Layer ◽  
Surface Region ◽  
Silicon On Insulator ◽  
Rich Region ◽  
Near Surface ◽  
Enhanced Diffusion ◽  
Float Zone ◽  
Transient Enhanced Diffusion

ABSTRACTThe diffusion of Sb and B markers has been studied in vacancy supersaturations produced by MeV Si implantation in float zone (FZ) silicon and bonded etch-back silicon-on-insulator (BESOI) substrates. MeV Si implantation produces a vacancy supersaturated near-surface region and an interstitial-rich region at the projected ion range. Transient enhanced diffusion (TED) of Sb in the near surface layer was observed as a result of a 2 MeV Si+, 1×1016/cm2, implant. A 4× larger TED of Sb was observed in BESOI than in FZ silicon, demonstrating that the vacancy supersaturation persists longer in BESOI than in FZ. B markers in samples with MeV Si implant showed a factor of 10× smaller diffusion relative to markers without the MeV Si+ implant. This data demonstrates that a 2 MeV Si+ implant injects vacancies into the near surface region.

Physical properties and spatial distribution of the sea ice surface layer (SSL/snow) during the autumn phase of the MOSAiC expedition

2021 ◽  
Author(s):  
Ruzica Dadic ◽  
Martin Schneebeli ◽  
Henna-Reeta Hannula ◽  
Amy Macfarlane ◽  
Roberta Pirazzini
Keyword(s):  
Surface Layer ◽  
Spatial Distribution ◽  
Sea Ice ◽  
Physical Properties ◽  
Surface Scattering ◽  
Climate Feedback ◽  
Energy Fluxes ◽  
Scattering Layer ◽  
Near Surface ◽  
Ice Surface

<p>Snow cover dominates the thermal and optical properties of sea ice and the energy fluxes between the ocean and the atmosphere, yet data on the physical properties of snow and its effects on sea ice are limited. This lack of data leads to two significant problems: 1) significant biases in model representations of the sea ice cover and the processes that drive it, and 2) large uncertainties in how sea ice influences the global energy budget and the coupling of climate feedback. The  MOSAiC research initiative enabled the most extensive data collection of snow and surface scattering layer (SSL) properties over sea ice to date. During leg 5 of the MOSAiC expedition, we collected multi-scale (microscale to 100-m scale) measurements of the surface layer (snow/SSL) over first year ice (FYI) and MYI on a daily basis. The ultimate goal of our measurements is to determine the spatial distribution of physical properties of the surface layer. During leg 5 of the MOSAiC expedition, that surface layer changed from the  surface scattering layer (SSL),   characteristic for the melt season, to an early autumn snow pack. Here,  we will present data showing both a) the physical properties and the spatial distribution of the SSL during the late melt season and b) the transition of the sea ice surface from the SSL to the fresh autumn snowpack. The structural properties of this transition period are poorly documented, and this season is critical  for the initialization of sea ice and snow models. Furthermore, these data are crucial to interpret simultaneous observations of surface energy fluxes, surface optical and remote sensing data (microwave signals in particular), near-surface biochemical activity, and to understand the sea ice  processes that occur as the sea ice transitions from melting to freezing.</p>

Deepening of domains at e-beam writing on the -Z surface of lithium niobate

2021 ◽  
Author(s):  
Lyudmila Kokhanchik ◽  
Evgenii Emelin ◽  
Vadim Vladimirovch Sirotkin ◽  
Alexander Svintsov
Keyword(s):  
Surface Layer ◽  
Electron Beam ◽  
Lithium Niobate ◽  
Electric Field ◽  
Domain Walls ◽  
Normal Component ◽  
Beam Current ◽  
Near Surface ◽  
Domain Structures ◽  
Sign Inversion

Abstract The focus of the study was to investigate the peculiarities of the domains created by electron beam (e-beam) in a surface layer of congruent lithium niobate, which comparable to a depth of electron beam charge penetration. Direct e-beam writing (DEBW) of different domain structures with a scanning electron microscope was performed on the polar -Z cut. Accelerating voltage 15 kV and e-beam current 100 pA were applied. Different patterns of local irradiated squares were used to create domain structures and single domains. No domain contrast was observed by the PFM technique. Based on chemical etching, it was found that the vertices of the domains created do not reach the surface level. The average deepening of the domain vertices was several hundred nanometers and varied depending on the irradiation dose and the location of the irradiated areas (squares) relative to each other. Computer simulation was applied to analyze the spatial distribution of the electric field in the various irradiated patterns. The deepening was explained by the fact that in the near-surface layer there is a sign inversion of the normal component of the electric field strength vector, which controls the domain formation during DEBW. Thus, with the help of e-beam, domains were created completely located in the bulk, in contrast to the domains that are nucleated on the surface of the -Z cut during the polarization inversion with AFM tip. The detected deepening of e-beam domains suggests the possibility of creating the “head-to-head” domain walls in the near-surface layer lithium niobate by DEBW.

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