scholarly journals Occurrence of chloritoid-bearing metapelitic rocks and their significance in the metamorphism of the Silgará Formation at the Central Santander Massif

2016 ◽  
pp. 5-15 ◽  
Author(s):  
Oscar Mauricio Castellanos-Alarcón ◽  
Carlos Alberto Ríos-Reyes ◽  
Carlos Alberto García-Ramírez

We report here for the first time the occurrence of chloritoid in Mg-Al-rich metapelitic rocks of the Silgará Formation at the Central Santander Massif, which was metamorphosed up to the amphibolite facies. These rocks contain an unusual mineral assemblage such as quartz + biotite + muscovite + garnet + staurolite ± kyanite ± chloritoid, with minor plagioclase and K-feldspar, and Fe-Ti oxides as the main accessory phases. Associated carbonate rocks containing the mineral assemblage tremolite + calcite. Chloritoid occurs as porphyroblastic tablets in graphite-bearing metapelitic schists highly tectonized that can be associated to the influence of the major tectonic structures in the study area. The occurrence of chloritoid as an index mineral in metapelitic rocks of the Silgará Formation is attributed to a thermal event (associated to the emplacement of small granitic masses) overimposed on the regional metamorphism.

2000 ◽  
Vol 64 (4) ◽  
pp. 737-753 ◽  
Author(s):  
Y. Ahmed-Said ◽  
P. W. G. Tanner

AbstractThe 590±2 Ma Ben Vuirich Granite was intruded into late Proterozoic Dalradian rocks prior to the Grampian orogeny, during which it was affected by upper amphibolite facies regional metamorphism. Spotted cordierite and andalusite (chiastolite) hornfelses at the granite margin were altered to kyanite-and garnet-bearing assemblages during regional metamorphism. From the inferred mineralogy of the hornfels, together with the normative Qz–Ab–Or values of the granite and the application of a simple cooling model, we conclude that the country rocks immediately adjacent to the granite were hornfelsed at T = ∼600°C and P ≤ 2 kbar.The hornfelsed rocks were subsequently metamorphosed during the regional D2 event to form an equilibrium mineral assemblage of muscovite + biotite + garnet + plagioclase + quartz + kyanite (after chiastolite). Garnet which grew during this event shows unusual reversed chemical zoning, with Ca increasing systematically from core to rim as Fe, Mg and Mn decrease. A study of element partitioning between coexisting phases in equilibrium (including zoned garnets), and use of an internally consistent thermodynamic dataset, suggest that isothermal (T = 577±42°C) compression (from P = 6.2±1.6 kbar to 9.0±1.9 kbar) occurred during crustal thickening. K-feldspar-plagioclase-quartz veinlets found in the hornfels close the granite contact are demonstrated to be of igneous origin.


Author(s):  
S. Aspiotis ◽  
S. Jung ◽  
F. Hauff ◽  
R. L. Romer

AbstractThe late-tectonic 511.4 ± 0.6 Ma-old Nomatsaus intrusion (Donkerhoek batholith, Damara orogen, Namibia) consists of moderately peraluminous, magnesian, calc-alkalic to calcic granites similar to I-type granites worldwide. Major and trace-element variations and LREE and HREE concentrations in evolved rocks imply that the fractionated mineral assemblage includes biotite, Fe–Ti oxides, zircon, plagioclase and monazite. Increasing K2O abundance with increasing SiO2 suggests accumulation of K-feldspar; compatible with a small positive Eu anomaly in the most evolved rocks. In comparison with experimental data, the Nomatsaus granite was likely generated from meta-igneous sources of possibly dacitic composition that melted under water-undersaturated conditions (X H2O: 0.25–0.50) and at temperatures between 800 and 850 °C, compatible with the zircon and monazite saturation temperatures of 812 and 852 °C, respectively. The Nomatsaus granite has moderately radiogenic initial 87Sr/86Sr ratios (0.7067–0.7082), relatively radiogenic initial εNd values (− 2.9 to − 4.8) and moderately evolved Pb isotope ratios. Although initial Sr and Nd isotopic compositions of the granite do not vary with SiO2 or MgO contents, fSm/Nd and initial εNd values are negatively correlated indicating limited assimilation of crustal components during monazite-dominated fractional crystallization. The preferred petrogenetic model for the generation of the Nomatsaus granite involves a continent–continent collisional setting with stacking of crustal slices that in combination with high radioactive heat production rates heated the thickened crust, leading to the medium-P/high-T environment characteristic of the southern Central Zone of the Damara orogen. Such a setting promoted partial melting of metasedimentary sources during the initial stages of crustal heating, followed by the partial melting of meta-igneous rocks at mid-crustal levels at higher P–T conditions and relatively late in the orogenic evolution.


2021 ◽  
Author(s):  
Yakov Dzhalatyan ◽  
Mikhail Charupa ◽  
Aydar Galiev ◽  
Yevgeniy Karpekin ◽  
Sergey Egorov ◽  
...  

Abstract In the presented paper, the object of the study are carbonate rocks of the Riphean and clastic-carbonate rocks of Vendian-Cambrian ages, uncovered by the well drilled at Yurubcheno-Tokhomskoye field. These reservoirs are characterized by extremely low porosity (1-4%) and determining saturation nature and fluid contacts cannot be reliably solved by conventional wireline petrophysical logging. Solutions to these problems are provided by interval testing using wireline formation evaluation testing tool (WFT). However, to obtain quality results from WFT testing it is important to identify porous intervals first by using advanced wireline logging services which are sensitive to porosity and fractures. In order to select the optimal WFT toolstring combination and to prospective testing intervals, advanced petrophysical wireline logging suit ran first. Porous reservoirs were identified from density, neutron and nuclear magnetic resonance evaluation. Saturation evaluated through dielectric and induction-based resistivity logging. In fracture-vug type reservoir, the main inflow of formation fluid into the well is provided from fractures, so it was very important to allocate conductive fractures to plan test intervals for WFT accordingly. based on imagers evaluation, fractures and faults were visualized; using Stoneley's wave conductive fractures, not clogged with drilling mud solids were identified; borehole acoustic reflection survey was used to segregate large fractures that propagated in the reservoir; During WFT logging, a total of 23 intervals were tested, for 8 of which reservoir fluid inflow was achieved, in all others, mainly with low porosity or single non-conductive fracture, the inflow was not achieved or was insignificant. According to the results of WFT testing, the nature of saturation for clastic-carbonate sediments of Vendian age was determined. Inflow of formation fluid (oil and water) from Riphean fractured reservoirs was achieved from 6 intervals, with identified fractures according to described above advanced logging suit. In addition, pressure transient analysis was performed, to measure the formation pressure, define pressure gradient curves and assess the fluids contact level with high confidence, for the first time for this field.


Author(s):  
M.A. Tugarova

The article considers the secondary transformations of carbonate rocks of oil and gas complexes, which are of fundamental importance in the formation of reservoir properties. For the first time, a schematic diagram, illustrating the regularities of secondary processes in carbonate reservoirs and their relationship with the physico-chemical conditions of the stratosphere is proposed.


2021 ◽  
Author(s):  
Christos Filis ◽  
Emmanuel Skourtsos ◽  
Nikolaos Karalemas ◽  
Vasilios Giannopoulos ◽  
Ioannis Giannopoulos ◽  
...  

<p>The most characteristic feature of carbonate rocks is that they are prone to dissolution due to the meteoric water circulation which is enriched in CO<sub>2</sub>. One of the factors influencing this phenomenon is the existence of discontinuities within the mass of carbonate rocks. The Diros Vlychada show cave, on the peninsula of Mani in Peloponnese, Greece, has developed in marbles that belong to the Plattenkalk geotectonic unit. Most of the cave is flooded with water and its level changes depending on the external weather conditions and variations in sea level. The deformation of the marbles is represented by tectonic structures formed during the Lower Miocene metamorphism and their subsequent exhumation. The final uplift stage took place during the Pliocene-Quaternary and is still active. Five joints systems were distinguished:</p><p>A NW-SE joint system which is subdivided into a subsystem with low-angle dips, mainly towards to the NW, related to the main foliation of the marbles and a second subsystem characterized by stretching joints of the same strike (elongated joints), which have high-angle dips, also towards the NW. The latter system intersects the former but is confined between marble bedding and does not extend to more than three beds (the bedding is defined by the first subsystem).</p><p>A NW-SE striking joint system characterized by stretching joints with high-angle dips, which intersects diagonally the two previous. This system extends between more than three marble beds.</p><p>Two systems show E-W and N-S strike with the first one much better expressed. Those joints have developed diagonally to the previous ones. These are mainly shear joints that intersect the first system and are propagated within many marble beds.</p><p>The chambers of the cave have been developed along NW-SE and E-W directions. The first one is identified with the joint system that has been developed transversely to the strike of the marble foliation and the second in parallel with the main system of the shear joints. It is interesting that the bays forming the coastline of the Mani peninsula, have developed in an E-W direction, which coincides with both one of the growth directions of the cave and one of the joints systems, which correspond to shear joints developed during the folding of the marbles. Stalactites and stalagmites grow in a NE-SW direction that is identical to the elongated joints which form the system that is parallel to the foliation strike. Groundwater flow along these branches may be slower as these branches appear to be restricted between marble bedding.</p>


Author(s):  
L. G. Vakulenko ◽  
◽  
O. D. Nikolenko ◽  
D. A. Novikov ◽  
P. A. Yan ◽  
...  

A comprehensive study of the composition of sand and silt deposits of the Yu1 horizon of the Vasyuganskaya Formation upper part of the Verkh-Tarskoye oil field has been carried out. Associations of authigenic minerals have been determined in their cement, among which the calcite is the most widespread. According to petrographic parameters, three generations of calcite have been identified for which detailed isotopicgeochemical and ultramicroscopic studies were carried out for the first time. Wide and multi directional changes in the isotopic composition of carbon and oxygen and in the chemical composition of carbonate minerals were recorded, they indicate significant variations in the conditions of diagenesis and catagenesis, primarily temperature, and different sources of CO2. Significant variations in the isotopic composition of formation waters and its relationship with the isotopic composition of carbonates have been established. Thus, a narrow interval of close δ13C values was revealed, amounting to –10.5 to –9.1 ‰ in the formation waters of group II, and from –10.7 to –9.1 ‰ in calcites of the third generation. The source of CO2 in this system should be considered a carbon dioxide, which is formed in the process of metamorphism of carbonate rocks of the Paleozoic age.


2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
Xu Kong ◽  
Xueyuan Qi ◽  
Wentian Mi ◽  
Xiaoxin Dong

We report zircon U–Pb ages and Lu-Hf isotopic data from two sample of the retrograded eclogite in the Chicheng area. Two groups of the metamorphic zircons from the Chicheng retrograded eclogite were identified: group one shows characteristics of depletion in LREE and flat in HREE curves and exhibit no significant Eu anomaly, and this may imply that they may form under eclogite facies metamorphic condition; group two is rich in HREE and shows slight negative Eu anomaly indicated that they may form under amphibolite facies metamorphic condition. Zircon Lu-Hf isotopic of εHf from the Chicheng eclogite has larger span range from 6.0 to 18.0, which suggests that the magma of the eclogite protolith may be mixed with partial crustal components. The peak eclogite facies metamorphism of Chicheng eclogite may occur at 348.5–344.2 Ma and its retrograde metamorphism of amphibolite fancies may occur at ca. 325.0 Ma. The Hongqiyingzi Complex may experience multistage metamorphic events mainly including Late Archean (2494–2448 Ma), Late Paleoproterozoic (1900–1734 Ma, peak age = 1824.6 Ma), and Phanerozoic (495–234 Ma, peak age = 323.7 Ma). Thus, the metamorphic event (348.5–325 Ma) of the Chicheng eclogite is in accordance with the Phanerozoic metamorphic event of the Hongqiyingzi Complex. The eclogite facies metamorphic age of the eclogite is in accordance with the metamorphism (granulite facies or amphibolite facies) of its surrounding rocks, which implied that the tectonic subduction and exhumation of the retrograded eclogite may cause the regional metamorphism of garnet biotite plagioclase gneiss.


2013 ◽  
Vol 50 (12) ◽  
pp. 1165-1177
Author(s):  
Natalie J. Pietrzak-Renaud

The base of the Proterozoic Negaunee Iron Formation is exposed in the open pit at Tilden Mine, Marquette, Michigan. Juxtaposed against the Archean-aged Palmer Gneiss, it is bounded by the regional-scale Southern Shear Zone and cut by two sets of dykes: an older chloritic and schistose set and a younger 1.1 Ga Keweenawan set. Tilden Mine is dominated by a 100 m scale plunging northwest-anticline and is cut by a growth fault locally termed the Tower Hill Fault that intersects the Southern Shear Zone. The base of the exposed iron formation is composed of three lithofacies, including lower clastics that grade into the overlying banded iron formation that in turn grades upward into granular iron formation. This succession is capped by chloritic metadiabases locally termed the Summit Hill Sill and Pillar Intrusive. Petrographic and mineral chemical investigations document primary or early diagenetic hematite, siderite and possibly ferri-hydrite, metamorphic and related hydrothermal magnetite, chlorite, late martite overgrowing earlier magnetite and growth of specularite. All three lithofacies are cut by brittle fractures and late quartz veins. Brittle fractures are coated with chlorite, carbonate minerals, fluor-apatite, and sparse Cu-sulphides. These lithofacies document initial clastic sedimentation of strained detrital quartz into a subsiding fault trough. Over time, as subsidence slowed or sea level fluctuated, clastic deposition competed with quiescent chemical sedimentation, leading to deposition of the banded iron formation facies. As a stable shelf platform emerged, the granular iron formation facies was deposited via wave reworking of hardgrounds. Subsequent diagenesis initiated dissolution of carbonate and chert and promoted diagenetic replacement of primary iron minerals and chert. Regional metamorphism during Penokean orogeny at 1875–1835 Ma produced a suite of secondary metamorphic and related hydrothermal minerals. Metamorphism and hydrothermal flux related to the 1750 Ma development of the Republic Metamorphic Node overprinted the iron formation at Tilden to greenschist facies and infilled brittle fractures with a unique mineral assemblage. This unique mineral assemblage exhibits some striking similarities to Mn, Au, and Cu-sulphides documented at Champion Mine, west of Tilden, and proximal to the core of the Republic Node.


Minerals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 560
Author(s):  
Evgeny Galuskin ◽  
Irina Galuskina ◽  
Yevgeny Vapnik ◽  
Mikhail Murashko

In the last 15 years, zeolite-like mayenite, Ca12Al14O33, has attracted significant attention in material science for its variety of potential applications and for its simple composition. Hydrogen plays a key role in processes of electride material synthesis from pristine mayenite: {Ca12Al14O32}2+(O2) → {Ca12Al14O32}2+(e−)2. A presence of molecular hydrogen in synthetic mayenite was not confirmed by the direct methods. Spectroscopy investigations of mayenite group mineral fluorkyuygenite, with empirical formula (Ca12.09Na0.03)∑12.12(Al13.67Si0.12Fe3+0.07Ti4+0.01)∑12.87O31.96 [F2.02Cl0.02(H2O)3.22(H2S)0.15□0.59]∑6.00, show the presence of an unusual band at 4038 cm−1, registered for the first time and related to molecular hydrogen, apart from usual bands responding to vibrations of mayenite framework. The band at 4038 cm−1 corresponding to stretching vibrations of H2 is at lower frequencies in comparison with positions of analogous bands of gaseous H2 (4156 cm−1) and H2 adsorbed at active cation sites of zeolites (4050–4100 cm−1). This points out relatively strong linking of molecular hydrogen with the fluorkyuygenite framework. An appearance of H2 in the fluorkyuyginite with ideal formula Ca12Al14O32[(H2O)4F2], which formed after fluormayenite, Ca12Al14O32[□4F2], is connected with its genesis. Fluorkyuygenite was detected in gehlenite fragments within brecciaed pyrometamorphic rock (Hatrurim Basin, Negev Desert, Israel), which contains reduced mineral assemblage of the Fe-P-C system (native iron, schreibersite, barringerite, murashkoite, and cohenite). The origin of phosphide-bearing associations is connected with the effect of highly reduced gases on earlier formed pyrometamorphic rocks.


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