Method for the determination of sorption isotherms of materials demonstrated through soil samples

2011 ◽  
Vol 2 (2) ◽  
pp. 117-121 ◽  
Author(s):  
Á. Lakatos
Keyword(s):  
Moisture Content ◽  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Soil Samples ◽  
Point Of View ◽  
Hysteresis Phenomenon ◽  
Simple Method ◽  
Sorption Behaviour ◽  
Fundamental Research ◽  
Solid Bodies

Abstract Proper understanding of sorption behaviour of the materials is important from the point of view of fundamental research and technology as well for applied building technology. In this paper a simple method is presented for measuring water sorption capability of solid bodies. Moisture sorption and desorption measurements were carried out on soil samples by using climatic chamber. After drying the samples in a Venticell 111 type drying equipment they were treated with a Climacell 111 type climate chamber, where the relative humidity (RH) was varied from 40 to 83% at 22°C for different times (40, 80, 120 and 240 minutes). The samples reached the equilibrium moisture content after 120 minutes for sorption. The desorption isotherm measurements were carried out at 22°C for 80 minutes of exposure at constant RH. At this point hysteresis phenomenon was observed. Besides the moisture content figures the time evolution of the damping process is also presented in this paper.

scholarly journals Moisture Sorption Behaviour and Mould Ecology of Trade Garri Sold in South Eastern Nigeria

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Tochukwu Samuel ◽  
J. Obeta Ugwuanyi
Keyword(s):  
Moisture Content ◽  
Water Activity ◽  
Central Africa ◽  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Fungal Species ◽  
Temperature Dependent ◽  
Sorption Behaviour ◽  
Moisture Sorption Isotherms ◽  
West And Central Africa

Garri is a creamy white or yellow starchy grit produced by roasting to gelatinization and dryness of peeled, washed, mashed, and fermented dewatered cassava roots. It is the most important product of cassava in West and Central Africa. Mean moisture content of yellow and white garri was 11.11% and 10.81% within 24 hrs of sampling from the market, increasing to 17.27% and 16.14%, respectively, following 3 months of storage at room temperature. The water activity of samples varied from initial 0.587 to 0.934 following storage. Moisture sorption isotherms, determined by static gravimetric techniques at 20° and 30°C, showed temperature dependent BET Sigmoidal type II behaviour typical of carbohydrate rich foods but modulated very slightly by the content of palm oil. Equilibrium moisture content decreased with increase in temperature at constant water activity. A total of 10 fungal species belonging to the generaMucor,Penicillium,Cephalosporium,Aspergillus,Scopulariopsis,Rhizopus, and Paecilomyceswere identified, with range increasing with water activity of samples.

scholarly journals Modelling the moisture sorption isotherms of Roselle (Hibiscus sabdariffa L.) in the temperature range of 5–35 °C

2013 ◽  
Vol 61 (6) ◽  
pp. 1769-1777 ◽  
Author(s):  
Jitka Langová ◽  
Donludee Jaisut ◽  
Ratiya Thuwapanichayanan ◽  
Charotorn Phowong ◽  
Jiří Štencl ◽  
...  
Keyword(s):  
Moisture Content ◽  
Water Sorption ◽  
Structural Changes ◽  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Ambient Air ◽  
Point Of View ◽  
Hibiscus Sabdariffa ◽  
Adsorption And Desorption ◽  
Moisture Sorption Isotherms

Water sorption tests of Roselle (Hibiscus sabdariffa L.) carried out under laboratory conditions are presented together with mathematical analyses of the moisture sorption isotherms (MSI’s). Moisture equilibrium data for adsorption and desorption of water from Roselle powder were investigated at near ambient air temperatures in the range of 5 and 35 °C and water activity (Aw) ranging from 0.11 to 0.97. The manometric method has been used for water sorption tests. Models for MSI’s are exponential equations. Coefficients of determination are 0.998 and 0.996 (for adsorption and desorption at 5 °C, respectively), 0.998 and 0.999 (for adsorption and desorption at 20 °C, respectively), and 0.998 and 0.999 (for adsorption and desorption at 35 °C, respectively). The equilibrium moisture content (EMC) of Roselle samples increased with an increase of Aw at a constant temperature both for adsorption and desorption. Adsorption curve equates to desorption curve at higher temperatures of tests carried out. Critical values of EMC of samples tested corresponding to the Aw equal to 0.6 were between 13.401% moisture content wet basis (MC w.b.) and 15.934% MC (w.b.) for moisture adsorption and desorption, respectively. These values are useful for storing conditions optimisation from point of view microorganisms grow and structural changes analyses. Crystal structure changes were observed during adsorption and desorption in the microscope, too. It was found out glass transition in dependence on the water content of samples tested.

scholarly journals Influence of chemical composition and environmental conditions on the textural properties of dried fruit bars

2011 ◽  
Vol 29 (No. 5) ◽  
pp. 539-547 ◽  
Author(s):  
S. Ozilgen
Keyword(s):  
Moisture Content ◽  
Water Activity ◽  
Gravimetric Method ◽  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Textural Properties ◽  
Real Data ◽  
Sorption Behaviour ◽  
High Sugar ◽  
Dried Fruit

The influences of the composition, environmental humidity, and temperature on the stability of dried fruit bars during storage were investigated. Sultana bars were chosen to represent similar types of fruit bars. The moisture sorption isotherms and textural stability of sultana bars with and without glucose and maltodextrin additives were determined at 20°C and 40°C using the standard static gravimetric method. The shape of all of the isotherms was found to be typical of high sugar foods and could be explained by four different models. Additives and storage temperatures affected the monolayer moisture content, equilibrium moisture content, and the textural stability of the sultana bars during storage at the same water activity. The relationship between the loss of stiffness and water activity had a sigmoid shape and was explained by Fermi’s equation. This paper fills an important gap with that which does not exist in a large number of sorption behaviour publications available in the literature. It presents real data explaining the true mechanism of textural change during storage with both water activity and glass transition theories for high sugar fruit pastes. The information obtained from this study may help the food producers, who make high sugar containing dried fruit products, to create better textural and sensory properties, and may also help to predict the storage stability and packaging requirements.

scholarly journals Moisture sorption isotherms and isosteric heat sorption of habanero pepper (Capsicum chínense) dehydrated powder

2018 ◽  
Author(s):  
Mario Luna-Flores ◽  
Mariana Gisela Peña-Juarez ◽  
Angélica Mara Bello-Ramirez ◽  
Javier Telis-Romero ◽  
Guadalupe Luna-Solano
Keyword(s):  
Moisture Content ◽  
Water Activity ◽  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Isosteric Heat ◽  
Convective Drying ◽  
Hysteresis Phenomenon ◽  
Dynamic Vapor Sorption ◽  
Habanero Pepper ◽  
Moisture Sorption Isotherms

Moisture sorption isotherms of the habanero pepper powder were determined using the Dynamic Vapor Sorption (DVS) method at 20, 25, 35, 45 and 55 °C in a range of water activity from 0.10 to 0.90 at which the processes of drying, packing and storage of habanero pepper are developed. The sorption capacity decreased with increasing temperature at a given water activity and the sorption isotherms showed a sigmoid form (Type II). The hysteresis phenomenon was observed in the sorption isotherms at all temperatures studied and it was more pronounced at temperatures high. The experimental sorption curves were fitting to the GAB, BET and Oswin models. It was concluded that the models that best describe the adsorption and desorption data for habanero pepper dehydrated powder were the GAB and Oswin models.  The isosteric heat of water sorption was calculated with the moisture content data in equilibrium. The desorption isotherms present a higher isosteric heat in relation to the adsorption isotherms. In both, the isosteric heat decreased as the moisture content increased. Keywords: Habanero pepper dehydrated powder; Convective drying; Moisture sorption isotherms; Mathematic models

scholarly journals Moisture sorption isotherms of castor beans. Part 1: Mathematical modeling and hysteresis

2016 ◽  
Vol 20 (8) ◽  
pp. 751-756 ◽  
Author(s):  
André L. D. Goneli ◽  
Paulo C. Corrêa ◽  
Gabriel H. H. de Oliveira ◽  
Osvaldo Resende ◽  
Munir Mauad
Keyword(s):  
Moisture Content ◽  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Environmental Condition ◽  
Adsorption And Desorption ◽  
Moisture Sorption Isotherms ◽  
Different Temperatures ◽  
The Difference ◽  
The Stability ◽  
And Storage

ABSTRACT Sorption isotherms are of great importance in post-harvest procedures, especially for predicting drying and storage, which help to establish the final moisture content of the product under certain environmental condition. Hysteresis is a phenomenon that occurs due to the difference between adsorption and desorption curves, which aids the evaluation of chemical and microbiological deteriorations, indicating the stability of stored products. Moisture sorption isotherms of castor beans were determined and hysteresis was analyzed. Static gravimetric technique at different temperatures (25, 35, 45 and 55 ± 1 °C) was used. Saturated salt solutions in the range of 37-87% ± 2% were utilized to create the required controlled relative humidity environment. Equilibrium moisture content data were correlated by different mathematical models and the Modified Halsey model presented good adjustment for the data, according to statistical procedures. Hysteresis between adsorption and desorption isotherms is present over the range of 0.2-0.9 of water activity, regardless of the temperature. This phenomenon decreases with temperature increase.

Sorption isotherms and moisture sorption hysteresis of intermediate moisture content banana

2008 ◽  
Vol 86 (3) ◽  
pp. 342-348 ◽  
Author(s):  
Zhengyong Yan ◽  
Maria J. Sousa-Gallagher ◽  
Fernanda A.R. Oliveira
Keyword(s):  
Moisture Content ◽  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Sorption Hysteresis

A hysteresis model suitable for numerical simulation of moisture content in wood

Holzforschung ◽  
2007 ◽  
Vol 61 (2) ◽  
pp. 175-181 ◽  
Author(s):  
Henrik Lund Frandsen ◽  
Staffan Svensson ◽  
Lars Damkilde
Keyword(s):  
Relative Humidity ◽  
Moisture Content ◽  
Sorption Isotherms ◽  
Ambient Air ◽  
Domain Model ◽  
Hysteresis Phenomenon ◽  
Hysteresis Model ◽  
Worst Case ◽  
Different Temperatures ◽  
History Of

Abstract The equilibrium moisture content in wood depends not only on the current relative humidity in ambient air, but also on the history of relative humidity variations. This hysteresis dependence of sorption in wood implies that in the worst case the moisture content for a given relative humidity may deviate by 30–35%. While researchers seem to have reached a general agreement on the hypothesis for the sorption hysteresis phenomenon, only a few models describing the phenomenon are available. Current models such as the independent domain model have numerical deficiencies and drawbacks. This paper presents a new hysteresis model, which mathematically resolves in closed-form expressions, with the current relative humidity and moisture content as the only input parameters. Furthermore, the model has the advantage of being applicable to different sorption isotherms, i.e., different species and different temperatures. These features make the model relatively easy to implement into a numerical method such as the finite element method.

Equilibrium Moisture Content Models for Lafun

2008 ◽  
Vol 4 (2) ◽  
Author(s):  
Olusegun J Oyelade
Keyword(s):  
Moisture Content ◽  
Equilibrium Moisture Content ◽  
Adsorption Isotherms ◽  
Gravimetric Method ◽  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Keeping Quality ◽  
Moisture Sorption Isotherms ◽  
Process Operation ◽  
The Relationship

Insights into the relationship between the air relative humidity (water activity (aw)) and equilibrium moisture content of food materials is essential to maintain good keeping quality and optimize process operation. The adsorption isotherms for cassava flour (lafun) were investigated with the static gravimetric method. Concentrated acid (H2SO4) solutions were used to vary the micro-climate in the study and presented in an easy-to-use template-like format over the range of temperature (27- 40oC) and aw (0.10-0.80) usually experienced in the tropical environment. The experimental data were compared with five widely recommended models in the literature for food sorption isotherms (GAB, modified GAB, modified Oswin, modified Henderson & modified Chung-Pfost). The moisture sorption isotherms were sigmoidal in shape and were influenced by temperature. The modified Oswin model was found to be most adequate whilst the modified GAB appears not suitable to model the adsorption isotherms for lafun.

scholarly journals Drying kinetics and determination of water sorption isotherms of corn

2017 ◽  
Vol 15 (2) ◽  
Author(s):  
J Roy ◽  
MA Alim ◽  
MN Islam
Keyword(s):  
Moisture Content ◽  
Sorption Isotherm ◽  
Water Sorption ◽  
Sorption Isotherms ◽  
Moisture Sorption ◽  
Drying Kinetics ◽  
Drying Time ◽  
Moisture Sorption Isotherm ◽  
Water Sorption Isotherm ◽  
Monolayer Moisture

The study was carried out for the purpose of determining the drying kinetics as well as moisture sorption isotherm of hybrid-81 corn. Corn at about 31% moisture content (wb) was dried in a forced convective hot air cabinet dryer at different drying conditions, such as variable air dry bulb temperature (40°C, 50°C and 60°C) and loading density (3.56 kg/m2, 7.12 kg/m2, and 10.68 kg/m2) as well as in shining sun at different layers (3.56 kg/m2, 7.12 kg/m2, and 10.68 kg/m2). The water sorption isotherm of the dried corn was developed using vacuum desiccators, which contained saturated salt solutions in the range of 11-93% RHs. The mono-layer moisture content calculated by the Brunauer–Emmett–Teller (BET) model (6.76 g/100 g solid) was lesser than that calculated by the Guggenheim–Anderson–De Boer (GAB) model (10.53 g/100 g solid). The energy constants were 10.45 and 4.64 as per BET and GAB equation, respectively. Both models gave suitable fits for corn. The activation energy (Ea) for diffusion of water was found to be 11.09 kcal/gm-mole for corn. Furthermore, it was noticed that, with the increase of corn layer, the drying rate decreased in case of both sun and mechanical drying. However, higher loading density resulted in efficient drying, at least up to 10.7 kg/m2. It was shown that the drying time to obtain stability was the lowest for moisture content (12.08 %) corresponding to aw of 0.65 in case of BET or GAB monolayer moisture content. This finding could be helpful in predicting the storage life of corn.J. Bangladesh Agril. Univ. 15(2): 309-317, December 2017

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