Effect of grain shape on environmental embrittlement in Ni3Al tested at elevated temperatures

1989 ◽  
Vol 4 (2) ◽  
pp. 294-299 ◽  
Author(s):  
C. T. Liu ◽  
B. F. Oliver

This paper describes the effect of grain shape on environmental embrittlement in boron-doped Ni3Al (24 at. % Al). The alloy showed severe embrittlement when tested at 600 and 760 °C in air. The embrittlement can be alleviated by control of grain shape, and the material with a columnar-grained structure produced by directional levitation zone remelting shows good tensile ductilities when tested in oxidizing environments. The columnar-grained structure with vertical grain boundaries minimizes the normal stress and consequently suppresses nucleation and propagation of cracks along the boundaries.

1990 ◽  
Vol 213 ◽  
Author(s):  
C. T. Liu ◽  
E. P. George

ABSTRACTThe room-temperature tensile properties of FeAl aluminides were determined as functionsof aluminum concentration (35 to 43 at. % Al), test environment, and surface (oil) coating. The two lower aluminum alloys containing 35 and 36.5% Al are prone to severe environmental embrittlement, while the two higher aluminum alloys with 40 and 43% Al are much less sensitive to change in test environment and surface coating. The reason for the different behavior is that the grain boundaries are intrinsically weak in the higher aluminum alloys, and these weak boundaries dominate the low ductility and brittle fracture behavior of the 40 and 43% Al alloys. When boron is added to the 40% Al alloy as a grain-boundary strengthener, the environmental effect becomes prominent. In this case, the tensile ductility of the boron-doped alloy, just like that of the lower aluminum alloys, can be dramatically improved by control of test environment (e.g. dry oxygen vs air). Strong segregation of boron to the grain boundaries, with a segregation factor of 43, was revealed by Auger analyses.


1988 ◽  
Vol 133 ◽  
Author(s):  
M. Takeyama ◽  
C. T. Liu

ABSTRACTThe ductility of preoxidized Ni3Al (Ni-23Al-0.5Hf-0.2B, at.%) specimens with various grain sizes (17∼193 μm) was evaluated by means of tensile tests at 600 and 760°C in vacuum. It was found that the preoxidation does not affect the ductility of the finest-grained material at either temperature, whereas it causes severe embrittlement in the largest-grained material, especially at 760°C. A continuous, thin Al-rich oxide layer, which forms on the fine-grained samples, protects the underlying alloy from oxygen penetration, preventing any loss of ductility, whereas the nickel-rich oxide which forms on the large-grained samples allows oxygen to penetrate along grain boundaries, causing severe embrittlement. The grain boundaries act as short-circuit paths for rapid diffusion of aluminum atoms from the bulk to the surfaces, and this is responsible for the difference in oxidation behavior between fine- and large-grained materials. The embrittlement of large-grained samples can be eliminated through control of oxide formation on Ni3Al surfaces.


1994 ◽  
Vol 364 ◽  
Author(s):  
D. A. Muller ◽  
S. Subramanian ◽  
S. L. Sass ◽  
J. Silcox ◽  
P. E. Batson

AbstractOne of the fundamental questions concerning Ni3Al is why doping with boron improves the room temperature ductility of the polycrystalline material. Boron is thought to prevent environmental embrittlement and increase the cohesive strength of grain boundaries since it changes the fracture mode from intergranular to transgranular. This change in cohesive energy must be reflected in the bonding changes at the grain boundary which can be probed using spatially resolved electron energy loss spectroscopy (EELS). We have examined grain boundaries in both undoped and boron doped Ni0.76Al0.24 using EELS, EDX and ADF imaging in a UHV STEM. Ni-enrichment is seen in a 0.5–1 nm wide region at large angle grain boundaries, both in the absence and presence of B. EELS shows that B segregation can vary along the interface. The Ni L2, 3 core edge fine structure which is sensitive to the filling of the Ni d-band, shows only the boron rich regions of the grain boundary to have a bonding similar to that of the bulk material. These results demonstrate that boron segregation increases the cohesive energy and hence improves the fracture resistance of the grain boundary, by making the bonding at boundaries similar to that in the bulk. The measured changes in d band filling may also affect the local solubility of hydrogen.


1993 ◽  
Vol 319 ◽  
Author(s):  
Patricia E. Johnson ◽  
W. Gourdin ◽  
A. Gonis ◽  
N. Kioussis ◽  
M. Vaudin

AbstractTo provide a sensitive measurement of the effect of boron segregation on the strength and ductility of Ni3A1 grain boundaries, bicrystal tensile tests were performed on small specimens of boron doped Ni76A124 cut from extremely large-grained boules. Five specimens with the same “random” or low-symmetry grain boundary (disorientations measured by means of backscattered Kikuchi patterns) and two specimens with a second random grain boundary were tested in quenched and slow-cooled conditions. Duplicate tests performed in a low (7 ppm) water-vapor environment showed that the fracture mode and the stress and strain at fracture are altered by environmental embrittlement at individual, partially strengthened grain boundaries.


2003 ◽  
Vol 764 ◽  
Author(s):  
Hiroyuki Togawa ◽  
Hideki Ichinose

AbstractAtomic resolution high-voltage transmission electron microscopy and electron energy loss spectroscopy were performed on grain boundaries of boron-doped diamond, cooperated with the ab-initio calculation. Segregated boron in the {112}∑3 boundary was caught by the EELS spectra. The change in atomic structure of the segregated boundary was successfully observed from the image by ARHVTEM. Based on the ARHVTEM image, a segregted structure model was proposed.


Author(s):  
V. Nengovhela ◽  
B. Linol ◽  
L. Bezuidenhout ◽  
T. Dhansay ◽  
T Muedi ◽  
...  

Abstract Contact metamorphism along widespread dolerite sills and dykes, emplaced at 182 to 183 Ma through the sedimentary host rocks of the Karoo Basin, triggered devolatilization of carbon-rich shales of the Lower Ecca Group. Hornfel samples collected from drill cores that intersect dolerite sills were analyzed for mineral phase equilibria, chemistry and porosity to characterize thermal aureoles at various distances from sill intrusions. Andalusite-chiastolite and cordierite porphyroblasts with biotite and muscovite occur within 10 to 20 m of many intrusive contacts. These metamorphic minerals crystallized when host shales attained maximum temperatures ranging between 450 and 600°C. Scanning electron microscopy imaging confirms that the hornfels are compact and that their metamorphic minerals limit porosity along grain boundaries. In few cases intra-mineral porosity occurs within individual crystals such as calcite, andalusite and cordierite. Disequilibrium metamorphic textures such as irregular grain boundaries, and inclusions in andalusite and cordierite reveal that the elevated temperatures were too short-lived to accomplish complete (re)crystallization. Thermal modeling results are consistent with the observed metamorphic mineral assemblages. Gas leakage calculations along a 7 m and a 47 m thick dolerite sill that intrude toward the top of the Whitehill Formation suggest that methane volumes ranging between 8 to 15 Tcf were generated during the sill emplacement. Methane was likely released into the atmosphere through hydrothermal vent complexes that are well preserved in the western Karoo Basin. If such loss was widespread across the entire basin, the implications for paleo-climate change and preserved shale gas reserves in the Karoo Basin of South Africa would be significant.


2020 ◽  
Vol 2020 (01) ◽  
pp. 86-97
Author(s):  
M. V. Remez ◽  
◽  
Yu. M. Podrezov ◽  
V. I. Danylenko ◽  
M. I. Danylenko ◽  
...  

The temperature, structural, and rate sensitivity of the plasticity characteristics in γ-tita¬nium aluminides with different Al contents, doped with β-phase stabilization elements, are studied. Particular attention is paid to dislocation mechanisms that control the brittle-plastic transition. The main role of grain boundaries in the formation of plasticity characteristics is demonstrated. At low temperatures, the grain boundaries stop propagation of brittle transgranular cracks and confine the development of the plastic zone beyond the boundaries of an individual grain, creating the prerequisites for fracture in the microdeformation level. At elevated temperatures, the boundaries contribute to the formation of dislocations pile-up in the plastic zone with a stress concentration required to set off the Frank-Reed sources and the displacement of the plastic zone beyond the boundaries of an individual grain, changing its configuration and stress distribution and inhibiting the propagation of cracks. Acceleration of rela¬xation processes in the vicinity of the crack’s tip creates the prerequisites for the development of macrodeformation. Local relaxation processes at the crack’s tip contribute to high speed sensitivity of the plasticity characteristics. This effect has important practical consequences, since there is a temperature region near the upper working temperature of γ-TiAl alloys, where the stress value remains high (yield strength σ02 ~700 MPa and ultimate stress σul ~ 1200 MPa at bending tests) regardless of the strain rate, while deformation sharply increases at low speeds. As a result, it is possible to achieve a combination of high strength and ductility during creep tests. In samples tested by tension with low speed (10-5 s-1) the neck formation take a place. Deformation occurs by the dislocation-twinning mechanisms. At small deformations (7%) a twinning mechanism is preferable. Concentration of dislocations sharply increases at large deformations (32%) with formation of dislocation clusters. Stress relaxation on the boundary between γ-phase twins and α2-lamella, occurs by macroscopic shift on α2-lamella. Keywords: γ-titanium-aluminides, structure, strength, plasticity, brittle-ductile transition, temperature and rate sensitivity.


2014 ◽  
Vol 783-786 ◽  
pp. 1634-1639
Author(s):  
Dmitri A. Molodov ◽  
Jann Erik Brandenburg ◽  
Luis Antonio Barrales-Mora ◽  
Günter Gottstein

The faceting and migration behavior of low angle <100> grain boundaries in high purity aluminum bicrystals was investigated. In-situ technique based on orientation contrast imaging was applied. In contrast to the pure tilt boundaries, which remained straight/flat and immobile during annealing at elevated temperatures, mixed tilt-twist boundaries readily assumed a curved shape and steadily moved under the capillary force. Computational analysis revealed that this behavior is due to the inclinational anisotropy of grain boundary energy, which in turn depends on boundary geometry – the energy of pure tilt low angle <100> boundaries is anisotropic, whereas that of mixed tilt-twist boundaries isotropic with respect to boundary inclination.


1986 ◽  
Vol 81 ◽  
Author(s):  
C. T. Liu

AbstractThis paper provides a comprehensive review of the recent work on tensile ductility and fracture behavior of Ni3AI alloys tested at ambient and elevated temperatures. Polycrystalline Ni3Al is intrinsically brittle along grain boundaries, and the brittleness has been attributed to the large difference in valency, electronegativity, and atom size between nickel and aluminum atoms. Alloying with B, Mn, Fe, and Be significantly increases the ductility and reduces the propensity for intergranular fracture in Ni3 Al alloys. Boron is found to be most effective in improving room-temperature ductility of Ni3Al with <24.5 at. % Al.The tensile ductility of Ni3Al alloys depends strongly on test environments at elevated temperatures, with much lower ductilities observed in air than in vacuum. The loss in ductility is accompanied by a change in fracture mode from transgranular to intergranular. This embrittlement is due to a dynamic effect involving simultaneously high localized stress, elevated temperature, and gaseous oxygen. The embrittlement can be alleviated by control of grain shape or alloying with chromium additions. All the results are discussed in terms of localized stress concentration and grain-boundary cohesive strength.


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