Effect Of Moisture On The Physical Properties Of Polyimide Films

1991 ◽  
Vol 227 ◽  
Author(s):  
Rajeevi Subramanian ◽  
Michael T. Pottiger ◽  
Jacqueline H. Morris ◽  
Joseph P. Curilla

ABSTRACTMoisture absorption and its effect on electrical properties were measured for several polyimides. A Quartz Crystal Microbalance (QCM) was used to investigate the moisture absorption in BPDA/PPD, PMDA/ODA, and BTDA//ODA/MPD polyimides. The steady-state moisture uptake in polyimides as a function of relative humidity (RH) was determined by exposing film samples to successively higher RH values ranging from 10 to 85% at 25°C. The isothermal moisture absorption as a function of percent RH was found to be nearly linear for all of the polyimides studied. The effect of moisture on the electrical properties of a BPDA/PPD polyimide was also investigated. The relative dielectric constant at 25 °C was found to be a linear function of the moisture absorbed.

1989 ◽  
Vol 154 ◽  
Author(s):  
Denice D. Denton ◽  
Hartono Pranjoto

AbstractPolyimide is used extensively in a variety of integrated circuit packaging applications. It is a good dielectric material with excellent planarizing capabilities, but like most polymers, it absorbs moisture. This hygroscopic behavior can lead to reliability problems in integrated circuit packages. The effects of variations in process history on moisture uptake are examined using gravimetric measurement techniques. In particular, the effects of cure schedule and exposure to high temperature/high humidity environments on steady state moisture uptake are reported. Steady state moisture uptake is shown to be a decreasing function of cure temperature. Moreover, the steady state moisture uptake in polyimide is greater after the samples have been “aged” in a high temperature and humidity ambient. Electrical measurements are used to examine the effects of cure temperature on diffusion kinetics of moisture in polyimide. The diffusion coefficient decreases with increasing cure temperature.


2007 ◽  
Vol 280-283 ◽  
pp. 289-292 ◽  
Author(s):  
Wen Bin Su ◽  
Jin Feng Wang ◽  
Hong Cun Chen ◽  
Guo Zhong Zang ◽  
Peng Qi ◽  
...  

The nonlinear electrical properties of TiO2-based varistor doped with 0.25mol% Ta2O5 and different contents of Sc2O3 were investigated. It was found that the TiO2 varistor ceramic doped with 0.10mol% Sc2O3 exhibited an optimal nonlinear coefficient of 7.8, a breakdown electrical field of 16.0V/mm, and relative dielectric constant of 1.27 × 105 (measured at 1 kHz). In order to analyze the effect of Sc2O3 on TiO2 varistors, studies were made on the capacitance versus voltage characteristics. A Schottky-type barrier, which is assumed as the origin of varistor behavior, was inferred from the C-V measurement. The barrier height and donor concentration were obtained as 0.41eV and 1.21 × 1026cm-3, respectively, for sample doped with 0.10mol% Sc2O3. Analogized to the ZnO varistors, the formation mechanism of Schottky-type barrier was discussed in this paper by the theory of defect in crystal lattice.


2011 ◽  
Vol 687 ◽  
pp. 380-384
Author(s):  
Jun Xia Wang ◽  
Xu Lan Zhen ◽  
Shi Yuan Yang ◽  
Jin Wang ◽  
Ke Tang

The effect of WO3 additions on the sintering ability and electrical properties of Pb(Zr0.95Ti0.05)O3 ferroelectric ceramics (PZT 95/5) was investigated. Pure and W-doped PZT 95/5 ceramics were prepared by the usual ceramic technique from raw oxides. The bulk density, microstructure, electrical properties of ceramics as a function of WO3 content were characterized. The results showed that the WO3 addition was benefit for the sintering densification of PZT, and the ceramics with 2.0 mol% WO3 addition exhibited the maximum value for the density (7.8 g/cm3) at a sintering temperature of 1250 °C. Moreover, piezoelectric constant (d33), relative dielectric constant (εr), dielectric loss (tanδ) and ferroelectric hysteresis loop of PZT 95/5 ceramics at the sintering temperature of 1250 °C all altered regularly with the change of WO3 doping level, whose optimum values were all obtained by doping 2.0 mol% WO3. The best values obtained for these parameters were: d33 = 65 pC/N, εr =314, tanδ = 0.028, Pr = 24.80 µC/cm2 and Ec = 1890 V/mm, respectively. These results show that tungsten doped Pb(Zr0.95Ti0.05)O3 ferroelectric ceramics can be hopefully used for the pulsed power devices.


2014 ◽  
Vol 114 ◽  
pp. 12-16 ◽  
Author(s):  
Yi-Lung Cheng ◽  
Ka-Wai Leon ◽  
Jun-Fu Huang ◽  
Wei-Yuan Chang ◽  
Yu-Min Chang ◽  
...  

Author(s):  
Nishanthi Sunthrasakaran ◽  
Nor Akmal Mohd Jamail ◽  
Rahisham Abd. Rahman ◽  
Md Nor Ramdon Bin Baharom ◽  
Qamarul Ezani Kamarudin ◽  
...  

<span>Almost all research on natural fibre reinforced composite has focused on the mechanical properties of the composite. Drawing on the important factors that effect the end product of composite, this paper reviews electrical properties of hybrid biocomposite when fibre content and surface treatment is varied. The compilation of dielectric constant, dissipation factor, loss factor and moisture absorption reported by researchers has been presented in this paper. The intrinsic characteristic of natural fibre which is hydrophilic is the main drawback that affects the electrical properties of the composite. Alkaline treatment on natural fibre has proven to overcome the hydrophilic characteristic and improves the adhesion between matrix and fibre. Besides that, the percentage of fibre content plays an important role in producing a good natural fibre reinforced hybrid composite. The moisture uptake, dielectric constant, dissipation factor and loss factor of the composite decreases with decreased fibre content.</span>


1990 ◽  
Vol 203 ◽  
Author(s):  
Hartono Pranjoto ◽  
Denice D. Denton

ABSTRACTElectronic packaging has been changing.rapidly to meet the often conflicting demands of higher speed and lower cost. In the multichip module (MCM), an array of semiconductor chips is mounted on a substrate and interconnected via a network of multilevel metal lines with polymer layers used as a dielectric between orthogonal metal signal paths. A potential reliability problem that must be investigated is the absorption of moisture by the dielectric in the MCM package. Moisture absorption may lead to long term problems such as loss of adhesion, corrosion of the metal interconnect and increased insulator conductivity.Bisbenzocyclobutene (BCB) is an insulating polymer that is being used in the MCM package as a dielectric material. In this work, the moisture uptake in BCB is investigated gravimetrically using a Cahn-1000 microbalance with a resolution of I pgram. The BCB films are spincoated onto silicon substrates and cured yielding film thickness ranging from 7 to 20µm. The moisture uptake of the BCB film is monitored in situ and non destructively to reveal the performance of the film as used in an integrated circuit environment. The moisture uptake of the films was monitored at different ambient relative humidity (RIH) values between 20% and 80% at 23°C. The transient behavior of the moisture absorption in BCB films has been characterized. Moisture uptake in BCB films increases as the relative humidity is increased, and reaches a maximum of less than 0.2% by weight at 80% RH. By comparison, this moisture uptake is significantly lower than that of fully cured PMDA-ODA polyimide, which is about 2.5% by weight under similar conditions. The transient data show that the equilibration time for a 22.8 µ.m film is approximately 220 seconds, yielding a diffusion coefficient of about 4.5µm2/s.


2003 ◽  
Vol 782 ◽  
Author(s):  
Alireza Modafe ◽  
Nima Ghalichechian ◽  
Benjamin Kleber ◽  
Reza Ghodssi

ABSTRACTElectrical properties and thickness of insulating dielectric films directly affect electrical energy loss and electrical breakdown limit in electric micromachines. A thick, low-k film exhibits low parasitic capacitive effects that help with the reduction of electrical energy loss. The electrical performance can be deteriorated due to degradation of the electrical properties of the insulating dielectric material caused by process, device structure, and moisture. In this paper, we introduce the application of CYCLOTENE, a spin-on, low-k, BCB-based polymer in electric micromachines as insulating layer and interlevel dielectric. A novel approach using interdigitated capacitors for electrical characterization of CYCLOTENE and the effect of moisture absorption is introduced in this paper. The dielectric constant of CYCLOTENE is extracted from two steps of capacitance measurements, giving an average value of 2.49 with a standard deviation of 1.5 %. The dielectric constant increases by 1.2 % after a humidity stress of 85 %RH at 85 °C. The measured I-V characteristics of CYCLOTENE show a dependency of the breakdown strength and leakage current on the geometrical dimensions of the device under test. A breakdown strength of 225 V/μm for 2 μm finger spacing and 320 V/μm for 3 μm finger spacing, and a leakage current of a few to tens of pA are measured. The I-V characteristics degrades drastically after a humidity stress of 85 %RH at 85 °C, showing a breakdown strength of 100 V/μm for 2 μm finger spacing and 180 V/μm for 3 μm finger spacing. Based on the results of this study, it is expected that the electrical efficiency of an electric micromachine is improved using BCB-based polymers with negligible dependency on moisture absorption. On the other hand, the maximum performance that depends on the maximum operating voltage is adversely affected by the degradation of the breakdown voltage after moisture absorption.


2010 ◽  
Vol 105-106 ◽  
pp. 324-328 ◽  
Author(s):  
Ji Kang Yan ◽  
Guo You Gan ◽  
Jing Hong Du ◽  
Jia Lin Sun

The effects of sintering temperature on microstructure, micro-composition, barrier structure and electrical properties of TiO2 varistors ceramics were investigated. The microstructures and chemical compositions of grains in TiO2 ceramics were measured by SEM and EDS. Based on the thermo electronic emission theory, Grain boundaries barrier structure was calculated by analyzing electrical properties of samples. The sample sintered at 1350°C exhibits better microstructure and properties. The grains size of the TiO2 sample sintered at 1350°C is about 15m, and other electrical properties are as follows: solid solubility of donor doping Nb5+ cation solute in TiO2 grains of 1.49mol%, barriers height of 0.28ev, barriers width of 48nm, varistor voltages of 5.25V/mm, non-linear coefficient of 4.2 and relative dielectric constant of 1.1×104.


2011 ◽  
Vol 341-342 ◽  
pp. 94-97
Author(s):  
Tian Guo Wang ◽  
Qun Qin ◽  
Wen Jun Zhang

The influence of TiO2 nano powder on the electrical properties and microstructure of TiO2 ceramics was studied. The results showed that nano additive reduces the size of TiO2 grain. The results also showed that the breakdown voltage and nonlinear constant of the samples were improved and the dielectric constant was reduced by doping nano-titania. An optimal composition dopant with 6 mol% nano-titania exhibited a low breakdown voltage of 11.3 V/mm, a nonlinear coefficient of 5.5, an ultrahigh relative dielectric constant of 7.11×104 and relatively low loss of 0.28.


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